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At least 235 records · Page 13

The photophysics of monomeric bacteriochlorophylls c and d and their derivatives: properties of the triplet state and singlet oxygen photogeneration and quenching

Measurements of pigment triplet-triplet absorption, pigment phosphorescence and photosensitized singlet oxygen luminescence were carried out on solutions containing monomeric bacteriochlorophylls (Bchl) c and d, isolated from green photosynthetic bacteria, and their magnesium-free and farnesyl-free analogs. The energies of the pigment triplet states fell in the range 1.29-1.34 eV. The triplet lifetimes in aerobic solutions were 200-250 ns; they increased to 280 +/- 70 microseconds after nitrogen purging in liquid solutions and to 0.7-2.1 ms in a solid matrix at ambient or liquid nitrogen temperatures. Rate constants for quenching of the pigment triplet state by oxygen were (2.0-2.5) x 10(9) M-1 s-1, which is close to 1/9 of the rate constant for diffusion-controlled reactions. This quenching was accompanied by singlet oxygen formation. The quantum yields for the triplet state formation and singlet oxygen production were 55-75% in air-saturated solutions. Singlet oxygen quenching by ground-state pigment molecules was observed. Quenching was the most efficient for magnesium-containing pigments, kq = (0.31-1.2) x 10(9) M-1 s-1. It is caused mainly by a physical process of singlet oxygen (1O2) deactivation. Thus, Bchl c and d and their derivatives, as well as chlorophyll and Bchl a, combine a high efficiency of singlet oxygen production with the ability to protect photochemical and photobiological systems against damage by singlet oxygen.

NASA Discipline Number 52-30↗

Mechanisms of Oxide Formation in the Self-Reacting Friction Stir Weld Process

The initial objective of this study was to evaluate the effect of an extended delay time between preweld cleaning and the completion of a self-reacting friction stir welding (SRFSW) process on the resulting quality of various thickness panels of AA2219-T87. The current NASA standard specifies no more than a 48 hour delay between preweld cleaning and actual welding. The concern is whether increasing the cleaning delay time results in development of the residual oxide defect (ROD) in SRFSW. This concern emanates from the possibility of increased time correlating with increased oxide layer thickness on the faying surfaces. Oxide content on the faying surfaces has been reported to correlate with the occurrence of the ROD which reduces mechanical properties. When the SRFSW process was first adopted by the NASA Marshall Space Flight Center (MSFC), unexpected low tensile values that resulted were attributed to oxides within the weld that appeared to follow the former faying surface contours. Mitigation of the ROD was achieved through a combination of modifications to the processing parameters, tool designs, and incorporation of a weld seam offset. Two operations are involved in preweld cleaning: the first is removal of oil and grease, and the second is removal of surface oxides. In arc welding, improper cleaning of the faying surfaces of aluminum welded joints can increase the sensitivity toward development of defects. As the aluminum is locally melted, these contaminants contribute toward the development of porosity, inclusions, entrapped oxides, and other discontinuities which can degrade the strength of the weld joint. For weldment of large structures, the weld joint is typically cleaned, fit-up, and tack welded prior to the final full penetration welding pass. Because of the stringent joint fit-up requirements for mismatch and peaking for launch vehicle structures, the joint fit-up can sometimes contribute to lengthy delays between cleaning and tack welding, especially for circumferential weld joints on large diameter components. When the conventional friction stir welding (CFSW) process was introduced at the NASA MSFC, there was no procedure for cleaning prior to the solid-state joining process. As the process expanded to include SRFSW, preparation of the faying, crown, and root surfaces were implemented to overcome the ROD. Although the solid-state process is not expected to reach temperatures high enough for dissociation of the native oxide layer, concern remained regarding the redeposition of the native oxide layer within the stir zone. NASA has previously established the allowable time at 48 hours between preweld cleaning and a SRFSW process. The effect of potential 2 contamination resulting from an extended delay to 188 hours was subsequently evaluated for SRFSWs using tensile testing and metallographic imaging. Tensile specimens were tested at room temperature (RT), and at cryogenic conditions of liquid nitrogen (LN2) and liquid hydrogen. No detrimental effect on weld quality, as determined by weld strength, was reported for cleaning delays of 48, 120, 168, 240 or 288 hours. While no trends were established in this study, which extended the delay from 48 to 188 hours, there were a few outliers in terms of ultimate tensile strength (UTS). According to M. Fisher's 2014 Boeing Company Memo no. EYBF-MAF-14-029, all outliers were above the minimum acceptance criteria, but out of family with respect to the average values. As the robustness and reliability of any process ultimately depends on the average values as well as the outliers, an understanding of the cause of these outliers will ultimately improve the process. This report examines those outliers and their possible causes.

