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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Measurements of soot formation and hydroxyl concentration in near critical equivalence ratio premixed ethylene flame

The testing and development of existing global and detailed chemical kinetic models for soot formation requires measurements of soot and radical concentrations in flames. A clearer understanding of soot particle inception relies upon the evaluation and refinement of these models in comparison with such measurements. We present measurements of soot formation and hydroxyl (OH) concentration in sequences of flat premixed atmospheric-pressure C2H4/O2/N2 flames and 80-torr C2H4/O2 flames for a unique range of equivalence ratios bracketting the critical equivalence ratio (phi(sub c)) and extending to more heavily sooting conditions. Soot volume fraction and number density profiles are measured using a laser scattering-extinction apparatus capable of resolving a 0.1 percent absorption. Hydroxyl number density profiles are measured using laser-induced fluorescence (LIF) with broadband detection. Temperature profiles are obtained from Rayleigh scattering measurements. The relative volume fraction and number density profiles of the richer sooting flames exhibit the expected trends in soot formation. In near-phi(sub c) visibility sooting flames, particle scattering and extinction are not detected, but an LIF signal due to polycyclic aromatic hydrocarbons (PAH's) can be detected upon excitation with an argon-ion laser. A linear correlation between the argon-ion LIF and the soot volume fraction implies a common mechanistic source for the growth of PAH's and soot particles. The peak OH number density in both the atmospheric and 80-torr flames declines with increasing equivalence ratio, but the profile shape remains unchanged in the transition to sooting, implying that the primary reaction pathways for OH remain unchanged over this transition. Chemical kinetic modeling is demonstrated by comparing predictions using two current reaction mechanisms with the atmospheric flame data. The measured and predicted OH number density profiles show good agreement. The predicted benzene number density profiles correlate with the measured trends in soot formation, although anomalies in the benzene profiles for the richer and cooler sooting flames suggest a need for the inclusion of benzene oxidation reactions.

Inbody, Michael Andrew↗
NASA NTRS2004

Validation of Laser-Induced Fluorescent Photogrammetric Targets on Membrane Structures

The need for static and dynamic characterization of a new generation of inflatable space structures requires the advancement of classical metrology techniques. A new photogrammetric-based method for non-contact ranging and surface profiling has been developed at NASA Langley Research Center (LaRC) to support modal analyses and structural validation of this class of space structures. This full field measurement method, known as Laser-Induced Fluorescence (LIF) photogrammetry, has previously yielded promising experimental results. However, data indicating the achievable measurement precision had not been published. This paper provides experimental results that indicate the LIF-photogrammetry measurement precision for three different target types used on a reflective membrane structure. The target types were: (1) non-contact targets generated using LIF, (2) surface attached retro-reflective targets, and (3) surface attached diffuse targets. Results from both static and dynamic investigations are included.

Jones, Thomas W.↗
NASA NTRS2015

SRAG Measurements Performed During the Orion EFT-1 Mission

The Exploration Flight Test 1 (EFT-1) was the first flight of the Orion Multi-Purpose Crew Vehicle (MPCV). The flight was launched on December 5, 2014, by a Delta IV Heavy rocket and lasted 4.5 hours. The EFT-1 trajectory involved one low altitude orbit and one high altitude orbit with an apogee of almost 6000 km. As a result of this particular flight profile, the Orion MPCV passed through intense regions of trapped protons and electron belts. In support of the radiation measurements aboard the EFT-1, the Space Radiation Analysis Group (SRAG) provided a Battery-operated Independent Radiation Detector (BIRD) based on Timepix radiation monitoring technology similar to that employed by the ISS Radiation Environmental Monitors (REM). In addition, SRAG provided a suite of optically and thermally stimulated luminescence detectors, with 2 Radiation Area Monitor (RAM) units collocated with the BIRD instrument for comparison purposes, and 6 RAM units distributed at different shielding configurations within the Orion MPCV. A summary of the EFT-1 Radiation Area Monitors (RAM) mission dose results obtained from measurements performed in the Space Radiation Dosimetry Laboratory at the NASA Johnson Space Center will be presented. Each RAM included LiF:Mg,Ti (TLD-100), (6)LiF:Mg,Ti (TLD-600), (7)LiF:Mg,Ti (TLD-700), Al2O3:C (Luxel trademark), and CaF2:Tm (TLD-300). The RAM mission dose values will be compared with the BIRD instrument total mission dose. In addition, a similar comparison will be shown for the ISS environment by comparing the ISS RAM data with data from the six Timepix-based REM units deployed on ISS as part of the NASA REM Technology Demonstration.

