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At least 235 records · Page 13

Analysis of Siderite Thermal Decomposition by Differential Scanning Calorimetry

Characterization of carbonate devolitilization has important implications for atmospheric interactions and climatic effects related to large meteorite impacts in platform sediments. On a smaller scale, meteorites contain carbonates which have witnessed shock metamorphic events and may record pressure/temperature histories of impact(s). ALH84001 meteorite contains zoned Ca-Mg-Fe-carbonates which formed on Mars. Magnetite crystals are found in the rims and cores of these carbonates and some are associated with void spaces leading to the suggestion by Brearley et al. that the crystals were produced by thermal decomposition of the carbonate at high temperature, possibly by incipient shock melting or devolitilization. Golden et al. recently synthesized spherical Mg-Fe-Ca-carbonates from solution under mild hydrothermal conditions that have similar carbonate compositional zoning to those of ALH84001. They have shown experimental evidence that the carbonate-sulfide-magnetite assemblage in ALH84001 can result from a multistep inorganic process involving heating possibly due to shock events. Experimental shock studies on calcium carbonate prove its stability to approx. 60 GPa, well in excess of the approx. 45 GPa peak pressures indicated by other shock features in ALH84001. In addition, Raman spectroscopy of carbonate globules in ALH84001 indicates no presence of CaO and MgO. Such oxide phases should be found associated with the magnetites in voids if these magnetites are high temperature shock products, the voids resulting from devolitilization of CO2 from calcium or magnesium carbonate. However, if the starting material was siderite (FeCO3), thermal breakdown of the ALH84001 carbonate at 470 C would produce iron oxide + CO2. As no documentation of shock effects in siderite exists, we have begun shock experiments to determine whether or not magnetite is produced by the decomposition of siderite within the < 45GPa pressure window and by the resultant thermal pulse to approx. 600 C experienced by ALH84001. Here, we report thermal and compositional characterization of unshocked siderite and its transition to magnetite. Additional information is contained in the original extended abstract.

Bell, M. S.↗

Mississippi Embayment Water Resources: Utilizing NASA Earth Observations to Understand Groundwater Recharge in the Mississippi Regional Aquifer System

The Memphis Sand Aquifer (MSA) is located in the Mississippi Embayment which extends 250,000 square kilometers across nine states. Groundwater recharge factors that influence the narrow recharge zone of the MSA include precipitation, potential evapotranspiration, and landcover changes. The unsustainable water practices and increasing landcover change from urban development in the MSA's narrow recharge zone threaten the aquifer’s groundwater storage. In partnership with Protect Our Aquifer, the team used data from Terra Moderate Resolution Imaging Spectroradiometer (MODIS), Integrated Multi-Satellite Retrievals for Global Precipitation Measurement (GPM IMERG), National Land Cover Dataset (NLCD), and Gravity Recovery and Climate Experiment (GRACE). These datasets included annually-averaged precipitation, evapotranspiration, potential evapotranspiration, biannual landcover change, and monthly total water storage which were used to create groundwater recharge factors maps and timeseries. The evaporative stress index map, water balance map, and landcover change maps were used to identify thriving areas. The team found precipitation did not express a strong linear trend and showed high precipitation years in 2017 and 2018, and a drought year in 2011. The potential evapotranspiration showed a weak negative linear trend. The landcover change showed shifts in forested areas and urban development. The team identified four thriving areas in the western side of Tennessee that successfully contribute to aquifer recharge due to increased forest area, sufficient water use, low changes in total water storage, and lateral positioning to streams. These end products allowed our partners to make informed decisions about areas that are thriving in the Mississippi Embayment recharge zone for conservation efforts of the aquifer.

Lauren Mahoney↗

The Contributions of Gauge-Based Precipitation and SMAP Brightness Temperature Observations to the Skill of the SMAP Level-4 Soil Moisture Product

