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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Stacked Greenfield and Brownfield ROZ Fairways in the Illinois Basin Geo-Laboratory: Co-Optimization of EOR and Associated CO 2 Storage

Residual oil zones (ROZs) are economically viable targets for carbon dioxide enhanced oil recovery (CO 2 -EOR); thick, carbonate ROZs in the San Andres Formation in the Wasson Field of the Permian Basin are an example. Incremental oil produced from CO 2 -EOR can be carbon negative via associated storage of injected CO 2 . Given the regional extent of ROZ fairways and generally higher net utilization of CO 2 (compared to conventional CO 2 -EOR), ROZs provide the opportunity for significant carbon neutral to carbon negative oil production with associated CO 2 storage, and therefore should be a priority target for exploration. However, ROZs have not been widely recognized or identified due to poor or no conventional oil production. Hence, in places like the Illinois Basin (ILB), exploratory analyses are required to recognize the existence of an ROZ. As part of this study, four formations were selected for detailed regional characterization and analysis: Carper Sandstone (part of the Borden Siltstone), Tar Springs Sandstone, Cypress Sandstone, and Middle Devonian (Geneva Dolomite and associated Dutch Creek Sandstone). The four formations underwent regional geological characterization to develop a regional geologic framework for the ROZs and their overlying seals. Findings of this study are supported by data from two field laboratory sites, one with stacked greenfield ROZs and the other with a stacked complex that includes a brownfield ROZ and depleted conventional reservoirs. The field laboratory sites were used to collect data and conduct tests to validate ROZ detection methodologies and identify economic field-deployable strategies to co-optimize CO 2 -EOR and associated storage in stacked ROZs. Findings from these field sites were extrapolated to characterize the basin-wide stacked ROZ fairway resource.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2024

Cyclic loading-unloading impacts on salt cavern stability: Implication for underground hydrogen storage

Underground caverns in salt formations are promising geologic features to store hydrogen (H2) because of salt’s extremely low permeability and self-healing behavior. Successful salt-cavern H2 storage schemes must maximize the efficiency of cyclic injection-production while minimizing H2 loss through adjacent damaged salt. The salt cavern storage community, however, has not fully understood the geomechanical behaviors of salt rocks driven by quick operation cycles of H2 injection-production, whic

Chang, Kyung Won↗
NASA NTRS1973

Botryococcene - A tetramethylated acyclic triterpenoid of algal origin

The green alga Botryococcus braunii, implicated in the formation of certain geological deposits, produces unusual isomeric C34H58 alkenes, botryococcene and isobotryococcene, during a particular physiological state. A structure for botryococcene is suggested, taking into account NMR techniques, oxidative degradation, and established biosynthetic principles. Botryococcene appears terpenoid in origin.

Cox, R. E.↗
NASA NTRS1987

The 1989 Magellan mission to Venus

The primary objective of the Magellan mission is to provide the needed topographical data at resolutions and coverages adequate to shed light on the geological history and formation of Venus. Altimetry and gravity experiments are also planned. The Magellan mission consists of the launch phase, the cruise phase, the Venus orbit insertion, and mapping. The prospective launch vehicle is the Shuttle 'Atlantis' with an IUS upper stage.

Brown, Charles D.↗
NASA NTRS2005

A High-Sensitivity Broad-Band Seismic Sensor for Shallow Seismic Sounding of the Lunar Regolith

The recently undertaken Space Exploration Initiative has prompted a renewed interest in techniques for characterizing the surface and shallow subsurface (0-10s of meters depth) of the Moon. There are several reasons for this: First, there is an intrinsic scientific interest in the subsurface structure. For example the stratigraphy, depth to bedrock, density/porosity, and block size distribution all have implications for the formation of, and geological processes affecting the surface, such as sequential crater ejecta deposition, impact gardening, and seismic settling. In some permanently shadowed craters there may be ice deposits just below the surface. Second, the geotechnical properties of the lunar surface layers are of keen interest to future mission planners. Regolith thickness, strength, density, grain size and compaction will affect construction of exploration infrastructure in terms of foundation strength and stability, ease of excavation, radiation shielding effectiveness, as well as raw material handling and processing techniques for resource extraction.

