In Situ Transmission Electron Microscopy Study of Electrochemical Lithiation and Delithiation Cycling of the Conversion Anode RuO 2
Conversion-type electrodes represent a broad class of materials with a new Li + reactivity concept. Of these materials, RuO 2 can be considered a model material due to its metallic-like conductivity and its high theoretical capacity of 806 mAh/g. In this study, we use in situ transmission electron microscopy to study the reaction between single-crystal RuO 2 nanowires and Li + . We show that a large volume expansion of 95% occurs after lithiation, 26% of which is irreversible after delithiation. Significant surface roughening and lithium embrittlement are also present. Furthermore, we show that the initial reaction from crystalline RuO 2 to the fully lithiated mixed phase of Ru/Li 2 O is not fully reversible, passing through an intermediate phase of Li x RuO 2 . In subsequent cycles, the phase transitions are between amorphous RuO2 in the delithiated state and a nanostructured network of Ru/Li 2 O in the fully lithiated phase.