Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Infrared”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Balloon-borne Infrared Telescope (BIRT) for far-infrared spectroscopy

The Japanese-made Balloon-borne Infrared Telescope (BIRT) designed for FIR astronomy is described. The BIRT system includes a 50-cm-diam telescope; an attitude-control system consisting of an attitude stabilization and a pointing and tracking subsystems; the ground support system consisting of four personal-computer systems; and electronics consisting of three small computer systems, servo circuits, power amplifiers, and other small circuits. Between 1985 and 1988, the BIRT has flown eight times, demonstrating that it is able to provide a suitable telescope observations on a stable platform with a long integration time. Structural diagrams of the BIRT overall system, the optical system, and the wobbling mechanism are presented along with a block diagram of the on-board electronics.

Shibai, Hiroshi↗
NASA NTRS1991

Infrared focal plane design for the Comet Rendezvous/Asteroid Flyby and Cassini Visible and Infrared Mapping Spectrometers

A focal plane assembly combining hybrid electronic components with passive optical components within a single hermetically sealed package has been designed by Cincinnati Electronics to meet the performance requirements imposed by the Comet Rendezvous/Asteroid Flyby (CRAF) and Cassini Visible and Infrared Mapping Spectrometers (VIMSs). A single line array of 256 InSb photodiodes, accessed by two 1 x 128 multiplexers, provides continuous spectral coverage from 0.85 to 5.1 microns. Intrinsic field-of-view apertures and a unique order sorting filter require critical optical alignment within the hybrid. FPA performance requirements, design approach, and critical issues are discussed.

Staller, Craig↗
NASA NTRS1994

Infrared observations of Comet Austin (1990 V) by the COBE/Diffuse Infrared Background Experiment

Comet Austin was observed by the Cosmic Background Explorer (COBE)/Diffuse Infrared Background Experiment (DIRBE) with broadband photometry at 1-240 micrometers during the comet's close passage by Earth in 1990 May. A 6 deg long (6 x 10(exp 6) km) dust tail was found at 12 and 25 micrometers, with detailed structure due to variations in particle properties and mass-loss rate. The spectrum of the central 42 x 42 sq arcmin pixel was found to agree with that of a graybody of temperature 309 +/- 5 K and optical depth 7.3 +/- 10(exp -8). Comparison with IUE and ground-based obervations indicates that particles of radius greater than 20 micrometers predominate by surface area. A mass-loss rate of 510 (+510/-205) kg/s and a total tail mass of 7 +/- 2 x 10(exp 10) kg was found for a model dust tail composed of Mie spheres with a differential particle mass distribution dn/d log m approx. m(exp -0.63) and 2:1 silicate:amorphous carbon composition by mass.

Lisse, C. M.↗
NASA NTRS1995

A far-infrared spectral line survey of 23 infrared-bright Galaxy nuclei

We present results from a KAO survey of fine-structure lines observed in 23 infrared-luminous galaxies. One or more of the following lines was observed and/or detected in each galaxy: (S III) 19, 33 microns, (Ne V) 24 microns, (O IV) 26 microns, (Fe II) 26 microns, (Si II) 35 microns, (O III) 52, 88 microns, (0 I) 63, 146 microns, (N III) 57 micro ns, (N II) 122, 205 microns, (C II) 158 microns. The galaxies span a wide range of morphologies (irregular to grand design), have varying metallicities, and include mergers, AGN's, and starburst systems. The observations were made beginning in 1988 using the facility Cryogenic Grating Spectrometer onboard the KAO at a typical resolution of approximately 60-140 km/s and with a 30-44 deg beam. We interpret the (C II) and (O I) fluxes, along with previous measurements of the IR continuum fluxes, in the context of photo dissociation region (PDR) models (Tielens & Hollenbach 1985; Wolfire et al. 1990). With these models, we obtain estimates of the typical interstellar UV fields incident on the line emitting regions (102-104 times the local interstellar radiation field) and the total masses (10(exp 7)-10(exp 8) Solar Mass), densities (10(exp 3)-10(exp 4)/cu cm), and temperatures (100-250 K) of the warm atomic gas. The (O III) (52/88) and (S III) (33/19) line flux ratios constrain the range of electron densities and pressures found within the ionized regions. The (O III) and (S III) lines also provide estimates of the effective temperature of the ionizing stars and elemental abundances within the ionized regions of these galactic nuclei. Our measurements imply typical gas pressures of nT approximately 5 x 10(exp 6)/cu cm K and typical upper mass cutoffs of 25-35 Solar Mass. The low-metallicity systems show high (C II)/CO and (O I)/CO flux ratios, 3-5 times the Milky Way value, indicating that they contain a larger fraction of photodissociated gas relative to the molecular material.