Pike, W. Thomas↗
DOE OSTI2021

Linear and Nonlinear Solvers for Simulating Multiphase Flow within Large-Scale Engineered Subsurface Systems

Simulation of multiphase flow in the subsurface is well-known to be computationally challenging. While there have been many studies that have explored approaches to overcoming these challenges, they often utilize relatively simple case studies. In this paper, we focus on the unique numerical challenges posed by modeling large-scale engineered subsurface systems, characterized by discrete features embedded in a heterogeneous natural subsurface setting. The man-made features such as shafts, tunnels, and barriers often cause multiple challenges in modeling the domain for multiphase porous media flow. This flow scenario can have a wide range of applications such as nuclear waste repositories, enhanced recovery of a petroleum reservoir, geothermal engineering, and carbon sequestration. An example of these severe numerical challenges is the case of performance assessment (PA) for Waste Isolation Pilot Plant (WIPP), the only operating deep geological repository in the US, which simulates extreme material properties of bedded salt rock formation and extreme contrast due to open excavation next to the formation. The models have extremes not only of permeability and porosity but also of the constitutive models needed for multiphase flow; additionally, they have process models like salt creep closure reducing porosity over time, fracturing in clay and anhydrite interbeds of the bedded salt, gas generation from the waste materials, and unintentional human borehole intrusions in some scenarios. Numerical simulations require the solution of coupled systems of nonlinear PDEs; in our work, we use the open-source simulator PFLOTRAN which is based on Finite Volume discretization. The solution of the nonlinear equations requires use of the Newton-Raphson iteration at each time step, which entails the solution of the linearized Jacobian system at each iteration. The effects of all the processes (i.e., large number of unknowns, highly nonlinear constitutive relations, large contrasts in material properties in short distances) lead to an ill-conditioned Jacobian matrix that severely challenges traditional linear solver, i.e., stabilized biconjugate gradient with block Jacobi incomplete LU preconditioner (BCGS-ILU) leading to non-convergence for traditional Newton-Raphson nonlinear solver causing unacceptably long computation time for each model. This paper presents linear solvers such as constrained pressure residual (CPR) two-stage preconditioner with alternate-block-factorization (ABF) and quasi- implicit pressure and explicit saturation (QIMPES) decouplers and flexible generalized residual solver (FGMRES). The new general-purpose nonlinear solver, Newton trust-region dogleg Cauchy (NTRDC), is also introduced to resolve extreme nonlinearities in the models. We demonstrate the effectiveness of each method relative to the default BCGS-Newton solver. The two best cases had nearly 50 times speed-up and achieved completion of a simulation in 14 hours that never completed due to non-convergence with the default solver. We also investigate the strong scalability of each method and discuss some of the deficiencies found for Block Jacobi preconditioner using parallel domain decomposition, and node packing effects of modern processor architecture.

Preconditioner, Nonlinear, Porous media, Multiphas↗
DOE OSTI2025

Stable isotope equilibria in the dihydrogen-water-methane-ethane-propane system. Part 2: Experimental determination of hydrogen isotopic equilibrium for ethane-H2 from 30 to 200 °C and propane-H2 from 75 to 200 °C

The stable isotopic compositions of light n-alkanes, including methane, ethane, and propane, are often used to identify the sources and thermal maturity of natural gas samples. Though stable isotopic compositions of these molecules are commonly assumed to be controlled by kinetic isotope effects, recent studies have proposed both carbon and hydrogen isotopic equilibrium may also occur in some samples. Assessing whether samples are in isotopic equilibrium requires knowledge of light alkane equilibrium fractionation factors over geologically relevant temperatures for formation and storage (up to ∼300 °C). In this study, we report experimental results of hydrogen isotopic equilibrium between ethane and H2 from 30 to 200 °C and propane and H2 from 75 to 200 °C. We compare these results with high-level theoretical calculations and provide a preferred polynomial fit to describe equilibrium fractionation factors. Comparison of these fractionation factors with a compilation of ∼500 compiled environmental gas samples supports the proposal that many (∼50%) of these natural gas samples exhibit hydrogen isotopic compositions consistent with having formed in or attained methane-ethane-propane hydrogen isotopic equilibrium over geologically relevant temperatures for formation and storage (50–300 °C).

