The Nd-Rh system
Phase diagram of Nd-Rh system determined by powder X ray diffraction, metallography and differential thermal analysis methods
Raman, A.↗
SEARCH · Engineering Papers
Results for “Diffraction systems”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Stream pattern analysis using optical processing of ERTS imagery of Kansas
A spatial frequency analysis was carried out to obtain large-scale geologic and other ground pattern spatial frequency and orientational data from an optical data processing system using Earth Resources Technology Satellite-1 (ERTS-1) imagery of Kansas as input. The Diffraction Pattern Sampling Unit (DPSU) of the optical data processing system consists of a photodiode array containing 32 wedge-shaped photodiodes and 32 annular ring diodes. The curve obtained from the intensity distribution of the frequency spectrum yielded by the ring diodes gives the spatial frequency contributions due to ground features on the image. The curve obtained from the wedge-shaped diodes indicates the orientation of features in the sample area. Ten sample sites were used for each of eight geologic-physiographic regions. Comparison of ERTS-1 images with their respective spatial frequency and orientational curves reveals that preferred orientations of drainage produce recognizable peaks.
Mccauley, J.↗
Stray light in the Infrared Astronomical Satellite (IRAS)
Changes made to the telescope and critical objects considered in modeling these changes into the APART program are described. The optical system was analyzed for scattered light, diffracted then scattered radiation, and thermally emitted radiation. The damaged area of the primary to mirror was also examined. Results are presented in tables and graphs.
Lange, S. R.↗
Acousto-optic spectrometer for radio astronomy
Recent developments in acousto-optic techniques and in photodetector arrays have made feasible a new type of RF spectrometer, offering the advantages of wide bandwidth, high resolution, large number of channels in compact, lightweight, energy efficient, and relatively low cost systems. Such a system employs an acousto-optic diffraction cell which serves the key role of converting RF signals to ultrasonic traveling-waves modulating the optical index of the cell. The cell is illuminated across its aperture by a monochromatic laser beam. A fraction of the light is diffracted by the acoustic waves. A focusing lens follows the cell and essentially performs a Fourier transform of the RF signal into a far-field intensity pattern. CSIRO in Australia and the Tokyo Astronomical Observatory in Japan have taken the lead in using acousto-optic techniques in astronomical applications. The first practical device was successfully made at CSIRO for obtaining dynamical spectrographs of solar radio emission.
Chin, G.↗
Stray light analysis of the Cryogenic Limb Array Etalon Spectrometer
The stray light analysis performance of the Cryogenic Limb Array Etalon Spectrometer (CLAES), which is to be flown on NASA's Upper Atmospheric Research Satellite, was evaluated using the APART/PADE code, and the results are reported. The analysis, together with Brassboard measurements, confirm that the data to be collected by CLAES should not be significantly degraded by stray light resulting from scattering within the system. It is also verified that diffraction effects are successfully controlled by the cascaded stop configuration.
Birge, Thomas A.↗
Construction of a Visible Diode Laser Source for Free Radical Photochemistry and Spectroscopy Experiments
Tunable diode lasers are reliable sources of narrow-band light and comparatively cheap. Optical feedback simplifies frequency tuning of the laser diodes. We are building an inexpensive diode laser system incorporating optical feedback from a diffraction grating. The external optical cavity can be used with lasers that emit between 2 and 100 mW, and will also work if they are pulsed, although this will significantly degrade the bandwidth. The diode laser output power and bandwidth are comparable to CW dye lasers used in kinetics and dynamics experiments. However, their cost and maintenance will be much less as will alignment time. We intend to use the diode lasers to investigate CN and C2 kinetics as well as to study dissociation dynamics of atmospherically important molecules.
Newman, Bronjelyn↗
Actuated Hybrid Mirrors for Space Telescopes
This paper describes new, large, ultra-lightweight, replicated, actively controlled mirrors, for use in space telescopes. These mirrors utilize SiC substrates, with embedded solid-state actuators, bonded to Nanolaminate metal foil reflective surfaces. Called Actuated Hybrid Mirrors (AHMs), they use replication techniques for high optical quality as well as rapid, low cost manufacturing. They enable an Active Optics space telescope architecture that uses periodic image-based wavefront sensing and control to assure diffraction-limited performance, while relaxing optical system fabrication, integration and test requirements. The proposed International Space Station Observatory seeks to demonstrate this architecture in space.
silicon carbide↗
X-ray spectrographs using radial groove gratings
A high efficiency spectrograph design for the EUV and soft X rays is presented. This grazing incidence system uses a plane surface reflection grating with rulings that are radial, like the spokes of a wheel. The grating is placed in a beam of light that is converging to a focus. The single reflection off the grating is in the conical diffraction mount ensuring maximum performance from the system. Aberrations and performance levels are discussed. The gratings can be manufactured with existing ruling engines. Sample applications to an X-ray monochromator and an EUV stellar spectrograph are discussed.