Schneider, J. A.↗

Validation of Heat Transfer Correlations in Line Chill-Down Tests of Cryogenic Fluid in SINDA/FLUINT

Line chill-down is an important process in cryogenic tank propellant management, storage, and usage Complex flow dynamics during these processes: boiling heat transfer (film, transition, and nucleate) Understanding boiling phenomena can lead to efficient line chill-down systems that use less propellant, propellant stored, reducing cost for space missions Line Chill-down heat transfer was modelled using SINDA/FLUINT version 5.8 (SF) Multiple chill-down tests were modelled using: heat transfer correlations readily available in SF using HTN/HTC TIES heat transfer empiricisms developed by the University of Florida (UF) based on a series of liquid nitrogen chill-down tests using SF HTU TIES Chill-down tests modelled: liquid nitrogen tests conducted by the University of Florida horizontal flow, upward flow, and downward flow (Reynolds Numbers ranging 850-231,000)liquid hydrogen tests conducted by NASA Glenn Research Center vertical upward flow (Reynolds Number range of 18,400 - 433,000)The flow rate was measured far downstream of the test section, near the system exit. Where to set the flow rate? SF was highly sensitive, and sometime unstable, setting the test flow rate downstream (the outlet) of the test section model and setting the test pressure upstream (the inlet) of the test section model higher flow rate oscillations at the entrance of the model's test section SF was more stable setting the test flow rate upstream (than the downstream flow rate set case)test pressure was used as an inlet (SF plenum) to set the thermodynamic state (temperature and quality) coming into the system setting the appropriate downstream pressure was the unknown. The pressure drops predicted by SF for the downstream set flow rate boundary condition were much smaller than test section measured pressure drops. The multiphase pressure drop correlations used internally in SF may need to be adjusted. Models with an upstream flow rate set assumed a pressure drop that was small

cryogenic modeling↗

Two-Phase Convection Heat Transfer Correlations for Liquid Hydrogen Pipe Chilldown

Recently, heat transfer correlations based on liquid nitrogen (LN2) and liquid hydrogen (LH2) pipe quenching data were developed to improve the predictive accuracy of lumped node codes like SINDA/FLUINT and the Generalized Fluid System Simulation Program (GFSSP). After implementing these correlations into both programs, updated model runs showed strong improvement in LN2 pipe chilldown modeling but only modest improvement in LH2 modeling. Due to large differences in thermal and fluid properties between the two fluids, results indicated a need to develop a separate set of LH2-only correlations to improve the accuracy of the simulations. This paper presents a new set of two-phase convection heat transfer correlations based on LH2 pipe quenching data. A correlation to predict the bulk vapor temperature was developed after analysis showed that high amounts of thermal nonequilibrium of the liquid and vapor phases occurred during film boiling of LH2. Implemented in a numerical model, the new correlations achieve a mean absolute error of 19.5 K in the predicted wall temperature when compared to recent LH2 pipe chilldown data, an improvement of 40% over recent GFSSP predictions. This correlation set can be implemented in simulations of the transient LH2 chilldown process. Such simulations are useful for predicting the chilldown time and boil-off mass of LH2 for applications such as the transfer of LH2 from a ground storage tank to the rocket vehicle propellant tank, or through a rocket engine feedline during engine startup.

