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At least 235 records · Page 13

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DOE OSTI2014

Analysis of Double-encapsulated Fuel Rods

In an LWR fuel rod, the cladding encapsulates the fuel, contains fission products, and transfers heat directly to the water coolant. In some situations, it may be advantageous to separate the cladding from the coolant through use of a secondary cladding or capsule. This may be done to increase confidence that the fuel or fission products will not mix with the coolant, to provide a mechanism for controlling the rod temperature, or to place multiple experimental rodlets within a single housing. With an axisymmetric assumption, it is possible to derive closed-form expressions for the temperature profile in a fuel rod using radially-constant thermal conductivity in the fuel. This is true for both a traditional fuel-cladding rod and a double-encapsulated fuel (fuel, cladding, capsule) configuration. Likewise, it is possible to employ a fuel performance code to analyse both a traditional and a double-encapsulated fuel. In the case of the latter, two sets of gap heat transfer conditions must be imposed. In this work, we review the equations associated with radial heat transfer in a cylindrical system, present analytic and computational results for a postulated power and gas mixture history for IFA-744, and describe the analysis of the AFC-2A, 2B metallic fuel alloy experiments at the Advanced Test Reactor, including the effect of a release of fission products into the cladding-capsule gap. The computational results for these two cases were obtained using BISON, a fuel performance code under development at Idaho National Laboratory.

BISON↗

DOE OSTI2016

Conformally encapsulated multi-electrode arrays with seamless insulation

Thin-film multi-electrode arrays (MEA) having one or more electrically conductive beams conformally encapsulated in a seamless block of electrically insulating material, and methods of fabricating such MEAs using reproducible, microfabrication processes. One or more electrically conductive traces are formed on scaffold material that is subsequently removed to suspend the traces over a substrate by support portions of the trace beam in contact with the substrate. By encapsulating the suspended traces, either individually or together, with a single continuous layer of an electrically insulating material, a seamless block of electrically insulating material is formed that conforms to the shape of the trace beam structure, including any trace backings which provide suspension support. Electrical contacts, electrodes, or leads of the traces are exposed from the encapsulated trace beam structure by removing the substrate.

36 MATERIALS SCIENCE↗

DOE OSTI2018

Thermal energy storage system comprising encapsulated phase change material

Methods of encapsulating a phase change material in a capsule including suspending a particle of the phase change material in an air stream, coating an entire surface of the suspended particle with at least one layer of a sacrificial compound, coating an entire surface of the layer of the sacrificial compound with at least one layer of a second material, and encapsulating the phase change material within a shell formed by the second material. The step of encapsulating comprising heating the particle coated with the sacrificial compound and the second material, thermally decomposing the sacrificial compound, and vaporizing the sacrificial, wherein the sacrificial compound has a decomposition temperature less than a phase change temperature of the phase change material and a phase change temperature of the second material.

25 ENERGY STORAGE↗

DOE OSTI2019

Encapsulated porous proppant

The present disclosure describes proppant materials encapsulated with a polymer encapsulation layer. Proppant particles are formed with a core having relatively larger inner pores and a shell having relatively smaller shell pores. The shell pores and/or inner pores can be loaded with a treatment product, such as a methanogenic microbial consortium capable of converting coal into methane. The polymer encapsulation layer surrounds the shell and provides for sustained time-release of the treatment product when the proppant material has been delivered to a subterranean formation.

Han, Kyu-Bum↗

DOE OSTI2020

Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies

Nanofilm-encapsulated sulfide glass solid electrolyte structures and methods for making the encapsulated glass structures involve a lithium ion conducting sulfide glass sheet encapsulated on its opposing major surfaces by a continuous and conformal nanofilm made by atomic layer deposition (ALD). During manufacture, the reactive surfaces of the sulfide glass sheet are protected from deleterious reaction with ambient moisture, and the nanofilm can be configured to provide additional performance advantages, including enhanced mechanical strength and improved chemical resistance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2020

Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies

Visco, Steven J.↗

DOE OSTI2021

Hybrid chip-on-board LED module with patterned encapsulation

Light modules and methods of forming light modules are disclosed. A light module includes a first plurality and a second plurality of light emitting elements configured to emit, respectively, a first light and a second light, and both arranged on a substrate. An encapsulation layer is disposed over the first and second plurality of the light emitting elements, and a wavelength converting element is dispersed in the encapsulation layer. A concentration of the wavelength converting element in the encapsulation layer varies, is larger over the first plurality of light emitting elements and is smaller over the second plurality of light emitting elements.

