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At least 235 records · Page 13

Large sulfur isotope fractionations in Martian sediments at Gale crater

Variability in the sulfur isotopic composition in sediments can reflect atmospheric, geologic and biological processes. Evidence for ancient fluvio-lacustrine environments at Gale crater on Mars and a lack of efficient crustal recycling mechanisms on the planet suggests a surface environment that was once warm enough to allow the presence of liquid water, at least for discrete periods of time, and implies a greenhouse effect that may have been influenced by sulfur-bearing volcanic gases. Here we report in situ analyses of the sulfur isotopic compositions of SO 2 volatilized from ten sediment samples acquired by NASA's Curiosity rover along a 13 km traverse of Gale crater. We find large variations in sulfur isotopic composition that exceed those measured for Martian meteorites and show both depletion and enrichment in34S. Measured values of δ 34 S range from - 47 ± 14‰ to 28 ± 7‰, similar to the range typical of terrestrial environments. Although limited geochronological constraints on the stratigraphy traversed by Curiosity are available, we propose that the observed sulfur isotopic signatures at Gale crater can be explained by equilibrium fractionation between sulfate and sulfide in an impact-driven hydrothermal system and atmospheric processing of sulfur-bearing gases during transient warm periods.

58 GEOSCIENCES↗

Foreword: Selected papers from the 2020 Nuclear and Emerging Technologies for Space Topical Meeting (NETS 2020)

Humanity’s curiosity of and intrigue for exploring space has been with our species since we first looked up into the night sky. This age-old curiosity has driven humankind to innovate technologies for millennia, including efforts ranging from the construction of Stonehenge to track the annual movements of the sun to the investigation of advanced propulsion systems capable of transporting people to distant planets. Today’s technical communities dedicated to researching and developing innovative technologies for space exploration have seen a recent reinvigoration. Over the past few years, impressive progress made by industry, with exceptional support from government agencies, to reestablish and develop new capabilities has renewed confidence in humanity’s ability to reach the stars—a confidence that has not been present since the days of the Apollo program. Moreover, history shows that innovation and collaboration within the scientific and engineering communities reaches unparalleled pinnacles during periods of astrophilia. Finally, given the advancements in computational capacities for advanced modeling and simulation, unprecedented breakthroughs in commercializing advanced manufacturing techniques, and powerful collaborative relationships between industry and national scientific organizations, today we are limited only by our own imaginations.

99 GENERAL AND MISCELLANEOUS↗

Redox stratification of an ancient lake in Gale crater, Mars

In 2012, NASA’s Curiosity rover landed on Mars to assess its potential as a habitat for past life and investigate the paleoclimate record preserved by sedimentary rocks inside the ~150-kilometer-diameter Gale impact crater. Geological reconstructions from Curiosity rover data have revealed an ancient, habitable lake environment fed by rivers draining into the crater. We synthesize geochemical and mineralogical data from lake-bed mudstones collected during the first 1300 martian solar days of rover operations in Gale. We present evidence for lake redox stratification, established by depth-dependent variations in atmospheric oxidant and dissolved-solute concentrations. Paleoclimate proxy data indicate that a transition from colder to warmer climate conditions is preserved in the stratigraphy. Lastly, a late phase of geochemical modification by saline fluids is recognized.

58 GEOSCIENCES↗

Constraints on iron sulfate and iron oxide mineralogy from ChemCam visible/near-infrared reflectance spectroscopy of Mt. Sharp basal units, Gale Crater, Mars