Turner, Andrew C↗
NASA NTRS1992

Magellan stereo images and Venusian geology

Areas of Venus imaged by Magellan radar with multiple viewing conditions provide unique data that will contribute to the solution of venusian geologic problems and provide a basis for quantitative comparison of venusian landforms with those on other planetary bodies. Three sets of images with different viewing conditions have been acquired: (1) left-looking with variable incidence angles (cycle 1 profile), (2) right-looking with nearly constant incidence angles (cycle 2 profile), and (3) left-looking with variable incidence angles that are almost always smaller than those in (1) (cycle 3 profiles). The unique data provided by paired images of the same scene with different incidence angles arises from image displacements caused by the relief of individual landforms at scales comparable to the ground-range and azimuth resolutions of the images. There are two aspects of the data: (1) Stereopsis achieved by simultaneous viewing of paired left-looking images of the same scene permits three-dimensional perception and interpretation of the morphologies of landforms at resolutions much finer than the altimetry footprints. (2) Measurements of differences of image displacements (parallax) on paired images with known imaging geometries provide quantitative estimates of the relief and shapes of landforms. The potential scientific contributions of the data can be grouped into two interrelated classes: (A) geologic mapping, analysis, and interpretation and (B) topical studies that involve topographic measurements. Stereopsis, without quantitative measurements, enhances geologic mapping, analysis, and interpretation of the rock units of Venus to a degree that cannot be overestimated. In geologic mapping, assemblages of landforms, assessments of backscatter and variations in backscatter, and fine-scale topography are used to define and characterize geologic map units that represent laterally continuous deposits or rock units. Stereopsis adds the important dimension of local relief for characterization of geologic units at a scale that is not possible with Magellan altimetry or products derived from the altimetry. Relative ages of the geologic units are determined using the well-known principles of superposition and intersection. Here, the perception of relief is invaluable because superposition relations among the geological units are more readily and clearly established. The recognition of folds, faults, and fault systems, regardless of their orientations, is facilitated with stereopsis so that sequences of deformation of the geologic units can be determined and structural analyses vastly improved. Shapes of landforms are readily perceived so that they can be properly interpreted. The end result of the mapping, analyses, and interpretations is a geologic history of Venus that includes the sequences of formation and deformation of various geologic units. Measurements of relief at the finest scale possible are necessary for numerous topical studies. Standard altimetry will provide the necessary information on the relief of most large landforms, but it tends to underestimate the relief of small landforms and distorts their shapes. Although special processing of the altimeter echoes improves the estimates of the relief and shapes of some landforms, there are uncertainties in the interpretations of the echoes. Examples of topical studies requiring measurements of relief are given.

Moore, H. J.↗
NASA NTRS2023

Overview and Results From the Mars 2020 Perseverance Rover's First Science Campaign on the Jezero Crater Floor

The Mars 2020 Perseverance rover landed in Jezero crater on 18 February 2021. After a 100-sol period of commissioning and the Ingenuity Helicopter technology demonstration, Perseverance began its first science campaign to explore the enigmatic Jezero crater floor, whose igneous or sedimentary origins have been much debated in the scientific community. This paper describes the campaign plan developed to explore the crater floor's Máaz and Séítah formations and summarizes the results of the campaign between sols 100–379. By the end of the campaign, Perseverance had traversed more than 5 km, created seven abrasion patches, and sealed nine samples and a witness tube. Analysis of remote and proximity science observations show that the Máaz and Séítah formations are igneous in origin and composed of five and two geologic members, respectively. The Séítah formation represents the olivine-rich cumulate formed from differentiation of a slowly cooling melt or magma body, and the Máaz formation likely represents a separate series of lava flows emplaced after Séítah. The Máaz and Séítah rocks also preserve evidence of multiple episodes of aqueous alteration in secondary minerals like carbonate, Fe/Mg phyllosilicates, sulfates, and perchlorate, and surficial coatings. Post-emplacement processes tilted the rocks near the Máaz-Séítah contact and substantial erosion modified the crater floor rocks to their present-day expressions. Results from this crater floor campaign, including those obtained upon return of the collected samples, will help to build the geologic history of events that occurred in Jezero crater and provide time constraints on the formation of the Jezero delta.

