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At least 235 records · Page 13

A method for measuring coupling coefficients between cores and corrections to mode propagation constants in multicore fibres

A new experimental method is proposed for reconstructing supermode profiles of a multicore fibre (MCF), small corrections to the propagation constants of its cores and coupling coefficients between the cores without phase-sensitive measurements. The method is based on intensity measurements in the cores at the output of several MCF segments differing in length, using several configurations of controlled light launch into the cores at the fibre input (in the simplest case, by sequentially exciting each core), followed by numerical treatment using an iterative algorithm. The use of the method is demonstrated experimentally for a seven-core fibre. Using numerical simulation, we assess the stability of the method and the effect of the number of measurements on the accuracy of fibre parameter reconstruction. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Absolute photoneutron cross sections of Sm isotopes

Photoneutron cross sections for seven samarium isotopes, {sup 144}Sm, {sup 147}Sm, {sup 148}Sm, {sup 149}Sm, {sup 150}Sm, {sup 152}Sm and {sup 154}Sm, have been investigated near neutron emission threshold using quasimonochromatic laser-Compton scattering γ-rays produced at the synchrotron radiation facility NewSUBARU. The results are important for nuclear astrophysics calculations and also for probing γ-ray strength functions in the vicinity of neutron threshold. Here we describe the neutron detection system and we discuss the related data analysis and the necessary method improvements for adapting the current experimental method to the working parameters of the future Gamma Beam System of Extreme Light Infrastructure - Nuclear Physics facility.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Advances in Entry Systems Modeling: Modeling Summer Visit 2025 Technical Reports

This NASA Technical Memorandum presents the collective work carried out during the Modeling Summer Visit (MSV) 2025, a collaborative research program between NASA Ames Research Center and three leading European research institutions: the University of Bordeaux, the von Karman Institute (VKI), and Ecole Polytechnique. Held from July 7th to August 1st, 2025, the NASA ARC MSV program brought together 42 researchers from Europe to work alongside NASA staff on 22 projects in entry systems modeling. The program was organized by Bruno Dias, Sergio Fraile-Izquierdo, and Jeremie Meurisse from Analytical Mechanics Associates, Inc., in collaboration with Marc Massot (Ecole Polytechnique), Jean Lachaud (University of Bordeaux), and Thierry Magin (VKI). The MSV program traces its origins to an initiative started by Nagi N. Mansour in 2018, with this 2025 edition representing a consolidation and expansion of that original vision. The projects were organized into six thematic groups: Porous Media, Numerical Methods, Plasma/Rarefied Methods, Experimental Reconstruction, Flow and Material Coupling Methods, and Transition and High-Speed Flows. Throughout the four-week program, participants presented their work in three public presentations (July 7th, July 21st, and August 1st), allowing for continuous feedback and discussion of their evolving research.

Plasmas↗

Electronic Energies Are Not Enough: An Ion Mobility-Aided, Quantum Chemical Benchmark Analysis of H + GPGG Conformers

Peptides and proteins exist not as single, lowest energy structures but as ensembles of states separated by small barriers. In order to study these species we must be able to correctly identify their gas phase conformational distributions, and ion mobility spectrometry (IMS) has arisen as an experimental method for assessing the gas phase energetics of flexible peptides. Here, we present a thorough exploration and benchmarking of the low energy conformers of the small, hairpin peptide H+ GPGG with the aid of ion mobility spectrometry against a wide swath of density functionals (35 dispersion-corrected and uncorrected functionals represented by 21 unique exchange–correlation functionals) and wave function theory methods (15 total levels of theory). The three experimentally resolved IMS peaks were found to correspond to three distinct pairs of conformers, each pair composed of species differing only by the chair or boat configuration of the proline. Two of the H+ GPGG conformer pairs possess a cis configuration about the Pro–Gly1 peptide bond while the other adopts a trans configuration. While the experimental spectrum reports a higher intensity for the cis-1 conformer than the trans conformer, 13 WFT levels of theory, including a complete basis set CCSD(T) extrapolation, obtain trans to be favored in terms of the electronic energy. This same effect is seen in 14 of the 18 dispersion-corrected density functionals studied, whereas the remaining 17 functionals show more variety. Only when Gibbs free energies are considered do the WFT methods and dispersion-corrected functionals reflect the experimental distribution. CAM-B3LYP-D3BJ emerges as the best-performing density functional, matching the experimental distribution and the CCSD(T)/CBS relative energies within 6%. Further analysis reveals the trans conformer to be favored electronically, but entropically disfavored, leading to the experimental preference of the cis-1 conformer. Furthermore, these results highlight the danger in considering only the electronic energies, which is common practice in electronic structure theory predictions of conformational energy distributions. Additionally, the effects of temperature and scaling of the frequencies used in obtaining the Gibbs free energies are explored.