Soil Moisture Active Passive (SMAP) mission L-band brightness temperature (Tb) observations are routinely assimilated into the Catchment land surface model to generate Level-4 Soil Moisture (L4_SM) estimates of global surface and root-zone soil moisture at 9-km, 3-hourly resolution with ~2.5-day latency. The Catchment model in the L4_SM algorithm is driven with ¼-degree, hourly surface meteorological forcing data from the Goddard Earth Observing System (GEOS). Outside of Africa and the high latitudes, GEOS precipitation is corrected using Climate Prediction Center Unified (CPCU) gauge-based, ½-degree, daily precipitation. L4_SM soil moisture was previously shown to improve over land model-only estimates that use CPCU precipitation but no Tb assimilation (CPCU_SIM). Here, we additionally examine the skill of model-only (CTRL) and Tb assimilation-only (SMAP_DA) estimates derived without CPCU precipitation. Soil moisture is assessed versus in situ measurements in well-instrumented regions and globally through the Instrumental Variable (IV) method using independent soil moisture retrievals from the Advanced Scatterometer. At the in situ locations, SMAP_DA and CPCU_SIM have comparable soil moisture skill improvements relative to CTRL for the unbiased root-mean-square error (surface and root-zone) and correlation metrics (root-zone only). In the global average, SMAP Tb assimilation increases the surface soil moisture anomaly correlation by 0.10-0.11 compared to an increase of 0.02-0.03 from the CPCU-based precipitation corrections. The contrast is particularly strong in central Australia, where CPCU is known to have errors and observation-minus-forecast Tb residuals are larger when CPCU precipitation is used. Validation versus streamflow measurements in the contiguous U.S. reveals that CPCU precipitation provides most of the skill gained in L4_SM runoff estimates over CTRL.

SMAP↗

Accomplishments of the NASA Johnson Space Center portion of the soil moisture project in fiscal year 1981

The NASA/JSC ground scatterometer system was used in a row structure and row direction effects experiment to understand these effects on radar remote sensing of soil moisture. Also, a modification of the scatterometer system was begun and is continuing, to allow cross-polarization experiments to be conducted in fiscal years 1982 and 1983. Preprocessing of the 1978 agricultural soil moisture experiment (ASME) data was completed. Preparations for analysis of the ASME data is fiscal year 1982 were completed. A radar image simulation procedure developed by the University of Kansas is being improved. Profile soil moisture model outputs were compared quantitatively for the same soil and climate conditions. A new model was developed and tested to predict the soil moisture characteristic (water tension versus volumetric soil moisture content) from particle-size distribution and bulk density data. Relationships between surface-zone soil moisture, surface flux, and subsurface moisture conditions are being studied as well as the ways in which measured soil moisture (as obtained from remote sensing) can be used for agricultural applications.

Paris, J. F.↗

A Review of Global Satellite-Derived Snow Products

Snow cover over the Northern Hemisphere plays a crucial role in the Earth's hydrology and surface energy balance, and modulates feedbacks that control variations of global climate. While many of these variations are associated with exchanges of energy and mass between the land surface and the atmosphere, other expected changes are likely to propagate downstream and affect oceanic processes in coastal zones. For example, a large component of the freshwater flux into the Arctic Ocean comes from snow melt. The timing and magnitude of this flux affects biological and thermodynamic processes in the Arctic Ocean, and potentially across the globe through their impact on North Atlantic Deep Water formation. Several recent global remotely sensed products provide information at unprecedented temporal, spatial, and spectral resolutions. In this article we review the theoretical underpinnings and characteristics of three key products. We also demonstrate the seasonal and spatial patterns of agreement and disagreement amongst them, and discuss current and future directions in their application and development. Though there is general agreement amongst these products, there can be disagreement over certain geographic regions and under conditions of ephemeral, patchy and melting snow.

Frei, Allan↗

A Review of Global Satellite-Derived Snow Products

Snow cover over the Northern Hemisphere plays a crucial role in the Earth s hydrology and surface energy balance, and modulates feedbacks that control variations of global climate. While many of these variations are associated with exchanges of energy and mass between the land surface and the atmosphere, other expected changes are likely to propagate downstream and affect oceanic processes in coastal zones. For example, a large component of the freshwater flux into the Arctic Ocean comes from snow melt. The timing and magnitude of this flux affects biological and thermodynamic processes in the Arctic Ocean, and potentially across the globe through their impact on North Atlantic Deep Water formation. Several recent global remotely sensed products provide information at unprecedented temporal, spatial, and spectral resolutions. In this article we review the theoretical underpinnings and characteristics of three key products. We also demonstrate the seasonal and spatial patterns of agreement and disagreement amongst them, and discuss current and future directions in their application and development. Though there is general agreement amongst these products, there can be disagreement over certain geographic regions and under conditions of ephemeral, patchy and melting snow

