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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Pulsed excimer laser processing

The status of pulsed excimer laser processing of PV cells is presented. The cost effective feasibility of fabricating high efficiency solar cells on Czochralski wafers using a pulsed excimer laser for junction formation, surface passivation, and front metallization. Laser annealing results were promising with the best AR coated cell having an efficiency of 16.1%. Better results would be expected with larger laser spot size because there was some degradation in open circuit voltage caused by laser spot overlap and edge effects. Surface heating and photolytic decomposition by the laser was used to deposit tungsten from the reaction of tungsten hexafluoride and hydrogen. The line widths were 5 to 10 mils, and the depositions passed the tape adhesion test. Thinner lines are practical using an optimized optical system.

Wong, D.↗
NASA NTRS1989

The penultimate supernova in the Large Magellanic Cloud - SNR 0540-69.3

Spectra of the SNR 0540-69.3 in the LMC are presented that cover the wavelength interval 3500-9800 A. An optical continuum is observed over this entire wavelength range from synchrotron emission near the 50 ms pulsar inside the remnant. The spectrum contains emission lines shifted by + 370 km/s from the local LMC rest velocity. The line widths average 2735 + or - 200 km/s, indicating an expansion age of 762 + or - 50 yr. Lines of forbidden O I, forbidden O II, forbidden O III, forbidden S II, forbidden S III, forbidden Ar III, forbidden Ni II, forbidden Fe II, forbidden Fe III, and H-alpha are detected, and forbidden Fe V and forbidden Fe VII may be detected. It is very likely that the object is the young SNR following core collapse of a massive star akin to the progenitor of SN 1987A.

Kirshner, Robert P.↗
NASA NTRS2010

Uncertainties Associated with Theoretically Calculated N2-Broadened Half-Widths of H2O Lines

With different choices of the cut-offs used in theoretical calculations, we have carried out extensive numerical calculations of the N2-broadend Lorentzian half-widths of the H2O lines using the modified Robert-Bonamy formalism. Based on these results, we are able to thoroughly check for convergence. We find that, with the low-order cut-offs commonly used in the literature, one is able to obtain converged values only for lines with large half-widths. Conversely, for lines with small half-widths, much higher cut-offs are necessary to guarantee convergence. We also analyse the uncertainties associated with calculated half-widths, and these are correlated as above. In general, the smaller the half-widths, the poorer the convergence and the larger the uncertainty associated with them. For convenience, one can divide all H2O lines into three categories, large, intermediate, and small, according to their half-width values. One can use this division to judge whether the calculated half-widths are converged or not, based on the cut-offs used, and also to estimate how large their uncertainties are. We conclude that with the current Robert- Bonamy formalism, for lines in category lone can achieve the accuracy requirement set by HITRAN, whereas for lines in category 3, it 'is impossible to meet this goal.

Ma, Q.↗
DOE OSTI2023

Spectral widths and Stokes shifts in InP-based quantum dots

InP-based quantum dots (QDs) have Stokes shifts and photoluminescence (PL) line widths that are larger than in II–VI semiconductor QDs with comparable exciton energies. The mechanisms responsible for these spectral characteristics are investigated in this paper. Upon comparing different semiconductors, we find the Stokes shift decreases in the following order: InP > CdTe > CdSe. We also find that the Stokes shift decreases with core size and decreases upon deposition of a ZnSe shell. We suggest that the Stokes shift is largely due to different absorption and luminescent states in the angular momentum fine structure. The energy difference between the fine structure levels, and hence the Stokes shifts, are controlled by the electron–hole exchange interaction. Luminescence polarization results are reported and are consistent with this assignment. Spectral widths are controlled by the extent of homogeneous and inhomogeneous broadening. Here, we report PL and PL excitation (PLE) spectra that facilitate assessing the roles of homogeneous and different inhomogeneous broadening mechanisms in the spectra of zinc-treated InP and InP/ZnSe/ZnS particles. There are two distinct types of inhomogeneous broadening: size inhomogeneity and core–shell interface inhomogeneity. The latter results in a distribution of core–shell band offsets and is caused by interfacial dipoles associated with In–Se or P–Zn bonding. Quantitative modeling of the spectra shows that the offset inhomogeneity is comparable to but somewhat smaller than the size inhomogeneity. The combination of these two types of inhomogeneity also explains several aspects of reversible hole trapping dynamics involving localized In 3+ /V Zn 2– impurity states in the ZnSe shells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1988

Spectroscopic evidence supporting the gravitational lens hypothesis for 1635+267 A,B

The gravitational lens hypothesis is tested for 1613+267 A,B by comparing the detailed line widths and shapes of the 2799-A Mg II and semiforbidden 1909-A C-III lines in each component. Following subtraction of an interpolating polynomial fit to the continua and the determination of a single optimum scaling factor (an amplification ratio of 2.83), reasonable agreement between the profiles of both lines in the two composites is obtained. Comparison of these lines to those in an unrelated quasar with a similar redshift and apparent magnitude does not produce a good match. It is suggested that the observed match in the 1635+267 A,B spectra arises from gravitational lensing.

