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At least 235 records · Page 13

Durability and damage tolerance of Large Composite Primary Aircraft Structure (LCPAS)

Analysis and testing addressing the key technology areas of durability and damage tolerance were completed for wing surface panels. The wing of a fuel-efficient, 200-passenger commercial transport airplane for 1990 delivery was sized using graphite-epoxy materials. Coupons of various layups used in the wing sizing were tested in tension, compression, and spectrum fatigue with typical fastener penetrations. The compression strength after barely visible impact damage was determined from coupon and structural element tests. One current material system and one toughened system were evaluated by coupon testing. The results of the coupon and element tests were used to design three distinctly different compression panels meeting the strength, stiffness, and damage-tolerance requirements of the upper wing panels. These three concepts were tested with various amounts of damage ranging from barely visible impact to through-penetration. The results of this program provide the key technology data required to assess the durability and damage-tolerance capability or advanced composites for use in commercial aircraft wing panel structure.

Mccarty, John E.↗

eCC++ : A Compiler Construction Framework for Embedded Domain-Specific Languages

eCC++ is a new compiler construction framework for embedding domain-specific programming languages within C++. That is, the host language is C++, the guest language is the DSL to be embedded in C++, and eCC++ is the tool that enables the embedding. The eCC++ framework is composed of three main components: a front-end, an API for program verification based on a functional and declarative intermediate representation (IR), and a Multi-Level Intermediate Representation (MLIR) code generator. The eCC++ front-end consists of a library of C++ classes and operators that can be used to define the guest language. Guest sources are compiled with any standard C++ compiler, and when run, the resulting executable generates an eCC++ IR representation of the program, which can be verified within the eCC++ framework. Finally, eCC++ allows for high-level and domain-specific optimizations before generating MLIR. In summary, eCC++ aims to act as a generic front-end that enables embedding guest languages into C++, and provides necessary compiler technology for program verification, targeting the existing capabilities in the MLIR infrastructure. The paper evaluates the eCC++ expressiveness and usability describing the process of embedding GraphIt, a high-performance graph language in C++.

Gonzalez Tallada, Marc↗

Performance, Facility Pressure Effects, and Stability Characterization Tests of NASA's Hall Effect Rocket with Magnetic Shielding Thruster

NASA's Hall Effect Rocket with Magnetic Shielding (HERMeS) 12.5 kW Technology Demonstration Unit-1 (TDU-1) has been the subject of extensive technology maturation in preparation for flight system development. Part of the technology maturation effort included experimental evaluation of the TDU-1 thruster with conducting and dielectric front pole cover materials in two different electrical configurations. A graphite front magnetic pole cover thruster configuration with the thruster body electrically tied to cathode, and an alumina front pole cover thruster configuration with the thruster body floating were evaluated. Both configurations were also evaluated at different facility background pressure conditions to evaluate background pressure effects on thruster operation. Performance characterization tests found that higher thruster performance was attained with the graphite front pole cover configuration with the thruster electrically tied to cathode. A total thrust efficiency of 68% and a total specific impulse of 2,820 s was demonstrated at a discharge voltage of 600 V and a discharge power of 12.5 kW. Thruster stability regimes were characterized with respect to the thruster discharge current oscillations and with maps of the discharge current-voltage-magnetic field (IVB). Analysis of TDU-1 discharge current waveforms found that lower normalized discharge current peak-to-peak and root mean square magnitudes were attained when the thruster was electrically floated with alumina front pole covers. Background pressure effects characterization tests indicated that the thruster performance and stability were mostly invariant to changes in the facility background pressure for vacuum chamber pressure below 1×10-5 Torr-Xe (for thruster flow rates of 20.5 mg/s). Power spectral density analysis of the discharge current waveforms showed that increasing the vacuum chamber background pressure resulted in a higher discharge current dominant breathing mode frequency. Finally, IVB maps of the TDU-1 thruster indicated that the discharge current became more oscillatory with higher discharge current peak-to-peak and RMS values with increased facility background pressure at lower thruster mass flow rates; thruster operation at higher flow rates resulted in less change to the thruster's IVB characteristics with elevated background pressure.