Gaza, Ramona↗
NASA NTRS2015

Mineralogy and Astrobiology Detection Using Laser Remote Sensing Instrument

A multispectral instrument based on Raman, laser-induced fluorescence (LIF), laser-induced breakdown spectroscopy (LIBS), and a lidar system provides high-fidelity scientific investigations, scientific input, and science operation constraints in the context of planetary field campaigns with the Jupiter Europa Robotic Lander and Mars Sample Return mission opportunities. This instrument conducts scientific investigations analogous to investigations anticipated for missions to Mars and Jupiter's icy moons. This combined multispectral instrument is capable of performing Raman and fluorescence spectroscopy out to a >100 m target distance from the rover system and provides single-wavelength atmospheric profiling over long ranges (>20 km). In this article, we will reveal integrated remote Raman, LIF, and lidar technologies for use in robotic and lander-based planetary remote sensing applications. Discussions are focused on recently developed Raman, LIF, and lidar systems in addition to emphasizing surface water ice, surface and subsurface minerals, organics, biogenic, biomarker identification, atmospheric aerosols and clouds distributions, i.e., near-field atmospheric thin layers detection for next robotic-lander based instruments to measure all the above-mentioned parameters. OCIS codes: (120.0280) Remote sensing and sensors; (130.0250) Optoelectronics; (280.3640) Lidar; (300.2530) Fluorescence, laser-induced; (300.6450) Spectroscopy, Raman; (300.6365) Spectroscopy, laser induced breakdown

Abedin, M. Nurul↗
NASA NTRS2018

Optimization of the Magnetic Field Topology in the Hall Effect Rocket with Magnetic Shielding

NASA's Hall Effect Rocket with Magnetic Shielding (HERMeS) 12.5kW Technology Demonstration Unit-1 (TDU-1) has been the subject of extensive technology maturation in preparation for flight system development. The TDU-1 thruster implements a magnetically shielded field topology and has demonstrated the elimination of the discharge channel erosion. Extensive wear testing the TDU Hall thrusters has identified the thruster front pole covers as the next life limiting component. This effort aims to explore and investigate alternate magnetic field topologies to assess whether reductions in the front pole cover erosion can be attained while still maintaining very low erosion rates on the discharge channel walls. NASA GRC and JPL have begun a magnetic field topology characterization and optimization study by designing four candidate magnetic field topologies that reduce the effectiveness of the shielding along the discharge channel walls with the intent to also reduce the erosion rates along the pole covers. Three of the four candidate magnetic field topologies have been manufactured subjected to an extensive test campaign that includes performance, plume, and stability characterization. In Phase I of the testing campaign, the thruster's oscillation magnitude and Laser Induced fluorescence (LIF) measurements of the plasma plume were performed for the three candidate topologies. In Phase I, the thruster's oscillation magnitude and LIF measurements were performed for the three candidate topologies. Phase I test results found that the B1 configuration attained lower oscillation levels than B0. Additionally, LIF measurements along the discharge chamber centerline found that upstream retraction of the thruster's peak magnetic field does result in an upstream shift of the acceleration zone but the magnitude of the shift does not correspond one-to-one to the shift in the location of the peak radial magnetic field magnitude. Phase II test segment will include performing performance, stability, plume, and erosion measurements for the various candidate magnetic field topologies.