Lord, Steven D.↗
NASA NTRS1996

Spectral Irradiance Calibration in the Infrared: New Composite Spectra, Comparison with Model Atmospheres, and Far-Infrared Extrapolations - Part 7

We present five new absolutely calibrated continuous stellar spectra constructed as far as possible from spectral fragments observed from the ground, the Kuiper Airborne Observatory (KAO), and the IRAS Low Resolution Spectrometer. These stars-alpha Boo, gamma Dra, alpha Cet, gamma Cru, and mu UMa-augment our six, published, absolutely calibrated spectra of K and early-M giants. All spectra have a common calibration pedigree. A revised composite for alpha Boo has been constructed from higher quality spectral fragments than our previously published one. The spectrum of gamma Dra was created in direct response to the needs of instruments aboard the Infrared Space Observatory (ISO); this star's location near the north ecliptic pole renders it highly visible throughout the mission. We compare all our low-resolution composite spectra with Kurucz model atmospheres and find good agreement in shape, with the obvious exception of the SiO fundamental, still lacking in current grids of model atmospheres. The CO fundamental seems slightly too deep in these models, but this could reflect our use of generic models with solar metal abundances rather than models specific to the metallicities of the individual stars. Angular diameters derived from these spectra and models are in excellent agreement with the best observed diameters. The ratio of our adopted Sirius and Vega models is vindicated by spectral observations. We compare IRAS fluxes predicted from our cool stellar spectra with those observed and conclude that, at 12 and 25 microns, flux densities measured by IRAS should be revised downwards by about 4.1% and 5.7%, respectively, for consistency with our absolute calibration. We have provided extrapolated continuum versions of these spectra to 300 microns, in direct support of ISO (PHT and LWS instruments). These spectra are consistent with IRAS flux densities at 60 and 100 microns.

Cohen, Martin↗
NASA NTRS2002

Development of Infrared Phase Closure Capability in the Infrared-Optical Telescope Array (IOTA)

We completed all major fabrication and testing for the third telescope and phase-closure operation at the Infrared-Optical Telescope Array (IOTA) during this period. In particular we successfully tested the phase-closure operation, using a laboratory light source illuminating the full delay-line optical paths, and using an integrated-optic beam combiner coupled to our Picnic-detector camera. This demonstration is an important and near-final milestone achievement. As of this writing, however, several tasks yet remain, owing to development snags and weather, so the final proof of success, phase-closure observation of a star, is now expected to occur in early 2002, soon after this report has been submitted.

Traub, Wesley A.↗
NASA NTRS2004

Surveying Galaxy Evolution in the Far-Infrared: A Far-Infrared All-Sky Survey Concept

Half of the total luminosity in the Universe is emitted at rest wavelengths approximately 80-100 microns. At the highest known galaxy redshifts (z greater than or equal to 6) this energy is redshifted to approximately 600 microns. Quantifying the evolution of galaxies at these wavelengths is crucial to our understanding of the formation of structure in the Universe following the big bang. Surveying the whole sky will find the rare and unique objects, enabling follow-up observations. SIRCE, the Survey of Infrared Cosmic Evolution, is such a mission concept under study at NASA's Goddard Space Flight Center. A helium-cooled telescope with ultrasensitive detectors can image the whole sky to the confusion limit in 6 months. Multiple wavelength bands permit the extraction of photometric redshifts, while a large telescope yields a low confusion limit. We discuss the implications of such a survey for galaxy formation and evolution, large-scale structure, star formation, and the structure of interstellar dust.