Electric Propulsion↗

Performance, Facility Pressure Effects, and Stability Characterization Tests of NASA's Hall Effect Rocket with Magnetic Shielding Thruster

NASAs Hall Effect Rocket with Magnetic Shielding (HERMeS) 12.5 kW Technology Demonstration Unit-1 (TDU-1) Hall thruster has been the subject of extensive technology maturation in preparation for flight system development. Part of the technology maturation effort included experimental evaluation of the TDU-1 thruster with conducting and dielectric front pole cover materials in two different electrical configurations. A graphite front pole cover thruster configuration with the thruster body electrically tied to cathode and an alumina front pole cover thruster configuration with the thruster body floating were evaluated. Both configurations were also evaluated at different facility background pressure conditions to evaluate background pressure effects on thruster operation. Performance characterization tests found that higher thruster performance was attained with the graphite front pole cover configuration with the thruster electrically tied to cathode. A total thrust efficiency of 68 and a total specific impulse of 2,820 s was demonstrated at a discharge voltage of 600 V and a discharge power of 12.5 kW. Thruster stability regimes were characterized with respect to the thruster discharge current oscillations and with maps of the current-voltage-magnetic field (IVB). Analysis of TDU-1 discharge current waveforms found that lower normalized discharge current peak-to-peak and root mean square magnitudes were attained when the thruster was electrically floated with alumina front pole covers. Background pressure effects characterization tests indicated that the thruster performance and stability was mostly invariant to changes in the facility background pressure for vacuum chamber pressure below 110-5 Torr-Xe (for thruster flow rate above 8 mgs). Power spectral density analysis of the discharge current waveform showed that increasing the vacuum chamber background pressure resulted in a higher discharge current dominant frequency. Finally the IVB maps of the TDU-1 thruster taken at elevated magnetic fields indicated that the discharge current became more oscillatory with increased facility background pressure at lower thruster mass flow rates, where thruster operation at higher flow rates resulted in less change to the thrusters IVB characteristics.

Hall Thrusters↗

Energy Transitions: Local Water Concerns and Climate Impacts

This report summarizes important nuances in local water concerns and potential climate impacts that could influence the roll-out of technologies associated with energy transitions. Current investments in clean energy technologies are very high, which is driving a lot of investments in related manufacturing (i.e., hydrogen, solar, wind, and batteries) and mining (e.g., lithium, copper, and graphite) around the world. To understand how water and climate dynamics could be influencing these activities, we conducted a phased literature review for three countries: China, Germany, and France. China was selected due to its global dominance in manufacturing of solar panels, batteries, and electrolyzers as well as production of rare earth elements while Germany and France were selected due to their emerging leadership in energy transitions-related manufacturing within the European Union. For each of these three nations, we identified areas where manufacturing is occurring within the country and then evaluated relevant water resources and climate impacts. Multiple sources were consulted for this review, including BloombergNEF, international reports, industry sources, peer-reviewed literature, climate data, and media coverage.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Progress in composite structure and space construction systems technology

The development of deployable and fabricated composite trusses for large space structures by NASA and private industry is reviewed. Composite materials technology is discussed with a view toward fabrication processes and the characteristics of finished truss beams. Advances in roll-forming open section caps from graphite-composite strip material and new ultrasonic welding techniques are outlined. Vacuum- and gravity-effect test results show that the ultrasonic welding of graphite-thermoplastic materials in space is feasible. The structural characteristics of a prototype truss segment are presented. A new deployable graphite-composite truss with high packaging density for broad application to large space platforms is described.

Bodle, J. B.↗

Graphitization of banana peel – synergistic effect of Ca and other elements of the biomass on carbon structure transformation

Recently, growing interest has been observed in using calcium as an effective catalyst for graphitizing disordered carbon materials derived from biomass and bioprecursors, such as cellulose and lignin, at relatively low tem peratures (<2000 °C). Herein, it is demonstrated that in the presence of elements such as calcium, silicon, sulfur, and potassium, which are abundant in banana peel composed of cellulose and lignin base, graphitization occurs much more effectively. The addition of external calcium source, in the form of calcium carbonate, to the banana peel-derived carbon and heat-treatment of the mixture under protective atmosphere up to 1750 °C results in a significant increase in the degree of the graphitization order and local formation of graphite crystals, whereas the same preparation and heat-treatment procedure applied to carbon material derived from pristine cellulose does not lead to such effective graphitization. It is indicated that the graphitization of banana peel carbon occurs due to the synergistic effect of the external Ca-based catalyst and the internal elements present in the raw biomass, supporting the transformation of the disordered graphene-like layers into graphitic structures. These findings are important for the future production of green graphite from biomass