Frei, Allan↗

A Review of Global Satellite-derived Snow Products

Snow cover over the Northern Hemisphere plays a crucial role in the Earth's hydrology and surface energy balance, and modulates feedbacks that control variations of global climate. While many of these variations are associated with exchanges of energy and mass between the land surface and the atmosphere, other expected changes are likely to propagate downstream and affect oceanic processes in coastal zones. For example, a large component of the freshwater flux into the Arctic Ocean comes from snow melt. The timing and magnitude of this flux affects biological and thermodynamic processes in the Arctic Ocean, and potentially across the globe through their impact on North Atlantic Deep Water formation. Several recent global remotely sensed products provide information at unprecedented temporal, spatial, and spectral resolutions. In this article we review the theoretical underpinnings and characteristics of three key products. We also demonstrate the seasonal and spatial patterns of agreement and disagreement amongst them, and discuss current and future directions in their application and development. Though there is general agreement amongst these products, there can be disagreement over certain geographic regions and under conditions of ephemeral, patchy and melting snow.

Frei, Allan↗

Reactive Transport and Mass Balance Modeling of the Stimson Sedimentary Formation and Altered Fracture Zones Constrain Diagenetic Conditions at Gale Crater, Mars

On a planet as cold and dry as present-day Mars, evidence of multiple aqueous episodes offers an intriguing view into very different past environments. Fluvial, lacustrine, and eolian depositional environments are being investigated by the Mars Science Laboratory Curiosity in Gale crater, Mars. Geochemical and mineralogical observations of these sedimentary rocks suggest diagenetic processes affected the sediments. Here, we analyze diagenesis of the Stimson formation eolian parent material, which caused loss of olivine and formation of magnetite. Additional, later alteration in fracture zones resulted in preferential dissolution of pyroxene and precipitation of secondary amorphous silica and Ca sulfate. The ability to compare the unaltered parent material with the reacted material allows constraints to be placed on the characteristics of the altering solutions. In this work we use a combination of a mass balance approach calculating the fraction of a mobile element lost or gained, tau, with fundamental geochemical kinetics and thermodynamics in the reactive transport code CrunchFlow to examine the characteristics of multiple stages of aqueous alteration at Gale crater, Mars. Our model results indicate that early diagenesis of the Stimson sedimentary formation is consistent with leaching of an eolian deposit by a near-neutral solution, and that formation of the altered fracture zones is consistent with a very acidic, high sulfate solution containing Ca, P and Si. These results indicate a range of past aqueous conditions occurring at Gale crater, Mars, with important implications for past martian climate and environments.

Gale↗

Renewable Energy Contingencies in Power Systems: Concept and Case Study

This paper introduces the concept of renewable energy contingencies that represent long-term/extended variability of variable renewable energy (VRE) resources, namely, significant periods (e.g., days/weeks) of low wind/solar availability. These contingencies have not received much attention to date but are likely to emerge as a major issue in some countries such as India as the share of VRE increases. Using 38 years of climate model reanalysis data for wind over India, we demonstrate that low periods of wind contingency below long-term (Indian) national average of 5 m/s can extend for more than 100 days in several zones some of which are deploying large wind farms. Even in some of the best wind resource areas in India with long term average wind speed close to 7 m/s, low wind days (e.g., 5 m/s which is substantially below average) can extend up to 60 days. We propose a four-step methodology around a co-optimization based energy-ancillary services dispatch model to assess the impact of renewable contingency and implemented it for the state of Tamil Nadu, the most wind-rich state of India. We have estimated that annual renewable contingency cost impact of 5 GW additional wind in Tamil Nadu to be in the range of US$27-76 million pa. Planning analysis should embrace the concept of renewable contingency to recognize these costs and put in place necessary spinning reserve and back-up generation resources.

