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At least 235 records · Page 13

Cosmic ray exposure ages of features and events at the Apollo landing sites

Cosmic-ray exposure ages of lunar samples have been used to date surface features related to impact cratering and downslope movement of material. Only when multiple samples related to a feature have the same rare-gas exposure age or when a single sample has the same Kr-81 -Kr and track-exposure age can a feature be considered as reliably dated. Based on these criteria, there are only five well-dated lunar features: Cone Crater (Apollo 14), 26 m.y,; North Ray Crater (Apollo 16), 50 m.y.; South Ray Crater (Apollo 16), 2 m.y.; the emplacement of the Station 6 boulders (Apollo 17), 22 m.y.; and the emplacement of the Station 7 boulder (Apollo 17), 28 m.y. Other features are tentatively dated or have limits set on their ages: Bench Crater (Apollo 12), upper limit of 99 m.y.; Baby Ray Crater (Apollo 16), upper limit of 2 m.y.; Shorty Crater (Apollo 17), approximately 30 m.y.; Camelot Crater (Apollo 17) upper limit of 140 m.y.; the emplacement of the Station 2 boulder 1 (Apollo 17), 45 to 55 m.y.; and the slide which generated the light mantle (Apollo 17), lower limit of 50 m.y.

Arvidson, R.↗

Atmospheric rare gases in lunar rock 60015

Aliquots of lunar rock 60015 were subjected to various types of exposure and handling designed to produce terrestrial contamination, in order to test the possibility of a terrestrial origin for the terrestrial-like trapped Xe reported for lunar rock samples. Crushing the rock produced up to order-of-magnitude increases in the abundances of Ar, Kr, and Xe relative to the millimeter-sized chips of 60015 previously analyzed. Contrary to expectations for atmospheric contamination, high temperatures (above 1000 C) were necessary to remove about 75% of the trapped Kr and Xe, and the rare-gas elemental abundance ratios differed from those in terrestrial samples believed to have occluded atmospheric gases. It is concluded, on the basis of similar temperature-release profiles and elemental-fractionation patterns, that the trapped Xe observed in all these 60015 analyses is atmospheric contamination. Such a conclusion cannot unequivocally be drawn for other lunar rocks containing terrestrial-like Xe, but the present results demonstrate that arguments based on high extraction temperatures and elemental abundance ratios cannot be useful to rule out rare-gas atmospheric contamination in such samples.

Niemeyer, S.↗

History and genesis of lunar troctolite 76535 or: How old is old

The history of lunar troctolite 76535 was investigated on the basis of information from the Sm-147-Nd-143 mineral isochron age, the Nd-143 evolution, extinct Pu-224, the Kr-81-Kr exposure age and the cosmic ray exposure record. It was found that the troctolite minerals last equilibrated 4.26 plus or minus 0.06 AE ago and that the Sm-Nd system became closed at this time. The rock remained at temperatures where the loss of radiogenic Ar-40 was small.

Lugmair, G. W.↗

Sm-Nd-Pu timepieces in the Angra dos Reis meteorite

Isotope ratios and age estimations are presented for the ultramafic pyroxenite Angra dos Reis meteorite. A pyroxene-phosphate internal isochron age of 4.55 plus or minus 0.04 eons was obtained, in agreement with reported Pb-Pb ages. It is suggested that Sm-146 decay led to an increase in the ratio of Nd-142 to Nd-144 in pyroxene, which is greater than the ratio of the Nd isotopes in phosphates. The effect of Pu-244 on the fission xenon components in pyroxene and phosphate is examined. The ratios of Pu-244 to Nd, U-238, and Th-232 are compared for pyroxene and phosphate separates. The exposure age of the meteorite, as obtained by the Kr-81 to Kr-83 method, was found to be 55.5 plus or minus 1.2 million years.

Lugmair, G. W.↗

Cosmic-ray exposure history at Taurus-Littrow

Recent surface history at Taurus-Littrow is dominated by emplacement of the Central Cluster and Bright Mantle morphological units, both believed to have resulted from arrival of ejecta from a large primary crater, probably Tycho. This paper reports new noble gas data for eight Apollo 17 rocks. Kr-81 - Kr cosmic ray exposure ages for these rocks affirm the observation of a pronounced grouping of ages, reinforcing the photogeologic evidence for the site-wide nature of the Central Cluster event. The consequences of post-cratering shielding changes are considered and it is concluded that the differences can reasonably be attributed to these changes, particularly because of the greater likelihood of rollover and impact fragmentation of the relatively smaller rocks from which most age data have been obtained. These considerations also lead to a more refined age estimate of 109 plus or minus 4 m.y. for Central Cluster, the Bright Mantle, and Tycho.