09 BIOMASS FUELS↗

Antenna Technology for QUASAT application

A hybrid growth version of the advanced Sunflower, or precision deployable, antenna was adopted as the configuration proposed for the QUASAT very long baseline interferometry mission. The antenna consists of rigid panels of graphite-epoxy facesheets covering aluminum honeycomb sandwich. The six main folding panels are hinged to a cantilevered support ring attached to the periphery of the center section. Six pairs of intermediate panels are located between these panels and are hinged to each other and to the main panels. The flight configuration, antenna weight, a mass properties, frequency, and contour tolerance are discussed. The advantages of the solid antenna surface cover an all-mesh contour are examined.

Archer, J. S.↗

You can't eat moon rocks

The effects produced by the aerospace program are investigated. The technology developed from aerospace-related research, development, and manufacturing has been made available to the public for its use through the NASA Technology Utilization Program. A description is presented of 'spinoffs' of NASA's aerospace programs which are used on a daily basis by the public. Attention is given to the liquid cooled garment technology, meal systems for the elderly, the zinc-rich coating, the emergency blanket, the flexible urethane foam Temper Foam, the 'Fog-Away Coating', and composite graphite equipment.

Kubokawa, C. C.↗

Graphite crystals in catalytically-graphitized glass-like carbon

Catalytic graphitization of glass-like carbon leads to enhanced growth of micro-sized graphitic crystals with unusual shapes of wires, filaments, tubes, rods, whiskers, and spirals. Similar particles with axial symmetry are also found in pure glass-like carbon heat-treated at high temperatures. Nonetheless, the presence of a graphitization catalyst, Si in this case, in the heat-treatment process supports the transformation of porous, disordered carbon structure towards the graphitic atomic order and the formation of manifold peculiar polyhedral wires and particles of geometry distinct from the plate-like shape typical for conventional graphite. In contrast to conventional carbon nanotubes and fibers, the graphene layers are stacked perpendicular to the tube axis, while the size of the most common tube fibers can reach up to 10 μm in diameter and 100 μm in length. X-ray diffraction, Raman spectroscopy, scanning and transmission electron microscopy, small-angle X-ray scattering combined with complementary techniques have been used to characterize the structure of the glass-like carbon derived from furfuryl alcohol catalytically-graphitized using Si particles at 3000 °C. Finally, since control of graphite shape is vital to achieving the level of performance required in contemporary applications, the obtained results demonstrate that the catalytic graphitization method may be employed to produce filamentous graphite crystals.

36 MATERIALS SCIENCE↗

Filament-wound composite vessels material technology

Programs are reviewed that were conducted to establish a technology base for applying advanced fibers or resins to high performance filament-wound pressure vessels for containment of cryogens and high pressure gases. Materials evaluated included boron, graphite, PRD 49-1 and 3/epoxy and S-glass/polyimide composites. Closed-end cylindrical, and oblate spheroid-shaped vessels were fabricated in 4- and 8-inch diameter sizes. Vessels were subjected to single-cycle burst, low-cycle fatigue, and sustained loading tests over a -423 F to room temperature range for epoxy composites and a -423 to 500 F temperature range for the polyimide composites. Vessels tested at cryogenic and/or 500 F had thin (3 to 20 mils) metallic liners whereas vessels tested at room temperature had elastomeric liners. Correlations between acoustic emissions and burst and cyclic properties of PRD 49-1 filament-wound vessels are discussed.

Lark, R. F.↗

Resin/graphite fiber composites

Processing techniques were developed for the fabrication of both polyphenylquinoxaline and polyimide composites by the in situ polymerization of monomeric reactants directly on the graphite reinforcing fibers, rather than using previously prepared prepolymer varnishes. Void-free polyphenylquinoxaline composites were fabricated and evaluated for room and elevated flexure and shear properties. The technology of the polyimide system was advanced to the point where the material is ready for commercial exploitation. A reproducible processing cycle free of operator judgment factors was developed for fabrication of void-free composites exhibiting excellent mechanical properties and a long time isothermal life in the range of 288 C to 316 C. The effects of monomer reactant stoichiometry and process modification on resin flow were investigated. Demonstration of the utility and quality of this polyimide system was provided through the successful fabrication and evaluation of four complex high tip speed fan blades.