Mohar Chattopadhyay↗

Discounting Water for Optimal Carbon Gain as a Basis of Stomatal Closure

The exchange of carbon dioxide and water vapor between terrestrial ecosystems and the atmosphere is regulated by stomata (small pores in the leaves of plants). Unsurprisingly, environmental factors controlling the opening and closure of stomata has been sought as early as 1800. One approach, popularized in the early 1970s, is a stomatal optimization framework. This framework is based on the hypothesis that plants optimize carbon gain subject to water loss or water availability constraints. This constraint optimization problem was solved in various forms assuming instantaneous adjustments of stomatal aperture to maximize a reward function with no future foresight or legacy effects. Holtzman et al. (2024, https://doi.org/10.1029/2023av001113) offers a novel approach that can diagnose the effective timescale over which the reward function maximization must be time-integrated. The developed method thus optimizes an integrated carbon gain function but adjusted by a discount factor subject to water availability in the root zone. The discount factor considers how the plant values carbon gain to save water and its timescale can be inferred from observations because the model is analytically tractable. The results suggest that the most important climate factor that determines this discount timescale is multi-annual mean of the longest dry period during the growing season. The findings highlight how local climate traits influence the spatial variation in ecosystem-level water use strategies. This sets the stage for expanding such a framework to cases where multiple constraints act in concert while operating at distinct time scales.

stomata↗

Synoptic Traveling Weather Systems on Mars: Effects of Radiatively-Active Water Ice Clouds

Atmospheric aerosols on Mars are critical in determining the nature of its thermal structure, its large-scale circulation, and hence the overall climate of the planet. We conduct multi-annual simulations with the latest version of the NASA Ames Mars global climate model (GCM), gcm2.3+, that includes a modernized radiative-transfer package and complex water-ice cloud microphysics package which permit radiative effects and interactions of suspended atmospheric aerosols (e.g., water ice clouds, water vapor, dust, and mutual interactions) to influence the net diabatic heating. Results indicate that radiatively active water ice clouds profoundly affect the seasonal and annual mean climate. The mean thermal structure and balanced circulation patterns are strongly modified near the surface and aloft. Warming of the subtropical atmosphere at altitude and cooling of the high latitude atmosphere at low levels takes place, which increases the mean pole-to-equator temperature contrast (i.e., "baroclinicity"). With radiatively active water ice clouds (RAC) compared to radiatively inert water ice clouds (nonRAC), significant changes in the intensity of the mean state and forced stationary Rossby modes occur, both of which affect the vigor and intensity of traveling, synoptic period weather systems.Such weather systems not only act as key agents in the transport of heat and momentum beyond the extent of the Hadley circulation, but also the transport of trace species such as water vapor, water ice-clouds, dust and others. The northern hemisphere (NH) forced Rossby waves and resultant wave train are augmented in the RAC case: the modes are more intense and the wave train is shifted equatorward. Significant changes also occur within the subtropics and tropics. The Rossby wave train sets up, combined with the traveling synoptic period weather systems (i.e., cyclones and anticyclones), the geographic extent of storm zones (or storm tracks) within the NH. A variety of circulation features will be presented which indicate contrasts between the RAC and nonRAC cases, and which highlight key effects radiatively-active clouds have on physical and dynamical processes active in the current climate of Mars.

GCM-global climate model↗

Synoptic Traveling Weather Systems on Mars: Effects of Radiatively-Active Water Ice Clouds

Atmospheric aerosols on Mars are critical in determining the nature of its thermal structure, its large-scale circulation, and hence the overall climate of the planet. We conduct multi-annual simulations with the latest version of the NASA Ames Mars global climate model (GCM), gcm2.3+, that includes a modernized radiative-transfer package and complex water-ice cloud microphysics package which permit radiative effects and interactions of suspended atmospheric aerosols (e.g., water ice clouds, water vapor, dust, and mutual interactions) to influence the net diabatic heating. Results indicate that radiatively active water ice clouds profoundly affect the seasonal and annual mean climate. The mean thermal structure and balanced circulation patterns are strongly modified near the surface and aloft. Warming of the subtropical atmosphere at altitude and cooling of the high latitude atmosphere at low levels takes place, which increases the mean pole-to-equator temperature contrast (i.e., "baroclinicity"). With radiatively active water ice clouds (RAC) compared to radiatively inert water ice clouds (nonRAC), significant changes in the intensity of the mean state and forced stationary Rossby modes occur, both of which affect the vigor and intensity of traveling, synoptic period weather systems. Such weather systems not only act as key agents in the transport of heat and momentum beyond the extent of the Hadley circulation, but also the transport of trace species such as water vapor, water ice-clouds, dust and others. The northern hemisphere (NH) forced Rossby waves and resultant wave train are augmented in the RAC case: the modes are more intense and the wave train is shifted equatorward. Significant changes also occur within the subtropics and tropics. The Rossby wave train sets up, combined with the traveling synoptic period weather systems (i.e., cyclones and anticyclones), the geographic extent of storm zones (or storm tracks) within the NH. A variety of circulation features will be presented which indicate contrasts between the RAC and nonRAC cases, and which highlight key effects radiatively-active clouds have on physical and dynamical processes active in the current climate of Mars.

