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At least 235 records · Page 13

Stress-Alteration Enhancement of the Reactivity of Aluminum Nanoparticles in the Catalytic Decomposition of exo -Tetrahydrodicyclopentadiene (JP-10)

High energy density aluminum nanoparticles (AlNP) upon thermal annealing followed by super-quenching results in elevated stress levels in the metallic core and reduced surface energy at the core-shell interface. Isomer-selective vacuum ultraviolet based photoionization mass spectrometry coupled to a high temperature chemical microreactor reveals that these stress-altered (SA) AlNPs exhibit distinctive temperature-dependent reactivities towards catalytic decomposition of the hydrocarbon jet fuel exo-tetrahydrodicyclopentadiene (JP-10, C 10 H 16 ) compared to untreated (UN) AlNPs. SA-AlNPs show a delayed initiation of the decomposition for JP-10 by 200 K relative to the UN-AlNPs, however, the full decomposition is achieved at 100 K lower temperature. Furthermore, there is less oxygenated products that are generated from the alumina surface-induced heterogeneous oxidation process, and a larger fraction of closed and open-shell hydrocarbons. Furthermore, chemical insight bridging the reactivity order of SA-AlNPs at low and high temperatures, simultaneously, is obtained via a detailed examination of the product branching ratios obtained in this study.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The interplay between vapour, liquid, and solid phases in laser powder bed fusion

The capability of producing complex, high performance metal parts on demand has established laser powder bed fusion (LPBF) as a promising additive manufacturing technology, yet deeper understanding of the laser-material interaction is crucial to exploit the potential of the process. By simultaneous in-situ synchrotron x-ray and schlieren imaging, we probe directly the interconnected fluid dynamics of the vapour jet formed by the laser and the depression it produces in the melt pool. The combined imaging shows the formation of a stable plume over stable surface depressions, which becomes chaotic following transition to a full keyhole. We quantify process instability across several parameter sets by analysing keyhole and plume morphologies, and identify a previously unreported threshold of the energy input required for stable line scans. The effect of the powder layer and its impact on process stability is explored. These high-speed visualisations of the fluid mechanics governing LPBF enable us to identify unfavourable process dynamics associated with unwanted porosity, aiding the design of process windows at higher power and speed, and providing the potential for in-process monitoring of process stability.

36 MATERIALS SCIENCE↗

21-Year Modeled Spatiotemporal Low-Level Jet Climatology Along the U.S. Mid-Atlantic Coast

Offshore wind farms are influenced by a variety of meteorological phenomena, ranging in spatial and temporal extent. One of these phenomena, the low-level jet (LLJ), is defined as a local maximum in wind speed with height in the planetary boundary layer, exhibiting a "nose-like" structure usually in the lowest few hundred meters above the surface. This vertical extent of LLJs may coincide with the rotor-swept area of a wind turbine, thus having implications for potential power production and mechanical loading. Previous studies in this area based on observations have confirmed the prevalence of LLJs here, with implications on power generation, wind turbine loads, and wake recovery depending on the LLJ characteristics, such as nose height and what part of the wind turbine power curve is being impacted.

LLJ↗

How do intermittency and simultaneous processes obfuscate the Arctic influence on midlatitude winter extreme weather events?

Abstract Pronounced changes in the Arctic environment add a new potential driver of anomalous weather patterns in midlatitudes that affect billions of people. Recent studies of these Arctic/midlatitude weather linkages, however, state inconsistent conclusions. A source of uncertainty arises from the chaotic nature of the atmosphere. Thermodynamic forcing by a rapidly warming Arctic contributes to weather events through changing surface heat fluxes and large-scale temperature and pressure gradients. But internal shifts in atmospheric dynamics—the variability of the location, strength, and character of the jet stream, blocking, and stratospheric polar vortex (SPV)—obscure the direct causes and effects. It is important to understand these associated processes to differentiate Arctic-forced variability from natural variability. For example in early winter, reduced Barents/Kara Seas sea-ice coverage may reinforce existing atmospheric teleconnections between the North Atlantic/Arctic and central Asia, and affect downstream weather in East Asia. Reduced sea ice in the Chukchi Sea can amplify atmospheric ridging of high pressure near Alaska, influencing downstream weather across North America. In late winter southward displacement of the SPV, coupled to the troposphere, leads to weather extremes in Eurasia and North America. Combined tropical and sea ice conditions can modulate the variability of the SPV. Observational evidence for Arctic/midlatitude weather linkages continues to accumulate, along with understanding of connections with pre-existing climate states. Relative to natural atmospheric variability, sea-ice loss alone has played a secondary role in Arctic/midlatitude weather linkages; the full influence of Arctic amplification remains uncertain.

