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At least 235 records · Page 13

Calorimetric Identification of Composite Nuclei in LAr

In neutrino-nucleus interactions, Final State Interactions (FSI) can cause nucleons to scatter or form heavier composite particles like deuterons and tritons. Observing these particles would provide direct evidence of FSI and help improve interaction models, which is essential for precise neutrino energy reconstruction in future experiments like DUNE. Our Goal: Develop an analysis to detect particles heavier than protons in ICARUS data to better constrain FSI models.

McCright, Hannah [Maryland U., College Park]↗

Refining Methods to Determine the Isotopic Composition of Uranium Particles by Laser Ablation MC-ICP-MS

We report on efforts to mitigate the generation of isotopic anomalies during the ablation of micrometer-sized uranium oxide particles and analysis by MC-ICP-MS. The results of testing on particles of U200 indicate that laser fluence and frequency can affect isotopic data produced by laser ablation, but no settings were tested that could eradicate the signal spiking effect and generation of anomalous isotopic data for 234U/238U and 236U/238U. These anomalies are more frequent in samples with higher 235U enrichments, which is expected given their higher abundances of 234U and 236U. Of the standards tested here, only U005-A was anomaly-free. Efforts to compare the laser traces for particles with normal and anomalous isotopic compositions showed subtle differences in the behavior of the 234U/238U and 236U/238U ratios. However, it would be challenging to identify anomalous data points from a population of unknowns using this distinction, i.e., this is unlikely to be diagnostic. Thus, using current analytical hardware, we cannot eradicate the signal spiking phenomenon and cannot unambiguously identify isotopic anomalies from laser ablation traces. Ultimately, laser ablation ICP-MS would either require dramatic improvement to the ablation process and generation of more homogenous aerosols and/or improvements to detector electronics to identify and correct for the spiking phenomenon. Even if the reliability of the technique could be improved, a broader question to address is whether current data quality is of a high enough standard for laser ablation MC-ICP-MS to be used as a complementary technique to LG-SIMS for Safeguards.

organic↗

Editorial: Functionalization of porous materials for sustainable energy applications

Global energy demands are shifting toward a more sustainable future, with the goal of achieving carbon neutrality by 2050. Emerging technologies are driving this transition. The industry, academia, government, non-profit organizations, and the broader community are collaboratively working to reduce greenhouse gas (GHG) emissions and address climate change to ensure a sustainable future. According to the International Energy Agency, in 2022, the production, transportation, and processing of oil and gas resulted in 5.1 billion tons of CO 2 -equivalent emissions, representing nearly 15% of all energy-related GHG emissions. Moreover, the end-use of oil and gas accounted for an additional 40% of emissions. The IEA’s Net Zero Emissions by 2050 Scenario calls for immediate, collective action from the industry, transportation and other stakeholders to mitigate these emissions. In this effort, the development of energy materials will play a critical role in reducing emissions. Among these, porous materials offer an innovative solution, leveraging their high surface area, adjustable pore sizes, and chemical versatility to address these pressing challenges effectively. By carefully designing their nanostructures, the architecture and properties of these materials can be tailored for specific applications. Key factors such as chemical composition, particle size, pore distribution, and surface area optimization enhance the reactivity and energy conversion efficiency. Additionally, pre- and post-functionalization processes can introduce targeted chemical properties, further improving their performance. This Research Topic explores recent advancements in energy and materials science through four scholarly papers, showcasing innovative solutions for sustainable energy technologies while providing valuable insights into the unique properties and structure of porous materials (Figure 1). Li et al. present their work on highly defective NiFeV layered triple hydroxides, highlighting enhanced electrocatalytic activity and stability for oxygen evolution reactions (OER). Kovalskii et al. contribute a mini-review on hydrogen storage using hexagonal boron nitride (h-BN) and BN-based materials, offering an insightful overview of these promising materials. Chava et al. discuss their recent achievements in ceramic electrolytes used for improvement of performance of solid-state batteries. Lastly, Li et al. review the properties of porous materials with a focus on shrinkage behavior during the drying process, shedding light on key considerations for material design.

36 MATERIALS SCIENCE↗

A remote sensing algorithm for vertically resolved cloud condensation nuclei number concentrations from airborne and spaceborne lidar observations