critical heat flux↗

Universal Two-Phase Convection Heat Transfer Correlations for Cryogenic Pipe Chilldown

This paper presents a set of universal two-phase convection heat transfer correlations for modeling boiling heat transfer during pipe chilldown fit over the widest available range of cryogenic fluids and thermodynamic conditions. The correlations improve upon prior correlations that were developed separately for liquid nitrogen (LN2) and liquid hydrogen (LH2) pipe quenching datasets. The new correlations include equations to calculate the single-phase vapor heat transfer, film boiling heat transfer, transition boiling heat transfer, nucleate boiling heat transfer, single-phase liquid heat transfer, bulk vapor temperature during high quality film boiling, Leidenfrost temperature, critical heat flux, critical heat flux temperature, and the onset of nucleate boiling temperature. The correlations were validated against LH2, LN2, liquid methane, liquid oxygen, and liquid argon pipe quenching datasets. The eight datasets cover the following parameter ranges: pipe lengths of 0.1 to 6.5m; outer pipe diameters of 12.7 to 25.4 mm; pipe wall thicknesses from 0.51 to 1.64 mm; flow directions of upward, downward, and horizontal; gravity levels of 1g and 0g±0.01g. A numerical model assumes homogeneous mixing between the vapor and liquid and implicitly integrates the coupled energy equations for the pipe and fluid, as well as continuity for the fluid. The model was used to estimate the equilibrium quality and fluid mass accumulation along the pipes during chilldown from estimates of the fluid-pipe heat transfer extracted from temperature measurements. The correlations can be implemented in lumped parameter codes such as SINDA/FLUINT and the Generalized Fluid System Simulation Program (GFSSP) to improve the accuracy of chilldown time and chilldown boiloff mass predictions. Such predictions are useful for designing ground or in-space cryogenic liquid transfer systems.

Universal Correlations↗

Passively Cooled Superconductors Final Report

A highly reflective spray-on coating and tile material has been under development at Kennedy Space Center (KSC) that scatters away most of the Sun’s energy, thereby allowing coated objects to remain cool in space. The best performing tile material has achieved 1% solar absorptivity while the best performing spray-on coating has achieved around 4%. Both versions passively maintain cryogenic temperatures below 120 K at 1 astronomical unit (AU) from the Sun, but the tile material consistently sustains temperatures below 90 K, which is low enough to preserve oxygen and methane in a liquid state. Besides keeping propellants cold, this “solar white” material has the potential to passively maintain high-temperature superconductors (HTS) in a superconducting state without the support of liquid nitrogen cooling. If superconductors can be operated without the added infrastructure of liquid nitrogen cooling, it may enable them to be used in space for applications like magnetic radiation shielding and efficient energy management. Long duration exposure to both galactic cosmic radiation and coronal mass ejections can pose health risks for the astronauts and increase the potential for damage to electronics. This makes shielding essential to accomplish long duration missions, particularly when astronauts are onboard. The objective of this project was to determine the extent we could keep a high-temperature superconducting (HTS) material passively chilled to maintain its superconducting state. Both the tile and spray-on versions of solar white were investigated. We focused on finding a version that could support passive cooling at 1 AU from the Sun and determined the closest operating distances for samples that were unable to perform at 1 AU. Early in the project, we selected bismuth strontium calcium copper oxide (BSCCO) as the HTS to test based on its reputable usage in superconducting wires. The version we selected was Bi-2223, which has a critical temperature of about 108 K. Sample bars with contacts for a four-point probe were obtained from Quantum Levitation: https://quantumlevitation.com/product/superconductor-bar-for-4-point-tc-experiment/.

