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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Raman spectra of adsorbed layers on space shuttle and AOTV thermal protection system surface

Surfaces of interest to space vehicle heat shield design were struck by a 2 W argon ion laser line while subjected to supersonic arc jet flow conditions. Emission spectra were taken at 90 deg to the angle of laser incidence on the test object. Results showed possible weak Raman shifts which could not be directly tied to any particular parameter such as surface temperature or gas composition. The investigation must be considered exploratory in terms of findings. Many undesirable effects were found and corrected as the project progressed. For instance, initial spectra settings led to ghosts which were eliminated by closing the intermediate of filter slit of the Spex from 8 to 3 mm. Further, under certain conditions, plasma lines from the laser were observed. Several materials were also investigated at room temperature for Raman shifts. Results showed Raman shifts for RCC and TEOS coated materials. The HRSI materials showed only weak Raman shifts, however, substantial efforts were made in studying these materials. Baseline materials showed the technique to be sound. The original goal was to find a Raman shift for the High-temperature Reusable Surface Insulation (HRSI) Reaction Cured borosilicate Glass (RCG) coated material and tie the amplitude of this peak to Arc jet conditions. Weak Raman shifts may be present, however, time limitations prevented confirmation.

Willey, Ronald J.↗
NASA NTRS1994

Very high energy gamma rays from active galactic nuclei: Cascading on the cosmic background radiation fields and the formation of pair halos

Recent high-energy gamma-ray observations (E(sub gamma) greater than 100 MeV) of blazar Active Galactic Nuclei (AGNs) show emission spectra with no clear upper energy cutoff. AGNs, considered to be possible sources for the observed flux of cosmic rays beyond 10(exp 19) eV, may well have emission extending into the very high energy (VHE), (E(sub gamma) greater than 100 GeV) domain. Because VHE gamma-rays are absorbed by pair production on the intergalactic background radiation fields, much of this emission may not be directly visible. The electromagnetic cascades initiated by absorbed VHE gamma-rays, however, may be observable. Since, most probably, the velocities of (e(+), e(-)) pairs produced in a cascade are quickly isotropized by an ambient random magnetic field, extended 'halos' (R greater than 1 Mpc) of pairs will be formed around AGNs with VHE emission. The cascade radiation from these pair halos is emitted isotropically and should be observable at energies below a few TeV. The halo radiation can be distinguished by its characteristic variation in spectrum and intensity with angular distance from the central source. This variation depends weakly on the details of the central source model, e.g., the orientation and beaming/opening angle of an emitting jet. Limiting or determining the intensity of the pair halo can thus serve as a model-independent bound on or measure of the VHE power of AGNs. Next-generation Cherenkov telescopes may be able to image a pair halo.

Aharonian, F. A.↗
NASA NTRS1987

The origin of the diffuse galactic IR/submm emission: Revisited after IRAS

Balloon observations are compared with Infrared Astronomy Satellite observations. There was good agreement for the longitudinal profiles. However, the dust emission observed by IRAS, contrary to the balloon observations which show dust emission only within the absolute value of b is equal to or less than 3 degrees, extends all the way to the galactic pole. The model fits were repeated using more recent parameters for the distribution of interstellar matter in the galactic disk and central region. The IR luminosities are derived for the revised galactic distance scale of solar radius - 8.5 Kpc. A total IR luminosity of 1.2 E10 solar luminosity is obtained, which is about one third of the estimated stellar luminosity of the Galaxy. The dust emission spectrum lambdaI(sub lambda) attains it maximum at 100 microns. A secondary maximum in the dust emission spectrum occurs at 10 microns, which contains 15% of the total IR luminosity of the Galaxy. The galactic dust emission spectrum was compared with the dust emission spectra of external IRAS galaxies. The warm dust luminosity relates to the present OB star formation rate, while flux densities observed at longer submm wavelengths are dominated by cold dust emission and thus can be used to estimate gas masses.

Cox, P.↗
NASA NTRS2013

Automating Hyperspectral Data for Rapid Response in Volcanic Emergencies

In a volcanic emergency, time is of the essence. It is vital to quantify eruption parameters (thermal emission, effusion rate, location of activity) and distribute this information as quickly as possible to decision-makers in order to enable effective evaluation of eruption-related risk and hazard. The goal of this work was to automate and streamline processing of spacecraft hyperspectral data, automate product generation, and automate distribution of products. Visible and Short-Wave Infrared Images of volcanic eruption in Iceland in May 2010." class="caption" align="right">The software rapidly processes hyperspectral data, correcting for incident sunlight where necessary, and atmospheric transmission; detects thermally anomalous pixels; fits data with model black-body thermal emission spectra to determine radiant flux; calculates atmospheric convection thermal removal; and then calculates total heat loss. From these results, an estimation of effusion rate is made. Maps are generated of thermal emission and location (see figure). Products are posted online, and relevant parties notified. Effusion rate data are added to historical record and plotted to identify spikes in activity for persistently active eruptions. The entire process from start to end is autonomous. Future spacecraft, especially those in deep space, can react to detection of transient processes without the need to communicate with Earth, thus increasing science return. Terrestrially, this removes the need for human intervention.