Environmental Sciences & Ecology↗

Process-structure-property relationships for droplet-on-demand liquid-metal-jetted parts

Liquid metal jetting droplet-on-demand additive manufacturing is an attractive alternative to industry-standard, laser-based metal additive manufacturing techniques that use powder feedstocks and produce large heat affected zones. Liquid metal jetting provides a low feedstock footprint, minimal materials waste, less contamination and inclusions from feedstock, and is compatible with a large range of materials. However, little has been reported on the liquid metal jetting process-structure-property relationships that are crucial to understanding how to consistently print high quality metal parts. We investigate the effects of build plate temperature, infill pattern, and track raster rate on the macro- and microstructure, density, hardness, and tensile strength of metal parts created with our custom droplet-on-demand setup using pure tin feedstock as a surrogate for more relevant structural materials. We found that although the build plate temperature had the largest influence on the structure and properties, the infill pattern is an important factor for optimal structural integrity. It was observed that the track raster rate influenced track-to-track porosity and should be considered in toolpath development. Despite printing in ambient air, we could not identify oxide on the surface or in the bulk of the parts and saw no adverse effects on microstructure or tensile performance. The results and methods of this study will help guide future work in optimizing the liquid metal jetting process to reliably print parts using any liquid metal jetting system for a wide variety of metal feedstocks.

36 MATERIALS SCIENCE↗

Characterization of plasma catalytic decomposition of methane: role of atomic O and reaction mechanism

In this work, we investigated atmospheric pressure plasma jet (APPJ)-assisted methane oxidation over a Ni-SiO 2 /Al 2 O 3 catalyst. We evaluated possible reaction mechanisms by analyzing the correlation of gas phase, surface and plasma-produced species. Plasma feed gas compositions, plasma powers, and catalyst temperatures were varied to expand the experimental parameters. Real-time Fourier-transform infrared spectroscopy was applied to quantify gas phase species from the reactions. The reactive incident fluxes generated by plasma were measured by molecular beam mass spectroscopy using an identical APPJ operating at the same conditions. A strong correlation of the quantified fluxes of plasma-produced atomic oxygen with that of CH 4 consumption, and CO and CO 2 formation implies that O atoms play an essential role in CH 4 oxidation for the investigated conditions. With the integration of APPJ, the apparent activation energy was lowered and a synergistic effect of 30% was observed. We also performed in-situ diffuse reflectance infrared Fourier-transform spectroscopy to analyze the catalyst surface. The surface analysis showed that surface CO abundance mirrored the surface coverage of CH n at 25 °C. This suggests that CH n adsorbed on the catalyst surface as an intermediate species that was subsequently transformed into surface CO. We observed very little surface CH n absorbance at 500 °C, while a ten-fold increase of surface CO and stronger CO 2 absorption were seen. This indicates that for a nickel catalyst at 500 °C, the dissociation of CH 4 to CHn may be the rate-determining step in the plasma-assisted CH 4 oxidation for our conditions. We also found the CO vibrational frequency changes from 2143 cm –1 for gas phase CO to 2196 cm –1 for CO on a 25 °C catalyst surface, whereas the frequency of CO on a 500 °C catalyst was 2188 cm –1 . Here, the change in CO vibrational frequency may be related to the oxidation of the catalyst.

methane oxidation↗

Offshore wind energy forecasting sensitivity to sea surface temperature input in the Mid-Atlantic