Mars 2020↗
DOE OSTI2022

Separation of CO 2 from Flue Gas and Potential for Geologic Sequestration

The objectives of this study were to review various methods reported in the literature for the separation and geologic sequestration of carbon dioxide and evaluate the potential of TVA fossil fuel-burning plant locations for onsite geologic sequestration of CO 2 from stack emissions. Several conventional and nonconventional technologies for the separation of CO 2 from flue gas, including absorption, adsorption, cryogenic distillation, membranes, hydrate formation and dissociation, and ammonia carbonation, have been reviewed in terms of separation mechanisms, flow diagrams, and costs. Most of the technologies that have been reviewed are still at the research and development stage. Critical information needed to assess and compare these technologies is still lacking. In addition, information on some of the technologies that have been tested at a pilot or industrial scale has not been fully disclosed in the open literature. Because of this lack of data, it is difficult to make a critical assessment of each of the separation technologies. Based on limited information, it was concluded that the most promising methods are membrane separation and the Mitsubishi process for chemical absorption. Both processes involve separating CO 2 at high temperature, minimizing the cost for cooling prior to separation. Physical and chemical geologic formations of CO 2 were also reviewed. It was concluded that due to the geologic time scale of CO 2 sequestration periods, relatively safe conditions, general proximity to CO 2 sources, and extensive knowledge of underground conditions, sequestration of CO 2 in underground aquifers and coal beds is a very promising method of mitigating greenhouse gas emissions. The cost is predicted to be relatively low and the suitable sites are numerous for this application, with many of these sites located close to the plants.

20 FOSSIL-FUELED POWER PLANTS↗
NASA NTRS2005

Northern Hemisphere Gullies on Mars: Analysis of Spacecraft Data and Implications for Formation Mechanisms

The origin of geologically recent gullies on Mars has remained controversial since the discovery of these features by Malin and Edgett in 2000. Numerous models have been proposed which invoke various physical processes as well as various agents of erosion to explain the origin of the Martian gullies. Hypotheses to explain the formation of the gullies invoke shallow liquid water aquifers, deep liquid water aquifers, melting ground ice, snowmelt, dry landslides, and carbon dioxide aquifers. We test the validity of such gully formation mechanisms by analyzing data from the Mars Global Surveyor and Mars Odyssey spacecrafts to uncover trends in the dimensional and physical properties of the gullies and their surrounding terrain. A similar study has previously been completed for gullies located in the southern hemisphere of Mars. The work presented here focuses exclusively on gullies in the northern hemisphere based on the identification of 136 Mars Orbiter Camera (MOC) images containing clear evidence of gully landforms, distributed in the northern mid and high latitudes. These sites have been analyzed in combination with Mars Orbiter Laser Altimeter (MOLA), Thermal Emission Spectrometer (TES), and Gamma Ray Spectrometer (GRS) data to provide quantitative measurements of numerous gully characteristics. Parameters measured include apparent source depth and distribution, vertical and horizontal dimensions, slopes, compass orientations, near-surface ice content, and factors controlling present-day climatic conditions.

Heldmann, J. L.↗
NASA NTRS2022

Geology and Stratigraphic Correlation of the Murray and Carolyn Shoemaker Formations Across the Glen Torridon Region, Gale Crater, Mars

The Glen Torridon (GT) region within Gale crater, Mars, occurs in contact with the southern side of Vera Rubin ridge (VRR), a well-defined geomorphic feature that is comparatively resistant to erosion. Prior to detailed ground-based investigation of GT, its geologic relationship with VRR was unknown. Distinct lithologic subunits within the Jura member (Murray formation), which forms the upper part of VRR, made it possible to be also identified within GT. This indicates that the strata pass across the geomorphic divide between regions. Furthermore, the cross-bedded lower part of the overlying Knockfarril Hill member (Carolyn Shoemaker formation) also occurs within both VRR and GT. Correlation of both units demonstrates that the strata form a continuous stratigraphic succession regardless of large-scale geomorphic expression. The lithologic change from mudstone (Jura member) to cross-bedded sandstone (Knockfarril Hill member) heralds a significant shift in paleoenvironment from lacustrine to fluvial. The upper part of the Knockfarril Hill member consists of interbedded mudstone and sandstone that transitions to the overlying finely laminated mudstone of the Glasgow member, and a return to lacustrine deposition. In GT, the Stimson formation unconformably overlies the Glasgow member, where it demarks the southern boundary of GT. Contacts for each stratigraphic unit were defined and transferred to a high-resolution image base to make a geologic map and cross sections perpendicular to the NE strike. Stratal dips cannot exceed 2° NW to retain the positions of stratigraphic units in the locations they are exposed throughout GT.