Atmospheric aerosols↗

Synoptic Traveling Weather Systems on Mars: Effects of Radiatively-Active Water Ice Clouds

Atmospheric aerosols on Mars are critical in determining the nature of its thermal structure, its large-scale circulation, and hence the overall climate of the planet. We conduct multi-annual simulations with the latest version of the NASA Ames Mars global climate model (GCM), gcm2.3+, that includes a modernized radiative-transfer package and complex water-ice cloud microphysics package which permit radiative effects and interactions of suspended atmospheric aerosols (e.g., water ice clouds, water vapor, dust, and mutual interactions) to influence the net diabatic heating. Results indicate that radiatively active water ice clouds profoundly affect the seasonal and annual mean climate. The mean thermal structure and balanced circulation patterns are strongly modified near the surface and aloft. Warming of the subtropical atmosphere at altitude and cooling of the high latitude atmosphere at low levels takes place, which increases the mean pole-to-equator temperature contrast (i.e., "baroclinicity"). With radiatively active water ice clouds (RAC) compared to radiatively inert water ice clouds (nonRAC), significant changes in the intensity of the mean state and forced stationary Rossby modes occur, both of which affect the vigor and intensity of traveling, synoptic period weather systems. Such weather systems not only act as key agents in the transport of heat and momentum beyond the extent of the Hadley circulation, but also the transport of trace species such as water vapor, water ice-clouds, dust and others. The northern hemisphere (NH) forced Rossby waves and resultant wave train are augmented in the RAC case: the modes are more intense and the wave train is shifted equatorward. Significant changes also occur within the subtropics and tropics. The Rossby wave train sets up, combined with the traveling synoptic-period weather systems (i.e., cyclones and anticyclones), the geographic extent of storm zones (or storm tracks) within the NH. A variety of circulation features will be presented which indicate contrasts between the RAC and nonRAC cases, and which highlight key effects radiatively-active clouds have on physical and dynamical processes active in the current climate of Mars.

NASA Ames Mars global climate model (GCM)↗

The Sensitivity of the Equatorial Pacific ODZ to Particulate Organic Matter Remineralization in A Climate Model Under Pre-Industrial Conditions

Marine oxygen plays a fundamental role in regulating the transfer of organic carbon and nutrients to their dissolved inorganic forms, serving as the terminal electron acceptor for heterotrophic respiration. Oxygen can become limiting to these processes in coastal and open-ocean oxygen deficient zones (ODZs). The maintenance of ODZs depends on the balance between physical processes such as ventilation and biogeochemical processes such as remineralization. These two processes act in opposing directions on ODZs, with ventilation responsible for transporting oxygen from the surface, where it is near saturation with the partial pressure of O2 in the atmosphere, to deeper oxygen-depleted layers, and remineralization acting to consume oxygen through biogeochemical processes such as microbial degradation throughout the water column. Remineralization is represented in all CMIP6 models, but the actual parameterizations, as well as their magnitude, are widely varying. In this study, we examine the sensitivity to remineralization of the equatorial Pacific ODZ O2 ol/kg) in a model; the NASA GISS Ocean Biogeochemical Model (NOBM-G) embedded in the NASA-GISS coupled atmosphere-ocean model. We find that increasing the remineralization rate shoals the ODZ onset depth (i.e. the regionally averaged upper bound of the ODZ), and decreases ODZ volume and regional-averaged thickness. Changes in biological consumption and vertical convergence of oxygen are identified as the primary contributors to changes in ODZ onset depth. ODZ thickness is mainly influenced by the shoaling of the bottom boundary of the ODZ, which decreases with maximum remineralization rate due to decreasing oxygen consumption and increasing horizontal oxygen convergence in deep waters. On the other hand, vertically-averaged ODZ area has a more complex, non-monotonic relationship with maximum remineralization rate. While these findings suggest an important role for remineralization in determining the shape of the ODZ in our model, the relative importance of remineralization vs. other physical parameterizations remains to be established. While our results reflect the structure of our ocean biogeochemical model, the relationship of remineralization to ODZ characteristics in other models should be examined to better inform model inter-comparisons.