Cash, W. C., Jr.↗
Large space antenna communications systems: Integrated Langley Research Center/Jet Propulsion Laboratory development activities. 2: Langley Research Center activities
The electromagnetic analysis activities at the Langley Research Center are resulting in efficient and accurate analytical methods for predicting both far- and near-field radiation characteristics of large offset multiple-beam multiple-aperture mesh reflector antennas. The utilization of aperture integration augmented with Geometrical Theory of Diffraction in analyzing the large reflector antenna system is emphasized.
Cambell, T. G.↗
Predicting Pulsed-Laser Deposition SrTiO 3 Homoepitaxy Growth Dynamics Using High-Speed Reflection High-Energy Electron Diffraction
Pulsed-laser deposition (PLD) is a powerful technique for growing complex oxides with controlled stoichiometry. To understand growth dynamics therein, it is common to leverage in situ spectroscopies, such as reflection high-energy electron diffraction (RHEED), to monitor surface crystallinity. Most commercial systems rely on video-rate cameras operating at 60-120 Hz that lack sufficient temporal resolution to capture growth dynamics at practical deposition frequencies. Here, a high-speed platform to record in situ dynamics via RHEED at >500 Hz is implemented. An open-source analysis package is designed to fit diffraction spots to 2D Gaussians, allowing single-pulse surface reconstruction kinetics extraction. Using homoepitaxially deposited (001)-oriented SrTiO 3 as a model system, we demonstrate how high-speed RHEED can provide real-time insight into growth processes obscured by slower acquisition systems. By fitting the single-pulse intensity to a set of exponential functions, we observe changes in the characteristic decay time and mechanism correlated to the substrate step width and surface termination. We observe distinct surface effects, with diffraction intensity decaying on lower-energy TiO 2 -terminated surfaces and stabilizing on SrO- or mixed-terminated surfaces. Similarly, using an exponential model, the extracted characteristic time of adatom deposition decreases with increased density of bonding sites associated with mixed termination and narrower step widths. Ultimately, this work shows how increasing RHEED temporal resolution can uncover new insights into growth processes, with practical implications for the design and control of PLD processes. This experimental platform provides new capabilities to enable data-driven machine learning analysis and autonomous control systems to enhance the complexity and fecundity of PLD.
(SrO)↗
Optical Interference for the Guidance of Cryogenic Focused Ion Beam Milling Beyond the Axial Diffraction Limit
Using a tri-coincident cryogenic FIB-SEM-LM system, we identify an interferometric optical response that can be used for targeting lamella production to fluorescently labelled structures with accuracy beyond the diffraction limit. We demonstrate the approach using synthetic samples of fluorescent beads embedded in micron-scale droplets of water. Here, we then apply the approach to capture virions inside host cells. Successful targeting is confirmed by cryogenic electron tomography revealing clusters of virions in intracellular vesicles.
Sica, Anthony V. [SLAC National Accelerator Labora↗
The far field diffraction pattern for corner reflectors with complex reflection coefficients
The far field diffraction pattern of a geometrically perfect corner reflector is examined analytically for normally incident monochromatic light. The states of polarization and the complex amplitudes of the emerging light are expressed through transformation matrices in terms of those of the original incident light for each sextant of the face in a single coordinate system. The analytic expression of the total diffraction pattern is obtained for a circular face. This expression consists of three component functions in addition to the basic Airy function. The coefficient of each function is expressed in terms of complex coefficients of reflectance of the reflecting surface. Some numerical results for different reflecting surfaces, including total internal reflection, are presented. The iso-intensity contours of the diffraction pattern evaluated from the analytical expressions for an uncoated solid corner reflector are also presented along with the photographs of the pattern.
Chang, R. F.↗
Simultaneous measurements of volume, pressure, optical images, and crystal structure with a dynamic diamond anvil cell: A real-time event monitoring system
The dynamic diamond anvil cell (dDAC) technique has attracted great interest because it possibly provides a bridge between static and dynamic compression studies with fast, repeatable, and controllable compression rates. The dDAC can be a particularly useful tool to study the pathways and kinetics of phase transitions under dynamic pressurization if simultaneous measurements of physical quantities are possible as a function of time. We report the development of a real-time event monitoring (RTEM) system with dDAC, which can simultaneously record the volume, pressure, optical image, and structure of materials during dynamic compression runs. In particular, the volume measurement using both Fabry–Pérot interferogram and optical images facilitates the construction of an equation of state (EoS) using the dDAC in a home-laboratory. We also developed an in-line ruby pressure measurement (IRPM) system to be deployed at a synchrotron x-ray facility. This system provides simultaneous measurements of pressure and x-ray diffraction in low and narrow pressure ranges. The EoSs of ice VI obtained from the RTEM and the x-ray diffraction data with the IRPM are consistent with each other. The complementarity of both RTEM and IRPM systems will provide a great opportunity to scrutinize the detailed kinetic pathways of phase transitions using dDAC.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Modeling and experimental validation of dynamical effects in Bragg coherent x-ray diffractive imaging of finite crystals
Bragg coherent diffractive imaging (BCDI) is a noninvasive microscopy technique that can visualize the shape and internal lattice deviations of crystals with nanoscale spatial resolution and picometer deformation sensitivity. Its strain imaging capability relies on Fourier transform–based iterative phase retrieval algorithms, which are mostly developed under the kinematical approximation. Such approximation prohibits the application of BCDI on larger crystals, which are commonly seen in most emerging functional materials. Understanding the dynamical effect in BCDI, as well as developing a validated method for modeling BCDI at the dynamical diffraction limit, is crucial for applying BCDI to hierarchical systems that contain micron-sized crystals and grains. Thus we report a comparative study on the impact of dynamical diffraction effects by comparing the reconstruction results from two measurements of the same crystal. Forward simulation is implemented to show subtle changes of interference fringes in the diffraction pattern due to the dynamical diffraction, and is compared directly with the experimental data.
