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At least 235 records · Page 13

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DOE OSTI2024

A general mechanistic framework for cross-scale understanding of hot spots and hot moments in carbon and water fluxes

Semi-arid ecosystems, like those in the American Southwest, exert a massive impact on the interannual variability of carbon and water cycling. Unfortunately, these carbon and water fluxes are notoriously difficult to predict due to their high spatial and temporal variability, which is poorly captured by the current generation of vegetation models. Indeed, this region is exemplified by the ‘hot spots and hot moments’ concept, which states that small areas in space (‘hot spots’) and transient moments in time (‘hot moments’) exert an outsized influence on biogeochemical cycling. However, the factors that regulate these pulses in biogeochemical activity are unknown, as is their variability across space and time. These uncertainties severely limit efforts to better represent hot spots and hot moments in models. Here, we seek to develop a generalized method for detecting and quantifying the importance of hot spots and hot moments from individual plant to regional scales. Underpinning this method is our recently developed statistical approach for identifying hot spots and hot moments. By applying this method to semi-continuous measurements of plant water status, a depth profile of soil water potential, and ecosystem fluxes via eddy covariance, we will track the fate of water through the soil-plant-atmosphere continuum and identify the mechanistic drivers of these transient pulses in biogeochemical activity. Then, we will expand this approach across a broad network of Ameriflux towers, and apply a machine learning approach that will allow us to upscale measurements of hot spots and hot moments across the American Southwest and quantify their impact on carbon and water cycles. These products will allow us to identify hot spots and hot moments across spatio-temporal scales and will serve as crucial data sources for validating a new generation of models that can better capture highly dynamic carbon and water fluxes. The proposed method will be easily transferable across biomes and will serve as a framework for future research on hot spots and hot moments across the plant ecophysiology, biometeorology, and vegetation modeling communities.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Unraveling the Effects of Melt–Mantle Interactions on the Gold Fertility of Magmas

The oxidation state of the Earth’s mantle and its partial melting products exert a key control on the behavior and distribution of sulfur and chalcophile and siderophile elements between the mantle and crust, underpinning models of ore deposit formation. Whether the oxidized nature of magmas is inherited from the asthenospheric mantle source or acquired during ascent and differentiation is vigorously debated, limiting our understanding of the mechanisms of extraction of sulfur and metals from the mantle. Here, we focused on the redox-sensitive behavior of sulfur in apatite crystallized from quenched alkaline basaltic melts preserved within a peridotite xenolith from the El Deseado Massif auriferous province in southern Patagonia. We took advantage of this unique setting to elucidate the redox evolution of melts during their ascent through the subcontinental lithospheric mantle (SCLM) and grasp the inner workings of the Earth’s mantle during gold metallogenesis. Our data reveal that an initially reduced silicate melt (ΔFMQ -2.2 to -1.2) was oxidized to ΔFMQ between 0 and 1.2 during percolation and interaction with the surrounding peridotite wall-rock (ΔFMQ 0 to +0.8). This process triggered changes in sulfur speciation and solubility in the silicate melt, boosting the potential of the melt to scavenge ore metals such as gold. We suggest that large redox gradients resulting from the interaction between ascending melts and the surrounding mantle can potentially modify the oxidation state of primitive melts and enhance their metallogenic fertility. Among other factors including an enriched metal source and favorable geodynamic conditions, redox gradients in the mantle may exert a first-order control on the global-scale localization of crustal provinces endowed with gold deposits.

58 GEOSCIENCES↗

DOE OSTI2021

Seasonal changes in the drivers of water physico-chemistry variability of a small freshwater tidal river

