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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Vanadium As a Potential Membrane Material for Carbon Capture: Effects of Minor Flue Gas Species

Vanadium and its surface oxides were studied as a potential nitrogen-selective membrane material for indirect carbon capture from coal or natural gas power plants. The effects of minor flue gas components (SO 2 , NO, NO 2 , H 2 O, and O 2 ) on vanadium at 500–600 °C were investigated by thermochemical exposure in combination with X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and in situ X-ray diffraction (XRD). The results showed that SO 2 , NO, and NO 2 are unlikely to have adsorbed on the surface vanadium oxides at 600 °C after exposure for up to 10 h, although NO and NO 2 may have exhibited oxidizing effects (e.g., exposure to 250 ppmv NO/N 2 resulted in an 2.4 times increase in surface V 2 O 5 compared to exposure to just N 2 ). We hypothesize that decomposition of surface vanadium oxides and diffusion of surface oxygen into the metal bulk are both important mechanisms affecting the composition and morphology of the vanadium membrane. Additionally, the results and hypothesis suggest that the carbon capture performance of the vanadium membrane can potentially be strengthened by material and process improvements such as alloying, operating temperature reduction, and flue gas treatment.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Hydrogen Spillover Is Regulating Minority Rh 1 Active Sites on TiO 2 in Room-Temperature Ethylene Hydrogenation

The complicated dynamics of active sites on single-atom catalysts under reducing conditions limits their applications in hydrogenation reactions and mechanistic understanding. Herein, we report that on Rh 1 /TiO 2 , *H spillover during room-temperature ethylene hydrogenation hydroxylates and reduces TiO 2 , enhancing the intrinsic activity of Rh 1 by 9-fold. Spectroscopic and kinetic evidence suggests that the spillover of *H is suppressed by their facile reaction with C 2 H 4 , most of the spilled *H are nonreactive spectators, and >99% turnovers occur on a small subset (<20%) of exposed “active Rh 1 ”. Steady-state kinetics indicates competitive adsorption between H and C 2 H 4 , H 2 dissociation is the rate-determining step, and the apparent activation barrier (E a,app ) of the reaction is ~48 kJ/mol. The evolution of Rh 1 under H 2 was further tracked by spectroscopic and microscopic techniques at elevated temperatures. At 200 °C, more Rh 1 are exposed, but these Rh 1 are at least 5-fold less active than that of the “active Rh 1 ”. At 300 °C, Rh clusters derived from Rh 1 become the main active sites, shifting E a,app to 62 kJ/mol, characteristic of Rh nanoparticles. At ≥400 °C, larger and more active Rh particles in the strong metal–support interaction state are created. In conclusion, this work revealed the unexpected regulation effects of *H spillover on M 1 active sites under ambient conditions, differentiated the minority active M 1 sites, and demonstrated how the stability of M 1 under reducing atmospheres affects hydrogenation catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Contrasting long-term temperature trends reveal minor changes in projected potential evapotranspiration in the US Midwest

Abstract Warming generally leads to increased evaporative demand, altering the amount of water needed for growing crops. For the Midwest, some studies have suggested that reaching yield targets by 2050 will not be possible without additional precipitation or large expansion of irrigation. Here, we show that this claim is not supported by the historical summer climate trends, which indicate that the warming of daily average temperatures is largely driven by increases in minimum temperatures, while maximum temperatures have decreased. This has translated into a net decrease in vapor pressure deficit (VPD) and potential evapotranspiration (PET). With the increasing rainfall, this suggests that crop water deficits have likely become less frequent in the region despite the warming climate. By projecting these trends into 2050 and ancillary use of a crop model, we estimate minor changes in PET that would have minimal effects on corn yields (<6%) under persistence of these trends.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2013

Minority-spin t 2 g states and the degree of spin polarization in ferromagnetic metallic La 2-2x Sr 1+2x Mn 2 O 7 (x = 0.38)

In this paper, a half-metal is a material with conductive electrons of one spin orientation. This type of substance has been extensively searched for due to the fascinating physics as well as the potential applications for spintronics. Ferromagnetic manganites are considered to be good candidates, though there is no conclusive evidence for this notion. Here we show that the ferromagnet La 2–2x Sr 1+2x Mn 2 O 7 (x = 0.38) possesses minority-spin states, challenging whether any of the manganites may be true half-metals. However, when electron transport properties are taken into account on the basis of the electronic band structure, we found that the La 2–2x Sr 1+2x Mn 2 O 7 (x = 0.38) can essentially behave like a complete half metal.