36 MATERIALS SCIENCE↗
Reaction kinetics during early hydration of calcined phyllosilicates in clinker-free model systems
Investigations of nearly pure, calcined phyllosilicates (“meta-phyllosilicates”) in clinker-free model systems were performed in presence and absence of sulfate. Calorimetric investigations show a pronounced reaction during the early reaction period only for metakaolin. Quantitative in situ X-ray diffraction reveals calcium silicate hydrate formation in the systems with metakaolin and metaillite, but not in those with metamuscovite. Ettringite crystallizes in all systems containing sulfate, where only the metakaolin system reaches the maximum ettringite content possible. The amount of aluminum ions released from 2:1 meta-phyllosilicates seems to be insufficient to reach the maximum content. Differences in portlandite dissolution and bound water indicate adsorption effects of calcium or calcium – sulfate ion pair complexes on surfaces of the calcined clay particles. Thus, the chemical as well as the physical influence of the meta-phyllosilicates must be considered to predict the reaction kinetics of calcined clays during early hydration.
36 MATERIALS SCIENCE↗
Double diffraction imaging of x-ray induced structural dynamics in single free nanoparticles
Abstract Because of their high photon flux, x-ray free-electron lasers (FEL) allow to resolve the structure of individual nanoparticles via coherent diffractive imaging (CDI) within a single x-ray pulse. Since the inevitable rapid destruction of the sample limits the achievable resolution, a thorough understanding of the spatiotemporal evolution of matter on the nanoscale following the irradiation is crucial. We present a technique to track x-ray induced structural changes in time and space by recording two consecutive diffraction patterns of the same single, free-flying nanoparticle, acquired separately on two large-area detectors opposite to each other, thus examining both the initial and evolved particle structure. We demonstrate the method at the extreme ultraviolet (XUV) and soft x-ray Free-electron LASer in Hamburg (FLASH), investigating xenon clusters as model systems. By splitting a single XUV pulse, two diffraction patterns from the same particle can be obtained. For focus intensities of about 2 × 10 12 W cm −2 we observe still largely intact clusters even at the longest delays of up to 650 picoseconds of the second pulse, indicating that in the highly absorbing systems the damage remains confined to one side of the cluster. Instead, in case of five times higher flux, the diffraction patterns show clear signatures of disintegration, namely increased diameters and density fluctuations in the fragmenting clusters. Future improvements to the accessible range of dynamics and time resolution of the approach are discussed.
Sauppe, M. (ORCID:0000000163123102)↗
Linear polarization sensitivity specifications for space-borne instruments
The radiometric accuracy of space-borne instruments such as radiometers and spectroradiometers which make measurements of the earth and other celestial objects can be compromised by the linear polarization sensitivity (LPS) induced by the optical system. Most of these optical systems contain optical elements whose reflectance or transmission is polarization dependent, such as diffraction gratings, folding and scanning mirrors, dichroic filters, and optical fibers. Optical system incorporating such elements generally display linear polarization sensitivity; different linear polarization states incident with equal radiometric power will be measured as different power levels. If the incident polarization state is unknown, the linear polarization sensitivity cannot be compensated during the data reduction. The light reflected from the earth and other planets and moons is usually partially linearly polarized, but in a random distribution. Thus, to make accurate radiometric measurements of these bodies, a radiometer or spectrometer should have a low level of linear polarization sensitivity. This paper contains a mathematical description of LPS, contains references to systems which have imposed a LPS specification, describes some of the sources of LPS, describes how to model LPS by polarization ray tracing, and discusses methods to reduce the LPS of an optical system.
Maymon, Peter W.↗
Correcting for diffraction in the far-infrared reflectance measurement of rough surfaces
The manner in which diffraction can increase the reflectance measured from very rough surfaces is shown by observations of diffracted light within the instrument profile of a far-IR reflectometer system. A correction to the calibration signal based on numerical integration of the diffracted part of the instrument profile is described. Diffraction correction factors as large as 2.94 have been found with small optics at long wavelength (630 microns). The effect of diffraction on diffuse reflectance measurements of a very rough perfect reflector is shown at wavelengths from 56 to 200 microns.
Smith, Sheldon M.↗