Kamhawi, Hani↗
NASA NTRS2024

Optimization of Mission Enabling Broadband Lyman Ultraviolet Series to Infrared Aluminum Lithium Fluoride Reflectors

The Habitable Worlds Observatory (HWO) concept NASA flagship mission aims extend the ultraviolet (UV) observation range and sensitivity capabilities of the Hubble Space Telescope (HST) with respective goals of reaching photons down to 100 nm and containing an ultraviolet multi-object spectrograph with sensitivity improved 30-100 times. Adding the sensitivity capabilities near the Lyman series spectral range of ~100-121.6 nm reduces the reliance of redshift for key diagnostic ion lines such as O VI (103.2 nm), and heavily ionized gases of Ne VIII (77.5 nm) and MgX (62.5 nm). Clean and unoxidized aluminum (Al) reflectors provide optimal efficiency over a broadband down to the extreme ultraviolet (EUV) wavelength of ~83 nm. To prevent oxidation and maintain high spectral efficiency down to ~100 nm, the Al reflector is conventionally overcoated with a thin lithium fluoride (LiF) layer. We investigate the optimization of the deposition of the Al+LiF coating material composition to attain high spectral efficiency broadband reflectors down to 100 nm and enable the scientific goals of HWO. Lithium hexafluoroaluminate (Li3AlF6) is investigated as a different composition form of LiF to overcoat Al. The spectral efficiency and durability of the reflectors is evaluated. We will demonstrate the use of Li3AlF6 as an overcoat to protect aluminum yields ultra-high efficiency at the Hydrogen Lyman-alpha (HLyα, 121.6 nm) line with experimental reflectance values peaking up to 99%.

optical coatings↗
NASA NTRS2024

Optimization of Mission Enabling Broadband Lyman Ultraviolet Series to Infrared Aluminum Lithium Fluoride Reflectors

The Habitable Worlds Observatory (HWO) concept NASA flagship mission aims extend the ultraviolet (UV) observation range and sensitivity capabilities of the Hubble Space Telescope (HST) with respective goals of reaching photons down to 100 nm and containing an ultraviolet multi-object spectrograph with sensitivity improved 30-100 times. Adding the sensitivity capabilities near the Lyman series spectral range of ~100-121.6 nm reduces the reliance of redshift for key diagnostic ion lines such as O VI (103.2 nm), and heavily ionized gases of Ne VIII (77.5 nm) and MgX (62.5 nm). Clean and unoxidized aluminum (Al) reflectors provide optimal efficiency over a broadband down to the extreme ultraviolet (EUV) wavelength of ~83 nm. To prevent oxidation and maintain high spectral efficiency down to ~100 nm, the Al reflector is conventionally overcoated with a thin lithium fluoride (LiF) layer. We investigate the optimization of the deposition of the Al+LiF coating material composition to attain high spectral efficiency broadband reflectors down to 100 nm and enable the scientific goals of HWO. Lithium hexafluoroaluminate (Li3AlF6) is investigated as a different composition form of LiF to overcoat Al. The spectral efficiency and durability of the reflectors is evaluated. We will demonstrate the use of Li3AlF6 as an overcoat to protect aluminum yields ultra-high efficiency at the Hydrogen Lyman-alpha (HLyα, 121.6 nm) line with experimental reflectance values peaking up to 99%.

optical coatings↗
NASA NTRSDate not supplied

Exposure of Highly Reflective Far-Ultraviolet Coatings to LEO Environment for TRL Advancement for the Habitable Worlds Observatory