superconductors↗

Screen Channel Liquid Acquisition Devices for Cryogenic Propellants

This paper describes an on-going project to study the application screen channel liquid acquisition devices to cryogenic propellant systems. The literature of screen liquid acquisition devices is reviewed for prior cryogenic experience. Test programs and apparatus are presented to study these devices. Preliminary results are shown demonstrating bubble points for 200 x 1400 wires per inch and 325 x 2300 wires per inch Dutch twill screens. The 200 x 1400 screen has a bubble point of 15.8 inches of water in isopropyl alcohol and 6.6 inches of water in liquid nitrogen. The 325 x 2300 screen has a bubble point of 24.5 inches of water in isopropyl alcohol, 10.7 inches of water in liquid nitrogen, and 1.83 inches of water in liquid hydrogen. These values are found to be in good agreement with the results reported in the literature.

Chato, David J.↗

Permeability testing of composite material and adhesive bonds for the DC-XA composite feedline program

Hercules IM7/8552 carbon/epoxy and Hysol EA 9394 epoxy adhesive bonded between composite/titanium were tested for permeability after various numbers of thermal cycles between 100 C and liquid nitrogen (-196 C). The specimens were quenched from the 100 C temperature into liquid nitrogen to induce thermal shock into the material. Results showed that the carbon/epoxy system was practically impermeable even after 12 thermal cycles. The EA 9394 adhesive bondline was more permeable than the carbon/epoxy, but vacuum mixing minimized the permeability and kept it within allowable limits. Thermal cycling had little effect on the permeability values of the bondline specimens.

Nettles, A. T.↗

Effects of proof loads and combined mode loadings on fracture and flaw growth characteristics of aerospace alloys

This experimental program was undertaken to determine the effects of (1) combined tensile and bending loadings, (2) combined tensile and shear loadings, and (3) proof overloads on fracture and flaw growth characteristics of aerospace alloys. Tests were performed on four alloys: 2219-T87 aluminum, 5Al-2.5Sn (ELl) titanium, 6Al-4V beta STA titanium and high strength 4340 steel. Tests were conducted in room air, gaseous nitrogen at -200F (144K), liquid nitrogen and liquid hydrogen. Flat center cracked and surface flawed specimens, cracked tube specimens, circumferentially notched round bar and surface flawed cylindrical specimens were tested. The three-dimensional photoelastic technique of stress freezing and slicing was used to determine stress intensity factors for surface flawed cylindrical specimens subjected to tension or torsion. Results showed that proof load/temperature histories used in the tests have a small beneficial effect or no effect on subsequent fracture strength and flaw growth rates.

Shah, R. C.↗

Real gas effects 2: Influence of condensation on minimum operating temperatures of cryogenic wind tunnels

Condensation effects are responsible for the minimum operating temperatures of cryogenic wind tunnels at total pressures up to about 9 atmospheres. The two primary modes of condensation homogeneous nucleation and heterogeneous nucleation and the conditions with which either may limit minimum operating temperatures are reveiwed. Previous hypersonic and supersonic condensation data are reviewed as are data taken in the nitrogen gas, Langley 0.3 Meter Transonic Cryogenic Tunnel. Analysis of data in the 0.3 m tunnel suggests that the onset of homogenous nucleation may be approximated by an analysis by sivier and that the onset of heterogeneous nucleation is only apparent just below free stream saturation. Extension of the results from the 0.3 m tunnel to other nitrogen gas cryogenic tunnels is discussed and is shown to depend on length scales, purity of the liquid nitrogen injected for cooling, number of particulates in the flow, and the extent to which the injected liquid nitrogen is evaporated.