Davies, Ashley G.↗
NASA NTRS1977

Nonthermal galactic emission below 10 MHz

The Radio Astronomy Explorer-2 (RAE-2) satellite has provided new measurements of the nonthermal galactic radio emission at frequencies below 10 MHz. Measurements of the emission spectra are presented for the center, anticenter, north polar, and south polar directions at 22 frequencies between 0.25 and 9.18 MHz. Survey maps of the spatial distribution of the observed low frequency galactic emission at 1.31, 2.20, 3.93, 4.70, 6.55, and 9.18 MHz are presented. The observations were obtained with the 229-meter traveling-wave V-antenna on this lunar orbiting spacecraft. The improved frequency coverage offers additional insights into structure of the local galactic neighborhood.

Novaco, J. C.↗
NASA NTRS1997

High-Resolution Studies of Extreme-Ultraviolet Emission from CO by Electron Impact

We report a high-resolution study (0.0036 nm full width at half maximum) of electron-impact-induced emission spectra of CO at 30-, 75-, and 100-eV electron-impact energies. The spectral features were acquired in optically thin conditions. At the specified resolution, attainable with our 3-m vacuum ultraviolet spectrometer, we observe rotationally resolved emission bands of CO in the extreme ultraviolet, from the vibronic states B (sup 1)sigma(sup +)(0), C (sup 1)sigma(sup+)(0), and E (sup 1)pi(0), to the ground state X (sup 1)sigma(sup +)(0). A simple model of these bands, based on the Honl-London factors and the rotational constants, is constructed and is shown to be in good agreement with the observed spectra. The predissociation yield for the E (sup 1)pi electronic state has been determined, showing that the E state has the largest predissociation cross section of CO for all singlet-state Rydberg series members. The excitation function of the [E (sup 1)pi(0) yields X (sup 1)sigma(sup +)(0)] transition, in the 0-800-eV impact energy range, is measured, permitting determination of the oscillator strength by using a modified Born approximation analytical fit.

Ciocca, Marco↗
NASA NTRS1978

Nonthermal galactic emission below 10 megahertz

The Radio Astronomy Explorer 2 (RAE 2) lunar-orbiting satellite has provided measurements of the nonthermal galactic radio emission at frequencies below 10 MHz. Measurements of the emission spectra are presented for the center, anticenter, north polar, and south polar directions at 22 frequencies between 0.25 and 9.18 MHz. Survey maps of the spatial distribution of the observed low-frequency Galactic emission at 1.31, 2.20, 3.93, 4.70, 6.55, and 9.18 MHz are presented. The observations were obtained with the 229-m traveling-wave V antenna on this lunar-orbiting spacecraft. The improved frequency coverage offers additional insights into the structure of the local Galactic neighborhood.

Milky Way↗
NASA NTRS1988

Molecular processes in comets

The transition dipole moments of the c 3 Pi u - a 3 Sigma g +, i 3 Pi g - c 3 Pi u, and i 3 Pi g - b 3 Sigma u + transitions of molecular hydrogen were calculated over a wide range of internuclear distances R. Calculations of the emission spectra are nearing completion. Substantial progress was made in the calculation of the absorption coefficient of a colliding pair of hydrogen atoms in the binary encounter approximation. Detailed calculations were performed on the continuum emission arising from the excitation of the a 3 sigma g + state of H2 by the impact of electrons of various energies. Each curve is labelled by the electron energy in electron volts. The strong emission near Lyman alpha is interesting in that it is produced by excitation of molecular hydrogen.