Turner, Edwin L.↗
NASA NTRS1988

Measurements of argon-, helium-, hydrogen-, and nitrogen-broadened widths of methane lines near 9000 per cm

Pressure-broadened widths of rotational-vibrational lines in CH4 have been measured at very high spectral resolution in the R-branch of the 3nu3 overtone. The broadening gases were Ar, He, H2, and N2. Results are presented as averages for J-multiplets at ambient temperature. The overall values (per cm per atm) for these R-branch lines are 0.0651 (CH4-Ar), 0.0508 (CH4-He), 0.0728 (CH4-H2), and 0.0715 (CH4-N2).

Fox, Kenneth↗
NASA NTRS1994

High-resolution spectroscopy of Balmer-dominated shocks in the Large Magellanic Cloud

We present high-resolution spectra of the four Balmar-dominated supernova remnants (SNRs) in the Large Magellanic Cloud (LMC). These data allow us to measure the width of the narrow component of H alpha emission in the nonradiative filaments present in these SNRs. We find that the widths range from 30 to 50 km/s FWHM, similar to the only previously measured width of a nonradiative shock filament, that of about 30 km/s in the NE Cygnus Loop. The line widths do not appear to scale with shock velocity. These observations severely limit the possible broadening mechanisms. We discuss several possibilities, the most promising of which is a precursor associtated with cosmic rays. Assuming a cosmic-ray precursor, we are able to place constraints on the cosmic-ray diffusion coefficient. Observations such as these may provide the best method currently available to probe cosmic-ray acceleration in SNR shock waves.

Smith, R. Chris↗
NASA NTRS1986

New interstellar masers in nonmetastable ammonia

The first astronomical detections of several ammonia inversion transitions involving nonmetastable levels with energies as high as 1090 K above the ground state are reported. The (J, K) = (9, 6) inversion transition shows maser-like emission in the directions of W51, NGC 7538, W49, and DR 21(OH). The NH3 (6, 3) line exhibits similar characteristics in W51 but is seen in absorption in NGC 7538. These are the first definite detections of ammonia masers in space. The intensities and narrow line widths (0.5-1.5 km/s) for the emission features are in contrast to the previously detected broad, weak, nonmetastable lines attributed to thermal emission in these sources. Temporal variability appears to be evident in the (9, 6) emission in W49 over a 4 month period. The highly excited (J, K) = (9, 6) and (6, 3) ammonia lines are found in regions containig compact H II regions and strongly infrared sources with associated H2O and OH masers; i.e., in regions of active star formation.

Madden, S. C.↗
NASA NTRS1990

High spectral resolution observations of fluorescent molecular hydrogen in molecular clouds

The 1-0 S(1) line of molecular hydrogen has been observed at high spectral resolution in several sources where the emission was suspected of being fluorescent. In NGC 2023, the Orion Bar, and Parsamyan 18, the S(1) line is unresolved, and the line center close to the rest velocity of the ambient molecular cloud. Such behavior is expected for UV-excited line emission. The H2 line widths in molecular clouds thus can serve as diagnostic for shocked and UV-excitation mechanisms. If the lines are broader than several km/s or velocity shifts are observed across a source it is likely that shocks are responsible for the excitation of the gas.

Burton, Michael G.↗
NASA NTRS1994

High-velocity plasma in the transition region of AU Microscopii: Evidence for magnetic reconnection and saturated heating during quiescent and flaring conditions

We analyze high-resolution HST spectra of the dMOe flare star AU Mic, including the profiles of the C IV 1548.2 A, 1550.8 A and Si IV 1393.8 A, 1402.8 A lines obtained with the G160M grating of the Goddard High-Resolution Spectrograph. The quiescent profiles of the C IV and Si IV lines are broad, and not simple Gaussians in shape. Flux in the C IV and Si IV lines, for example, can be measured reliably out to about +/- 200 km/s from line center. Each of the C IV and Si IV profiles can be fitted accurately by two Gaussians (one narrow and the other broad) centered on nearly the same wavelength, with the narrower component accounting for roughly 60% ofthe total integrated flux. The narrow components have similar line widths to those observed in solar active and quiet regions. The broad Gaussian components of the AU Mic line profiles are reminiscent of the broad C IV profiles observed in solar transition region explosive events, which are thought to be associated with emerging magnetic flux regions where field reconnection occurs.