Where rivers meet the sea, tides can exert a physical and chemical influence on the lower reaches of a river. How tidal dynamics in these tidal river reaches interact with upstream hydrological drivers such as storm rainfall, which ultimately determines the quantity and composition of material transferred from watersheds to estuaries, is currently unknown. We monitored a small freshwater tidal river in the Pacific Northwest, USA in high resolution over one year to evaluate the relative importance of tides versus upstream hydrological flows (i.e., base flow and precipitation events) on basic physico-chemical parameters (pH, dissolved oxygen, turbidity, specific conductivity, and temperature), and how these interactions relate to the downstream estuary. Tidal variability and diurnal cycles (i.e. solar radiation) dominated water physico-chemical variability in the summer, but the influence of these drivers was overshadowed by storm-driven sharp pulses in river physico-chemistry during the remainder of the year. Within such events, we found incidences of counterclockwise hysteresis of pH, counterclockwise hysteresis of dissolved oxygen, and clockwise hysteresis of turbidity, although systematic trends were not observed across events. The dominance of storm rainfall in the river’s physico-chemistry dynamics, and similar pulses of decreased pH observed in adjacent estuarine waters, suggest that the linkage between tidal streams and the broader system is variable throughout the year. High-frequency monitoring of tidal river biogeochemistry is therefore crucial to enable the assessment of how the relative strength of these drivers may change with future sea level rise and altered precipitation patterns to modulate biogeochemical dynamics across the land-ocean-atmosphere continuum.

aquatic↗

DOE OSTI2018

Climate Change Impacts on Natural Sulfur Production: Ocean Acidification and Community Shifts

Utilizing the reduced-complexity model Hector, a regional scale analysis was conducted quantifying the possible effects climate change may have on dimethyl sulfide (DMS) emissions within the oceans. The investigation began with a review of the sulfur cycle in modern Earth system models. We then expanded the biogeochemical representation within Hector to include a natural ocean component while accounting for acidification and planktonic community shifts. The report presents results from both a latitudinal and a global perspective. This new approach highlights disparate outcomes which have been inadequately characterized via planetary averages in past publications. Our findings suggest that natural sulfur emissions (ESN) may exert a forcing up to 4 times that of the CO 2 marine feedback, 0.62 and 0.15 Wm –2 , respectively, and reverse the radiative forcing sign in low latitudes. Additionally, sensitivity tests were conducted to demonstrate the need for further examination of the DMS loop. As a result, the present work attempts to include dynamic ESN within reduced-complexity simulations of the sulfur cycle, illustrating its impact on the global radiative budget.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2019

Governing Constraints of Chromium(VI) Formation from Chromium(III)-Bearing Minerals in Soils and Sediments

The potential for geogenic Cr(VI) contamination is vast, yet it is difficult to predict susceptible environments as groundwater Cr(VI) concentrations vary significantly, even within a given aquifer, due to physical and hydrologic heterogeneity. The physical structure of soils and sediments exerts a dominant control on Cr(VI) production by dictating the separation distance of reactive phases, the diffusion distance from Cr(VI) generation sites to advecting groundwater, and by influencing infiltration rates and porewater velocity. Here, we used a dual-pore domain model to investigate the relative control of these parameters on Cr(VI) production. The reaction distance between Cr(III)-bearing minerals and Mn oxides predominantly controls Cr(VI) export to advecting groundwater, while changes in diffusion distance between sites of Cr(VI) generation and advective flow channels generally have little impact on steady-state Cr(VI) concentrations. Changes in Cr(VI) diffusion distance can, however, increase the time required for groundwater Cr(VI) concentrations to reach a steady-state; thus, under fluctuating hydrologic and biogeochemical conditions, long diffusion distances still have the potential to suppress Cr(VI) supply to advecting water. Furthermore, we show that high porewater flow velocities effectively dilute Cr(VI) diffusing from soil/sediment aggregates, thus minimizing Cr(VI) concentrations relative to lower porewater velocities. The strong control that the physical/hydrologic parameters exert on Cr(VI) production appears to overwhelm the impact of Cr(III)-mineral solubility within soils and sediments.