Oxygen-deficient zone↗

Remote Sensing of the Urban Heat Island Effect Across Biomes in the Continental USA

Impervious surface area (ISA) from the Landsat TM-based NLCD 2001 dataset and land surface temperature (LST) from MODIS averaged over three annual cycles (2003-2005) are used in a spatial analysis to assess the urban heat island (UHI) skin temperature amplitude and its relationship to development intensity, size, and ecological setting for 38 of the most populous cities in the continental United States. Development intensity zones based on %ISA are defined for each urban area emanating outward from the urban core to the nonurban rural areas nearby and used to stratify sampling for land surface temperatures and NDVI. Sampling is further constrained by biome and elevation to insure objective intercomparisons between zones and between cities in different biomes permitting the definition of hierarchically ordered zones that are consistent across urban areas in different ecological setting and across scales. We find that ecological context significantly influences the amplitude of summer daytime UHI (urban-rural temperature difference) the largest (8 C average) observed for cities built in biomes dominated by temperate broadleaf and mixed forest. For all cities combined, ISA is the primary driver for increase in temperature explaining 70% of the total variance in LST. On a yearly average, urban areas are substantially warmer than the non-urban fringe by 2.9 C, except for urban areas in biomes with arid and semiarid climates. The average amplitude of the UHI is remarkably asymmetric with a 4.3 C temperature difference in summer and only 1.3 C in winter. In desert environments, the LST's response to ISA presents an uncharacteristic "U-shaped" horizontal gradient decreasing from the urban core to the outskirts of the city and then increasing again in the suburban to the rural zones. UHI's calculated for these cities point to a possible heat sink effect. These observational results show that the urban heat island amplitude both increases with city size and is seasonally asymmetric for a large number of cities across most biomes. The implications are that for urban areas developed within forested ecosystems the summertime UHI can be quite high relative to the wintertime UHI suggesting that the residential energy consumption required for summer cooling is likely to increase with urban growth within those biomes.

Imhoff, Marc L.↗

Absorption Properties of Mediterranean Aerosols Obtained from Multi-year Ground-based and Satellite Remote Sensing Observations

Aerosol absorption properties are of high importance to assess aerosol impact on regional climate. This study presents an analysis of aerosol absorption products obtained over the Mediterranean Basin or land stations in the region from multi-year ground-based AERONET and satellite observations with a focus on the Absorbing Aerosol Optical Depth (AAOD), Single Scattering Albedo (SSA) and their spectral dependence. The AAOD and Absorption Angstrom Exponent (AAE) data set is composed of daily averaged AERONET level 2 data from a total of 22 Mediterranean stations having long time series, mainly under the influence of urban-industrial aerosols and/or soil dust. This data set covers the 17 yr period 1996-2012 with most data being from 2003-2011 (approximately 89 percent of level-2 AAOD data). Since AERONET level-2 absorption products require a high aerosol load (AOD at 440 nm greater than 0.4), which is most often related to the presence of desert dust, we also consider level-1.5 SSA data, despite their higher uncertainty, and filter out data with an Angstrom exponent less than 1.0 in order to study absorption by carbonaceous aerosols. The SSA data set includes both AERONET level-2 and satellite level-3 products. Satellite-derived SSA data considered are monthly level 3 products mapped at the regional scale for the spring and summer seasons that exhibit the largest aerosol loads. The satellite SSA dataset includes the following products: (i) Multi-angle Imaging SpectroRadiometer (MISR) over 2000-2011, (ii) Ozone Monitoring Instrument (OMI) near-UV algorithm over 2004-2010, and (iii) MODerate resolution Imaging Spectroradiometer (MODIS) Deep-Blue algorithm over 2005-2011, derived only over land in dusty conditions. Sun-photometer observations show that values of AAOD at 440 nm vary between 0.024 +/- 0.01 (resp. 0.040 +/- 0.01) and 0.050 +/- 0.01 (0.055 +/- 0.01) for urban (dusty) sites. Analysis shows that the Mediterranean urban-industrial aerosols appear "moderately" absorbing with values of SSA close to approximately 0.94-0.95 +/- 0.04 (at 440 nm) in most cases except over the large cities of Rome and Athens, where aerosol appears more absorbing (SSA approximately 0.89-0.90 +/- 0.04). The aerosol Absorption Angstrom Exponent (AAE, estimated using 440 and 870 nm) is found to be larger than 1 for most sites over the Mediterranean, a manifestation of mineral dust (iron) and/or brown carbon producing the observed absorption. AERONET level-2 sun-photometer data indicate the existence of a moderate East-West gradient, with higher values over the eastern basin (AAEEast. = 1.39/AAEWest. = 1.33) due to the influence of desert dust. The North-South AAE gradient is more pronounced, especially over the western basin. Our additional analysis of AERONET level-1.5 data also shows that organic absorbing aerosols significantly affect some Mediterranean sites. These results indicate that current climate models treating organics as nonabsorbing over the Mediterranean certainly underestimate the warming effect due to carbonaceous aerosols. A~comparative analysis of the regional SSA variability has been attempted using satellite data. OMI and MODIS data show an absorbing zone (SSA approximately 0.90 at 470-500 nm) over Northeastern Africa that does not appear in the MISR retrievals. In contrast, MISR seems able to observe the East-West SSA gradient during summer, as also detected by AERONET. Also, the analysis of SSA provided by satellites indicates that the aerosol over the Mediterranean Sea appears less absorbing during spring (MAM) than summer (JJA).