Hall, R. M.↗

Minimization of thermal deformation in crystal optics for high repetition-rate FEL

Minimizing thermal deformation in X-ray crystal optics is crucial for preserving coherence and wavefront in high-repetition-rate free-electron lasers (FELs). This study presents two approaches to reduce pulse-by-pulse transient thermal deformation in diamond crystals used in cavity-based X-ray FELs (CBXFELs): (1) cryogenic cooling with liquid nitrogen (LN₂), and (2) second-order correction via focusing optics. We revisit the temperature-dependent thermal-mechanical properties of diamond and silicon, implement a finite-element analysis (FEA) method to accelerate convergence to a quasisteady-state regime. Results show that LN₂-cooled diamond crystals meet the stringent deformation requirement of less than 15 pm RMS for the pulse at mJ scale at 1 MHz repetition frequency, and up to 1.5 mJ for 100 kHz. Second-order correction by using focusing elements within the cavity can reduce the impact of thermal deformation for both liquid nitrogen and water cooling.

free electron laser↗

CryoCart Restoration and Vacuum Pipe Construction

Propulsion systems that utilize hypergolic propellants have been used to power space vehicles since the beginning of the space program. Liquid methane and oxygen propulsion systems have emerged as an alternative and have proven to be more environmentally friendly. The incorporation of liquid methane/liquid oxygen (LOX) into the propulsion system has demonstrated an increase in engine performance, as well as a reduction in the volume, size and complexity of the system. Consequently, reducing the total mass of the vehicle which is a crucial aspect that is considered when planning space missions to both the Moon and Mars [1]. Project Morpheus has made significant advancements in liquid oxygen/liquid methane propulsion system technologies by incorporating a LOX/methane propulsion system to a vertical test bed. The vehicle consisted of a 5,000 lb main engine and four 20 lb remote control system (RCS) engines that utilize liquid methane/LOX as its propellant [1]. The vehicle completed successful flight testing at Kennedy Space Center in 2014 which marked the completion of the Morpheus project. Subsequent projects utilizing Morpheus' vertical test bed have been developed to make further advancements. One of the subsequent projects consisted of the addition of a smaller 2,000 lb main engine and a cold helium heat exchanger which would make it possible for a pressurant tank systems to be send to Mars or the Moon by significantly decreasing the overall mass and volume of the pressurant tank. The hot fire tests of the integrated system with the smaller main engine and cold helium heat exchanger were successful at sea level, but further studies are being conducted to better understand how the vertical test bed will behave under thermal-vacuum conditions. For this reason, the integrated vehicle will be taken to Plum Brook to be tested in a chamber capable of simulating these conditions. To ensure that the vehicle will function properly under vacuum conditions, testing will be first completed at the component level. During this process, the igniter of the main engine and the RCS thrusters will be tested under a vacuum. To complete the testing of the components, the test setup first needed to be finalized. The CryoCart is being used to feed the propellants to the test article. The CryoCart is a movable test set-up that was developed in 2009 to provide a mobile platform for testing oxygen/methane systems with hot-fire capability up to 100 lbf. The CryoCart consists of three different systems: Oxygen, Methane, and liquid Nitrogen. The Oxygen and Methane systems are placed into two different carts while the liquid nitrogen system is mainly located in the methane cart. Over the years, the CryoCart has been utilized for different projects and has undergone deterioration. For this reason, a new phase has been developed