Hausladen, Debra (ORCID:0000000342356294)↗

DOE OSTI2016

Decadal trends in the seasonal-cycle amplitude of terrestrial CO 2 exchange resulting from the ensemble of terrestrial biosphere models

The seasonal-cycle amplitude (SCA) of the atmosphere–ecosystem carbon dioxide (CO 2 ) exchange rate is a useful metric of the responsiveness of the terrestrial biosphere to environmental variations. It is unclear, however, what underlying mechanisms are responsible for the observed increasing trend of SCA in atmospheric CO 2 concentration. Using output data from the Multi-scale Terrestrial Model Intercomparison Project (MsTMIP), we investigated how well the SCA of atmosphere–ecosystem CO 2 exchange was simulated with 15 contemporary terrestrial ecosystem models during the period 1901–2010. Also, we made attempt to evaluate the contributions of potential mechanisms such as atmospheric CO 2 , climate, land-use, and nitrogen deposition, through factorial experiments using different combinations of forcing data. Under contemporary conditions, the simulated global-scale SCA of the cumulative net ecosystem carbon flux of most models was comparable in magnitude with the SCA of atmospheric CO 2 concentrations. Results from factorial simulation experiments showed that elevated atmospheric CO 2 exerted a strong influence on the seasonality amplification. When the model considered not only climate change but also land-use and atmospheric CO 2 changes, the majority of the models showed amplification trends of the SCAs of photosynthesis, respiration, and net ecosystem production (+0.19 % to +0.50 % yr -1 ). In the case of land-use change, it was difficult to separate the contribution of agricultural management to SCA because of inadequacies in both the data and models. The simulated amplification of SCA was approximately consistent with the observational evidence of the SCA in atmospheric CO 2 concentrations. Large inter-model differences remained, however, in the simulated global tendencies and spatial patterns of CO 2 exchanges. Further studies are required to identify a consistent explanation for the simulated and observed amplification trends, including their underlying mechanisms. Nevertheless, this study implied that monitoring of ecosystem seasonality would provide useful insights concerning ecosystem dynamics.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Localized basal area affects soil respiration temperature sensitivity in a coastal deciduous forest

Abstract. Soil respiration (Rs), the flow of CO2 from the soil surface to the atmosphere, is one of the largest carbon fluxes in the terrestrial biosphere. The spatial variability of Rs is both large and poorly understood, limiting our ability to robustly scale it in space. One factor in Rs spatial variability is the autotrophic contribution from plant roots, but it is uncertain how the presence of plants affects the magnitude and temperature sensitivity of Rs. This study used 1 year of Rs measurements to examine the effect of localized basal area on Rs in the growing and dormant seasons, as well as during moisture-limited times, in a temperate, coastal, deciduous forest in eastern Maryland, USA. In a linear mixed-effects model, tree basal area within a 5 m radius (BA5) exerted a significant positive effect on the temperature sensitivity of soil respiration. Soil moisture was the dominant control on Rs during the dry portions of the year, while soil moisture, temperature, and BA5 all exerted significant effects on Rs in wetter periods. Our results suggest that autotrophic respiration is more sensitive to temperature than heterotrophic respiration at these sites, although we did not measure these source fluxes directly, and that soil respiration is highly moisture sensitive, even in a record-rainfall year. The Rs flux magnitudes (0.46–15.0 µmol m-2 s-1) and variability (coefficient of variability 10 %–23 % across plots) observed in this study were comparable to values observed in similar forests. Six Rs observations would be required in order to estimate the mean across all study sites to within 50 %, and 518 would be required in order to estimate it to within 5 %, with 95 % confidence. A better understanding of the spatial interactions between plants and microbes, as well as the strength and speed of above- and belowground coupling, is necessary to link these processes with large-scale soil-to-atmosphere C fluxes.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1972

Space shuttle orbiter windshield system design and test

The development and testing of primary structural elements that are necessary to design a windshield system for the space shuttle orbiter are summarized. The elements include the outer (heat shield) panes, the inner pressure panes, the seals for both panes, and components of both window frames. One test article representing a pressure pane, including frames and seals, was tested under two sets of conditions. One set represented 100 mission cycles with temperature and pressure typical of those exerted on the innermost pane of the three-pane window system, and the second set represented 100 mission cycles with temperature and pressure typical of those exerted on a middle pane. A second test article representing an outer (heat sheild) pane was tested to conditions of 120 entry cycles, which equates to 100 entry cycles plus sufficient fatigue on the pane to account for 100 boost cycles. All elements of the design survived the test conditions in good condition. Window system for the shuttle orbiter vehicle.