Abstract. As offshore wind farm development expands, accurate wind resource forecasting over the ocean is needed. One important yet relatively unexplored aspect of offshore wind resource assessment is the role of sea surface temperature (SST). Models are generally forced with reanalysis data sets, which employ daily SST products. Compared with observations, significant variations in SSTs that occur on finer timescales are often not captured. Consequently, shorter-lived events such as sea breezes and low-level jets (among others), which are influenced by SSTs, may not be correctly represented in model results. The use of hourly SST products may improve the forecasting of these events. In this study, we examine the sensitivity of model output from the Weather Research and Forecasting model (WRF) 4.2.1 to different SST products. We first evaluate three different data sets: the Multiscale Ultrahigh Resolution (MUR25) SST analysis, a daily, 0.25∘ × 0.25∘ resolution product; the Operational Sea Surface Temperature and Ice Analysis (OSTIA), a daily, 0.054∘ × 0.054∘ resolution product; and SSTs from the Geostationary Operational Environmental Satellite 16 (GOES-16), an hourly, 0.02∘ × 0.02∘ resolution product. GOES-16 is not processed at the same level as OSTIA and MUR25; therefore, the product requires gap-filling using an interpolation method to create a complete map with no missing data points. OSTIA and GOES-16 SSTs validate markedly better against buoy observations than MUR25, so these two products are selected for use with model simulations, while MUR25 is at this point removed from consideration. We run the model for June and July of 2020 and find that for this time period, in the Mid-Atlantic, although OSTIA SSTs overall validate better against in situ observations taken via a buoy array in the area, the two products result in comparable hub-height (140 m) wind characterization performance on monthly timescales. Additionally, during hours-long flagged events (< 30 h each) that show statistically significant wind speed deviations between the two simulations, both simulations once again demonstrate similar validation performance (differences in bias, earth mover's distance, correlation, and root mean square error on the order of 10−1 or less), with GOES-16 winds validating nominally better than OSTIA winds. With a more refined GOES-16 product, which has been not only gap-filled but also assimilated with in situ SST measurements in the region, it is likely that hub-height winds characterized by GOES-16-informed simulations would definitively validate better than those informed by OSTIA SSTs.

17 WIND ENERGY↗

MHD modeling of shattered pellet injection in JET

Abstract Nonlinear 3D MHD simulations of shattered-pellet injection (SPI) in JET show prototypical SPI-driven disruptions using the M3D-C1 and NIMROD extended-MHD codes. Initially, radiation-driven thermal quenches are accelerated by MHD activity as the pellet crosses rational surfaces, leading to a radiation spike, global stochasticization of the magnetic field, and a complete thermal quench. Eventually, current quenches, preceded by a current spike are seen as the Ohmic heating becomes equal to the radiative cooling. The results are qualitatively similar for both a single monolithic pellet, pencil-beam model, and a realistic shatter to represent the SPI plume. A scan in viscosity from 500 to 2000 m 2 s −1 for MHD simulations finds that reducing viscosity increases MHD activity and decreases thermal quench time slightly. A realistic cloud of fragments modeling shows that mixed-D–Ne pellet travels deeper into the plasma core before the thermal quench. At the slow pellet speeds, the pellet is found to be moving slowly enough inward that even the 5% neon in the mixed pellet is enough to effectively radiate the thermal energy available. Radiation toroidal peaking is predicted to be at levels consistent with experimental observations and reduced as the pellet travels deeper into the plasma. These simulations lay the ground work for more-sophisticated validative and predictive modeling of SPI in JET using both M3D-C1 and NIMROD.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Robust Solar Receivers Using MAX Phase Materials

