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At least 235 records · Page 13

Closed-Cycle Engine Program Used to Study Brayton Power Conversion

One form of power conversion under consideration in NASA Glenn Research Center's Thermal Energy Conversion Branch is the closed-Brayton-cycle engine. In the tens-of-kilowatts to multimegawatt class, the Brayton engine lends itself to potential space nuclear power applications such as electric propulsion or surface power. The Thermal Energy Conversion Branch has most recently concentrated its Brayton studies on electric propulsion for Prometheus. One piece of software used for evaluating such designs over a limited tradeoff space has been the Closed Cycle Engine Program (CCEP). The CCEP originated in the mid-1980s from a Fortran aircraft engine code known as the Navy/NASA Engine Program (NNEP). Components such as a solar collector, heat exchangers, ducting, a pumped-loop radiator, a nuclear heat source, and radial turbomachinery were added to NNEP, transforming it into a high-fidelity design and performance tool for closed-Brayton-cycle power conversion and heat rejection. CCEP was used in the 1990s in conjunction with the Solar Dynamic Ground Test Demonstration conducted at Glenn. Over the past year, updates were made to CCEP to adapt it for an electric propulsion application. The pumped-loop radiator coolant can now be n-heptane, water, or sodium-potassium (NaK); liquid-metal pump design tables were added to accommodate the NaK fluid. For the reactor and shield, a user can now elect to calculate a higher fidelity mass estimate. In addition, helium-xenon working-fluid properties were recalculated and updated.

Johnson, Paul K.↗

A Comparison of Coolant Options for Brayton Power Conversion Heat Rejection Systems

This paper describes potential heat rejection design concepts for Brayton power conversion systems. Brayton conversion systems are currently under study by NASA for Nuclear Electric Propulsion (NEP) and surface power applications. The Brayton Heat Rejection Subsystem (HRS) must dissipate waste heat generated by the power conversion system due to inefficiencies in the thermal-to-electric conversion process. Sodium potassium (NaK) and H2O are two coolant working fluids that have been investigated in the design of a pumped loop and heat pipe space HRS. In general NaK systems are high temperature (300 to 1000 K) low pressure systems, and H2O systems are low temperature (300 to 600 K) high pressure systems. NaK is an alkali metal with health and safety hazards that require special handling procedures. On the other hand, H2O is a common fluid, with no health hazards and no special handling procedures. This paper compares NaK and H20 for the HRS pumped loop coolant working fluid. A detailed Microsoft Excel (Microsoft Corporation, Redmond, WA) analytical model, HRS_Opt, was developed to evaluate the various HRS design parameters. It is capable of analyzing NaK or H2O coolant, parallel or series flow configurations, and numerous combinations of other key parameters (heat pipe spacing, diameter and radial flux, radiator facesheet thickness, fluid duct system pressure drop, system rejected power, etc.) of the HRS. This paper compares NaK against water for the HRS coolant working fluid with respect to the relative mass, performance, design and implementation issues between the two fluids.

Mason, Lee S.↗

Status of NASA's Advanced Radioisotope Power Conversion Technology Research and Development

NASA s Advanced Radioisotope Power Systems (RPS) development program is funding the advancement of next generation power conversion technologies that will enable future missions that have requirements that can not be met by either the ubiquitous photovoltaic systems or by current Radioisotope Power Systems (RPS). Requirements of advanced radioisotope power systems include high efficiency and high specific power (watts/kilogram) in order to meet mission requirements with less radioisotope fuel and lower mass. Other Advanced RPS development goals include long-life, reliability, and scalability so that these systems can meet requirements for a variety of future space applications including continual operation surface missions, outer-planetary missions, and solar probe. This paper provides an update on the Radioisotope Power Conversion Technology Project which awarded ten Phase I contracts for research and development of a variety of power conversion technologies consisting of Brayton, Stirling, thermoelectrics, and thermophotovoltaics. Three of the contracts continue during the current Phase II in the areas of thermoelectric and Stirling power conversion. The accomplishments to date of the contractors, project plans, and status will be summarized.