Relative reflectace point spectra (400–840 nm) were acquired by the Chemistry and Camera (ChemCam) instrument on the Mars Science Laboratory (MSL) rover Curiosity in passive mode (no laser) of drill tailings and broken rock fragments near the rover as it entered the lower reaches of Mt. Sharp and of landforms at distances of 2–8 km. Freshly disturbed surfaces are less subject to the spectral masking effects of dust, and revealed spectral features consistent with the presence of iron oxides and ferric sulfates. Here, we present the first detection on Mars of a ~433 nm absorption band consistent with small abundances of ferric sulfates, corroborated by jarosite detections by the Chemistry and Mineralogy (CheMin) X-ray diffraction instrument in the Mojave, Telegraph Peak, and Confidence Hills drilled samples. The disturbed materials near the Bonanza King region also exhibited strong 433 nm bands and negative near-infrared spectral slopes consistent with jarosite. ChemCam passive spectra of the Confidence Hills and Mojave drill tailings showed features suggestive of the crystalline hematite identified by CheMin analyses. The Windjana drill sample tailings exhibited flat, low relative reflectance spectra, explained by the occurrence of magnetite detected by CheMin. Passive spectra of Bonanza King were similar, suggesting the presence of spectrally dark and neutral minerals such as magnetite. Long-distance spectra of the “Hematite Ridge” feature (3–5 km from the rover) exhibited features consistent with crystalline hematite. The Bagnold dune field north of the Hematite Ridge area exhibited low relative reflectance and near-infrared features indicative of basaltic materials (olivine, pyroxene). Light-toned layers south of Hematite Ridge lacked distinct spectral features in the 400–840 nm region, and may represent portions of nearby clay minerals and sulfates mapped with orbital near-infrared observations. The presence of ferric sulfates such as jarosite in the drill tailings suggests a relatively acidic environment, likely associated with flow of iron-bearing fluids, associated oxidation, and/or hydrothermal leaching of sedimentary rocks. Combined with other remote sensing data sets, mineralogical constraints from ChemCam passive spectra will continue to play an important role in interpreting the mineralogy and composition of materials encountered as Curiosity traverses further south within the basal layers of the Mt. Sharp complex.

58 GEOSCIENCES↗

Housedon-Hill - A ChemCam/RMI mega mosaic to investigate distant features

The ChemCam Remote Microscopic Imager (RMI) onboard Curiosity was originally designed to document the tiny areas analyzed by ChemCam’s laser-induced breakdown spectroscopy (LIBS) technique on rocks at few meters distance around the rover. The RMI produces 1024 x 1024 pixel black and white images directly from ChemCam’s telescope focal plane. Early in the mission, it was recognized that, thanks to its powerful optics, RMI could also play a role as a long-distance reconnaissance tool, complementing other cameras on the remote sensing mast, and taking advantage of its very long 700 mm focal length. Imaging areas several kilometers from the rover provides pictures that are very complementary to orbital observations and gives a more human-like, ground-based perspective. Between sols 2878 and 2921, Curiosity stayed parked at the same place to perform various rock sampling analyses. This opportunity was used to target very distant areas of interest, daily building an RMI mosaic of 216 overlapping images covering an area ranging from the bottom layers of Mount Sharp to the edge of Vera Rubin Ridge. This product is so far the largest RMI mosaic acquired during the entire mission.

79 ASTRONOMY AND ASTROPHYSICS↗

Assembly, Test and Launch Operations for a Nuclear-enabled NASA Mission: Considerations that are Specific to Use of a Nuclear Payload

For more than five decades, Radioisotope Power Systems (RPS) have played a critical role in the exploration of space, enabling missions of scientific discovery to destinations across the solar system by providing electrical power to explore remote, challenging and extreme environments. In particular, RPS enable deep space missions where increased heliocentric distances reduce the ability of solar power to adequately meet spacecraft and instruments power requirements. Some previous notable missions that were enabled by RPS include Nimbus III, the Apollo Surface Experiments, the Pioneers 10 and 11, the Viking Mars Landers, Galileo, Ulysses, Cassini, New Horizons and Curiosity. The current operating set of missions that are enabled by RPS are Voyagers 1 and 2, Cassini, New Horizons, and Curiosity. The Multi-Mission Radioisotope Thermal Generator (MMRTG) is the current RPS used for missions. An enhanced version of this generator outfitted with higher efficiency thermoelectrics is under development for potential use in the future. Other previously deployed power systems include the Multi-hundred Watt Radisotope Thermo-electric Generator (MHW RTG) and the General Purpose Heat Source Radisotope Thermo-electric Generator (GPHS RTG). The common thread for all of these power systems is that they are fueled with Pu-238. The use of this unique isotope involves additional planning activities and requires specific actions when the devices are delivered to Kennedy Space Center (KSC), launch site, and incorporated into the assembly, test and launch operations (ATLO) process to ensure mission success, met safety and security challenges. It has been forecasted that the use of a nuclear reactor system is on the horizon. This system could be used for either specifically powering S/C propulsion system or for surface power use once the mission arrived at its destina-tion. Since a nuclear-fission-based system has never been handled or integrated into a spacecraft at KSC, this nuclear reactor system would potentially require further challenges that must be accounted for in the ATLO process. This paper will explain ATLO considerations for the recent RTG-enabled launches that have occurred and planned in the near future (Mars 2020 NASA mission). It will also describe where further challenges that need to be met for the placement of a nuclear reactor (either for propulsion or transportation for surface power use) onto a space mission. Specifically, the following topics will be addressed: • Approach for nuclear safety planning for nuclear material use and its transportation to launch site • Planning for security posture for nuclear materials at launch site • Preparation for transportation of the nuclear power system from the fueling/testing location to the launch site • Preparation of documentation and procedures for nuclear material use at launch site • Planning for coordination between power system and space mission groups • Planning for appropriate staffing and scheduling of operations

