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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

High Operating Temperature Midwave Quantum Dot Barrier Infrared Detector (QD-BIRD)

The nBn or XBn barrier infrared detector has the advantage of reduced dark current resulting from suppressed Shockley-Read-Hall (SRH) recombination and surface leakage. High performance detectors and focal plane arrays (FPAs) based on InAsSb absorber lattice matched to GaSb substrate, with a matching AlAsSb unipolar electron barrier, have been demonstrated. The band gap of lattice-matched InAsSb yields a detector cutoff wavelength of approximately 4.2 ??m when operating at ~150K. We report results on extending the cutoff wavelength of midwave barrier infrared detectors by incorporating self-assembled InSb quantum dots into the active area of the detector. Using this approach, we were able to extend the detector cutoff wavelength to ~6 ?m, allowing the coverage of the full midwave infrared (MWIR) transmission window. The quantum dot barrier infrared detector (QD-BIRD) shows infrared response at temperatures up to 225 K.

quantum dot↗
DOE OSTI2026

Near-Infrared Photoluminescence from Spin-Flip Excited States of π-Conjugated Tris(quinolinolate) Chromium(III) Complexes

Tuning metal–ligand covalency offers promising design strategies to tailor the photoluminescence (PL) emission energies of metal-centered, spin-flip excited states. Herein, we report a series of tris(quinolinolate) chromium(III) complexes that exhibit record-low near-infrared II emission energies in a fluid solution at room temperature, afforded by their strong metal–ligand covalencies. Appending π-conjugated arylethynyl substituents to quinolinolate ligands resulted in minimal changes to metal–ligand bond lengths, facilitating nearly indiscriminate metal–ligand covalencies for each tris(quinolinolate) chromium(III) complex. As a result, near-infrared II emission was observed across the series, while simultaneously affording careful tuning of the 4 LMCT/ 4 ( 1 ILCT) electronic transition energies across the visible region. Here, detailed analyses of ground-state electronic structures and excited-state electronic transitions revealed that PL arises from a ligand-field, 2 E excited state, admixed with charge-transfer character. This assignment was supported by solvent-dependent near-infrared emission energies and long excited-state lifetimes, consistent with spin-forbidden relaxation (ranging from 115 ± 5 to 123 ± 1 ns across the series). Utilizing spectroscopic data, ligand-field parameters were quantified, further rationalizing the role of strong metal–ligand covalency in enabling near-infrared II emission. Supported by these results, this study presents a new class of ligands that enable room-temperature near-infrared II emission in chromium(III)-based spin-flip excited states.

Absorption spectroscopy↗
DOE OSTI2024

Near-Infrared Optical Gain of Colloidal Quantum Wells via Intraband Transitions

Tunable, unipolar, near-infrared intraband optical gain is demonstrated in semiconductor colloidal quantum wells, expanding the form and optical range for potential infrared applications. Atomically flat colloidal quantum wells of cadmium selenide display photoinduced absorption features in the near-infrared assigned to intraband (alternatively intersubband) transitions from the first to second electron subbands of the quantum wells. Under ultraviolet optical excitation, these same transitions from the first to second electron subbands are shown to exhibit stimulated emission, resulting in optical gain covering the near-infrared spectral region. The modal gain, bandwidth, and lifetime of this intraband gain are manipulated by using excitation energy, fluence, temperature, and surface chemistry. Unlike previous demonstrations of intraband optical gain in epitaxial quantum wells (e.g., quantum cascade lasers), the colloidal quantum wells are undoped. As a result, nearly thresholdless gain is in principle possible and limited in practice by the measurement of small optical losses of the samples in the near-infrared. Furthermore, the observations may be understood as a modified "quantum fountain" employing the valence band, a strategy that may be applied to many other materials.