Over the past several years, our team at the NASA Goddard Space Flight Center (GSFC), in collaboration with the Jet Propulsion Laboratory (JPL) and the Naval Research Laboratory (NRL), have developed several new protected Al coating technologies with improved Far-Ultraviolet (FUV) reflectance performance and more robust environmental stability. These include Al protected with lithium-based fluoride (LiF) coatings such as hot deposited LiF (eLiF), XeF 2 -passivated LiF coatings (XeLiF), Li 3 AlF 6 overcoats, AlF 3 (plasma passivated), and XeF 2 passivated MgF 2 coatings (XeMgF 2 ). However, despite these developments, relatively little experimental information exists regarding the long-term stability of these coatings after simultaneous exposure to the Low Earth Orbit (LEO) environment. To evaluate their environmental durability and advance their Technology Readiness Level (TRL), representative samples of these coating technologies, Al+XeLiF, Al+eLiF, Al+Li 3 AlF 6 , Al+AlF 3 , Al+XeMgF 2 , and bare Al as reference samples, were flown onboard the International Space Station (ISS) as part of the Materials International Space Station Experiment 20 (MISSE-20). The MISSE platform is operated by Aegis Aerospace for relatively long-duration (e.g. 6 months) external exposure experiments in a space environment. The coatings were deposited on ULE and Zerodur substrates, and witness samples deposited on the same coatings runs, but on glass slides were left on Earth as control. A subset of the flight samples were fitted with MgF 2 windows to reduce direct exposure to atomic oxygen (AO) and charged particles, and still let through UV and other types of radiation on these samples. After approximately 6 months of exposure in the forward-facing (RAM) direction, the samples were returned to Earth and characterized by performing FUV/NUV/VIS/NIR reflectance measurements to quantify degradation, spectroscopic ellipsometry to evaluate coating thickness and optical constants, atomic force microscopy (AFM) to quantify surface roughness evolution during the flight in the ISS. The MgF 2 protective windows were also analyzed through FUV transmission measurements. Comparison with the witness samples left on the ground and with the flown bare Al samples (with just the naturally occurring Al 2 O 3 layer) provided a quantitative assessment of coating thickness variations, optical performance degradation, and morphological changes induced by prolonged exposure to the LEO environment.

Far Ultraviolet (FUV)↗
DOE OSTI2025

Toward the Development of Molten Salt Reactor Diagnostics based on Resonantly Enhanced Laser Spectroscopy

One emerging concern within the safeguards community is how to best ensure compliance with nuclear security regulations within molten salt reactor (MSR) facilities. This problem is nontrivial as molten salts used for fuel or coolant are highly corrosive, chemically complex, and inherently require high operational temperatures. Laser spectroscopy methods such as laser-induced breakdown spectroscopy (LIBS) and laser-induced fluorescence (LIF) have previously been suggested for molten salt diagnostics due to their compatibility with liquid phase samples and potential for in-situ measurements [1]. In the former, the laser is used to ionize the sample, allowing for the characteristic light from electronic de-excitation as the resultant plasma cools to be used for material characterization. In the latter, a tunable light source is set be resonant with a specific transition, resulting in element specific excitation and the emission of fluorescence light. In our previous work [2], we demonstrated that LIF could be used for the detection of fission fragments such as Nd in solution through the separation of laser scatter and fluorescence within the time domain. Here, we present progress towards two alternate measurement schemes: LIF measurements based on spectroscopic discrimination of fluorescence emissions and resonant LIBS measurements that induce plasma using a light source set to the resonant frequency of a specific electronic transition. Both methods aim to exploit resonant excitation methods to enhance the emitted signal. The studies may provide routes for element-specific detection of constituents within complicated matrices and a means to better understand the chemical behavior of lanthanides and actinides relevant to MSRs.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗
DOE OSTI2022

Enhancing Cycling Stability and Capacity Retention of NMC811 Cathodes by Reengineering Interfaces via Electrochemical Fluorination

High-capacity cathodes (LiNi 0.8 Mn 0.1 Co 0.1 O 2 ) that can boost the energy density of lithium-ion batteries are promising candidates for vehicle electrification. However, several factors specific to high energy density materials entailing electrode reactions inhibit their application. Fluorination has shown a promising ability to combat the detrimental electrochemical performances of cathode materials, however, it remains difficult to achieve the desired functionality. In this work, a novel electrochemical fluorination (ECF) that demonstrates a promising electrochemical performance enhancement via stabilization of the cathode–electrolyte-interphase (CEI) by forming conformal LiF is proposed. Besides LiF surface layer formation, ECF reduces the degree of fluorination-induced Ni/Li disordering and enhances the layered structural stability as probed by X-ray diffraction. Because of the robust CEI, ECF-NMC811 cathodes deliver 203.0 mAh g -1 first discharge capacity at the current rate of C/10, with ≈98% capacity retention up to 100 cycles. Similarly, it delivers ≈180 mAh g -1 capacity at a 1 C rate with 86.4% capacity retention up to 200 cycles with average coulombic efficiency of > 99.5%. Comprehensive characterization with a multitude of probes reveals that ECF enhances the cycling stability of the electrode without altering bulk structure and morphology.