Cavano, P. J.↗

Design aspects of the XV-15 advanced technology blade program

The paper discusses the design of a tiltrotor blade for application to the XV-15 research demonstration aircraft. The design features 43 deg nonlinear twist and nonuniform tapered planform. The structure is composite with extensive use of graphite in the primary structure. Instrumentation and wiring is encapsulated in the composite structure during the cure cycle. The tip shell is removable, providing access to the tracking and balance weights. This feature provides research facility of alternate tip configurations. The cuff is similarly removable. The graphite epoxy system used is high strain American Cyanamid's Celion 6000ST/Cycom 950. This is the first application of this material in rotor blades.

Smith, K. E.↗

AGR-1, AGR-2, AGR-3/4, and AGR-5/6/7 DimensionalChange Analysis

A series of fuel irradiation experiments have been planned in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) to support the licensing and operation of the Advanced Reactor Technologies high temperature gas-cooled reactor. The advanced gas reactor (AGR) experiments are comprised of multiple independent capsules containing multiple cylindrical fuel compacts, placed inside of a graphite cylinder in ATR. The purpose of the AGR experiments is to provide data on fuel performance under irradiation, support fuel process development, qualify the fuel for normal operating conditions, provide irradiated fuel for accident testing, and support the development of fuel performance and fission product transport models. The advanced graphite creep (AGC) experiments provide irradiation creep data for design and licensing. To date, six irradiation campaigns have been completed: AGR-1 (December, 2006 – November, 2009); AGR-2 (June, 2010 – October, 2013); AGR-3/4 (December, 2011 – April, 2014); AGC-1 (September, 2009 – January, 2011); AGC-2 (April, 2011 – May, 2012); and AGC-3 (November, 2012 – April, 2014).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Structure and spectroscopy of graphite monofluoride

The structure of graphite monofluoride, (CF) n , has been debated since its discovery in 1934. In this work, we investigate a commercial graphite monofluoride by vibrational spectroscopy (infrared, Raman and the first inelastic neutron scattering spectra of this material). The spectroscopy shows that the material contains unreacted graphite and the partially fluorinated product dicarbon fluoride, (C 2 F) n , We evaluate the previously proposed $P\bar{6}m2$ and $P\bar{3}m1$ structures using computational methods and find F···F contacts render the $P\bar{6}m2$ structure dynamically unstable. We propose two alternative structures, $Cmc2_1$ $P6_3mc$, generated by displacement of one layer relative to another and find that $Cmc2_1$ is also dynamically unstable. The calculations are validated by comparison of calculated and observed INS spectra

Density functional theory↗

Developing a Facile Technology for Converting Domestic US Coal into High-Value Graphene

Universal Matter Ltd. was formed in July 2019 to scale-up and commercialize a breakthrough process, Flash Joule Heating (FJH), to transform different coal grades, into high-quality graphene. This graphene is made using a high-voltage electric discharge that brings the carbon source to temperatures higher than 3,000 K in less than 10 milliseconds. The short burst of electricity breaks all chemical bonds in the feedstock and reorders the carbon atoms into exceptionally thin layers of a special type of graphene, at an estimated $100 per ton in electricity cost. This process is capable of producing 1-5 layer-thick high-quality graphene (with defects of <0.05% and purity of >99%) in a green, practical, and cost-effective process. The graphene produced in the FJH process is a very special kind of graphene called “turbostratic graphene” (TG). TG offers superior physical properties compared to other graphene structures on a similar weight basis. Unlike graphene made from graphite using traditional techniques, the graphene layers in TG stack in an irregular pattern that allows the graphene powder to be exfoliated more easily and blend more evenly within other materials. The TG produced using our FJH technology is the most economical graphene product that opens up significant large volume markets for end-use applications; it would allow the use of TG made from coal for commercial applications in several market segments including energy storage, sensors, hyper-lubricants, reinforced plastics, and building materials such as concrete.

01 COAL, LIGNITE, AND PEAT↗