This work was supported by the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy under the Solar Energy Technologies Office Award Number 35928. The objective of the proposed effort was to develop and optimize additive manufacturing technologies for low-cost fabrication of high-temperature receivers using MAX phase-based materials (Ti 3 SiC 2 and Ti 3 AlC 2 ). MAX phase materials are a group of ternary metal carbides and nitrides where M stands for an early transition metal element, A is a group 13–16 element, and X is C and/or N. In Phase 1, the binder jetting additive manufacturing process was used to synthesize and characterize the Ti 3 SiC 2 MAX phase material. The typical process involved first producing a TiC preform using binder jetting followed by infiltration of the preform with silicon melt to form Ti 3 SiC 2 in situ. The reaction-infiltrated samples showed formation of MAX phase in the sample core; however, the surface showed cracking. Various process conditions—cooling rates, hold times, Si proportion, etc.—were varied to minimize the surface cracking. The fabricated MAX phase core was characterized by microstructure analysis and evaluations of mechanical properties such as hardness and thermal shock. In Phase 2, the focus included fabrication of Ti 3 SiC 2 MAX phase materials by spark plasma sintering (SPS) and synthesis of Ti 3 AlC 2 MAX phase materials by the Al melt infiltration process. It is expected that Al infiltration will not cause sample cracking, since Al does not expand during solidification. In addition, other processing approaches were investigated to fabricate the MAX phase materials, such as SPS with a graphite bedding approach for producing short-length Ti 3 AlC 2 MAX phase tubes for demonstration of prototypical Concentrating Solar Power receiver tubes. Fabricated samples underwent thermo-mechanical testing to validate the materials for the solar receiver application at temperatures >1000°C. In Phase 3, the effort focused on the development and optimization of the Ti-Al-C MAX phase composite material using the Al melt infiltration approach. We started with optimization of precursor powders and making preform structures by either pressing them in a die or using the binder jetting additive manufacturing process followed by Al melt infiltration. In addition, we investigated the formation of preform structures by cold isostatic pressing followed by Al melt infiltration for making Ti-Al-C MAX phase composite. Thermo-mechanical characterizations, such as creep, strength, and thermal shock, were conducted to establish the structures’ performance.

36 MATERIALS SCIENCE↗

Large-eddy simulation of an atmospheric bore and associated gravity wave effects on wind farm performance in the southern Great Plains

Gravity waves are a common occurrence in the atmosphere, with a variety of generation mechanisms. Their impact on wind farms has only recently gained attention, with most studies focused on wind farm-induced gravity waves. In this study, the interaction between a wind farm and gravity waves generated by an atmospheric bore event is assessed using multiscale large-eddy simulations. The atmospheric bore is created by a thunderstorm downdraft from a nocturnal mesoscale convective system (MCS). The associated gravity waves impact the wind resource and power production at a nearby wind farm during the American Wake Experiment (AWAKEN) in the US southern Great Plains. A two-domain nested setup (Δx=300 and 20 m) is used in the Weather Research and Forecasting (WRF) model, forced with data from the High-Resolution Rapid Refresh model, to capture both the formation of the bore and its interaction with individual wind turbines. The MCS is resolved on the large outer domain, where the structure of the bore and the associated gravity waves are found to be especially sensitive to parameterized microphysics processes. On the finer inner domain, gravity wave interactions with individual wind turbines are resolved; wake dynamics are captured using a generalized actuator disk parameterization in WRF. The gravity waves are found to have a strong effect on the atmosphere above the wind farm; however, the effect of the waves is more nuanced closer to the surface where there is additional turbulence, both ambient and wake-generated. Notably, the gravity waves modulate the mesoscale environment by weakening and dissipating the preexisting low-level jet, which reduces hub-height wind speed and hence the simulated power output, which is confirmed by the observed supervisory control and data acquisition (SCADA) power data. Additionally, the gravity waves induce local wind direction variations correlated with fluctuations in pressure, which lead to fluctuations in the simulated power output as various turbines within the farm are subjected to waking from nearby turbines.

17 WIND ENERGY↗

A numerical study of an atomizing jet in a resonant acoustic field

By applying state-of-the-art, high-fidelity methods for compressible multiphase flows, this work features a parametric study of a turbulent liquid jet atomizing under the influence of standing acoustic waves with five different amplitude values. We perform these simulations in a semi-periodic domain to isolate interactions between acoustic and atomization processes and to emulate a pure liquid fuel spray placed at the pressure node of a resonant acoustic field. Characterization of the flow includes measurements of the mean dimensions, droplet number, and surface area of the liquid distribution, alongside qualitative depictions of the interface evolution, breakup events, and hydrodynamic fields. As acoustic forcing is provided to the flow, the added energy provokes atomization when shear would otherwise be insufficient for breakup. The magnitude of the forcing determines the rate of droplet production, which accelerates as the evolving liquid surface modifies the induced motion of the gas phase. At the nodal plane, the acoustic field produces an organizing effect on the liquid structures.

