Mineralization on the moon? Theoretical considerations of Apollo 16 'rusty rocks', sulfide replacement in 67016, and surface-correlated volatiles on lunar volcanic glass
Theoretical considerations of vapor-rock interactions in the lunar environment are a useful supplement to petrologic studies of mineralization or alteration in rocks from the moon. They also provide insights into the potential for the existence of more extensive mineralization on the moon than is found in the limited sample set. Discussed in this paper are the coexistence and textural association in 66095 of the phases lawrencite, troilite, schreibersite, iron metal, and sphalerite; the replacement of olivine in certain clasts of 67016 by troilite and enstatite; and the existence of Zn + S deposits on the surfaces of volcanic glass beads. Particular attention is given in each case to whether the observed mineralization implies that metals, as well as S, P, or Cl, have been mobilized in the vapor. Vapor species that might mobilize metals in the absence of H2O are considered. Most importantly, the suggestion is made that in the dry lunar environment carbonyl species may be important carriers of S and metals. The implications of this possibility are discussed.