Wong, Wayne A.↗

Development of a Reactor Model for Chemical Conversion of Lunar Regolith

Lunar regolith will be used for a variety of purposes such as oxygen and propellant production and manufacture of various materials. The design and development of chemical conversion reactors for processing lunar regolith will require an understanding of the coupling among the chemical, mass and energy transport processes occurring at the length and time scales of the overall reactor with those occurring at the corresponding scales of the regolith particles. To this end, a coupled transport model is developed using, as an example, the reduction of ilmenite-containing regolith by a continuous flow of hydrogen in a flow-through reactor. The ilmenite conversion occurs on the surface and within the regolith particles. As the ilmenite reduction proceeds, the hydrogen in the reactor is consumed, and this, in turn, affects the conversion rate of the ilmenite in the particles. Several important quantities are identified as a result of the analysis. Reactor scale parameters include the void fraction (i.e., the fraction of the reactor volume not occupied by the regolith particles) and the residence time of hydrogen in the reactor. Particle scale quantities include the time for hydrogen to diffuse into the pores of the regolith particles and the chemical reaction time. The paper investigates the relationships between these quantities and their impact on the regolith conversion. Application of the model to various chemical reactor types, such as fluidized-bed, packed-bed, and rotary-bed configurations, are discussed.

Hedge, uday↗

NASA's Advanced Radioisotope Power Conversion Technology Development Status

NASA's Advanced Radioisotope Power Systems (ARPS) project is developing the next generation of radioisotope power conversion technologies that will enable future missions that have requirements that cannot be met by either photovoltaic systems or by current radioisotope power systems (RPSs). Requirements of advanced RPSs include high efficiency and high specific power (watts/kilogram) in order to meet future mission requirements with less radioisotope fuel and lower mass so that these systems can meet requirements for a variety of future space applications, including continual operation surface missions, outer-planetary missions, and solar probe. These advances would enable a factor of 2 to 4 decrease in the amount of fuel required to generate electrical power. Advanced RPS development goals also include long-life, reliability, and scalability. This paper provides an update on the contractual efforts under the Radioisotope Power Conversion Technology (RPCT) NASA Research Announcement (NRA) for research and development of Stirling, thermoelectric, and thermophotovoltaic power conversion technologies. The paper summarizes the current RPCT NRA efforts with a brief description of the effort, a status and/or summary of the contractor's key accomplishments, a discussion of upcoming plans, and a discussion of relevant system-level benefits and implications. The paper also provides a general discussion of the benefits from the development of these advanced power conversion technologies and the eventual payoffs to future missions (discussing system benefits due to overall improvements in efficiency, specific power, etc.).

Anderson, David J.↗

Development of a Reactor Model for Chemical Conversion of Lunar Regolith

Lunar regolith will be used for a variety of purposes such as oxygen and propellant production and manufacture of various materials. The design and development of chemical conversion reactors for processing lunar regolith will require an understanding of the coupling among the chemical, mass and energy transport processes occurring at the length and time scales of the overall reactor with those occurring at the corresponding scales of the regolith particles. To this end, a coupled transport model is developed using, as an example, the reduction of ilmenite-containing regolith by a continuous flow of hydrogen in a flow-through reactor. The ilmenite conversion occurs on the surface and within the regolith particles. As the ilmenite reduction proceeds, the hydrogen in the reactor is consumed, and this, in turn, affects the conversion rate of the ilmenite in the particles. Several important quantities are identified as a result of the analysis. Reactor scale parameters include the void fraction (i.e., the fraction of the reactor volume not occupied by the regolith particles) and the residence time of hydrogen in the reactor. Particle scale quantities include the time for hydrogen to diffuse into the pores of the regolith particles and the chemical reaction time. The paper investigates the relationships between these quantities and their impact on the regolith conversion. Application of the model to various chemical reactor types, such as fluidized-bed, packed-bed, and rotary-bed configurations, are discussed.

Hegde, U.↗

Recent Advances in Power Conversion and Heat Rejection Technology for Fission Surface Power

Under the Exploration Technology Development Program, the National Aeronautics and Space Administration (NASA) and the Department of Energy (DOE) are jointly developing Fission Surface Power (FSP) technology for possible use in human missions to the Moon and Mars. A preliminary reference concept was generated to guide FSP technology development. The concept consists of a liquid-metal-cooled reactor, Stirling power conversion, and water heat rejection, with Brayton power conversion as a backup option. The FSP project has begun risk reduction activities on some key components with the eventual goal of conducting an end-to-end, non-nuclear, integrated system test. Several power conversion and heat rejection hardware prototypes have been built and tested. These include multi-kilowatt Stirling and Brayton power conversion units, titanium-water heat pipes, and composite radiator panels.