Cloud condensation nuclei (CCN) are mediators of aerosol–cloud interactions (ACIs), contributing to the largest uncertainties in the understandings of global climate change. We present a novel remote-sensing-based algorithm that quantifies the vertically resolved CCN number concentrations (N CCN ) using aerosol optical properties measured by a multiwavelength lidar. The algorithm considers five distinct aerosol subtypes with bimodal size distributions. The inversion used the lookup tables developed in this study, based on the observations from the Aerosol Robotic Network, to efficiently retrieve optimal particle size distributions from lidar measurements. The method derives dry aerosol optical properties by implementing hygroscopic enhancement factors in lidar measurements. The retrieved optically equivalent particle size distributions and aerosol-type-dependent particle composition are utilized to calculate critical diameters using κ-Köhler theory and N CCN at six supersaturations ranging from 0.07 % to 1.0 %. Sensitivity analyses indicate that uncertainties in extinction coefficients and relative humidity greatly influence the retrieval error in N CCN . The potential of this algorithm is further evaluated by retrieving N CCN using airborne lidar from the NASA ObseRvations of Aerosols above CLouds and their intEractionS (ORACLES) campaign and is validated against simultaneous measurements from the CCN counter. The independent validation with robust correlation demonstrates promising results. Furthermore, the N CCN has been retrieved for the first time using a proposed algorithm from spaceborne lidar – Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) – measurements. The application of this new capability demonstrates the potential for constructing a 3D CCN climatology at a global scale, which helps to better quantify ACI effects and thus reduce the uncertainty in aerosol climate forcing.

54 ENVIRONMENTAL SCIENCES↗

Lunar soil coefficient of friction determined from Surveyor data and laboratory tests

A series of laboratory tests on simulated soils was conducted to evaluate some of these physical properties. Using soils similar to lunar soil composition, particle size distribution, and cohesion as determined from the Surveyor mission, the coefficient of friction and bulk density were evaluated by reproducing soils with the same force vs penetration characteristics as demonstrated at the Surveyor landing sites. The determination of soil coefficient of friction is presented in this paper; the soil density is treated separately in the previous paper’ of this report.

Choate, R.↗

Variations of the relative abundances of He, (C,N,O) and Fe-group nuclei in solar cosmic rays and their relationship to solar particle acceleration

Measurements of the flux of helium nuclei in the 24 January 1971 event and of helium and (C,N,O) nuclei in the 1 September 1971 event are combined with previous measurements to obtain the relative abundances of helium, (C,N,O), and Fe-group nuclei in these events. These data are then summarized together with previously reported results to show that, even when the same detector system using a dE/dx plus range technique is used, differences in the He/(C,N,O) value in the same energy/nucleon interval are observed in solar cosmic ray events. Further, when the He/(C,N,O) value is lower the He/(Fe-group nuclei) value is also systematically lower in these large events. When solar particle acceleration theory is analyzed, it is seen that the results suggest that, for large events, Coulomb energy loss probably does not play a major role in determining solar particle composition at higher energies (10 MeV). The variations in multicharged nuclei composition are more likely due to partial ionization during the acceleration phase.

Bertsch, D. L.↗

Preliminary results from the noctilucent sampling from Kiruna in 1970.

On Aug. 8, 1970 at 0148 and 0354 local time, two Pandora sounding rocket payloads were launched from the ESRO range in Kiruna, Sweden, during a noctilucent cloud display. Large numbers of particles were collected, many of which appear to be micrometeorites coated with a low density material. Typical electron micrographs are shown, and numerical densities as a function of altitude are given. Particle composition information has been obtained by use of dispersive X-ray analysis equipment attached to our Philips EM 300 electron microscope.

Hallgren, D. S.↗

Preliminary stratigraphy of the Apollo 15 drill core

The crew of Apollo 15 collected a 242-cm-long core of the regolith developed on the surface of Palus Putredinus (3 deg 39 min 20 sec E, 26 deg 26 min 00 sec N). This core consists of 42 major textural units, which range from a few millimeters to 13 cm thick. The regolith at this site was deposited layer by layer, each layer having been reworked, to some degree, by micrometeorite bombardment. The particle composition of six layers for which samples were obtained varies in a random fashion, thus supporting the heterogeneous, layered model of the regolith. The ratio of lithic fragments derived from the Apennine Front to that derived from the mare surface is about 1:1. This lithic ratio, in a regolith section 3.75 km from the base of the front, is an indication of the efficiency of lateral transport of soil by impact processes and mass wasting.

Heiken, G.↗

The neutral atmosphere temperature experiment

The AEROS Neutral Atmosphere Temperature Experiment (NATE) is designed to measure the kinetic temperature of molecular nitrogen in the thermosphere. A quadrupole mass spectrometer tuned to N2 measures the N2 density variation in a small spherical antechamber having a knife-edged orifice which is exposed to the atmosphere at the outer surface of the spacecraft. The changing density of N2 due to the spinning motion of the spacecraft permits determination of the velocity distribution of the N2 from which the temperature is calculated. An alternate mode of operation of the instrument allows measurement of the other gases in the atmosphere as well as N2 permitting determination of the neutral particle composition of the atmosphere.

Spencer, N. W.↗

Nucleon and heavy-ion total and absorption cross section for selected nuclei

Approximate solutions of the coupled-channel equations for high-energy composite particle scattering are obtained and are applied to the nuclear scattering problem. Relationships between several approximation procedures are established and discussed. The eikonal formalism is used with a small-angle approximation to calculate the coherent elastic scattered amplitude from which total and absorption cross sections are derived. Detailed comparisons with nucleon-nucleus experiments show agreement within 5 percent except at lower energies where the eikonal approximation is of questionable accuracy. Even at these lower energies, agreement is within 15 percent. Tables of cross sections required for cosmic heavy-ion transport and shielding studies are presented.