25 ENERGY STORAGE↗
DOE OSTI2021

Following O and OH in He/O 2 and He/H 2 O gas mixtures—from the gas phase through the liquid phase to modifications on a biological sample

Abstract Applied cold atmospheric plasma allows for the controlled delivery of reactive oxygen and nitrogen species tailored for specific applications. Through the manipulation of the plasma parameters, feed gases, and careful consideration of the environment surrounding the treatment target, selective chemistries that preferentially influence the target can be produced and delivered. To demonstrate this, the COST reference microscale atmospheric pressure plasma jet is used to study the generation and transport of O and ⋅ OH from the gas phase through the liquid to the biological model target cysteine. Relative and absolute species densities of ⋅ OH and O are measured in the gas phase through laser induced fluorescence (LIF) and two-photon absorption LIF respectively. The transport of these species is followed into the liquid phase by hydrogen peroxide quantification and visualized by a fluorescence assay. Modifications to the model biological sample cysteine exposed to ⋅ OH and H 2 O 2 dominated chemistry (He/H 2 O (0.25%)) and O dominated chemistry (He/O 2 (0.6%)) is measured by FTIR spectroscopy. The origin of these species that modify cysteine is considered through the use of heavy water (H 2 18 O) and mass spectrometry. It is found that the reaction pathways differ significantly for He/O 2 and He/H 2 O. Hydrogen peroxide is formed mainly in the liquid phase in the presence of a substrate for He/O 2 whereas for He/H 2 O it forms in the gas phase. The liquid chemistry resulting from the He/O 2 admixture mainly targets the sulfur moiety of cysteine for oxidation up to irreversible oxidation states, while He/H 2 O treatment leads preferentially to reversible oxidation products. The more O or OH/H 2 O 2 dominated chemistry produced by the two gas admixtures studied offers the possibility to select species for target modification.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1994

Measurement of the V-T Energy Transfer Rates of Highly Excited (sup 2)A(sub 1) NO(sub 2)

Production of electronic ground state NO(sub 2) from 248 nm photolysis of HNO(sub 3) was detected by laser induced fluorescence (LIF). A growth in the LIF signal was observed following the photolysis and has been interpreted as the relaxation of NO(sub 2) through the higher vibrational levels of the X state; an energy region where the probe laser photodissociates the NO(sub 2) instead of inducing fluorescence.

laser induced fluorescence (LIF)↗
NASA NTRSDate not supplied

A New Linear Polarizer Design for Application in the Far-Ultraviolet Spectral Range

New mission concepts that are under consideration by NASA (such as the Polstar MIDEX mission concept) call for the design and implementation of Far Ultraviolet (FUV) polarizer technologies that have not been developed yet. A team that includes members from the NASA Goddard Space Flight Center (GSFC), Arizona State University (ASU), and Woodruff Consulting, worked on the design and development of a polarizer design that may produce extinction ratios higher than have ever been reported before in the FUV spectral range (100-200 nm). This polarizer consists of transmitting linearly polarized light through a series of reflections from a combination of two silicon carbide (SiC) and two lithium fluoride (LiF) crystals positioned at angles of incidence (relative to surface normal) close to the LiF Brewster’s angle. The performance of this polarizer concept was fabricated and tested with an existing McPherson 225 Vacuum Ultraviolet (VUV) spectrometer located in the Optics Branch at NASA-GSFC. Initial testing has shown that in the FUV spectral range, this design can produce state-of-the-art extinction ratios at the Hydrogen Lyman-Alpha (Ly-α) wavelength of 121.6 nm. A polarizer with such a performance has never been reported and it signifies a breakthrough in FUV polarization technology. The levels of effectiveness paired with the design’s compact design allows for a new polarizer capability that would one day be implemented in a future spectropolarimetry space mission. In addition, this polarizer concept could potentially be used to characterize the optical properties of new mirror coatings that will be used in a future Habitable World Observatory (HWO) mission concept as proposed by the 2020 Decadal Survey.2