07 ISOTOPE AND RADIATION SOURCES↗

Radioisotope Power Systems: Considerations for use of Dynamic versus Static Conversion Technologies for NASA Missions

For more than five decades, Radioisotope Power Systems (RPS) have played a critical role in the exploration of space, enabling missions of scientific discovery to destinations across the solar system by providing electrical power to explore remote, challenging and extreme environments. In particular, RPS enable deep space missions where increased heliocentric distances reduce the ability of solar power to adequately meet spacecraft and instruments power requirements. Some previous notable missions that were enabled by RPS include Nimbus III, the Apollo Sur-face Experiments, the Pioneers 10 and 11, the Viking Mars Landers, Galileo, Ulysses, Cassini, New Horizons and Curiosity. The current operating set of missions that are enabled by RPS are Voyagers 1 and 2, Cassini, New Hori-zons, and Curiosity. The Multi-Mission Radioisotope Thermal Generator (MMRTG) is the current RPS used for mis-sions. An enhanced version of this generator outfitted with higher efficiency thermoelectrics is under development for potential use in the future. There are also current development efforts underway by NASA to explore dynamic power conversion systems such as Brayton and Stirling. This paper will compare and contrast the pros and cons of a generalized dynamic system with the current state-of-the-art thermoelectric static conversion system. The reason for this paper is to calmly analyze the pros and cons so that all the pertinent factors are placed under the same examination light with equal brightness. As with any purchase made the “newness” of certain items sometimes overrides a needed desire to fully vet all characteristics of the merchandise so that the best choice is made. The following areas will be specifically examined and discussed as they may impact the choice of radioisotope power system for a specific mission: • Projected power output to weight ratio (We/kg) • Amount of Pu-238 required per a fixed power output • Excess heat available to be rejected or used • Fueling operations during assembly by the Department of Energy (DOE) • Planetary protection protocol during fueling and testing of RPS • Transportation operations from DOE assembly site to Kennedy Space Center (KSC) • Remote operations at KSC prior to launch during Assembly Test and Launch Operations (ATLO) phase o Timing of the placement of the RPS onto spacecraft/rover o Off-normal operations at KSC

99 GENERAL AND MISCELLANEOUS↗

Calibration of the Quadrupole Mass Spectrometer of the Sample Analysis at Mars Instrument Suite

The SAM suite of instruments on the "Curiosity" Rover of the Mars Science Laboratory (MSL) is designed to provide chemical and isotopic analysis of organic and inorganic volatiles for both atmospheric and solid samples. The mission of the MSL investigations is to advance beyond the successful search for aqueous transformation in surface environments at Mars toward a quantitative assessment of habitability and preservation through a series of chemical and geological measurements. The SAM suite was delivered in December 2010 (Figure 1) to the Jet Propulsion Laboratory for integration into the Curiosity Rover. We previously outlined the range of SAM solid and gas calibrations implemented or planned and here we discuss a specific set of calibration experiments to establish the response of the SAM Quadrupole Mass Spectrometer (QMS) to the four most abundant gases in the Martian atmosphere CO2, N2, Ar, and O2, A full SAM instrument description and calibration report is presently in preparation.

Mahaffy, P. R.↗

The Mars Science Laboratory Organic Check Material

The Organic Check Material (OCM) has been developed for use on the Mars Science Laboratory mission to serve as a sample standard for verification of organic cleanliness and characterization of potential sample alteration as a function of the sample acquisition and portioning process on the Curiosity rover. OCM samples will be acquired using the same procedures for drilling, portioning and delivery as are used to study martian samples with The Sample Analysis at Mars (SAM) instrument suite during MSL surface operations. Because the SAM suite is highly sensitive to organic molecules, the mission can better verify the cleanliness of Curiosity's sample acquisition hardware if a known material can be processed through SAM and compared with the results obtained from martian samples.