Mason, Lee↗

A Comparison of Coolant Options for Brayton Power Conversion Heat Rejection Systems

This paper describes potential heat rejection design concepts for Brayton power conversion systems. Brayton conversion systems are currently under study by NASA for Nuclear Electric Propulsion (NEP) and surface power applications. The Brayton Heat Rejection Subsystem (HRS) must dissipate waste heat generated by the power conversion system due to inefficiencies in the thermal-to-electric conversion process. Sodium potassium (NaK) and H2O are two coolant working fluids that have been investigated in the design of a pumped loop and heat pipe space HRS. In general NaK systems are high temperature (300 to 1000 K) low pressure systems, and H2O systems are low temperature (300 to 600 K) high pressure systems. NaK is an alkali metal with health and safety hazards that require special handling procedures. On the other hand, H2O is a common fluid, with no health hazards and no special handling procedures. This paper compares NaK and H2O for the HRS pumped loop coolant working fluid. A detailed Microsoft Excel (Microsoft Corporation, Redmond, WA) analytical model, HRS_Opt, was developed to evaluate the various HRS design parameters. It is capable of analyzing NaK or H2O coolant, parallel or series flow configurations, and numerous combinations of other key parameters (heat pipe spacing, diameter and radial flux, radiator facesheet thickness, fluid duct system pressure drop, system rejected power, etc.) of the HRS. This paper compares NaK against water for the HRS coolant working fluid with respect to the relative mass, performance, design and implementation issues between the two fluids.

Siamidis, John↗

29P/Schwassmann–Wachmann 1: A Rosetta Stone for Amorphous Water Ice and CO↔CO 2 Conversion in Centaurs and Comets?

Centaur 29P/Schwassmann–Wachmann 1 (SW1) is a highly active object orbiting in the transitional "Gateway" region between the Centaur and Jupiter-family comet (JFC) regions. SW1 is unique among the Centaurs in that it experiences quasi-regular major outbursts and produces CO emission continuously; however, the source of the CO is unclear. We argue that, due to its very large size (∼32 km radius), SW1 is likely still responding, via amorphous water ice (AWI) conversion to crystalline water ice (CWI), to the "sudden" change in its external thermal environment produced by its Myrs-long dynamical migration from the Kuiper Belt to its current location at the inner edge of the Centaur region. It is this conversion process that is the source of the abundant CO and dust released from the object during its quiescent and outburst phases. If correct, these arguments have a number of important predictions testable via remote sensing and in situ spacecraft characterization, including the quick release on Myr timescales of CO from AWI conversion for any few kilometer-scale scattered disk Kuiper Belt Objects transiting into the inner system; that to date SW1 has only converted between 50% and 65% of its nuclear AWI to CWI; that volume changes on AWI conversion could have caused subsidence and cave-ins, but not significant mass wasting or crater loss; that SW1's coma should contain abundant amounts of CWI+CO 2 "dust" particles; and that when SW1 transits into the inner system within the next 10,000 yr, it will be a very different kind of JFC.

Centaur 29P/Schwassmann–Wachmann 1(SW1)↗

Direct Imaging of Magnetohydrodynamic Wave Mode Conversion Near A 3D Null Point on the Sun

Mutual conversion of various kinds of magnetohydrodynamic (MHD) waves can have profound impacts on wave propagation, energy transfer, and heating of the solar chromosphere and corona. Mode conversion occurs when an MHD wave travels through a region where the Alfvén and sound speeds are equal (e.g., a 3D magnetic null point). Here we report the direct extreme ultraviolet (EUV) imaging of mode conversion from a fast-mode to a slow-mode MHD wave near a 3D null point using Solar Dynamics Observatory/Atmospheric Imaging Assembly (SDO/AIA) observations. An incident fast EUV wavefront associated with an adjacent eruptive flare propagates laterally through a neighboring pseudostreamer. Shortly after the passage of the fast EUV wave through the null point, a slow-mode wave appears near the null that propagates upward along the open structures and simultaneously downward along the separatrix encompassing the fan loops of the pseudostreamer base. These observations suggest the existence of mode conversion near 3D nulls in the solar corona, as predicted by theory and MHD simulations. Moreover, we observe decaying transverse oscillations in both the open and closed structures of the pseudostreamer, along with quasiperiodic type III radio bursts indicative of repetitive episodes of electron acceleration.