Linsky, Jeffrey L.↗
NASA NTRS1974

Beam maser measurements of CH3OH rotational transitions

Precise measurements of rotational transitions in methanol are reported that were made by means of beam maser spectrometers. No hyperfine structure was resolved at a resonance line width of 8 kHz. Accurate center frequencies for the transitions measured are useful for determining Doppler shifts for observed interstellar lines.

Gaines, L.↗
NASA NTRS1976

A frequency doubled pressure-tunable oscillator-amplifier dye laser system

A tunable high-repetition-rate oscillator-amplifier dye-laser system is reported. The dye laser described was longitudinally pumped with the second harmonic of a Nd-YAG laser operating at 10 Hz. Using three Faraday-Perot etalons and pressure tuning, a maximum fundamental output power of the order of 6 MW with a corresponding spectral width of less than 0.003 nm at 564 nm was obtained. The fundamental at 564 nm was frequency doubled to give a maximum power level of 0.6 MW of second-harmonic output power with a spectral width less than 0.0015 nm at 282 nm. Frequency stability could be maintained to within approximately 15% of the line-width.

Moriarty, A.↗
NASA NTRS1979

Variability of Lyman-alpha emission from Jupiter

The Jovian Lyman-alpha emission line was again observed in 1978 using the high resolution spectrometer on the Copernicus satellite. In intensity of 8.4+3.0 kilo Rayleighs was measured. This value represents a significant increase in intensity over previous (1976) Copernicus observations, but is lower than the recent (1979) values obtained by Voyager I and IUE. The increase in intensity was accompanied by a significant increase in line width, giving strong support to the theory that the emission results from resonant scattering of the solar Ly-alpha line by H atoms in the upper Jovian atmosphere. The strength of Jovian Ly-alpha emission correlates well with the level of solar activity. The solar extreme ultraviolet radiation varies with the solar cycle. This radiation causes the dissociation of H2 and CH4 into H atoms in the Jovian atmosphere. Therefore, in times of high solar activity, the H column density will increase, causing the observed stronger Jovian Ly-alpha emission.

Source record↗
NASA NTRS1979

Variability of Lyman-alpha emission from Jupiter

The Jovian Lyman-alpha emission line was reobserved in 1978 March using the high-resolution spectrometer of the Copernicus satellite. An intensity of 8.3 plus or minus 2.9 kilorayleighs was measured. This value represents a significant increase in intensity over previous (1976) Copernicus observations, but is lower than the recent (1979) values obtained by Voyager 1 and IUE. The increase in intensity has been accompanied by a significant increase in line width giving strong support to the theory that the emission results from resonant scattering of the solar Lyman-alpha line by H atoms in the upper Jovian atmossphere. The strength of Jovian Lyman-alpha emission correlates well with the level of solar activity. The solar extreme ultraviolet radiation varies with the solar cycle. This radiation causes the dissociation of H2 and CH4 into H atoms in the Jovian atmosphere. Therefore, in times of high solar activity, the H column density will increase, causing the observed strong Jovian Lyman-alpha emission.

Cochran, W. D.↗
NASA NTRS1984

Detection of far-infrared forbidden O I and forbidden O III emission from the galaxy M82

Observations in M82 of the lowest-lying transitions of neutral and doubly ionized oxygen, forbidden O I 63.2 microns and forbidden O III 88.4 microns, which have wavelengths at which the extinction toward M82 is negligible, are reported. For O III, the +220 km/s velocity of the line center with respect to the local standard of rest, the 300 km/s intrinsic line width, and the asymmetry of the profile are consistent with the systemic velocity and rotational broadening seen in other ionic lines in the nucleus of M82. The fraction of oxygen that is present in doubly ionized form, indicates that the ionization state is similar to that found in H II regions in the disk of the Milky Way Galaxy. The central velocity of the O I line is +130 km/s, and no broadening in excess of instrumental resolution is seen. This result appears to rule out association of this emission with the periphery of the central H II region.

Watson, D. M.↗
NASA NTRS1986

Laser-assisted solar cell metallization processing

The status of the laser-assisted solar cell metallization processing is described. Metallo-organic silver films were spun-on by argon ion laser beam pyrolysis. The metallo-organic decomposition (MOD) film was spun-on an evaporated Ti/Pd film to produce tood adhesion. In a maskless process, the argon ion laser writes the contact pattern. The film is then built up to obtain the required conductivity using conventional silverplating process. The Ti/Pd film in the field is chemically etched using the plated silver film as the mask. The width of the contact pattern is determined by the power of the laser. Widths as thin as 20 microns were obtained using 0.66 W of laser power. Cells fabricated with the 50 micron line widths of 4 ohm-cm floating zone (Fz) silicon-produced efficiencies of 16.6% (no passivation) which were equivalent to the best cells using conventional metallization/lithography and no passivation.

Meier, D. L.↗