Optical gain↗
NASA NTRS2006

Quantum Well and Quantum Dot Modeling for Advanced Infrared Detectors and Focal Plane Arrays

This viewgraph presentation reviews the modeling of Quantum Well Infrared Detectors (QWIP) and Quantum Dot Infrared Detectors (QDIP) in the development of Focal Plane Arrays (FPA). The QWIP Detector being developed is a dual band detector. It is capable of running on two bands Long-Wave Infrared (LWIR) and Medium Wavelength Infrared (MWIR). The same large-format dual-band FPA technology can be applied to Quantum Dot Infrared Photodetector (QDIP) with no modification, once QDIP exceeds QWIP in single device performance. Details of the devices are reviewed.

quantum well↗
NASA NTRS2018

Infrared Spectra and Interstellar Sulfur: New Laboratory Results for H2S and Four Malodorous Thiol Ices

New infrared spectra are presented for H2S and four other sulfur-containing compounds, all thiols, at 10–140 K to aid in the study of interstellar and solar system ices. Infrared spectral changes on warming H2S and each thiol are described with an emphasis on the S–H stretching vibration at 2550–2525 cm(exp -1) (λ=3.92–3.96 μm) as it is in a relatively unobscured part of the infrared spectra of interstellar and planetary ices. Infrared positions and band strengths for each thiol’s S–H and C–H stretching vibrations are reported, along with the S–H band strength of H2S. Two band strengths of near-infrared features of CH3SH are included. Results for these compounds are compared, and some areas of agreement and disagreement with the literature are described.

Astrobiology↗
NASA NTRS2018

Infrared Spectra and Interstellar Sulfur: New Laboratory Results for H2S and Four Malodorous Thiol Ices

New infrared spectra are presented for H2S and four other sulfur-containing compounds, all thiols, at 10–140 K to aid in the study of interstellar and solar system ices. Infrared spectral changes on warming H2S and each thiol are described with an emphasis on the S–H stretching vibration at 2550–2525 cm(exp −1) (λ = 3.92–3.96 μm) as it is in a relatively unobscured part of the infrared spectra of interstellar and planetary ices. Infrared positions and band strengths for each thiol’s S–H and C–H stretching vibrations are reported, along with the S–H band strength of H2S. Two band strengths of near-infrared features of CH3SH are included. Results for these compounds are compared, and some areas of agreement and disagreement with the literature are described.

Astrochemistry; infrared: ISM; ISM: molecules; mol↗
NASA NTRS2018

Infrared Spectra and Interstellar Sulfur - New Laboratory Results for H2S and Four Malodorous Thiol Ices

New infrared spectra are presented for H2S and four other sulfur-containing compounds, all thiols, at 10–140 K to aid in the study of interstellar and solar system ices. Infrared spectral changes on warming H2S and each thiol are described with an emphasis on the S–H stretching vibration at 2550–2525 cm(exp −1) (λ = 3.92–3.96 μm) as it is in a relatively unobscured part of the infrared spectra of interstellar and planetary ices. Infrared positions and band strengths for each thiol’s S–H and C–H stretching vibrations are reported, along with the S–H band strength of H2S. Two band strengths of near-infrared features of CH3SH are included. Results for these compounds are compared, and some areas of agreement and disagreement with the literature are described.

Astrochemistry; infrared: ISM; ISM: molecules; mol↗
DOE OSTI2025

Quantitative infrared spectroscopy of aerosols: Mie theory modeling with experimental validation

Infrared spectroscopy is a well-established method for identifying solid, liquid, and gas-phase chemicals. Accurate infrared spectroscopic analysis requires reference libraries where library endmembers reflect all optical phenomena contributing to the observed spectra. Traditional spectral libraries most often contain molecular-based absorption spectra, but these do not account for the complex scattering effects that become significant when measuring aerosols. In this work, we combine the laboratory-derived, wavelength-dependent complex optical vectors ( n / k ) of liquid dioctyl sebacate (DOS) with Mie scattering theory and the Beer–Lambert law to generate synthetic infrared transmission spectra of aerosolized DOS. Additionally, we record experimental infrared transmission spectra using an FTIR spectrometer coupled to a simple aerosol chamber filled with a quantified number size distribution of aerosolized DOS. The modeled and measured spectra show strong agreement, with Mie scattering effects clearly altering the overall spectral shape as well as the positions and profiles of absorption features. The results demonstrate that synthetic spectra generated from n / k values can reliably capture aerosol-specific spectral behavior and thus serve as a foundation for building scalable, physics-based aerosol reference libraries to enable infrared spectroscopic detection of aerosols.