Hayashida, K.↗

NASA NTRS1974

Method of fabricating an article with cavities

An article having a cavity with a thin bottom wall is provided by assembling a thin sheet, for example, a metal sheet, adjacent to the surface of a member having one or more apertures. A bonding adhesive is interposed between the thin sheet and the subadjacent member, and the thin sheet is subjected to a high fluid pressure. In order to prevent the differential pressure from being exerted against the thin sheet, the aperture is filled with a plug of solid material having a linear coefficient of thermal expansion higher than that of the member. When the assembly is subjected to pressure, the material is heated to a temperature such that its expansion exerts a pressure against the thin sheet thus reducing the differential pressure.

Dale, W. J.↗

NASA NTRS1980

Dynamics of erythrocyte count, hemoglobin, and catalase activity in rat blood in hypokinesia, muscular activity and restoration

Tests were conducted to prove that muscular exertion (in this instance swimming) of different duration and intensity, as well as hypodynamia, result in an increase of hemoglobin and number of red blood cells in peripheral blood rats. Catalase activity increased with an increase in the duration of swimming, but only up to 6 hr; with 7-9 hr of swimming as well as in hypodynamia, catalase activity decreased. It was also observed that under hypodynamia as well as in 3, 5 and 6 hr exertion (swimming) the color index of blood decreased. Pressure chamber treatment (for 8 min each day for one week), alternating a 2 min negative pressure up to 35 mm Hg with 1 min positive pressure, increased the erythrocyte count and hemoglobin content.

Taneyeva, G. V.↗

NASA NTRS1980

Tectonic stress - Models and magnitudes

It is shown that global data on directions of principal stresses in plate interiors can serve as a test of possible plate tectonic force models. Such tests performed to date favor force models in which ridge pushing forces play a significant role. For such models the general magnitude of regional deviatoric stresses is comparable to the 200-300 bar compressive stress exerted by spreading ridges. An alternative approach to estimating magnitudes of regional deviatoric stresses from stress orientations is to seek regions of local stress either demonstrably smaller than or larger than the regional stresses. The regional stresses in oceanic intraplate regions are larger than the 100-bar compression exerted by the Ninetyeast Ridge and less than the bending stresses (not less than 1 kbar) beneath Hawaii.

Solomon, S. C.↗

NASA NTRS1985

Force Sensor for Large Robot Arms

Modified Maltese-cross force sensor larger and more sensitive than earlier designs. Measures inertial forces and torques exerted on large robot arms during free movement as well as those exerted by claw on manipulated objects. Large central hole of sensor allows claw drive mounted inside arm instead of perpendicular to its axis, eliminating potentially hazardous projection. Originally developed for Space Shuttle, sensor finds applications in large industrial robots.

Bejczy, A. K.↗

NASA NTRS1984

Excerpts from the paper: Research Status and Recommendation from the Alaska Workshop on Gravity Waves and Turbulence in the Middle Atmosphere, part 1.3A

Internal gravity waves are disturbances whose intrinsic frequencies k(c - u) are smaller than the Brunt-Vaisala frequency (N). Their importance arises because: they are the major components of the total flow and temperature variability fields of the mesosphere (i.e., shears and lapse rates) and hence constitute the likely sources of turbulence; and they are associated with fluxes of momentum that communicate stresses over large distances. For example, gravity waves exert a drag on the flow in the upper mesosphere. However, in order for gravity waves to exert a net drag on the atmosphere, they must be attenuated. There are two general types of processes that seek to attenuate gravity waves: dissipation and saturation. Dissipation is any process that is effective independent of the wave amplitude, while saturation occurs when certain wave amplitude conditions are met. Radiative damping is an example of dissipation, while convective overturning is an example of saturation. The two processes are not mutually exclusive.