Far Ultraviolet (FUV), polarimetry, instrumentatio↗
NASA NTRSDate not supplied

Linear Polarizer Design for Application in the Far-Ultraviolet Spectral Range

New mission concepts that are under consideration by NASA (such as the Polstar MIDEX mission concept) call for the design and implementation of Far Ultraviolet (FUV) polarizer technologies that have not been developed yet. A team that includes members from the NASA Goddard Space Flight Center (GSFC), Arizona State University (ASU), and Woodruff Consulting, worked on the design and development of a polarizer design that may produce extinction ratios higher than have ever been reported before in the FUV spectral range (100-200 nm). This polarizer consists of transmitting linearly polarized light through a series of reflections from a combination of two silicon carbide (SiC) and two lithium fluoride (LiF) crystals positioned at angles of incidence (relative to surface normal) close to the LiF Brewster’s angle. The performance of this polarizer concept was fabricated and tested with an existing McPherson 225 Vacuum Ultraviolet (VUV) spectrometer located in the Optics Branch at NASA-GSFC. Initial testing has shown that in the FUV spectral range, this design can produce state-of-the-art extinction ratios at the Hydrogen Lyman-Alpha (Ly-α) wavelength of 121.6 nm. A polarizer with such a performance has never been reported and it signifies a breakthrough in FUV polarization technology. The levels of effectiveness paired with the design’s compact design allows for a new polarizer capability that would one day be implemented in a future spectropolarimetry space mission. In addition, this polarizer concept could potentially be used to characterize the optical properties of new mirror coatings that will be used in a future Habitable World Observatory (HWO) mission concept as proposed by the 2020 Decadal Survey.2

Far Ultraviolet (FUV), polarimetry, instrumentatio↗
NASA NTRSDate not supplied

Linear Polarizer Design for Application in the Far-Ultraviolet Spectral Range

New mission concepts that are under consideration by NASA call for the design and implementation of Far Ultraviolet (FUV) polarizer technologies that have not been developed yet. A team that includes members from the NASA Goddard Space Flight Center (GSFC), Arizona State University (ASU), and Woodruff Consulting, worked on the design and development of a polarizer design that produce very high extinction ratios in the FUV spectral range (100-200 nm). This polarizer consists of reflecting light through a series of mirrors from a combination of two silicon carbide (SiC) and two lithium fluoride (LiF) crystals positioned at angles of incidence (relative to surface normal) close to the average LiF Brewster’s angle in the FUV. The output is a highly linearly polarized beam. This polarizer concept was fabricated and tested in the existing McPherson 225 Vacuum Ultraviolet (VUV) spectrometer located in the Optics Branch at NASA-GSFC. Initial testing using a MgF2 crystal at the Brewster’s angle as an analyzer has shown that this design can produce state-of-the-art extinction ratios at the Hydrogen Lyman-Alpha (Ly-α) wavelength of 121.6 nm, and that the measured extinction ratio of the two crossed polarizers, ≈114, is mostly limited by the MgF2 analyzer. A polarizer with such a performance at this wavelength has never been reported and it signifies a breakthrough in FUV polarization technology. The levels of effectiveness paired with the polarizer’s compact design allows for a new polarizer capability that would one day be implemented in a future FUV spectropolarimetry space mission.