Salcido, Jessica M. O. [Pacific Northwest National↗
DOE OSTI2025

Infrared Cloud Imager Instrument Intercomparison Report

The Infrared Cloud Imager Instrument Intercomparison was a guest instrument deployment by NWB Sensors to the U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) User Facility observatory on the Southern Great Plains (SGP) between May 18 and December 12, 2023. NWB Sensors is a company that has developed a commercially available infrared cloud imager (ICI). The ICI provides radiometrically calibrated, full-sky images of the downwelling infrared radiance in the 7.3-14 µm band. In addition, it provides cloud radiance as the residual between the observed radiance and the modeled cloud-free radiance as well as derived cloud products. The instrument is used in applications that require consistent detection of clouds across day and night. For more information, consult the instrument's webpage. The primary goal of the deployment was to validate the radiometric accuracy of the ICI. The ICI uses a proprietary calibration method to convert the raw data from its infrared camera into downwelling radiance. Unlike similar instruments, the system does not have an onboard blackbody calibration standard. Instead, NWB Sensors characterizes each ICI camera individually in an environmental chamber while looking at a blackbody standard. The resulting (proprietary) calibration is used operationally in the instrument and has been demonstrated to be stable over long periods. To validate the radiometric products from the ICI, an intercomparison between the ICI data products and those from ARM’s atmospheric emitted radiance interferometer (AERI) was made. The AERI is a best-in-class instrument for measuring downwelling infrared radiance (Gero et al. 2025). A weighted integration of the AERI’s spectral radiances across the ICI’s camera response was performed. The resulting radiance (herein called the AERI radiance) was directly compared to the zenith radiance concurrently observed by the ICI. The results of these comparisons are reported in the next section of this report.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

The interaction of infrared radiation with the eye: A review of the literature

A compilation of data concerning the effects of infrared radiation on the eye is presented. Information in the following areas is included: (1) transmission and absorption of infrared radiation by the ocular tissues, (2) range of infrared radiation which is harmful to the ocular tissues, (3) infrared radiation thresholds of the various oscular tissues, and (4) infrared radiation transmission and absorption of current optic materials.

Turner, H. S.↗
NASA NTRS1974

Infrared stars in binary systems

The peculiar F-type supergiant HD 101584, which has a large and unusual infrared excess, is discussed along with the possibility that the infrared radiation could be accounted for by a cool companion. The peculiar F supergiants 89 Her, v Sgr, and R CrB are also considered as possible binary systems containing an infrared star. It is pointed out that all four of these stars have infrared excesses with characteristics similar to the infrared radiation from several cool objects which are known single stars.

Humphreys, R. M.↗
NASA NTRS1974

An infrared survey of RW Aurigae stars

An infrared photometric survey of 89 RW Aur type variables in both hemispheres has been made. JHKL magnitudes and colors are listed. The RW Aur variables include a small number of highly reddened late-type stars. All T Tauri and hot Orion population stars show infrared excesses and the infrared properties mark certain field stars as being young. The greatest infrared excesses are found for A and F stars while young variable B stars usually show no excesses. The location of the RW Aur stars in the two-color H-K, K-L diagram favor dust re-radiation over free-free emission as the mechanism responsible for the infrared excess. A weak correlation of H-K with emission class links the occurrence of circumstellar dust and gas shells.

Glass, I. S.↗
NASA NTRS1975

Radiative transfer in spherical circumstellar dust envelopes. II - Is the infrared continuum of eta Carinae produced by thermal dust emission

The radiative transfer techniques of Huang have been further extended in an attempt to construct a specific thermal dust-emission model of eta Carinae which fits the observations of both the spectral and the spatial distribution of the infrared radiation. The model which best fits the observations requires infrared emissivities considerably higher than those of normal-size nonsilicate grains. Evidence is presented that the high infrared emissivities are caused by large particles rather than a heavy concentration of infrared-active silicates. The possibility that synchrotron radiation is responsible for some of the infrared continuum is discussed.