Energy↗

Equation of State for Technetium Metal up to 153 GPa

The transition metal, technetium, is a major fission product with a fission yield greater the 6 % for {sup 235}U and as such is found in large quantities in nuclear waste. However, few studies have investigated the behavior of technetium under extreme conditions. Previously, three studies have reported bulk moduli values for technetium metal determined by experimental methods: ultrasonic techniques at ambient pressure, estimated from elastic constants determined from experimental phonon dispersion curves and by high pressure X-ray diffraction. Numerous estimates have been made from computational methods - . The bulk moduli of transition metals is used as a benchmark for validating computation methods. With so little experimental data on technetium, it cannot serve as a useful benchmark. In our previous study the equation of state was measured up to 67 GPa using a 4:1 mixture of methanol-ethanol as the pressure transmitting medium. The non-hydrostatic data produced there resulted in an equation of state defined by B{sub 0} = 288 GPa, and B' = 5.9. Reported here is the high pressure X-ray diffraction measurements made on technetium metal up to a maximum pressure of 153 GPa (1.53 Mbar) and the resulting equation of state. (authors)

36 MATERIALS SCIENCE↗

Resolving femtosecond photoinduced energy flow: capture of nonadiabatic reaction pathway topography and wavepacket dynamics from photoexcitation through the conical intersection seam (Final Technical Report)

The dynamics that take place within just tens to hundreds of femtoseconds following the absorption of light by a molecule can play a critical role in how the absorbed energy is directed, allowing it to be used for a specific function or dissipated harmlessly. The form of chemical change that occurs rapidly in these molecules is called a “nonadiabatic electronic transition.” Such transitions are known to mediate energy flow in natural biological systems such as the ultraviolet photoprotection mechanism of DNA and the first step of the human vision response. Understanding how these mechanisms work precisely may help scientists achieve controlled manipulation of solar energy or optical control of a wide range of energy management functions in artificial systems. Experimental methods, however, have not yet allowed a precisely resolved and complete measurement of nonadiabatic electronic transitions. This constitutes a major obstacle to progress in the field. For progress to occur that would inform a wide body of research aiming to efficiently harness the energy of light for practical purposes, it is especially important to benchmark computational models of the molecules undergoing these rapid changes with experimental measurements, in order to learn which models are accurate. With Dept. of Energy funding, we have made strong progress towards establishing a new optical method for experimentally detecting the full nonadiabatic electronic transition. This requires having coordinated pulses of light covering the visible through the mid-infrared range of the electromagnetic spectrum that last only ten femtoseconds. We have developed a new, relatively simple approach for generating such pulses of laser light, and have incorporated them into a time-resolved spectrometer for measuring rapid changes in molecules. These tools can provide the greater precision and new types of data that are needed to benchmark computational models of molecular change and thus to make progress in the field. Our tools were tested on graphene, an excellent solid-state sample for verifying the capabilities and limitations of our instrumentation. The investment made in these tools by the Dept. of Energy Office of Science will allow new fundamental scientific understanding of energy dynamics in molecules in future studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Verification of experimental dynamic strength methods with atomistic ramp-release simulations

Material strength and moduli can be determined from dynamic high-pressure ramp-release experiments using an indirect method of Lagrangian wave profile analysis of surface velocities. This method, termed self-consistent Lagrangian analysis (SCLA), has been difficult to calibrate and corroborate with other experimental methods. Using nonequilibrium molecular dynamics, we validate the SCLA technique by demonstrating that it accurately predicts the same bulk modulus, shear modulus, and strength as those calculated from the full stress tensor data, especially where strain rate induced relaxation effects and wave attenuation are small. We show here that introducing a hold in the loading profile at peak pressure gives improved accuracy in the shear moduli and relaxation-adjusted strength by reducing the effect of wave attenuation. When rate-dependent effects coupled with wave attenuation are large, we find that Lagrangian analysis overpredicts the maximum unload wavespeed, leading to increased error in the measured dynamic shear modulus. Furthermore, these simulations provide insight into the definition of dynamic strength, as well as a plausible explanation for experimental disagreement in reported dynamic strength values.