Conrad, Pamela G.↗

The Sample Analysis at Mars Investigation and Instrument Suite

The Sample Analysis at Mars (SAM) investigation of the Mars Science Laboratory (MSL) addresses the chemical and isotopic composition of the atmosphere and volatiles extracted from solid samples. The SAM investigation is designed to contribute substantially to the mission goal of quantitatively assessing the habitability of Mars as an essential step in the search for past or present life on Mars. SAM is a 40 kg instrument suite located in the interior of MSL's Curiosity rover. The SAM instruments are a quadrupole mass spectrometer, a tunable laser spectrometer, and a 6-column gas chromatograph all coupled through solid and gas processing systems to provide complementary information on the same samples. The SAM suite is able to measure a suite of light isotopes and to analyze volatiles directly from the atmosphere or thermally released from solid samples. In addition to measurements of simple inorganic compounds and noble gases SAM will conduct a sensitive search for organic compounds with either thermal or chemical extraction from sieved samples delivered by the sample processing system on the Curiosity rover's robotic arm,

Mahaffy, Paul↗

Gale Crater - Why are We There and What do We Hope to Learn?

The Mars Science Laboratory Rover Curiosity is commencing a two-year investigation of Gale crater and Mt. Sharp, the craters prominent central mound. Gale is a 155 km, late Noachian/early Hesperian impact crater located near the dichotomy boundary separating the southern highlands from the northern plains. The central mound is composed of layered sedimentary rock, with upper and lower mound units separated by a prominent erosional unconformity. The lower mound is of particular interest, as it contains secondary minerals indicative of a striking shift from water-rich to water-poor conditions on early Mars. A key unknown in the history of Gale is the relationship between the sedimentary units in the mound and sedimentary sequences in the surrounding region. We employed orbital remote sensing data to determine if areas within a 1,000 km radius of Gale match the characteristics of sedimentary units in Mt. Sharp. Regions of interest were defined based on: the mound s inferred age, altitude range, and THEMIS nighttime brightness (a proxy for thermal inertia). Using orbital CTX, MOC and HiRISE images we examined all areas within our regions of interest for analogous geomorphic units in the same altitude ranges as the corresponding units in Mt. Sharp. The results are consistent with the hypothesis that sedimentary units in both the upper and lower sections of the Gale mound are related to nearby regional units located along the dichotomy boundary. This relationship supports an inferred geologic history that includes several episodes of widespread sedimentary deposition and erosion in the martian mid-latitudes. In this model Mt. Sharp is the remnant of regional sedimentary deposits that partially or completely filled the crater, became lithified, and were subsequently deeply eroded. Key questions that will be addressed by Curiosity include the compositions of the sediments, the modes of deposition, the mechanisms of lithification, and the nature of the erosion.

Allen, Carlton C.↗

Post-Flight EDL Entry Guidance Performance for the 2011 Mars Science Laboratory Mission

Mars Science Laboratory landed Curiosity in Gale Crater on 5 Aug 2012. Curiosity landed successfully only 2.2 km away from the expected target given the onboard navigation state. Better than the average Apollo capsule splashdown miss distance. A late bank reversal and a suspected tail wind contributed to this slight miss. Entry guidance is derived from the Apollo capsule "final phase" logic and adjusts the range flown during entry by varying the direction of the lift vector (i.e., bank angle). Refinement of the guidance gains and alternative parachute deploy triggers to reduce the ellipse size will be studied for future Mars landing missions.

Mendeck, G.↗

Evidence for a Global Martian Soil Composition Extends to Gale Crater

The eolian bedform within Gale Crater referred to as "Rocknest" was investigated by the science instruments of the Curiosity Mars rover. Physical, chemical and mineralogical results are consistent with data collected from soils at other landing sites, suggesting a globally-similar composition. Results from the Curiosity payload from Rocknest should be considered relevant beyond a single, localized region with Gale Crater, providing key insights into planetary scale processes.