Dalgarno, A.↗
NASA NTRS2016

The UK Met Office GCM with a Sophisticated Radiation Scheme Applied to the Hot Jupiter HD 209458b

To study the complexity of hot Jupiter atmospheres revealed by observations of increasing quality, we have adapted the UK Met Office Global Circulation Model (GCM), the Unified Model (UM), to these exoplanets. The UM solves the full 3D Navier-Stokes equations with a height-varying gravity, avoiding the simplifications used in most GCMs currently applied to exoplanets. In this work we present the coupling of the UM dynamical core to an accurate radiation scheme based on the two-stream approximation and correlated-k method with state-of-the-art opacities from ExoMol. Our first application of this model is devoted to the extensively studied hot Jupiter HD 209458b. We derive synthetic emission spectra and phase curves, and compare them to both previous models also based on state-of-the-art radiative transfer, and to observations. We find a reasonable a agreement between observations and both our days side emission and hot spot offset, however, our night side emissions is too large. Overall our results are qualitatively similar to those found by Showman et al. (2009) with the SPARCMIT gcm, however, we note several quantitative differences: Our simulations show significant variation in the position of the hottest part of the atmosphere with pressure, as expected from simple timescale arguments, and in contrast to the vertical coherency found by Showman et al. (2009). We also see significant quantitative differences in calculated synthetic observations. Our comparisons strengthen the need for detailed intercomparisons of dynamical cores, radiation schemes and post-processing tools to understand these differences. This effort is necessary in order to make robust conclusions about these atmospheres based on GCM results.

radiation↗
NASA NTRS2008

Laser Infrared Desorption Spectroscopy to Detect Complex Organic Molecules on Icy Planetary Surfaces

Laser Desorption-Infrared Spectroscopy (LD-IR) uses an IR laser pulse to desorb surface materials while a spectrometer measures the emission spectrum of the desorbed materials (Figure 1). In this example, laser desorption operates by having the incident laser energy absorbed by near surface material (~10 microns in depth). This desorption produces a plume that exists in an excited state at elevated temperatures. A natural analog for this phenomenon can be observed when comets approach the sun and become active and individual molecular emission spectra can be observed in the IR [1,2,3,4,5]. When this occurs in comets, the same species that initially emit radiation down to the ground state are free to absorb it, reducing the amount of detectable emission features. The nature of our technique results in absorption not occurring, because the laser pulse could easily be moved away form the initial desorption plume, and still have better spatial resolution then reflectance spectroscopy. In reflectance spectroscopy, trace components have a relatively weak signal when compared to the entire active nature of the surface. With LDIR, the emission spectrum is used to identify and analyze surface materials.

Laser Desorption-Infrared Spectroscopy↗
NASA NTRS2019

Measuring the D/H Ratios of Exoplanets and Brown Dwarfs

The relative abundance of deuterium and hydrogen is a potent tracer of planet formation and evolution. Jupiter and Saturn have protosolar atmospheric D/H ratios, a relic of substantial gas accretion from the nebula, while the atmospheres of Neptune and Uranus are enhanced in D by accretion of ices into their envelopes. For terrestrial planets, D/H ratios are used to determine the mechanisms of volatile delivery and subsequent atmosphere loss over the lifetime of the planet. Planets and brown dwarfs more massive than ~13 M(J) quickly fuse their initial D reservoir. Here, we simulate spectra for giant exoplanets and brown dwarfs (2 M(Neptune) to ~10 M(Jupiter)) from T(eff) = 200–1800 K including both CH3D and HDO to determine the observability of these dominant deuterium isotopologues in mid-infrared thermal emission spectra. Colder objects have stronger molecular features in their spectra, due to the temperature dependence of molecular cross sections. CH3D is easier to observe than HDO at all temperatures considered, due to the strength of its absorption bands and locations of features at wavelengths with few other strong absorption features. We predict that for nearby cool brown dwarfs, the CH3D abundance can be measured at high signal to noise with the James Webb Space Telescope (JWST); for objects from 200 to 800 K closer than 10 pc, a protosolar D/H ratio would be readily observable in 2.5 hr. Moderately young Jupiter-mass planets (100–300 Myr) and young Neptunes (10 Myr) may be discovered with JWST and provide the best targets for detecting deuterium on an exoplanet in the coming decade. Future telescope designs should consider the importance of isotopes for understanding the formation and evolution of planetary atmospheres.

Caroline V. Morley↗
NASA NTRS1986

Laser induced fluorescence and phosphorescence of matrix isolated glyoxal - Evidence for exciplex formation in the A 1Au and a 3Au states

Laser-induced fluorescence and phosphorescence as well as infrared and visible absorption spectra of glyoxal in Ar, N2, and CO matrices are presented and analyzed. Glyoxal in its first excited electronic state is shown to form an exciplex with its nearest neighbors in all three matrices, and transitions normally forbidden dominate the emission spectra. The spectral characteristics of these complexes are similar to those of the Ar-glyoxal complex found in supersonic beam experiments. Due to the matrix cage effect, no vibrational predissociation is observed. The phosphorescence lifetime is determined and an upper limit is given for the fluorescence lifetime. This, in combination with the relative intensities of fluorescence and phosphorescence, can be used to place limits on the quantum yields of the various relaxation processes.