Soer, Wouter Anthon↗

DOE OSTI2022

Value Proposition of UV-Absorbers in PV Module Encapsulation

Various common crystalline silicon cell technologies were exposed to UVA radiation (1.24 Wm-2 nm-1 at 340 nm peak) on the front and back faces at 45 degrees Celsius for periods up to 3000 h, representing about 3 y of solar exposure in Phoenix, Arizona, USA. The resulting degradation of the open-circuit voltage and short-circuit current is presented. Of the various cell types examined, significant levels of degradation were seen in all cases. Less degradation was generally found after UV irradiation of cell fronts and older cell types, whereas a bifacial PERC type exposed on the rear showed about 25% degradation in short circuit current, attributable to lack of a diffused surface field. Selected cells were exposed to UV irradiation with the addition of long pass UV filters to replicate UV-absorbers in encapsulants. Modern cell designs are sensitive to UV-ID because of reduced or eliminated front and back surface field and increased dependence on high quality surface passivation. Single transformation of the independent variable (t, kW h/m^2) could be used to achieve a linear model of the data to extrapolate to 50 y. Solar Advisor Model (SAM) shows appropriate filtering of UV-irradiation can improve LCOE and net present value of plant. Some advanced cell types are seen to be UV-resistant (cell level solutions also exist). Solutions therefore exist on the cell, glass, and encapsulant level. Changes over time in each of these would also need to be considered (solarization, encapsulant browning...).

ENGINEERING,SOLAR ENERGY↗

DOE OSTI2022

Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies

Visco, Steven J.↗

DOE OSTI2017

Selection of Binders for a Reactive Metal (Tungsten) Encapsulation - 17211

Waste containing reactive metals is produced by nuclear activities, and the usual strategy is to encapsulate this waste in ordinary Portland cement (OPC) or alternative binders in a state suitable for storage. However, in the case of tungsten metal, corrosion by the pore solution of the binders could occur with hydrogen release. Based on Potential-pH diagram, tungsten metal corrosion depends on pH conditions. Consequently, studies have been performed with tungsten in a large pH scale relevant for various binders such as ordinary Portland cement (OPC), sodium geo-polymer (Na-Geo), magnesium-phosphate cement (MKP) and wollastonite-based cement (Wo). The influence of representative pore solutions of OPC, Na-Geo, MKP and Wo on tungsten corrosion has been studied by electrochemical methods (Open Circuit Potential and impedance spectroscopy). The corrosion of tungsten encapsulated in OPC, Na-Geo, MKP and Wo has been investigated by measuring the production of hydrogen over time. It is shown that ordinary Portland cement is not a suitable binder for tungsten metal encapsulation while a binder producing a pore solution with a neutral pH such as MKP presents the lowest interaction with tungsten. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2017

Dry Storage of Encapsulated Defective Fuel Rods at Doel 1 and 2 in Belgium - 17581

The project of removing all fissile and non-fissile material out of the spent fuel ponds of Belgian Doel power plant is on-going and in that framework, a solution was needed for evacuating all used fuel elements from Doel 1 and 2 storage pool, including Defective Fuel Assemblies (DFA) and Defective Fuel Rods (DFR). Following the moving out of storage pool, all used fuel elements are intended to be loaded in dry storage casks, this used fuel management option being the one implemented today in Belgium while waiting for final management. Synatom, in charge of all fuel cycle related activities for the nuclear power plants of Belgium and Engie-Electrabel, the operator of both Belgium power plants (Doel and Tihange), had then to find an industrial solution for emptying Doel 1 and 2 used fuel pool and loading DFR in dry storage casks. After having thoroughly reviewed the possible options for implementing dry storage of DFR, Synatom selected AREVA technology. It consists in: - encapsulating each DFR by loading the fuel rod in a capsule, drying the fuel rod using a process which allows to physically verify with high accuracy the residual water content inside the DFR, and welding the capsule, - assembling the capsules in a capsule canister (a skeleton with external dimensions similar to fuel assembly's) and - transferring this capsule canister along with intact fuel assemblies in an associated dry transport and storage (dual purpose) cask, as already used for interim storage of used fuel at Doel site. The French as well as the Belgian competent authorities are parties to the licensing process project. The purpose of the paper is to present the on-going industrial project related to dry storage of dried and encapsulated DFR - along with intact used fuel in dual purpose casks - at Doel 1 and 2 in Belgium, its challenges and progress. The paper presents: - why the drying method, welded capsule and associated cask is the best available technology for dry storage of DFR; - a focus on fuel assembly repair operations (initial step before encapsulation) per-formed in 2015 which consisted in successful extraction of four DFR from their original fuel assembly, using proven and experienced methods and tools; - in conclusion, an update of Doel 1 and 2 DFR dry storage project: reaching of major qualifications and licensing milestones and overview of the project perspectives. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2018