36 MATERIALS SCIENCE↗

Chemical reactions of conformationally selected 3-aminophenol molecules in a beam with Coulomb-crystallized Ca{sup +} ions

Many molecules exhibit multiple conformers that often easily interconvert under thermal conditions. Therefore, single conformations are difficult to isolate which renders the study of their distinct chemical reactivities challenging. We have recently reported a new experimental method for the characterization of conformer-specific effects in chemical reactions [Y.-P. Chang, K. Długołęcki, J. Küpper, D. Rösch, D. Wild, and S. Willitsch, “Specific chemical reactivities of spatially separated 3-aminophenol conformers with cold Ca{sup +} ions,” Science 342, 98–101 (2013)]. Different conformers are spatially separated using inhomogeneous electric fields and reacted with a Coulomb crystal of cold, spatially localized ions in a trap. As a first application, we studied reactions between the two conformers of 3-aminophenol and Ca{sup +}. We observed a twofold larger rate constant for the cis compared to the trans conformer which was rationalized in terms of the differences in the long-range ion-molecule interactions. The present article provides a detailed description of the new method and a full account of the experimental results as well as the accompanying theoretical calculations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Theoretical study of time-resolved luminescence in semiconductors. III. Trap states in the band gap

In the third part of this series, we study the influence of trap states in the band gap of semiconductors on the time-resolved luminescence decay (TRL) after a pulsed excitation. The results based on simulations with Synopsys TCAD{sup ®} and analytical approximations are given for p-doped Cu(In,Ga)Se{sub 2} as a working example. We show that a single trap can be mostly described by two parameters which are assigned to minority carrier capture and emission. We analyze their influence on the luminescence decay and study the difference between a single trap and an energetic Gaussian trap distribution. It is found that trap states artificially increase the TRL decay and obscure the recombination dynamics. Thus, there is a demand for experimental methods which can reveal the recombination of minority carriers in a TRL experiment without trapping effect. In this regard, a variation of the device temperature, the excitation frequency, the injection level, as well as a bias illumination may be promising approaches. We study these methods, discuss advantages and disadvantages, and show experimental TRL for prove of concept. At the end, we validate our approach of simulating only band-to-band radiative recombination although photoluminescence spectra often exhibit free-to-bound radiative recombination of charge carriers.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Hydrodynamic Analysis of a Suspended Cylinder Under Regular Wave Loading Based on Computational Fluid Dynamics

An investigation into the computation of hydrodynamic loads on a suspended cylinder in regular waves is presented. The primary goal was to perform a three-way validation of the loads between experimental measurements and simulations from two computational methods. Experimental measurements of the longitudinal in-line force on a cylinder suspended at a fixed position were available from the Offshore Code Comparison Collaboration, Continued, with Correlation (OC5) project, Phase Ia. These measurements were compared to computational fluid dynamics (CFD) simulations based on the solution of Reynolds-averaged Navier-Stokes (RANS) equations, as implemented in STAR-CCM+. The study encompassed a sensitivity analysis of the loads computed in STAR-CCM+ based on wave modeling, boundary conditions, turbulence modeling, and spatial and temporal discretization. The analysis was supplemented by results generated with the offshore wind turbine engineering software OpenFAST, based on a hybrid combination of second-order potential flow and viscous drag from Morison's equation. The focus of the investigation was on the assessment of the accuracy of the computation of first- and higher-order hydrodynamic loads. Substantial differences were observed in the numerical prediction of the second and third harmonic force contribution. Local flow field analysis with CFD was applied to study the physics of wave run-up and diffraction dynamics to identify the causes.