Pankaj Kumar↗

Plasma Chemical Conversion and Resource Generation Beyond Low-Earth Orbit

As humanity gears up for its return to the moon after more than half a century, collaborative efforts between NASA, Artemis Accords Partners, and private industry are underway to establish the necessary infrastructure and technologies for lunar habitation and eventual Mars exploration. However, the traditional ISS resupply and waste management model is impractical and economically infeasible for prolonged missions to the Moon and Mars. Advanced chemical conversion technologies are needed to generate vital consumable products from local planetary resources (ISRU) and recycled gasses and waste within semi-closed loop life-support systems. Low-temperature plasma reactors are emerging power-to-gas technologies with the potential to facilitate various chemical synthesis processes with hardware commonality and redundancy. In plasma-based systems, electrical power is used to ionize a feedstock gas, creating a highly reactive environment that leverages electron excitation chemistry to break stable molecular bonds and form value added products. Unlike thermal chemical processes, plasma reactors operate at non-equilibrium conditions, allowing for lower-temperature operation and instantaneous start-up, making them adaptable to intermittent power availability. Moreover, their scalability permits deployment in both portable astronaut systems and large-scale industrial setups for colonies. One promising application of plasmas is for CO 2 conversion. Carbon dioxide comprises 96% of the Martian atmosphere and is a byproduct of human respiration, which typically must be scrubbed and vented from space habitats. A plasma source integrated with membrane separation technology could generate a stream of oxygen for life support and rocket propellant. CO 2 splitting may also be beneficial as a precursor to manufacture carbon-based products and fuels in situ, like methane, methanol, and polyethylene. Plasma-assisted CO 2 conversion is a simpler case to study without the concern of selectivity and is the first step toward complex chemical synthesis. This work presents preliminary experimental case study from a plasma reactor for CO 2 conversion and casts a vision for the potential of plasma technologies in a sub-architecture for resource production to enable the next generation of human spaceflight activities.

Plasma↗

2.3.4.104 - Lignin Conversion to Sustainable Aviation Fuel Blendstocks

The Lignin Conversion to Sustainable Aviation Fuel Blendstocks (LigSAF) project focuses on the conversion of lignin-rich streams to deoxygenated aromatic and cycloalkane blendstocks in the jet fuel range. This work is done in close collaboration with the BETO-funded Lignin-First Biorefinery Development project and industrial scale-up partners, and the work is closely guided by analysis to develop cost-effective and sustainable routes to produce lignin-based SAF blendstocks. To date, we have demonstrated the continuous catalytic conversion of a lignin oil from poplar to deoxygenated aromatic products at -85% C-mol yield. This hydrodeoxygenation process uses a stable, earth-abundant catalyst and requires no solvent. We have also established a baseline process model and associated techno-economic analysis and life cycle assessment that together demonstrate the potential to achieve cost parity with fossil carbon-based jet fuel at -70% reduction in greenhouse gas emissions. Current work is focused on expanding the slate of feedstocks for hydrodeoxygenation to include lignin oils from softwoods, agricultural residues, and grasses as well as from hydrolysis lignin substrates from biochemical conversion and pulp-and-paper processes. We are also undertaking catalyst development efforts to tune the reaction selectivity from aromatic compounds to cycloalkanes. Lastly, we are investigating reaction engineering strategies to slurry solids for hydrodeoxygenation reactions.