to rebuild it to working conditions once again. During my internship, I was aiding in the construction and restoration of the CryoCart. In the initial stages of the process, I updated the fluid and electrical schematics for the oxygen, methane, and test article systems. The original CryoCart consisted of an electrical panel that utilized electromechanical relays and a terminal to drive the igniter power and signal, as well as the main fuel and oxygen valves. This electrical panel connected to the CryoCart through various wire harnesses that could be found exiting from the CryoCart. First, it was determined how these harnesses connected to the electromechanical relays so that they worked correctly. Once the electrical system was understood, an alternative for the electromechanical relays and the Molex connectors used throughout the system was sought since these components can often prove to be unreliable. Solid State relays and MIL connectors were purchased to serve as replacements. Upon arrival of the parts, crimping and wiring was completed to install the new solid state relays and MIL connectors. During the replacement of the relays and connectors, system checks of the electrical system were ran to ensure that the system was working correctly. While completing system checks, the pressure transducers that were not functioning properly were also replaced and any issue with the wiring or signal was addressed. Once the electrical components were replaced, the restoration of the fluid system began. Parts of the tubing in the CryoCart had to be rebuild and often consisted of sizing, cutting, bending, filing, and sanding the tubing to prepare it to be flared. Many components had to be proof-tested to bring their certifications up to date, and several components had to be replaced. Various flex hoses, valves, and fittings were send to the Clean Lab because they were new, dirty, or had gone through proof-testing. Once they arrived from the cleaning lab they had to be put back to the system and leak checks and functional tests were conducted. In the Nitrogen system, the copper tubing located in the Oxygen cart was rebuild and Aerogel insulation was added to this section. A new gaseous nitrogen system was added to the CryoCart to purge the vacuum tube which will serve as the test chamber. Once the CryoCart was completed, construction of parts of the vacuum tube began. A flange was manufactured with welded fittings to hold the line of the vacuum pump as well as some extra fittings which will serve as extra inlets used to introduce fluid lines to the vacuum tube. Stress analysis was ran in this flange to ensure that it would not fail under vacuum conditions. The fluid lines leading from the air side of the vacuum to the test article were also constructed and added to the mount that had already been manufactured. Three different sets of tubing were constructed to accommodate the seven different RCS thruster and the main engine igniter that are going to be tested. Full electrical system checks were completed to ensure that all the wire harnesses and valves were functioning. Upon the completion of the CryoCart and the vacuum tube, hot fire testing for the RCS thrusters and the main engine igniter are going to begin. During this time any issues encountered with the engines or igniter will be addressed to ensure that the components function under vacuum conditions. After successful completion of testing, the vertical test bed, Morpheus, will be rebuilt and prepared to be sent to Plum Brook. In Plum Brook, the vehicle will be tested in the thermal-vacuum chamber to demonstrate that integrated lox-methane propulsion system operation in space-like conditions. This internship has allowed me the opportunity to gain valuable hands on experience and to develop skills that will aid in my education as well as in the workforce, while at the same time helping me determine that I would like to further pursue a career in propulsion engineering.