Van Ijzendoorn, L. J.↗
NASA NTRS1996

Spectroscopic Measurement of the Flows in an Arc-Jet Facility

To provide the proper test conditions for various applications, the characteristics of arcjet test facilities should be known. To determine the operational characteristics of an arcjet facility, emission spectroscopy measurements have been performed and analyzed in a previous study. As an extension of the study, radiation from the free stream and the shock layer of 15 cm diameter blunt-body test articles is measured under different test conditions in the NASA Ames 20 MW Arcjet Facility. The test gas is a mixture of argon and air or N2 and argon. To capture the spatially resolved emission spectra along the stagnation streamline of the blunt-body, a CCD camera (1024 x 256 array) with .275 m Czerny-Turner spectrograph is used. The optical system is calibrated in situ using tungsten and deuterium radiation sources. The emission measurements supplement the existing data base and will help provide better understanding of the equilibration processes in the shock layer region.

Park, C. S.↗
NASA NTRS1993

Planetary and satellite x ray spectroscopy: A new window on solid-body composition by remote sensing

The rings and most of the satellites of the outer planets orbit within the radiation belts of their parent bodies. This is an environment with intense fluxes of energetic electrons. As a result, these objects are strong emitters of X-rays. The characteristic X-ray lines from these bodies depend on atomic composition, but they are not sensitive to how the material is arranged in compounds or mixtures. X-ray fluorescence spectral analysis has demonstrated its unique value in the laboratory as a qualitative and quantitative analysis tool. This technique has yet to be fully exploited in a planetary instrument for remote sensing. The characteristic X-ray emissions provide atomic relative abundances. These results are complementary to the molecular composition information obtained from IR, visible, and UV emission spectra. The atomic relative abundances are crucial to understanding the formation and evolution of these bodies. They are also crucial to the proper interpretation of the molecular composition results from the other sensors. The intensities of the characteristic X-ray emissions are sufficiently strong to be measured with an instrument of modest size. Recent developments in X-ray detector technologies and electronic miniaturization have made possible space-flight X-ray imaging and nonimaging spectrometers of high sensitivity and excellent energy resolution that are rugged enough to survive long-duration space missions. Depending on the application, such instruments are capable of resolving elemental abundances of elements from carbon through iron. At the same time, by measuring the bremsstrahlung intensity and energy spectrum, the characteristics of the source electron flux can be determined. We will discuss these concepts, including estimated source strengths, and will describe a small instrument capable of providing this unique channel of information for future planetary missions. We propose to build this instrument using innovative electronics packaging methods to minimize size and weight.

Chenette, D. L.↗
NASA NTRS1980

Temperature gradients through EHD films and molecular alignment evidenced by infrared spectroscopy

Partial and complete emission band reversals have been observed in the infrared emission spectra from portions of operating sliding contacts. An elementary analysis has been carried out to show that partial reversals are due to temperature gradients in the fluid film - the film acts both as a radiation-emitter and absorber, and that total reversals - an emission spectrum appears as an absorption spectrum are likely to be due to a continuum source, such as hot solid asperities. The total energy radiated under the latter conditions exceeds that under the others. A decrease in gap width with increased load was accompanied by a dramatic spectral change in the case of 5P4E polyphenyl ether, which is indicative of molecular alignment.

King, V. W.↗
NASA NTRS1994

A Possible Cyclotron Line Signature from Quiescent Gamma-Ray Burst Counterparts

If gamma-ray bursts are associated with isolated, magnetized neutron stars in the Galaxy, they may be accreting directly from the interstellar medium after the burst event. In addition to a soft thermal component (T(sub e) approx. 100 eV), we predict that the faint quiescent emission spectra from these sources will possess a unique nonthermal signature: for magnetic field strengths B approx. equal to(0.7-7) x 10(exp 12) G, approx. 0.5-5% of the total luminosity could be emitted in a narrow (E/Delta E approx. 2-4) cyclotron emission line which peaks between approx. 5-20 keV below the cyclotron resonance energy (E(sub B) = 11.6(B/10(exp 12) G) keV). Unlike the soft thermal emission, this hard cyclotron component will not be strongly absorbed by the intervening H I gas. For stars with B approx. 10(exp 12) G, this nonthermal feature should be detectable by the instruments onboard ASCA and on the next generation of X-ray satellites (e.g., ASTRO-E). We therefore propose that deep X-ray images be taken on gamma-ray burst sources with excellent positions (error boxes less than or approx. equal to l') such as is being planned for GRB920501 to look for this feature. A positive detection would strongly suggest that at least some of the gamma-ray bursters are associated with isolated, magnetized neutron stars in the Galaxy.

Wang, John C. L.↗