36 MATERIALS SCIENCE↗
DOE OSTI2012

X-ray diffraction study of nanocrystalline and amorphous structure within major and minor ampullate dragline spider silks

Synchrotron X-ray micro-diffraction experiments were carried out on Nephila clavipes (NC) and Argiope aurantia (AA) major (MA) and minor ampullate (MiA) fibers that make up dragline spider silk. The diffraction patterns show a semi-crystalline structure with {beta}-poly(L-alanine) nanocrystallites embedded in a partially oriented amorphous matrix. A superlattice reflection 'S' diffraction ring is observed, which corresponds to a crystalline component larger in size and is poorly oriented, when compared to the {beta}-poly(L-alanine) nanocrystallites that are commonly observed in dragline spider silks. Crystallite size, crystallinity and orientation about the fiber axis have been determined from the wide-angle X-ray diffraction (WAXD) patterns. In both NC and AA, the MiA silks are found to be more highly crystalline, when compared with the corresponding MA silks. Detailed analysis on the amorphous matrix shows considerable differences in the degree of order of the oriented amorphous component between the different silks studied and may play a crucial role in determining the mechanical properties of the silks.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Plutonium and minor actinides utilization in Thorium molten salt reactor

FUJI-12 reactor is one of MSR systems that proposed by Japan. The original FUJI-12 design considers Th/{sup 233}U or Th/Pu as main fuel. In accordance with the currently suggestion to stay away from the separation of Pu and minor actinides (MA), in this study we evaluated the utilization of Pu and MA in FUJI-12. The reactor grade Pu was employed in the present study as a small effort of supporting THORIMS-NES scenario. The result shows that the reactor can achieve its criticality with the Pu and MA composition in the fuel of 5.96% or more.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2013

Evaluation of minority and majority spin band energies of ferromagnetic GdN thin film using optical absorption spectroscopy

Temperature dependent optical Tauc plots of AlN/GdN/AlN heterostructures have showed two optically induced transitions, and those optical transitions could be attributed to the minority and majority spin band energy. In contrast, temperature dependent magnetization measurements of GdN thin film provide direct evidence of spin ordering below 39 K, and which is also evidenced by Arrott plots.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Minor ion heating in spectra of linearly and circularly polarized Alfvén waves: Thermal and non-thermal motions associated with perpendicular heating

Minor ion (such as He{sup 2+}) heating via nonresonant interaction with spectra of linearly and circularly polarized Alfvén waves (LPAWs and CPAWs hereafter) is studied. The obtained analytic solutions are in good agreement with the simulation results, indicating that newborn ions are heated by low-frequency Alfvén waves with finite amplitude in low-beta plasmas such as the solar corona. The analytic solutions also reproduce the preferential heating of heavy ions in the solar wind. In the presence of parallel propagating Alfvén waves, turbulence-induced particle motion is clearly observed in the wave (magnetic field) polarized directions. After the waves diminish, the newborn ions are heated, which is caused by the phase difference (randomization) between ions due to their different parallel thermal motions. The heating is dominant in the direction perpendicular to the ambient magnetic field. The perpendicular heating, η=(T{sub i⊥}{sup R}−T{sub i0⊥}{sup R})/T{sub i0⊥}{sup R} (where T{sub i0⊥}{sup R} and T{sub i⊥}{sup R} are the perpendicular temperature of species i before and after genuine heating, respectively), in the spectrum of CPAWs is a factor of two stronger than that of LPAWs. Moreover, we also study the effect of field-aligned differential flow speed of species i relative to H{sup +}, δv{sub ip}=(v{sub i}−v{sub p})·B/|B| (where v{sub i} and v{sub p} denote vector velocities of the H{sup +} and species i, respectively), on the perpendicular heating. It reveals that large drift speed, v{sub d}=δv{sub ip}, has an effect on reducing the efficiency of perpendicular heating, which is consistent with observations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Generation-recombination and trap-assisted tunneling in long wavelength infrared minority electron unipolar photodetectors based on InAs/GaSb superlattice