aromatics↗

Optimizing Neutrino Flavor Conversion Measurements through Machine Learning

The phenomenon of neutrino flavor conversion whereby the flavor of a neutrino particle can change between its time of production and later detection was the first definitive evidence of physics beyond the Standard Model. Some of the oscillation parameters used to describe this conversion are not yet well measured, leaving important questions still open regarding flavor conversion both in vacuum and as neutrinos travel through matter. NOvA is a long-baseline neutrino oscillation experiment that uses Fermilab's predominantly $\nu_\mu$ NuMI beam. A 14 kton oil-based liquid scintillator far detector 810 km away is used to measure neutrino oscillation through the $\nu_\mu$ disappearance and $\nu_e$ appearance channels. Super-K is a 50 kton water Cherenkov detector, which measures the disappearance of $\nu_e$ produced during solar fusion. The high density environment of the sun decreases the $\nu_e$ survival probability at higher energies observable in Super-K compared to the vacuum-dominated oscillations at lower energies. However, the transition region is overshadowed by radioactive background in the detector. In both of these experiments, the separation of neutrino detection events from background and classification of neutrino flavor are crucial tasks that benefit from the introduction of machine learning. Chapter 1 gives an overview of neutrinos and the context under which flavor conversion is measured in this dissertation. Chapters 2-7 present the results of a Bayesian sampling approach for the latest NOvA 3-flavor oscillation analysis with $26.6 \times 10^{20}$ protons on target in neutrino mode and $12.5 \times 10^{20}$ in antineutrino mode collected over 10 years. Chapters 8-13 present the results of extending the Super-K solar analysis to lower energies during its fourth phase with 2970 days of livetime.

Yankelevich, Alejandro Jaime [UC, Irvine]↗

Optimizing Neutrino Flavor Conversion Measurements through Machine Learning

The phenomenon of neutrino flavor conversion whereby the flavor of a neutrino particle can change between its time of production and later detection was the first definitive evidence of physics beyond the Standard Model. Some of the oscillation parameters used to describe this conversion are not yet well measured, leaving important questions still open regarding flavor conversion both in vacuum and as neutrinos travel through matter. NOvA is a long-baseline neutrino oscillation experiment that uses Fermilab's predominantly $\nu_\mu$ NuMI beam. A 14 kton oil-based liquid scintillator far detector 810 km away is used to measure neutrino oscillation through the $\nu_\mu$ disappearance and $\nu_e$ appearance channels. Super-K is a 50 kton water Cherenkov detector, which measures the disappearance of $\nu_e$ produced during solar fusion. The high density environment of the sun decreases the $\nu_e$ survival probability at higher energies observable in Super-K compared to the vacuum-dominated oscillations at lower energies. However, the transition region is overshadowed by radioactive background in the detector. In both of these experiments, the separation of neutrino detection events from background and classification of neutrino flavor are crucial tasks that benefit from the introduction of machine learning. Chapter 1 gives an overview of neutrinos and the context under which flavor conversion is measured in this dissertation. Chapters 2-7 present the results of a Bayesian sampling approach for the latest NOvA 3-flavor oscillation analysis with $26.6 \times 10^{20}$ protons on target in neutrino mode and $12.5 \times 10^{20}$ in antineutrino mode collected over 10 years. Chapters 8-13 present the results of extending the Super-K solar analysis to lower energies during its fourth phase with 2970 days of livetime.

Yankelevich, Alejandro Jaime [UC, Irvine]↗

Optimizing Neutrino Flavor Conversion Measurements through Machine Learning

The phenomenon of neutrino flavor conversion whereby the flavor of a neutrino particle can change between its time of production and later detection was the first definitive evidence of physics beyond the Standard Model. Some of the oscillation parameters used to describe this conversion are not yet well measured, leaving important questions still open regarding flavor conversion both in vacuum and as neutrinos travel through matter. NOvA is a long-baseline neutrino oscillation experiment that uses Fermilab's predominantly $\nu_\mu$ NuMI beam. A 14 kton oil-based liquid scintillator far detector 810 km away is used to measure neutrino oscillation through the $\nu_\mu$ disappearance and $\nu_e$ appearance channels. Super-K is a 50 kton water Cherenkov detector, which measures the disappearance of $\nu_e$ produced during solar fusion. The high density environment of the sun decreases the $\nu_e$ survival probability at higher energies observable in Super-K compared to the vacuum-dominated oscillations at lower energies. However, the transition region is overshadowed by radioactive background in the detector. In both of these experiments, the separation of neutrino detection events from background and classification of neutrino flavor are crucial tasks that benefit from the introduction of machine learning. Chapter 1 gives an overview of neutrinos and the context under which flavor conversion is measured in this dissertation. Chapters 2-7 present the results of a Bayesian sampling approach for the latest NOvA 3-flavor oscillation analysis with $26.6 \times 10^{20}$ protons on target in neutrino mode and $12.5 \times 10^{20}$ in antineutrino mode collected over 10 years. Chapters 8-13 present the results of extending the Super-K solar analysis to lower energies during its fourth phase with 2970 days of livetime.