Fritts, D. C.↗

NASA NTRS1984

On the heating mechanism of magnetic flux loops in the solar atmosphere

An investigation is conducted of physical heating mechanisms due to the ponderomotive forces exerted by turbulent waves along the solar atmosphere's curved magnetic flux loops. Results indicate that the temperature difference between the inside and outside of the flux loop can be classified into three parts, two of which represent the cooling or heating effect exerted by the ponderomotive force, while the third is the heating effect due to turbulent energy conversion from the localized plasma. This heating mechanism is used to illustrate solar atmospheric heating by means of an example that leads to the formulation of plages.

Song, M. T.↗

NASA NTRS1987

Dynamics of magnetic clouds in interplanetary space

Magnetic clouds observed in interplanetary space may be regarded as extraneous bodies immersed in the magnetized medium of the solar wind. The interface between a magnetic cloud and its surrounding medium separates the internal and external magnetic fields. Polarization currents are induced in the peripheral layer to make the ambient magnetic field tangential. The motion of a magnetic cloud through the interplanetary medium may be partitioned into a translational motion of the magnetic cloud as a whole and an expansive motion of the volume relative to the axis of the magnetic cloud. The translational motion is determined by two kinds of forces, i.e., the gravitational force exerted by the Sun, and the hydromagnetic buoyancy force exerted by the surrounding medium. On the other hand, the expansive motion is determined by the pressure gradient sustaining the gross difference between the internal and external pressures and by the self-induced magnetic force that results from the interaction among the internal currents. The force resulting from the internal and external currents is a part of the hydromagnetic buoyancy force, manifested by a thermal stress caused by the inhomogeneity of the ambient magnetic pressure.

Yeh, Tyan↗

NASA NTRS1989

Corotation torques in the solar nebula - The cutoff function

The behavior of high-order corotation resonances in a disk of finite thickness is examined. The torque exerted at an mth-order resonance is determined by employing a vertically averaged disturbing function, and the ratio of this torque to that exerted on a cold, two-dimensional disk is identified as the so-called torque cutoff function. This function is then used to calculate contributions from the corotation torques to eccentricity variations of a perturber's orbit assumed orbiting in the disk.

Ward, William R.↗

NASA NTRS1990

Mechanized Fluid Connector And Assembly Tool

In new tool-and-connector system, necessary to have access to only one side of pipe, access offset from centerline. Connections made or broken in confined spaces and with small external forces. Tool turns spur gear on externally threaded retainer on left member of connector. Retainer engages nut on right member of connector. Intended for assembly of pipes in proposed Space Station, tool and fitting used on Earth to make or break plumbing connections in crowded utility runs or other confined spaces where wrenches cannot be turned, where forces exerted by wrenches might cause damage, or where lack of good grip prevents technician from exerting sufficient torque on connector.

Zentner, Ronald C.↗

NASA NTRS1989

Teleoperator comfort and psychometric stability: Criteria for limiting master-controller forces of operation and feedback during telemanipulation

The following question is addressed: How much force should operators exert, or experience, when operating a telemanipulator master-controller for sustained periods without encountering significant fatigue and discomfort, and without loss of stability in psychometric perception of force. The need to minimize exertion demands to avoid fatigue is diametrically opposed by the need to present a wide range of force stimuli to enhance perception of applied or reflected forces. For 104 minutes subjects repetitiously performed a series of 15 s isometric pinch grasps; controlled at 5, 15, and 25 percent of their maximum voluntary strength. Cyclic pinch grasps were separated by rest intervals of 7.5 and 15 s. Upon completion of every 10 minute period, subjects interrupted grasping activities to gage the intensity of fatigue and discomfort in the hand and forearm using a cross-modal matching technique. A series of psychometric tests were then conducted to determine accuracy and stability in the subject's perception of force experienced. Results showed that onset of sensations of discomfort and fatigue were dependent upon the magnitude of grasp force, work/rest ratio, and progression of task. Declines in force magnitude estimation slopes, indicating a reduction in force perception sensitivity, occurred with increased grasp force when work/rest ratios were greater than 1.0. Specific recommendations for avoiding discomfort and shifts in force perception, by limiting pinch grasp force required for master-controller operation and range of force reflection or work/rest ratios, are provided.

Wiker, Steven F.↗