Drozd, R. J.↗

Krypton and xenon in Apollo 14 samples - Fission and neutron capture effects in gas-rich samples

Gas-rich Apollo 14 breccias and trench soil are examined for fission xenon from the decay of the extinct isotopes Pu-244 and I-129, and some samples have been found to have an excess fission component which apparently was incorporated after decay elsewhere and was not produced by in situ decay. Two samples have excess Xe-129 resulting from the decay of I-129. The excess is correlated at low temperatures with excess Xe-128 resulting from neutron capture on I-127. This neutron capture effect is accompanied by related low-temperature excesses of Kr-80 and Kr-82 from neutron capture on the bromine isotopes. Surface correlated concentrations of iodine and bromine are calculated from the neutron capture excesses.

Drozd, R.↗

Comparisons between observed and predicted cosmogenic noble gases in lunar samples

Comparisons are made between cosmogenic production rates and isotopic ratios predicted on the basis of nuclear systematics with those observed in well-documented lunar samples. Although some significant differences are found, the agreement in general is surprisingly good. The predicted production rates for Ar-38 and Xe-126 agree reasonably well with observation but the predicted rate for Ne-21 appears to be too high; in most cases the predicted rate for Kr-83 agrees to within 50%, although some larger differences are apparent. There are some prominent cases in which predicted isotopic compositons differ from observation: Kr-78/Kr-83 trends in the wrong sense with the Zr/Sr ratio; Xe-124/Xe-126 is too large by about 13%; Xe-128/Xe-126 is too small by about 6%; Xe-130/Xe-126 is too low by 30-40%.

Hohenberg, C. M.↗

Discovery of a longitudinal asymmetry in the H Lyman-alpha brightness of Jupiter

A strong longitude variation in the midlatitude Lyman-alpha brightness of Jupiter has been discovered using data from the Voyager ultraviolet spectrometers. A minimum brightness of 14.4 kR was observed in the System III (1965) west longitude range 200-300 deg. The intensity rises to a broad peak of 19.6 kR near a longitude of 110 deg, a 36% increase over the minimum. This intensity 'bulge' was observed to rotate with the planet and appeared at the same longitude during both Voyager encounters, four months apart. This is a surprising discovery; no other planet studied to date has such a characteristic and the upper levels of the Jovian atmosphere were expected to be uniform in longitude. It is likely that a longitudinal asymmetry in charged particle precipitation leads to selective heating of the upper atmosphere and increased dissociation of H2, increasing the hydrogen column abundance. The resulting increase in resonant scattering could produce the observed intensity bulge.

Sandel, B. R.↗

Broad beam ion source operation with four common gases

A Kaufman-type broad beam ion source, used for sputtering and etching purposes, has been operated with Ar, Kr, O2 and N2 gas inputs over a wide range of beam energies (200-1200 eV) and gas flow rates (1-10 sccm). The maximum ion beam current density for each gas saturates at about 2.5 mA/sq cm as gas flow is increased. The discharge threshold voltage necessary to produce a beam and the beam efficiency (beam current/molecular current), however, varied considerably. Kr had the lowest threshold and highest efficiency, Ar next, then N2 and O2. The ion beam current varied only weakly with beam energy for low gas flow rates, but showed a factor of two increase when the gas flow was higher.

Pak, S.↗

The infrared spectrum of matrix isolated hydrogen and deuterium

The induced infrared spectra of H2 and D2, trapped in matrices of Ar, Kr, N2, CO, have been investigated. It is found that in Ar and Kr, the pure rotation spectrum is always readily observable. Portions of the fundamental region, however, are induced by impurities, while the entire spectrum is impurity induced in N2 matrices. These results are discussed in light of a recent Raman study of this system, and in comparison with several single crystal studies. Effective rotational and vibrational constants for matrix isolated H2 are also given.

Warren, J. A.↗

Morphology of the Venus ultraviolet night airglow

Images of the nightside of Venus in the (0,1)delta band of nitric oxide have been obtained by the Pioneer Venus orbiter ultraviolet spectrometer (OUVS). The emission, which is produced by radiative association of N and O, shows a bright spot reaching 5 kR and located at 2 a.m. local solar time just south of the equator. The emitting layer is at 111 + or - 7-km altitude. A one dimensional vertical transport model shows that the hemispheric average brightness of 0.8 kR is consistent with the orbiter neutral mass spectrometer (ONMS) measurements of N and O near 167 km, and that the altitude of the emitting layer is consistent with the eddy mixing model proposed to explain the dayside helium profile measured by the bus neutral mass spectrometer. In the model, N reaches a peak of 7 x 10 to the 8th per cu cm at 114 km, and O reaches a peak of 2.6 x 10 to the 11th per cu cm at 106 km. There is a fair degree of consistency between the ONMS, OUVS, and other airglow measurements, except as regards the local time dependence.