C. M. Fedo↗
NASA NTRS2008

Geological Implications of a Physical Libration on Enceladus

Given the non-spherical shape of Enceladus (Thomas et al., 2007), the satellite will experience gravitational torques that will cause it to physically librate as it orbits Saturn. Physical libration would produce a diurnal oscillation in the longitude of Enceladus tidal bulge which, could have a profound effect on the diurnal stresses experienced by the surface of the satellite. Although Cassini ISS has placed an observational upper limit on Enceladus libration amplitude of F < 1.5deg (Porco et al., 2006), smaller amplitudes can still have geologically significant consequences. Here we present the first detailed description of how physical libration affects tidal stresses and how those stresses then might affect geological processes including crack formation and propagation, south polar eruption activity, and tidal heating. Our goal is to provide a framework for testing the hypothesis that geologic features on Enceladus are produced by tidal stresses from diurnal physical and optical librations of the satellite.

Hurford, T. A.↗
DOE OSTI2020

Wellbore injectivity response to step-rate CO 2 injection: Coupled thermo-poro-elastic analysis in a vertically heterogeneous formation

Safe and permanent carbon geological storages require an elaborate analysis of geomechanical stability. Subsurface injection of CO 2 changes the local temperature and pore pressure and, further, alters the stress due to thermo-poro-elastic responses. A permanent CO 2 storage testing was conducted in the water leg of Cranfield reservoir in Mississippi, USA, where hosted CO 2 enhanced-oil recovery activities. During CO 2 injection, the injection rate was ramped up twice but the bottom-hole pressure did not increase with the imposed injection rates as expected. This unexpected field observation suggests the possibility of an open-mode fracture development at the injector. However, the injector response and potential fracture development have not been rigorously interpreted with detailed near-wellbore temperature and pore pressure change upon the CO 2 injection. In this study, we performed history matching of CO 2 injection using coupled thermo-poro-elastic reservoir simulation to examine the possibility of fracturing. We built a reservoir model including vertical heterogeneity in both petrophysical and geomechanical properties estimated from well-logging analysis and laboratory experiments. The simulation results show that CO 2 injection changes stresses and support the hypothesis of development of an open-mode fracture at the injector during the Cranfield test. The near-injector region exhibits a large temperature reduction up to 55 °C with ensuing effective horizontal stress reduction up to 9.1 MPa. However, a caprock integrity issue is unlikely because of the horizontal stress contrast within layers and low hydraulic communication with the injection zone. This work indicates that the injectant temperature should be considered in the design of high-rate CO 2 injector.

58 GEOSCIENCES↗
NASA NTRS1979

Processing of multispectral thermal IR data for geologic applications

Multispectral thermal IR data were acquired with a 24-channel scanner flown in an aircraft over the E. Tintic Utah mining district. These digital image data required extensive computer processing in order to put the information into a format useful for a geologic photointerpreter. Simple enhancement procedures were not sufficient to reveal the total information content because the data were highly correlated in all channels. The data were shown to be dominated by temperature variations across the scene, while the much more subtle spectral variations between the different rock types were of interest. The image processing techniques employed to analyze these data are described.

Kahle, A. B.↗
NASA NTRS1975

Summary of space imagery studies in Utah and Nevada

LANDSAT-1, Skylab, and RB-57 imagery acquired within days of each other of the San Rafael swell enabled geological mapping of individual formations of the southern portion of this broad anticlinal feature in eastern Utah. Mapping at a scale of 1/250,000 on an enhanced and enlarged S-190B image resulted in a geological map showing correlative mappable features that are indicated on the geological map of Utah at the same scale. An enhanced enlargement of an S-190B color image at a scale of 1/19,200 of the Bingham Porphyry Copper deposit allowed comparison of a geological map of the area with the space imagery map as fair for the intrusion boundaries and total lack of quality for mapping the sediments. Hydrothermal alteration is only slightly evident on space imagery at Bingham but in the Tintic mining district and the volcanic piles of the Keg and Thomas ranges, Utah, hydrothermal alteration is readily mapped on color enlargements of S-190B (SL-3, T3-3N Tr-2). A mercury soil-gas analyzer was developed for locating hidden mineralized zones which were suggested from space imagery.

Jensen, M. L.↗