Far Ultraviolet (FUV)↗
NASA NTRSDate not supplied

Metrological and Spectral Characterization of the Aspera Flight Optics

Aspera is a NASA's Astrophysics Pioneers mission, led by the University of Arizona. The aim of this mission is to study the presence of hot gasses (T=10^5-10^6 K) in the circumgalactic medium (CGM) and how the flow of these gasses affects galactic formation. One key enabling technology in the Aspera optical system is the use of more efficient UV-reflective optical coatings particularly at around 103.2 nm where the O VI emission line is located . In order to meet radiometric effective area requirements, the Goddard Space Flight Center (GSFC) code 551 Optics Branch applied Al (aluminum) + eLiF (enhanced lithium fluoride) on these optics, where the Al+LiF is annealed at elevated temperature (~250˚C) after the deposition and thus providing an improved version of the Al+LiF used in FUSE . Furthermore, these optics are encapsulated with a thin film of atomic layer deposited MgF2 at the Jet Propulsion Laboratory for enhanced durability . The efficiency and durability of these coatings depends on the quality of the optical surface in terms of cleanliness and roughness. Roughness increases the scatter off the coating and reduces the specular reflectance, and surface contaminants can accommodate moisture and other contaminants, increase scattering, and are weak points in the coating that may affect adhesion and subsequently the longevity of these coatings. Extensive optical metrology is necessary to minimize and quantify the impact of surface roughness and contaminants on optical surfaces. In this proceeding we report the inspection procedure implemented for Aspera optics at GSFC, from initial receiving of the optics to post-coating. Inspection includes Atomic Force Microscopy (AFM), Scanning White Light Interferometry (SWILI), Dark Field Microscopy (DFM), Phase Shifting Interferometry (PSI), and Vacuum ultraviolet (VUV) spectroscopy. Combinations of these techniques are used to inspect flight optics at each of the following steps: i) as-received, pre-cleaning inspection, ii) pre-coating, post-cleaning inspection, and iii) post-coating inspection. The evolution of roughness and other surface inspections such as contaminants are compared between each step to quantify the effect each step has on the flight optics. The final far ultraviolet (FUV) spectral performance of witness samples coated with the flight optics are presented.

Far Ultraviolet (FUV)↗
DOE OSTI2024

Fluoro‐Ethylene‐Carbonate Plays a Double‐Edged Role on the Stability of Si Anode‐Based Rechargeable Batteries During Cycling and Calendar Aging

Abstract The energy storage density of Li‐ion batteries can be improved by replacing graphite anodes with high‐capacity Si‐based materials, though instabilities have limited their implementation. Performance degradation mechanisms that occur in Si anodes can be divided into cycling stability (capacity retention after repeated battery cycles) and calendar aging (shelf life). While cycling instabilities and improvement strategies have been researched intensively, there is little known about the underlying mechanisms that cause calendar aging. In this work, multiple electron microscope techniques are used to explore the mechanism that governs calendar aging from the sub‐nanometer‐to‐electrode scale. Plasma focused ion beam tomography is used to create 3D reconstructions of calendar aged electrodes and revealed the growth of a LiF‐rich layer at the interface between the copper current collector and the silicon material, which can lead to delamination and increased interfacial impendence. The LiF layer appeared to derive from the fluoro‐ethylene‐carbonate electrolyte additive, which is commonly used to improve cycling stability in Si‐based systems. The results reveal that additives necessary to improve cycling stability can cause performance degradation over the long‐term during calendar aging. The results show that high performing, stable systems require careful design to simultaneously mitigate both cycling and calendar aging instabilities.

25 ENERGY STORAGE↗
DOE OSTI2020

A Fluorination Method for Improving Cation-Disordered Rocksalt Cathode Performance

In Li-rich cation-disordered rocksalt oxide cathodes (DRX), partial fluorine substitution in the oxygen anion sublattice can increase the capacity contribution from transition-metal (TM) redox while reducing that from the less reversible oxygen redox. To date, limited fluorination substitution has been achieved by introducing LiF precursor during the solid-state synthesis. To take full advantage of the fluorination effect, however, a higher F content is desired. In the present study, the successful use of a fluorinated polymeric precursor is reported to increase the F solubility in DRX and the incorporation of F content up to 10–12.5 at% into the rocksalt lattice of a model Li-Mn-Nb-O (LMNO) system, largely exceeding the 7.5 at% limit achieved with LiF synthesis. Higher F content in the fluorinated-DRX (F-DRX) significantly improves electrochemical performance, with a reversible discharge capacity of ≈255 mAh g –1 achieved at 10 at% of F substitution. After 30 cycles, up to a 40% increase in capacity retention is achieved through the fluorination. Overall, the study demonstrates the feasibility of using a new and effective fluorination process to synthesize advanced DRX cathode materials.

25 ENERGY STORAGE↗