A long wavelength infrared minority electron unipolar photodetector based on InAs/GaSb type-II superlattices is demonstrated. At 77 K, a dark current of 3 × 10{sup −5} A/cm{sup 2} and a differential resistance-area of 3700 Ω.cm{sup 2} are achieved at the turn-on bias, with a 50%-cutoff of 10.0 μm and a specific detectivity of 6.2 × 10{sup 11} Jones. The dark current is fitted as a function of bias and temperature using a model combining generation-recombination and trap-assisted tunneling. Good agreement was observed between the theory and the experimental dark current.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Influence of impurities on the transition from minority to mode conversion heating in ({sup 3}He)-H)- plasmas

Ion cyclotron resonance heating (ICRH) is one of the main auxiliary heating systems used in present-day tokamaks and is planned to be installed in ITER. In the initial full-field phase of ITER operating with hydrogen majority plasmas, fundamental resonance heating of helium-3 ions is one of a few ICRH schemes available. Past JET experiments with the carbon wall revealed a significant impact of impurities on the ICRH performance in ({sup 3}He)-H plasmas. A significant reduction of the helium-3 concentration, at which the transition from minority ion to mode conversion heating occurs, was found to be due to a high plasma contamination with carbon ions. In this paper we discuss the effect of Be and another impurity species present at JET after the installation of a new ITER-like wall on the transition helium-3 concentration in ({sup 3}He)-H plasmas. We suggest a potential method for controlling helium-3 level needed for a specific ICRH regime by puffing an extra helium-4 gas to the plasma.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Analysis on fuel breeding capability of FBR core region based on minor actinide recycling doping

Nuclear fuel breeding based on the capability of fuel conversion capability can be achieved by conversion ratio of some fertile materials into fissile materials during nuclear reaction processes such as main fissile materials of U-233, U-235, Pu-239 and Pu-241 and for fertile materials of Th-232, U-238, and Pu-240 as well as Pu-238. Minor actinide (MA) loading option which consists of neptunium, americium and curium will gives some additional contribution from converted MA into plutonium such as conversion Np-237 into Pu-238 and it's produced Pu-238 converts to Pu-239 via neutron capture. Increasing composition of Pu-238 can be used to produce fissile material of Pu-239 as additional contribution. Trans-uranium (TRU) fuel (Mixed fuel loading of MOX (U-Pu) and MA composition) and mixed oxide (MOX) fuel compositions are analyzed for comparative analysis in order to show the effect of MA to the plutonium productions in core in term of reactor criticality condition and fuel breeding capability. In the present study, neptunium (Np) nuclide is used as a representative of MAin trans-uranium (TRU) fuel composition as Np-MOX fuel type. It was loaded into the core region gives significant contribution to reduce the excess reactivity in comparing to mixed oxide (MOX) fuel and in the same time it contributes to increase nuclear fuel breeding capability of the reactor. Neptunium fuel loading scheme in FBR core region gives significant production of Pu-238 as fertile material to absorp neutrons for reducing excess reactivity and additional contribution for fuel breeding.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2015

Post-recombination early Universe cooling by translation–internal inter-conversion: The role of minor constituents