Stable Formamidinium-Based Perovskite Solar Cells via In Situ Grain Encapsulation

Formamidinium (FA)-based lead iodide perovskites have emerged as the most promising light-absorber materials in the prevailing perovskite solar cells (PSCs). However, they suffer from the phase-instability issue in the ambient atmosphere, which is holding back the realization of the full potential of FA-based PSCs in the context of high efficiency and stability. Herein, the tetraethylorthosilicate hydrolysis process is integrated with the solution crystallization of FA-based perovskites, forming a new film structure with individual perovskite grains encapsulated by amorphous silica layers that are in situ formed at the nanoscale. The silica not only protects perovskite grains from the degradation but also enhances the charge-carrier dynamics of perovskite films. The underlying mechanism is discussed using a joint experiment-theory approach. Through this in situ grain encapsulation method, PSCs show an efficiency close to 20% with an impressive 97% retention after 1000-h storage under ambient conditions.

14 SOLAR ENERGY↗

DOE OSTI2016

Encapsulation and backsheet adhesion metrology for photovoltaic modules

Photovoltaic modules are designed to operate for decades in terrestrial environments. However, mechanical stress, moisture, and ultraviolet radiation eventually degrade protective materials in modules, particularly their adhesion properties, eventually leading to reduced solar cell performance. Despite the significance of interfacial adhesion to module durability, currently there is no reliable technique for characterizing module adhesion properties. We present a simple and reproducible metrology for characterizing adhesion in photovoltaic modules that is grounded in fundamental concepts of beam and fracture mechanics. Using width-tapered cantilever beam fracture specimens, interfacial adhesion was evaluated on relevant interfaces of encapsulation and backsheet structures of new and 27-year-old historic modules. The adhesion energy, Gc [J/m 2 ], was calculated from the critical value of the strain energy release rate, G, using G = βP 2 , where β (a mechanical and geometric parameter of the fracture specimen) and P (the experimentally measured critical load) are constants. Under some circumstances where testing may result in cracking of brittle layers in the test specimen, measurement of the delamination length in addition to the critical load was necessary to determine G. Relative to new module materials, backsheet adhesion was 95% and 98% lower for historic modules that were exposed (operated in the field) and unexposed (stored on-site, but out of direct sunlight), respectively. Encapsulation adhesion was 87-94% lower in the exposed modules and 31% lower in the unexposed module. As a result, the metrology presented here can be used to improve module materials and assess long-term reliability.

14 SOLAR ENERGY↗

DOE OSTI2020

3D RNA nanocage for encapsulation and shielding of hydrophobic biomolecules to improve the in vivo biodistribution

Ribonucleic acid (RNA) nanotechnology platforms have the potential of harboring therapeutics for in vivo delivery in disease treatment. However, the nonspecific interaction between the harbored hydrophobic drugs and cells or other components before reaching the diseased site has been an obstacle in drug delivery. In this work, we report an encapsulation strategy to prevent such nonspecific hydrophobic interactions in vitro and in vivo based on a self-assembled three-dimensional (3D) RNA nanocage. By placing an RNA three-way junction (3WJ) in the cavity of the nanocage, the conjugated hydrophobic molecules were specifically positioned within the nanocage, preventing their exposure to the biological environment. The assembly of the nanocages was characterized by native polyacrylamide gel electrophoresis (PAGE), atomic force microscopy (AFM), and cryogenic electron microscopy (cryo-EM) imaging. The stealth effect of the nanocage for hydrophobic molecules in vitro was evaluated by gel electrophoresis, flow cytometry, and confocal microscopy. The in vivo sheathing effect of the nanocage for hydrophobic molecules was assessed by biodistribution profiling in mice. The RNA nanocages with hydrophobic biomolecules underwent faster clearance in liver and spleen in comparison to their counterparts. Therefore, this encapsulation strategy holds promise for in vivo delivery of hydrophobic drugs for disease treatment.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2018

Packed and fluidized bed absorber modeling for carbon capture with micro-encapsulated sodium carbonate solution