16 TIDAL AND WAVE POWER↗

Hydrodynamic Analysis of a Suspended Cylinder Under Regular Wave Loading Based on Computational Fluid Dynamics: Preprint

An investigation into the computation of hydrodynamic loads on a suspended cylinder in regular waves is presented. The primary goal was to perform a three-way-validation of the loads between experimental measurements and simulations from two computational methods. Experimental measurements of the longitudinal inline force on a cylinder suspended at a fixed po- sition were available from the Offshore Code Comparison Col- laboration, Continued, with Correlation (OC5) project, Phase Ia. These measurements were compared to Computational Fluid Dynamics (CFD) simulations based on the solution of Reynolds- averaged Navier-Stokes (RANS) equations, as implemented in STAR-CCM plus. The study encompassed a sensitivity analysis of the loads computed in STAR-CCM plus based on wave modeling, boundary conditions, turbulence modeling, and spatial and tem- poral discretization. The analysis was supplemented by results generated with the offshore wind turbine engineering software OpenFAST, based on a hybrid combination of second-order po- tential flow and viscous drag fromMorison's equation. The focus of the investigation was on the assessment of the accuracy of the computation of first- and higher-order hydrodynamic loads. Sub- stantial differences were observed in the numerical prediction of the second and third harmonic force contribution. Local flow field analysis with CFD was applied to study the physics of wave run-up and diffraction dynamics to identify the causes.

16 TIDAL AND WAVE POWER↗

Advancing Building Air Leakage Measurement and Modeling: Measurement of Interior Air Leaks, Experimental Comparison to Conventional Methods, and Building Modeling Characteristics

This report, Advancing Building Air Leakage Measurement and Modeling: Measurement of Interior Air Leaks, Experimental Comparison to Conventional Methods, and Building Modeling Characteristics, developed two new building air leakage measurement methods, experimentally evaluated the performance in comparison to conventional methods, experimentally evaluated the behavior of leaks for specific crack structures, and identified testing constraints and model implications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Ultrashort pulse generation in semiconductor lasers

Techniques to generate picosecond optical pulses from semiconductor lasers are reviewed. Experimental methods and results of theoretical analysis of active modelocking are presented. It is shown that modelocking will achieve the shortest pulses; but the use of a cumbersome external cavity will probably limit its practical use. Short pulses produced by direct modulation such as gain switching are considerably broader than those obtained by passive modelocking. However, no external cavity is needed; and the simplicity of this method makes it important to be explored further. Recent experimental results are discussed where picosecond pulses from a buried heterostructure laser diode with ultrashort current pulses obtained from a comb generator are generated. Also, 28 ps pulses were obtained at 2.5 GHz repetition frequency, using the gain switching method. An analytical analysis based on the rate equations shows qualitative agreement with our experimental results.

Auyeung, J.↗

Thermal desorption of metals from tungsten single crystal surfaces

After a short review of experimental methods used to determine desorption energies and frequencies the assumptions underlying the theoretical analysis of experimental data are discussed. Recent experimental results on the flash desorption of Cu, Ag, and Au from clean, well characterized W (110) and (100) surfaces are presented and analyzed in detail with respect to the coverage dependence. The results obtained clearly reveal the limitations of previous analytical methods and of the experimental technique per se (such as structure and phase changes below and in the temperature region in which desorption occurs).

Bauer, E.↗

Fluctuating flow angles and anisotropic flow measurements

Event-by-event fluctuations in the initial density distributions of the fireballs created in relativistic heavy-ion collisions lead to event-by-event fluctuations of the final anisotropic flow angles, and density inhomogeneities in the initial state cause these flow angles to vary with the transverse momentum of the emitted particles. It is shown that these effects lead to characteristically different transverse momentum dependencies for anisotropic flow coefficients extracted from different experimental methods. Finally, these differences can be used to experimentally constrain flow angle fluctuations in the final state of heavy-ion collisions which, in turn, are sensitive to the initial-state density fluctuations and the shear viscosity of the expanding fireball medium.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Airplane self-noise - four years of research

A critical assessment of the state of the art in airframe self-noise is presented. Full-scale data on the intensity, spectra, and directivity of this noise source are evaluated. Vibration of panels on the aircraft is identified as a possible additional source of airframe noise. The present understanding and methods for prediction of other component sources (airfoils, struts, and cavities) are discussed, and areas for further research as well as potential methods for airframe noise reduction are identified. Various experimental methods which have been developed for airframe noise research are discussed, and sample results are presented.

Hardin, J. C.↗