Little is known of the mechanism by which H and H{sub 2}, the principal constituents of the post-re-combination early Universe, cooled sufficiently to permit cluster formation, nucleosynthesis, and, eventually, the formation of structured objects. Radiative decay primarily cools the internal modes of H{sub 2}, as Δj = − 2 jumps accompany quadrupolar emission. This, however, would be a self-limiting mechanism. In this work, a translational energy cooling mechanism based on collision-induced, translation-to-internal mode conversion, is extended, following an earlier study [A. J. McCaffery and R. J. Marsh, J. Chem. Phys. 139, 234310 (2013)] of ensembles comprising H{sub 2} in a H atom bath gas. Here, the possible influence of minor species, such as HD, on this cooling mechanism is investigated. Results suggest that the influence of HD is small but not insignificant. Conversion is very rapid and an overall translation-to-internal energy conversion efficiency of some 5% could be expected. This finding may be of use in the further development of models of this complex phase of early Universe evolution. An unexpected finding in this study was that H{sub 2} + HD ensembles are capable of very rapid translation-to-internal conversion with efficiencies of >40% and relaxation rates that appear to be relatively slow. This may have potential as an energy storage mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Minority carrier lifetime and dark current measurements in mid-wavelength infrared InAs 0.91 Sb 0.09 alloy nBn photodetectors

Carrier lifetime and dark current measurements are reported for a mid-wavelength infrared InAs 0.91 Sb 0.09 alloy nBn photodetector. Minority carrier lifetimes are measured using a non-contact time-resolved microwave technique on unprocessed portions of the nBn wafer and the Auger recombination Bloch function parameter is determined to be |F 1 F 2 |=0.292. Moreover, the measured lifetimes are also used to calculate the expected diffusion dark current of the nBn devices and are compared with the experimental dark current measured in processed photodetector pixels from the same wafer. As a result, excellent agreement is found between the two, highlighting the important relationship between lifetimes and diffusion currents in nBn photodetectors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

Velocity space evolution of a minority energetic electron population undergoing the anomalous Doppler instability

The kinetic evolution in velocity space of a minority suprathermal electron population that is undergoing the anomalous Doppler instability (ADI) is investigated using the results from fully nonlinear numerical simulations that self-consistently evolve particles and fields in a plasma. Electron trajectories in phase space during different stages of the ADI are captured, and are analysed in relation to the characteristics of the excited electric fields and of the overall distribution of particles. For some electrons, trapping and mirroring effects are observed during the saturation phase. A relationship between the second order moments of the perpendicular electron distribution function and time is established, and is used to investigate the range of applicability of analytical approximations drawn from classical theory, that involve a quasilinear wave-driven diffusion operator.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Deep levels in as-grown and electron-irradiated n-type GaN studied by deep level transient spectroscopy and minority carrier transient spectroscopy

Development of high performance GaN-based devices is strongly dependent on the possibility to control and understand defects in material. Important information about deep level defects is obtained by deep level transient spectroscopy and minority carrier transient spectroscopy on as-grown and electron irradiated n-type bulk GaN with low threading dislocation density produced by halide vapor phase epitaxy. One hole trap labelled H1 (E{sub V} + 0.34 eV) has been detected on as-grown GaN sample. After 2 MeV electron irradiation, the concentration of H1 increases and at fluences higher than 5 × 10{sup 14 }cm{sup −2}, a second hole trap labelled H2 is observed. Simultaneously, the concentration of two electron traps, labelled T1 (E{sub C} – 0.12 eV) and T2 (E{sub C} – 0.23 eV), increases. By studying the increase of the defect concentration versus electron irradiation fluence, the introduction rate of T1 and T2 using 2 MeV- electrons was determined to be 7 × 10{sup −3 }cm{sup −1} and 0.9 cm{sup −1}, respectively. Due to the low introduction rate of T1, it is suggested that the defect is associated with a complex. The high introduction rate of trap H1 and T2 suggests that the defects are associated with primary intrinsic defects or complexes. Some deep levels previously observed in irradiated GaN layers with higher threading dislocation densities are not detected in present investigation. It is therefore suggested that the absent traps may be related to primary defects segregated around dislocations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