42 ENGINEERING↗

Winter Warming in North America Induced by Urbanization in China

Rapid urbanization in China in the past several decades has been shown to affect surface air temperature (SAT) locally, but its global impact is unclear. Using a global climate model, we have investigated the potential impact of urbanization in China on SAT at the global scale. The expansion of urban areas in China from 1985 to 2017 leads to winter surface air warming by as much as 0.8°C in North America (NA), largely caused by warm temperature advection due to global-scale atmospheric circulation changes. The East Asian jet stream moves northward in eastern and northeastern China where the expansion of urban areas has increased SAT and sensible heat flux, forcing change of the atmospheric stationary waves and so the structure of the jet streams.

54 ENVIRONMENTAL SCIENCES↗

Characterization of wind speed and directional shear at the AWAKEN field campaign site

The American wake experiment (AWAKEN) is taking place in northern Oklahoma, USA, close to the Atmospheric Radiation Measurement Southern Great Plains (ARM SGP) atmospheric observatory. The planning for the deployment of the instruments in this observational field campaign required an assessment of the wind characteristics of the site. This paper analyzes long-term data collected by instruments at the ARM SGP observatory to characterize the winds near the AWAKEN site. The analysis shows that this site experiences high wind shear and veer events with a large number of nocturnal low-level jets. A total of 7086 low-level jet wind profiles over 6 years are examined and found to be dominant from the south and southeast. Significant nocturnal wind veer is observed, which causes southerly wind near the surface to become westerly wind aloft. By identifying a strong relationship between atmospheric stability and wind shear, the wind shear at the site is predicted using the Monin–Obukhov similarity theory (MOST) and validated with the observational data collected by a scanning Doppler lidar. The results show that wind speed at a height of 91 m, a proxy hub height for wind turbines in this area, can be predicted from data collected at a height of 10 m with a bias of −0.35 and 0.65 m s−1 in unstable and stable atmospheric boundary layers, respectively. The bias of the predicted wind speed is mostly in the region of low wind speed, and wind speed above 5 m s−1 at a height of 91 m can be predicted with a bias of less than 0.2 m s−1, and the limitations of the MOST in predicting winds during the stably stratified boundary layer is well-observed.

17 WIND ENERGY↗

Bulk Motions in the Black Hole Jet Sheath as a Candidate for the Comptonizing Corona

Abstract Using two-dimensional general relativistic resistive magnetohydrodynamic simulations, we investigate the properties of the sheath separating the black hole jet from the surrounding medium. We find that the electromagnetic power flowing through the jet sheath is comparable to the overall accretion power of the black hole. The sheath is an important site of energy dissipation as revealed by the copious appearance of reconnection layers and plasmoid chains. About 20% of the sheath power is dissipated between 2 and 10 gravitational radii. The plasma in the dissipative sheath moves along a nearly paraboloidal surface with transrelativistic bulk motions dominated by the radial component, whose dimensionless 4-velocity is ∼1.2 ± 0.5. In the frame moving with the mean (radially dependent) velocity, the distribution of stochastic bulk motions resembles a Maxwellian with an “effective bulk temperature” of ∼100 keV. Scaling the global simulation to Cygnus X-1 parameters gives a rough estimate of the Thomson optical depth across the jet sheath, ∼0.01–0.1, and it may increase in future magnetohydrodynamic simulations with self-consistent radiative losses. These properties suggest that the dissipative jet sheath may be a viable “coronal” region, capable of upscattering seed soft photons into a hard, nonthermal tail, as seen during the hard states of X-ray binaries and active galactic nuclei.

Sridhar, Navin (ORCID:0000000255199550)↗

Predicting sintering window during supersolidus liquid phase sintering of steels using feedstock analysis and CALPHAD

Binder jet 3D printing results in carbon pickup from the binder at the inter-particle regions during binder burnout. The excess carbon lowers the solidus temperature of the green part locally during supersolidus liquid phase sintering (SLPS). Currently, thermodynamic calculations rely on the use of bulk powder compositions to predict the sintering window. This can overestimate the sintering temperature since the local increase in carbon on powder surfaces is not accounted for, that can locally lower the solidus temperature during SLPS. Here we show that using the inputs from feedstock and binder analysis, the excess carbon and hence the sintering window for the alloy can be predicted using CALPHAD. We present a case study on applying the proposed approach for pressureless sintering of binder jet additive manufactured (BJAM) of H13 steel via SLPS.