Apruzese, J. P.↗
NASA NTRS1975

Synopsis of current satellite snow mapping techniques, with emphasis on the application of near-infrared data

The Skylab EREP S192 Multispectral Scanner data have provided for the first time an opportunity to examine the reflectance characteristics of snowcover in several spectral bands extending from the visible into the near-infrared spectral region. The analysis of the S192 imagery and digital tape data indicates a sharp drop in reflectance of snow in the near-infrared, with snow becoming essentially nonreflective in Bands 11 (1.55-1.75 micron) and 12 (2.10-2.35 micron). Two potential applications to snow mapping of measurements in the near-infrared spectral region are possible: (1) the use of a near-infrared band in conjunction with a visible band to distinguish automatically between snow and water droplet clouds; and (2) the use of one or more near-infrared bands to detect areas of melting snow.

Barnes, J. C.↗
NASA NTRS1977

A high-resolution far-infrared survey of the W31 region

A 1-m balloon-borne telescope was used to conduct a far-infrared survey of the W31 region at an effective wavelength of 69 microns with a resolution of 1 arcmin. Within this region seven far-infrared sources were observed. Five of these sources were associated with thermal radio emission. For each of these sources the infrared luminosity is much greater than the Ly-alpha luminosity, a situation requiring either dust absorption of Lyman-continuum photons or a large nonionizing stellar luminosity. Two faint infrared sources had no radio counterparts. Far-infrared radiation was not detected from two known radio sources and from one midinfrared source in this region.

Wright, E. L.↗
NASA NTRS1978

Far-infrared observations of H II regions near the galactic center

This paper presents and discusses far-infrared observations of nine H II regions within 1 deg of the galactic center, including Sgr A, Sgr B2, Sgr C, and G0.5-0.0. The far-infrared luminosity, color temperature, and optical depth of these regions and the ratio of infrared flux to radio-continuum flux lie in the range characteristic of spiral-arm H II regions. The far-infrared results are therefore consistent with the idea that the galactic-center H II regions are ionized by luminous early-type stars. Steep systematic gradients in far-infrared color temperature and optical depth are seen along the galactic plane between Sgr B2 and G0.5-0.0; the appearance of this area is similar to that of regions of star formation in the spiral arms.

Gatley, I.↗
NASA NTRS1979

A comparison of high resolution radio and far-infrared maps of M 17

New 3.5-cm radio and 69-micron far-infrared maps of M17, both made with an angular resolution of about 1.5 arcmin, are presented. Each map has three distinct maxima. Two of the maxima on the far-IR map agree in position with the corresponding maxima on the radio map. However, the positions of the brightest peak in the radio and far-infrared maps, located in the SW part of M17, differ by 4.6 + or - 2.2 s in right ascension and +44 + or - 20 sec in declination, with the far-infrared peak lying between the radio peak and the dense molecular cloud southwest of the H II region. It is believed that the positional offset of the radio and far-infrared peak is physically significant. The origin of the far-infrared radiation appears to be thermal emission from dust at the interface of the ionized gas and molecular cloud. This interface region is probably heated by radiation from the H II region.

Wilson, T. L.↗
NASA NTRS1979

An infrared study of the NGC 7538 region

Infrared observations of the NGC 7538 region at wavelengths from 1 micron to 1 mm are presented and analyzed with the aim of understanding both the large-scale structure of this region of current star formation and the properties of the individual compact objects within it. At far-infrared wavelengths (25-130 microns), emission is seen from the visible H II region, from the vicinity of the previously known maser sources and dust-embedded compact HII regions, and from a new region called NGC 7538(E). Coincident with NGC 7538(E) are a point-like 1-25 micron infrared source, NGC 7538-IRS9, which probably provides the power for the far-infrared emission, and an extended source of 2.2 micron emission which appears to be an infrared reflection nebula. The compact H II regions, the maser sources and IRS9 are located within a dense molecular cloud at the edge of the optical H II region. This cloud, which has a mass of approximately 9000 solar masses, is detected in emission at 1 mm. The NGC 7538 region appears to contain examples of different stages in the formation of massive stars; it is suggested that the center of star formation is moving systematically to the southeast in this region.

Werner, M. W.↗