Micro-Encapsulated CO 2 Sorbents (MECS) are a promising technology for post-combustion carbon capture because they enable slow-reacting solvents like carbonate solution to compete with traditional amine solvents. Before scaling up MECS for pilot testing, modeling is needed to design a MECS absorber and quantify its size and energy penalty. To that end, a multi-scale model for MECS- that ranges from a single capsule to a 500 MWe power plant absorber- is developed and presented here in this paper. First, the individual capsule model is developed and fitted to experimental CO 2 absorption data collected on a 0.1 g sample of capsules filled with sodium carbonate solution. This capsule model is then validated against data collected on a 25 g batch of capsules exposed to flue gas conditions in a fluidized column. This model is then scaled up to represent two absorber designs: a multi-stage, counter-flow fluidized bed and a hollow, cylindrical packed bed with radial gas flow. These two absorber bed models are first optimized for a 1 MWe pilot-scale absorber, and then optimized for a 500 MWe coal plant. This model predicts absorbers of similar dimensions and smaller energy penalties than previously modeled absorbers filled with amine solvent capsules. Furthermore, it is demonstrated here that a few reasonable improvements to capsule design would result in absorber sizes and energy penalties lower than those of a benchmark amine solvent tower. These results demonstrate that micro-encapsulated carbonate solution can compete with faster-acting amine solvents for post-combustion carbon capture.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2015

Crystal orbital study on the double walls made of nanotubes encapsulated inside zigzag carbon nanotubes

The structure stabilities and electronic properties are investigated by using ab initio self-consistent-field crystal orbital method based on density functional theory for the one-dimensional (1D) double-wall nanotubes made of n-gon SiO{sub 2} nanotubes encapsulated inside zigzag carbon nanotubes. It is found that formation of the combined systems is energetically favorable when the distance between the two constituents is around the Van der Waals scope. The obtained band structures show that all the combined systems are semiconductors with nonzero energy gaps. The frontier energy bands (the highest occupied band and the lowest unoccupied band) of double-wall nanotubes are mainly derived from the corresponding carbon nanotubes. The mobilities of charge carriers are calculated to be within the range of 10{sup 2}–10{sup 4} cm{sup 2} V{sup −1} s{sup −1} for the hybrid double-wall nanotubes. Young’s moduli are also calculated for the combined systems. For the comparison, geometrical and electronic properties of n-gon SiO{sub 2} nanotubes are also calculated and discussed. - Graphical abstract: Structures and band structures of the optimum 1D Double walls nanotubes. The optimized structures are 3-gon SiO2@(15,0), 5-gon SiO2@(17,0), 6-gon SiO2@(18,0) and 7-gon SiO2@(19,0). - Highlights: • The structure and electronic properties of the 1D n-gon SiO{sub 2}@(m,0)s are studied using SCF-CO method. • The encapsulation of 1D n-gon SiO{sub 2} tubes inside zigzag carbon nanotubes can be energetically favorable. • The 1D n-gon SiO{sub 2}@(m,0)s are all semiconductors. • The mobility of charge carriers and Young’s moduli are calculated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Preventing native oxide formation in niobium thin films through platinum encapsulation

Superconducting transmon qubits are a key technology in quantum computing, with niobium (Nb) widely used due to its favorable superconducting properties and compatibility with scalable fabrication. However, the performance of Nb-based qubits is hindered by two-level systems (TLS), which arise predominantly from native oxide layers at surfaces and interfaces. These oxides and suboxides form rapidly in air and contribute significantly to decoherence by introducing dielectric losses. While various mitigation strategies, including thermal-annealing, chemical-etching, and nitrogen plasma treatment, have been explored, many are challenging to integrate into large-scale manufacturing due to complexity and instability in ambient conditions. In this study, we investigate the structural, chemical, and superconducting properties of room-temperature sputtered Nb thin films grown on sapphire substrates. We focus on a surface protection strategy using noble metal encapsulation with platinum (Pt) to suppress oxides and reduce TLS-related losses. Structural and chemical characterization were performed using X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. Superconducting properties were measured using a physical property measurement system. Results demonstrate that Pt encapsulation effectively suppresses surface oxidation and mitigates its detrimental impact on superconducting performance. In conclusion, this approach offers a promising path toward enhancing the coherence of Nb-based qubits while remaining compatible with scalable-fabrication processes.

36 MATERIALS SCIENCE↗

DOE OSTI2015

Superior Current Carrying Capacity of Boron Nitride Encapsulated Carbon Nanotubes with Zero-Dimensional Contacts

We report fabrication and characterization of hexagonal boron nitride (hBN)-encapsulated carbon nanotube (CNT) field effect transistors, which are coupled to electrical leads via zero-dimensional contacts. Device quality is attested by the ohmic contacts and observation of Coulomb blockade with a single periodicity in small bandgap semiconducing nanotubes. Surprisingly, hBN-encapsulated CNT devices demonstrate significantly enhanced current carrying capacity; a single-walled CNT can sustain >180 μA current or, equivalently, a current density of ~2 × 10 10 A/cm 2 , which is a factor of 6–7 higher than devices supported on SiO 2 substrates. Such dramatic enhancement of current carrying capacity arises from the high thermal conductivity of hBN and lower hBN-CNT interfacial thermal resistance and has implications for carbon electronic applications.

36 MATERIALS SCIENCE↗