Benford, D. J.↗
NASA NTRS2009

First Ground-Based Infrared Solar Absorption Measurements of Free Tropospheric Methanol (CH3OH): Multidecade Infrared Time Series from Kitt Peak (31.9 deg N 111.6 deg W): Trend, Seasonal Cycle, and Comparison with Previous Measurements

Atmospheric CH3OH (methanol) free tropospheric (2.09-14-km altitude) time series spanning 22 years has been analyzed on the basis of high-spectral resolution infrared solar absorption spectra of the strong n8 band recorded from the U.S. National Solar Observatory on Kitt Peak (latitude 31.9degN, 111.6degW, 2.09-km altitude) with a 1-m Fourier transform spectrometer (FTS). The measurements span October 1981 to December 2003 and are the first long time series of CH3OH measurements obtained from the ground. The results were analyzed with SFIT2 version 3.93 and show a factor of three variations with season, a maximum at the beginning of July, a winter minimum, and no statistically significant long-term trend over the measurement time span.

Rinsland, Curtis P.↗
NASA NTRS2009

First Ground-Based Infrared Solar Absorption Measurements of Free Tropospheric Methanol (CH3OH): Multidecade Infrared Time Series from Kitt Peak (31.9 deg N 111.6 deg W): Trend, Seasonal Cycle, and Comparison with Previous Measurements

Atmospheric CH3OH (methanol) free tropospheric (2.09-14-km altitude) time series spanning 22 years has been analyzed on the basis of high-spectral resolution infrared solar absorption spectra of the strong vs band recorded from the U.S. National Solar Observatory on Kitt Peak (latitude 31.9degN, 111.6degW, 2.09-km altitude) with a 1-m Fourier transform spectrometer (FTS). The measurements span October 1981 to December 2003 and are the first long time series of CH3OH measurements obtained from the ground. The results were analyzed with SFIT2 version 3.93 and show a factor of three variations with season, a maximum at the beginning of July, a winter minimum, and no statistically significant long-term trend over the measurement time span.

Rinsland, Curtis P.↗
NASA NTRS2019

Far-infrared room-temperature focal plane modules for polar radiant energy in the Far InfraRed experiment

This work presents focal plane modules for Polar Radiant Energy in the Far InfraRed Experiment, a passive remote-sensing instrument aimed to determine errors in the estimated outgoing longwave radiation in the Earth’s polar regions to reduce uncertainties in surface emissivity, mass balance, and ice flux. The focal plane arrays are micromachined at JPL and integrated into sub-assembly modules to be mounted on the optical telescope of the instrument.

White, Mary↗
DOE OSTI2018

Shortwave infrared fluorescence imaging with the clinically approved near-infrared dye indocyanine green

Significance Imaging in the shortwave IR (SWIR) spectral window allows the observation of processes deep within living animals. Recent studies have shown that SWIR imaging enables unprecedented imaging opportunities, including contact-free monitoring of vital signs, generation of microvasculature blood flow maps, real-time metabolic imaging, and molecularly targeted imaging. Yet, whereas bright SWIR fluorophores have been developed for preclinical research settings, applications in the clinic have been held back by the conventional belief that no clinically approved fluorophore is available. Here, we show that indocyanine green, a clinically approved near-IR dye, exhibits a remarkable amount of SWIR emission, which enables state-of-the-art SWIR imaging with direct translation potential into clinical settings, and even outperforms other commercially available SWIR emitters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

High-resolution infrared spectroscopy of the asymmetric NO stretch band of jet-cooled nitromethane and assignment of the lowest four torsional states