Yankelevich, Alejandro Jaime [UC, Irvine] (ORCID:0↗

Solid-State NMR Studies of Solvent-Mediated, Acid-Catalyzed Woody Biomass Pretreatment for Enzymatic Conversion of Residual Cellulose

Enzymes selectively hydrolyze the carbohydrate fractions of lignocellulosic biomass into corresponding sugars, but these processes are limited by low yields and slow catalytic turnovers. Under certain conditions, the rates and yields of enzymatic sugar production can be increased by pretreating biomass using solvents, heat, and dilute acid catalysts. However, the mechanistic details underlying this behavior are not fully elucidated, and designing effective pretreatment strategies remains an empirical challenge. Herein, using a combination of solid-state and high-resolution magic-angle-spinning NMR, infrared spectroscopy, and X-ray diffractometry, we show that the extent to which cellulase enzymes are able to hydrolyze solvent-pretreated biomass can be understood in terms of the ability of the solvent to break the chemical linkages between cellulose and noncellulosic materials in the cell wall. This finding is of general significance to enzymatic biomass conversion research, and implications for designing improved biomass conversion strategies are discussed. Furthermore, these findings demonstrate the utility of solid-state NMR as a tool to elucidate the key chemical and physical changes that occur during the liquid-phase conversion of real biomass.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Direct conversion of methane to aromatics and hydrogen via a heterogeneous trimetallic synergistic catalyst

Abstract Non-oxidative methane dehydro-aromatization reaction can co-produce hydrogen and benzene effectively on a molybdenum-zeolite based thermochemical catalyst, which is a very promising approach for natural-gas upgrading. However, the low methane conversion and aromatics selectivity and weak durability restrain the realistic application for industry. Here, a mechanism for enhancing catalysis activity on methane activation and carbon-carbon bond coupling has been found to promote conversion and selectivity simultaneously by adding platinum–bismuth alloy cluster to form a trimetallic catalyst on zeolite (Pt-Bi/Mo/ZSM-5). This bimetallic alloy cluster has synergistic interaction with molybdenum: the formed CH 3 * from Mo 2 C on the external surface of zeolite can efficiently move on for C-C coupling on the surface of Pt-Bi particle to produce C 2 compounds, which are the key intermediates of oligomerization. This pathway is parallel with the catalysis on Mo inside the cage. This catalyst demonstrated 18.7% methane conversion and 69.4% benzene selectivity at 710 °C. With 95% methane/5% nitrogen feedstock, it exhibited robust stability with slow deactivation rate of 9.3% after 2 h and instant recovery of 98.6% activity after regeneration in hydrogen. The enhanced catalytic activity is strongly associated with synergistic interaction with Mo and ligand effects of alloys by extensive mechanism studies and DFT calculation.

03 NATURAL GAS↗

Spectral emittance measurements of micro/nanostructures in energy conversion: a review

Micro/nanostructures play a key role in tuning the radiative properties of materials and have been applied to the high-temperature energy conversion systems for improved performance. Among the various radiative properties, spectral emittance is of integral importance for the design and analysis of materials that function as radiative absorbers or emitters. This article presents an overview of the spectral emittance measurement techniques using both the direct and indirect methods. Several micro/nanostructures are also introduced, and a special emphasis is placed on the emissometers developed for characterizing engineered micro/nanostructures in high-temperature applications (e.g., solar energy conversion and thermophotovoltaic devices). Both experimental facilities and measured results for different materials are summarized. Future prospects in developing instrumentation and micro/nanostructured surfaces for practical applications are also outlined. This study provides a comprehensive source of information for the application of micro/nanostructures in high-temperature energy conversion engineering.

14 SOLAR ENERGY↗