36 MATERIALS SCIENCE↗

Dynamic focusing of laser driven positron jets by self-generated fields

Abstract Focusing effect of laser-driven positron jets by self-generated target sheath fields has been observed for the first time experimentally and the results are supported by the computational studies. In the experiment, OMEGA EP short-pulse (0.7 ps, 500 J) irradiates mm-size gold targets with a concave back surface and reference flat-surface targets. Both targets exhibited positrons with quasi-monoenergetic energy peaks while targets with concave curvature also showed increased number of positrons at the detector. The data is consistent with hybrid-PIC simulations confirming that the time-varying electric fields driven by electrons escaping from the target significantly change the trajectories of positrons. These simulations show a small radius of curvature on the rear side increases the relative focusing effect and the positrons to electrons ratio in the escaping plasma. For the smallest radius of curvature, positron jets that are up to 10 times denser can be achieved.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Damage to Polystyrene Polymer Film by Shock Wave Induced Bubble Collapse

Metallic surfaces that are in contact with solutions are commonly used in numerous applications where these surfaces can be damaged by shock wave induced bubble collapse. Use of polymer films that coat such surfaces to prevent them from damage requires a better understanding of how much harm collapsing bubbles produce in the films. In this study, we report the results from coarse-grained molecular dynamics simulations to study the damage to polystyrene (PS) films coating a hard surface. The damage was caused by a collapsing nanobubble located in the proximity of the film and interacting with an impinging shock wave. This collapse produces a high-speed water jet that impacts the PS film with a greater force than the shock front and creates cavities/pits in the PS film. We observed that polymer molecules located in the jet vicinity undergo conformational extension in the direction perpendicular to the jet motion, while chain molecules in the rest of the film undergo compression. Furthermore, we also observed that damage to the film is sensitive to the strength of the shock wave.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evaluating Transfer and Pumping of Slurries from Pulsed Jet Mixed Vessels

Due to gravity, solids in slurries will settle if density differences between the solids and liquid are positive (i.e., particle has a negative buoyant force) unless rheological properties and flow conditions are adequate to overcome the gravitational effects. The rate of settling depends on the force balance of the particle, which includes the surface forces associated with fluid rheology. Given the same fluid and solid properties, particles that are larger and denser tend to settle faster. When pumping slurry into a vessel at concentrations precluding hindered settling with insufficient mixing, particle and density distributions can result in preferential settling, creating stratification in the solids concentration within the vessel. For vessels with transfer line inlets located in the lower portion of the tank, the stratified solids concentration may be detrimental to the transfer system performance. Elevated concentrations of solids in the slurry entrained at the inlet to the transfer line can result in the effective viscosity or slurry bulk density exceeding the design limits of the pump. These conditions could result in plugging of the transfer line or onset of cavitation of the pumps because of excessive pressure drop. These conditions can be exacerbated with periodic inlet conditions existing at the transfer line inlet. Periodic conditions can result when vessel mixing is intermittent such as with pulsed jet mixers (PJM). The transfer line inlet conditions are impacted by the periodic nature of the PJM operations with respect to suspension of solids and their transport to the inlet of the transfer line. A scaling approach is presented, and corresponding test requirements are developed for assessing the prevention of plugging the pipeline. Line plugging mechanisms are addressed that do not include plugging due to steady-state high-density slurry entering the transfer line and reducing the net positive suction head available (NPSHA) at the pump inlet to below that required for pump operation. Items considered include the transition to reduced relative flow velocities, such that the critical pipe velocity for solids deposition, Ucd, is not maintained, and segregation of heavy solids during the transport. The recommended requirements to prevent plugging include: • Limits for viscosity and density for entrained slurry to prevent the pressure drop in the pipeline from exceeding pump capacity. • Limits for viscosity and density for entrained slurry to prevent the net positive suction head available (NPSHA) from falling below the net positive suction head required (NPSHR) for operating the pump. • Transfer line velocity and flow rate requirements to maintain solids in suspension, while avoiding line plugging that results from deposition of solids within the transfer line. This paper describes the development of the scaling and testing requirements to verify that proposed approaches for transfer and pump out are appropriately developed

periodic flow, mixing, pipeline plugging, scaling,↗