A high-throughput CW slit-jet apparatus coupled to a high-resolution FTIR was used to record the asymmetric NO stretch band of nitromethane. The b-type band, including torsionally excited states with m ≤ 3, has been assigned for Ka" ≤ 10, J" ≤ 20. The ground state combination differences derived from these assigned levels were fit with the RAM36 program to give an RMS deviation of 0.0006 cm-1. The band origin is 1583.0 (+/- 0.1) cm-1 and the torsional level spacing is nearly identical to that in the ground state. The upper state levels are split into multiplets by perturbations. A subset of the available upper state combination differences for m = 0, Ka' ≤ 7, J' ≤ 10 were fit with the same program, but with rather poorer precision (0.01 cm-1) than for the ground state.

Dawadi, Mahesh B.↗
DOE OSTI2020

Effect of initial γ -irradiation on infrared laser ablation of poly(vinyl alcohol) studied by infrared spectroscopy

We report the effect of initial γ-irradiation of poly(vinyl alcohol) (PVA) on the kinetics of polymer ablation under CO 2 laser irradiation was studied using infra-red spectroscopy. The rate of laser ablation rapidly decreases with increasing time of laser ablation up to 10 s. Initial γ-irradiation of a dose up to 100 kGy reduces the rate of the laser ablation, just like the effect of laser exposure. The number of OH and CH groups decrease in PVA both with laser irradiation and with γ-irradiation. The number of OH groups decreases more under laser irradiation. Unsaturated bonds are formed in γ–irradiated PVA on the surface of the crater formed by laser ablation of the polymer that has undergone radiolysis. Increasing the dose of initial γ-irradiation from 100 to 2300 kGy leads to an increase in the intensity of the IR bands of the unsaturated bonds. The number of IR bands in the spectra of the laser ablation crater of PVA does not change with the dose of initial γ-irradiation. A dose of radiolysis of 3500 kGy significantly changes the IR spectra of both the ablation crater and the coating formed from the ablation products. Many bands characteristic for PVA are no longer present and the intensities of bands corresponding to unsaturated bonds are increased. A computational model for loss of water and ketone formation was developed for PVA and PVA including a diol using G3(MP2). The highest activation energy barrier step in the decomposition reaction was formation of the enol species and water was shown to catalyze all decomposition steps.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Resolving the Impact of Hydrogen Bonding on the Phylloquinone Cofactor through Two-Dimensional Infrared Spectroscopy

Phylloquinone (PhQ) is a molecule involved in photosynthetic electron transfer, where the local protein environment is known to tune the properties of PhQ through various noncovalent interactions. In this work, we determine how hydrogen bonding, one of these noncovalent interactions, alters the vibrational potential energy surface of PhQ. In addition, this work demonstrates how hydrogen bonding to PhQ manifests in ultrafast multidimensional vibrational spectra, which is an important step towards using ultrafast vibrational based spectroscopies to probe PhQ embedded in the binding pocket of photosynthetic reaction centers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Near infrared laser annealing of CdTe and in-situ measurement of the evolution of structural and optical properties

The high performance of polycrystalline CdTe thin film solar cells is enabled by annealing in the presence of Cl. This process is typically carried out for tens of minutes resulting in reduction of defect states within the bandgap among other beneficial effects. In this work, we investigate laser annealing as a means of rapidly annealing CdTe using a continuous wave sub-bandgap 1064 nm laser. The partial transmission of the beam allows us to monitor the annealing process in-situ and in real time. We find that optoelectronic and structural changes occur through two distinct kinetic processes resulting in the removal of deep defects and twinned regions, respectively. A multilayer optical model including surface roughness is used to interpret both the in-situ transmission as well as ex-situ reflectivity measurements. These experiments demonstrate beneficial material changes resulting from sub-bandgap laser-driven CdCl{sub 2} treatment of CdTe in minutes, which is an important step towards accelerating the processing of the CdTe absorber layer.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