Yen, A. S.↗

CheMin Instrument Performance and Calibration on Mars

The CheMin (Chemistry and Mineralogy) instrument on the Mars Science Laboratory rover Curiosity uses a CCD detector and a Co-anode X-ray tube source to acquire both mineralogy (from the pattern of Co diffraction) and chemical information (from energies of fluoresced X-rays). A key component of the CheMin instrument is the ability to move grains within sample cells during analysis, providing multiple, random grain orientations that disperse diffracted X-ray photons along Debye rings rather than producing discrete Laue spots. This movement is accomplished by piezoelectric vibration of the sample cells. A cryocooler is used to maintain the CCD at a temperature at about -50 C in order to obtain energy resolution better than 250 eV, allowing discrimination of diffracted Co K X-rays from Fe K and other fluorescent X-rays. A detailed description of CheMin is provided in [1]. The CheMin flight model (FM) is mounted within the body of Curiosity and has been operating on Mars since August 6, 2012. An essentially identical sister instrument, the CheMin demonstration model (DM), is operated in a Mars environment chamber at JPL.

Vaniman, D. T.↗

Mineralogy and Elemental Composition of Wind Drift Soil at Rocknest, Gale Crater

The Mars Science Laboratory rover Curiosity has been exploring Mars since August 5, 2012, conducting engineering and first-time activities with its mobility system, arm, sample acquisition and processing system (SA/SPaH-CHIMRA) and science instruments. Curiosity spent 54 sols at a location named "Rocknest," collecting and processing five scoops of loose, unconsolidated materials ("soil") acquired from an aeolian bedform (Fig. 1). The Chemistry and Mineralogy (CheMin) instrument analyzed portions of scoops 3, 4, and 5, to obtain the first quantitative mineralogical analysis of Mars soil, and to provide context for Sample Analysis at Mars (SAM) measurements of volatiles, isotopes and possible organic materials.

Blake, D. F.↗

The Amorphous Component in Martian Basaltic Soil in Global Perspective from MSL and MER Missions

The mineralogy instrument CheMin onboard the MSL rover Curiosity analyzed by transmission XRD [1] the <150 microns size fraction of putative global basaltic martian soil from scoops 4 and 5 of the Rocknest aeolian bedform (sol 81-120). Here, we combine chemical (APXS) and mineralogical (Mossbauer; MB) results from the MER rovers with chemical (APXS) and mineralogical (CheMin) results from Curiosity to constrain the relative proportions of amorphous and crystalline components, the bulk chemical composition of those components, and the

Morris, R. V.↗

X-Ray Diffraction Reference Intensity Ratios of Amorphous and Poorly Crystalline Phases: Implications for CheMin on the Mars Science Laboratory

The CheMin instrument on the Mars Science Laboratory (MSL) rover Curiosity is an X-ray diffraction (XRD) and X-ray fluorescence (XRF) instrument capable of providing the mineralogical and chemical compositions of rocks and soils on the surface of Mars. CheMin uses a microfocus X-ray tube with a Co target, transmission geometry, and an energy-discriminating X-ray sensitive CCD to produce simultaneous 2-D XRD patterns and energy-dispersive X-ray histograms from powdered samples. Piezoelectric vibration of the cell is used to randomize the sample to reduce preferred orientation effects. Instrument details are provided in [1, 2, 3]. Analyses of rock and soil samples by the Mars Exploration Rovers (MER) show nanophase ferric oxide (npOx) is a significant component of the Martian global soil [4] and is thought to be one of the major contributing phases that the Curiosity rover will encounter if a soil sample is analyzed in Gale Crater. Because of the nature of this material, npOx will likely contribute to an X-ray amorphous or short-order component of a XRD pattern measured by the CheMin instrument.

Morris, R. V.↗

Assessment of the Mars Science Laboratory Entry, Descent, and Landing Simulation

On August 5, 2012, the Mars Science Laboratory rover, Curiosity, successfully landed inside Gale Crater. This landing was only the seventh successful landing and fourth rover to be delivered to Mars. Weighing nearly one metric ton, Curiosity is the largest and most complex rover ever sent to investigate another planet. Safely landing such a large payload required an innovative Entry, Descent, and Landing system, which included the first guided entry at Mars, the largest supersonic parachute ever flown at Mars, and a novel and untested Sky Crane landing system. A complete, end-to-end, six degree-of-freedom, multi-body computer simulation of the Mars Science Laboratory Entry, Descent, and Landing sequence was developed at the NASA Langley Research Center. In-flight data gathered during the successful landing is compared to pre-flight statistical distributions, predicted by the simulation. These comparisons provide insight into both the accuracy of the simulation and the overall performance of the vehicle.

Way, David W.↗