Chaidez, Mariana↗

Experimental Effervescence and Freezing Point Depression Measurements of Nitrogen in Liquid Methane-Ethane Mixtures

NASA is designing an unmanned submarine to explore the depths of the hydrocarbon-rich seas on Saturn's moon Titan. Data from Cassini indicates that the Titan north polar environment sustains stable seas of variable concentrations of ethane, methane, and nitrogen, with a surface temperature near 93 K. The submarine must operate autonomously, study atmosphere/sea exchange, interact with the seabed, hover at the surface or any depth within the sea, and be capable of tolerating variable hydrocarbon compositions. Currently, the main thermal design concern is the effect of effervescence on submarine operation, which affects the ballast system, science instruments, and propellers. Twelve effervescence measurements on various liquid methane-ethane compositions with dissolved gaseous nitrogen are thus presented from 1.5 bar to 4.5 bar at temperatures from 92 K to 96 K to simulate the conditions of the seas. After conducting effervescence measurements, two freezing point depression measurements were conducted. The freezing liquid line was depressed more than 15 K below the triple point temperatures of pure ethane (90.4 K) and pure methane (90.7 K). Experimental effervescence measurements will be used to compare directly with effervescence modeling to determine if changes are required in the design of the thermal management system as well as the propellers.

Submarine↗

Propagation of Cryogenic Thermal Fractures from Unconfined PMMA Boreholes

In cryogenic fracturing, a rock surface exposed to cryogenic fluids undergoes a large thermal gradient, and the resultant local tensile stress overcomes rock strength and initiates fractures. This study investigates the development of cracks generated from the cryogenic treatment of a borehole under no external confining stress on specimens. The experiments were performed on transparent PMMA specimens to observe fracture proliferation around boreholes. Liquid nitrogen was flowed through the boreholes to cool the borehole surface. The results show that initial fracture growth is characterized by abrupt starts and stops, and as the fracture propagates outward, the growth appears more continuous. In an early stage, horizontal/radial fractures and vertical fractures are the defining patterns. Horizontal fractures tend to be separated by a specific exclusion distance (i.e., spacing between cracks). While distinct horizontal/vertical fractures and exclusion distance manifest themselves at an early stage, fractures resulting from fracture interactions and curvatures can develop into complex shapes at later stages. Cryogenic thermal loading induces distinctively curved fractures. The tendency of curvature may prevent greater penetration. An increase in the borehole pressure during liquid nitrogen flow, however, can lessen fracture tortuosity and facilitate radial propagation. A high flow pressure and rate are also advantageous in that they accelerate cooling and fracture propagation.

42 ENGINEERING↗

Performance tests of a cryogenic hybrid magnetic bearing for turbopumps

Experiments were performed on a Hybrid Magnetic Bearing designed for cryogenic applications such as turbopumps. This bearing is considerably smaller and lighter than conventional magnetic bearings and is more efficient because it uses a permanent magnet to provide a bias flux. The tests were performed in a test rig that used liquid nitrogen to simulate cryogenic turbopump temperatures. The bearing was tested at room temperature and at liquid nitrogen temperature (-320 F). The maximum speed for the test rig was 14000 rpm. For a magnetic bearing stiffness of 20000 lb/in, the flexible rotor had two critical speeds. A static (nonrotating) bearing stiffness of 85000 lb/in was achieved. Magnetic bearing stiffness, permanent magnet stiffness, actuator gain, and actuator force interaction between two axes were evaluated, and controller/power amplifier characteristics were determined. The tests revealed that it is feasible to use this bearing in the cryogenic environment and to control the rotor dynamics of flexible rotors when passing through bending critical speeds. The tests also revealed that more effort should be placed on enhancing the controller to achieve higher bearing stiffness and on developing displacement sensors that reduce drift caused by temperature and reduce sensor electrical noise.

Dirusso, Eliseo↗

A search for nitrogen on Triton

Improved spectrophotometry of Triton at 2.16 microns was obtained with the MMT infrared photometer at a resolution of 1.0 percent. The observations do not reveal an absorption feature due to liquid nitrogen. Three explanations are consistent with this finding: (1) there is liquid nitrogen on the surface but it is not distributed uniformly; (2) the feature varies with time, e.g., it is sometimes obscured by cloud cover; and (3) the feature might be relatively broad.

Rieke, G. H.↗

Near-Threshold Photoemission from Graphene-Coated Cu(110)

In this article, the brightness of electron beams emitted from photocathode sources plays a critical role in determining the performance of x-ray free-electron lasers and ultrafast electron-diffraction applications. In order to achieve the maximum brightness, the electrons need to be emitted from a photocathode with the lowest-possible mean transverse energy (MTE). Recent investigations have shown that capping a Cu(110) photocathode with a monolayer of graphene can protect the quantum efficiency (QE) from long-term exposure to varying vacuum conditions. However, there have been no studies that investigate the effects that a monolayer of graphene has on the MTE. Here, we report on measurements of a graphene-coated Cu(110) single crystal near the photoemission threshold for room and liquid-nitrogen temperatures. At room temperature, a minimum MTE of 25 meV is measured at 295 nm. At liquid-nitrogen temperatures, a minimum MTE of 9 meV is measured at the photoemission threshold of 290 nm.

36 MATERIALS SCIENCE↗

High T(sub c) superconductors: Are they magnetic

The objective is to demonstrate the magnetic characteristics of the new superconducting oxides with transition temperatures above liquid nitrogen temperature (77 K). The first task was to find out whether YBa2Cu3O7-x is magnetic at liquid nitrogen temperature, and if so, what the sign of its magnetic susceptibility is. Details of the experimental procedure are given.

Shull, Robert D.↗