Wilson, J. W.↗

resterilizable electrode for electrosurgery

Required properties of flexibility, electrical conductivity, tensile strength, and tear resistance of electrosurgical electrodes is retained through utilization of flexible-polymer/conductive particle composites for electrodes.

Engstrom, E. R.↗

The rings of Saturn

Consideration is given to the development of theories concerning the rings of Saturn. Particular attention is given to ring structure, noting its thinness, the separations between rings, and observed variations in brightness. Data gathered via infrared, radio and radar techniques are described in terms of ring particle composition and size. Hypotheses about ring origin and evolution are outlined, including the tidal disruption model, calculations of Saturn's gravitational contraction history, grazing, and meteoroid bombardment. Prospects for future observations of Saturn's rings are reviewed, such as the variation in their radar reflectivity as a function of the tilt of the ring plane.

Pollack, J. B.↗

Viking magnetic properties experiment - Extended mission results

The backhoe magnets on Viking Lander (VL) 2 were successfully cleaned, followed by a test involving successive insertions of the cleaned backhoe into the surface. Rapid saturation of the magnets confirmed evidence from primary mission results that the magnetic mineral in the Martian surface is widely distributed, most probably in the form of composite particles of magnetic and nonmagnetic minerals. An image of the VL 2 backhoe taken via the X4 magnifying mirror demonstrates the fine-grained nature of the attracted magnetic material. The presence of maghemite and its occurrence as a pigment in, or a thin coating on, all mineral particles or as discrete, finely divided and widely distributed crystallites, are consistent with data from the inorganic analysis experiments and with laboratory simulations of results of the biology experiments on Mars.

Hargraves, R. B.↗

EUV flux variations during solar cycle 21 from AE-E He/+/ abundances

The ionization rate of helium in the thermosphere is inferred from AE-E ion and neutral particle composition measurements, made on several days during solar cycle 21, in the context of a steady state photochemical model for helium ions. The inferred ionization rate varies by a factor of 4 between July 1976 and January 1979, a value consistent with the variation in the flux measured during the same period by the EUV spectrometer on board the AE-E satellite.

Oppenheimer, M.↗

Altered basaltic glass - A terrestrial analog to the soil of Mars

In order to understand the nature of weathering processes and the formation of clay-like substances on Mars, analogous terrestrial processes and materials have been examined including sideromelane and palagonite. It is shown that palagonite is a good analog to the soil of Mars to the level of precision available from Viking and ground-based telescopic spectral measurements. Points of resemblance between the two materials include bulk chemical composition, particle size, reflectance spectra, and magnetic properties. A mechanism for the formation of Martian soil, based on a palagonite model, is proposed.

Allen, C. C.↗

An optical model for composite nuclear scattering

The optical model of composite particle scattering is considered and compared to the accuracies of other models. A nonrelativistic Schroedinger equation with two-body potentials is used for the scattering of a single particle by an energy-dependent local potential. The potential for the elastic channel is composed of matrix elements of a single scattering operator taken between the ground states of the projectile and the target; the coherent amplitude is considered as dominating the scattering in the forward direction. A multiple scattering series is analytically explored and formally summed by the solution of an equivalent Schroedinger equation. Cross sections of nuclear scattering are then determined for He-4 and C-12 nuclei at 3.6 GeV/nucleus and O-16 projectiles at 2.1 GeV/nucleus, and the optical model approximations are found to be consistently lower and more accurate than approximations made by use of Glauber's theory.

Wilson, J. W.↗

Short-term EUV flux variations from AE-E He/+/ abundances

The ionization rate of helium in the thermosphere is inferred from AE-E ion and neutral particle composition measurements made on 20 days from January 1979 to June 1980. The variations in the inferred rate are consistent with variations in the UV flux measured during the same period by the AE-E UV spectrometer. The approximately 27-day modulation of the calculated ionization rate is the result of cyclical variations in the UV flux, which are in turn coupled to the rotation period of the sun. Results indicate that the ionization structure of helium in the thermosphere is closely coupled to both the long and short term EUV flux variations.

Sternberg, A.↗

Light elements in lunar soils revisited - Carbon, nitrogen, hydrogen and helium

Based on combined data from F2-stripping and step-wise heating experiments, it is found that about 30-40% of carbon and nitrogen in submature and mature lunar soils resides in the outermost 0.1 micron of grains, presumably in the amorphous coatings that are known to be present. The remainder of carbon and nitrogen resides in composite particles such as agglutinates and microbreccias, within which C and N are distributed in a roughly uniform way. Helium shows much larger variations in its distribution between grain surfaces and interiors, with helium yield related to ilmenite content of the soil. The depth distribution of solar wind hydrogen is not readily resolvable by the stripping technique.

Becker, R. H.↗