Stewart, A. I. F.↗

Rare gases in the past and present solar wind

The elemental abundances, fluxes and isotopic compositions of rare gases in the past and present-day solar wind are discussed on the basis of direct measurements and fossil evidence in lunar and meteorite samples. Spacecraft measurements of the abundances of He, O, Si, Fe, Ne, and Ar with respect to H in the solar wind are shown to agree with relative abundance measurements of these elements in the solar photosphere and corona, while the lack of evidence of systematic depletion with increasing ionic mass suggests solar abundances of the much less abundant Kr and Xe in the solar wind. Relative He, Ne and Ar abundances in the ancient solar wind as derived from lunar ilmenite and the Pesyanoe meteorite are similar to present-day values, except for a factor of two underabundance of He, while the heavy rare gases appear to be enriched by up to a factor of five. The isotopic compositions of solar wind Ar, Kr and Xe have apparently been fairly constant over most of the solar lifetime, whereas He and possibly Ne show evidence of an increasing abundance of their heavy isotopes with increasing solar wind age.

Pepin, R. O.↗

On krypton isotopic abundances in the sun and in the solar wind

The Kr isotopic systematics in the meteorite Pesyanoe which is known to contain solar-type gases, are reported. Discrepancies in the isotopic data of fractions released at stepwise increasing temperatures cannot be reconciled with spallation Kr components, although spallation effects are significant. Fractionation mechanisms on the parent body and in the solar wind source region are considered and the implications for solar abundances discussed.

Marti, K.↗

IUE observations of the Jovian HI Lyman alpha emission (1979 - 1982)

Observations of the Jovian H ion Lyman emission made with the IUE observatory beginning in December 1978 just before the time of the Voyager encounters and extending through January 1982 are presented. A constant disk center brightness of about 8 kR is observed for the central meridian longitude range wavelength III approximately equal 200 deg to 360 deg and a variable brightness 9-15 kR is found for the range lambda III approximately 50 deg to 150 deg. These brightness values persisted throughout the three years of observation. The hydrogen bulge near wavelength III approximately equal 100 deg appears to be a permanent feature of the Jovian atmosphere, and no long term change of the planetary Lyman emission is seen. Since the early IUE observations were made near the two Voyager encounters, this indicates that no substantial changes in the atomic hydrogen concentration or the average atmospheric conditions took place between then and now.

Skinner, T. E.↗

Adsorption of xenon and krypton on shales

A method that uses a mass spectrometer as a manometer is employed in the measurement of Xe and Kr adsorption parameters on shales and related samples, where gas partial pressures were lower than 10 to the -11th atm, corresponding adsorption coverages are only small fractions of a monolayer, and Henry's Law behavior is expected and observed. Results show heats of adsorption in the 2-7 kcal/mol range, and Henry constants at 0-25 C of 1 cu cm STP/g per atmosphere are extrapolated. Although the adsorption properties obtained are variable by sample, the range obtained suggests that shales may be capable of an equilibrium adsorption with modern air high enough to account for a significant fraction of the atmospheric inventory of Xe, and perhaps even of Kr. This effect will nevertheless not account for the factor-of-25 defficiency of atmospheric Xe, in comparison with the planetary gas patterns observed in meteorites.

Podosek, F. A.↗

Adsorption and excess fission xenon

The adsorption of Xe and Kr on lunar soil 10084 was measured by a method that employs only very low fractions of monolayer coverage. Results are presented as parameters for calculation of the Henry constant for adsorption as a function of temperature. The adsorption potentials are about 3 kcal/mole for Kr and 5 kcal/mole for Xe; heating the sample in vacuum increased the Xe potential to nearly 7 kcal/mole. Henry constants at the characteristic lunar temperature are about 0.3 cu cm STP/g-atm. These data were applied to consider whether adsorption is important in producing the excess fission Xe effect characteristic of highland breccias. Sorption equilibrium with a transient lunar atmosphere vented fission Xe produces concentrations seven orders of magnitude lower than observed concentrations. Higher concentrations result because of the resistance of the regolith to upward diffusion of Xe. A diffusion coefficient of 0.26 sq cm/sec is estimated for this process.

Podosek, F. A.↗