satellite remote sensing observations↗

Saharan Dust as a Causal Factor of Significant Cloud Cover Along the Saharan Air Layer in the Atlantic Ocean

The tropical Atlantic is frequently affected by Saharan dust intrusions. Based on MODIS cloud fraction (CF) data during the ten-year study period, we found that these dust intrusions contribute to significant cloud cover along the Saharan Air Layer (SAL). Below the temperature inversion at the SAL's base, the presence of large amounts of settling dust particles, together with marine aerosols, produces meteorological conditions suitable for the formation of shallow stratocumulus clouds. The significant cloud fraction along the SAL together with clouds over the Atlantic Inter-tropical Convergence Zone contributes to the 20% hemispheric CF asymmetry between the tropical North and South Atlantic. This leads to the imbalance in strong solar radiation, which reaches the sea surface between the tropical North and South Atlantic, and, consequently, affects climate formation in the tropical Atlantic. Therefore, despite the fact that, over the global ocean, there is no noticeable hemispheric asymmetry in cloud fraction, over the significant area such as the tropical Atlantic the hemispheric asymmetry in CF takes place. Saharan dust is also the major contributor to hemispheric aerosol asymmetry over the tropical Atlantic. The NASA GEOS-5 model with aerosol data assimilation was used to extend the MERRA reanalysis with five atmospheric aerosol species (desert dust, sulfates, organic carbon, black carbon, and sea-salt). The obtained ten-year (2002 - 2012) MERRA-driven aerosol reanalysis dataset (aka MERRAero) showed that, over the tropical Atlantic, dust and carbonaceous aerosols were distributed asymmetrically relative to the equator, while other aerosol species were distributed more symmetrically.

CF↗

Lightning Over Central Canada: Skill Assessment for Various Land-Atmosphere Model Configurations and Lightning Indices Over a Boreal Study Area

Current lightning predictions are uncertain because they rely on empirical diagnostic relationships and often use coarse-scale climate scenario simulations in which deep convection is parameterized. Previous studies demonstrated that simulations with convection permitting resolutions improve lightning predictions compared to coarser-grid simulations using convection parameterizations for different geographical locations but not over the boreal zone. In this study, lightning simulations with the NASA Unified-Weather Research and Forecasting (NU-WRF) model are evaluated over a domain including the Great Slave Lake in Canada, for six lightning seasons. The simulations are performed at convection parameterized (9 km) and convection-permitting (3 km) resolution using the Goddard 4ICE and the Thompson microphysics schemes. Four lightning indices are evaluated against observations from the Canadian Lightning Detection Network, in terms of spatiotemporal frequency distribution, spatial pattern, daily climatology, and an event-based overall skill assessment. The Thompson scheme is, regardless of the spatial resolution, superior to the Goddard 4ICE scheme in predicting daily climatology but worse in predicting the spatial patterns of lightning occurrence. Results indicate that lightning estimation benefits from modeling at convection-permitting resolution, in particular for the ice based lightning indices. In contrast, the product of convective available potential energy and precipitation rate proved to be the most robust index that was largely invariant to varying spatial resolution. Finally, this study reveals issues of the models to reproduce the observed spatial pattern of lightning well, which might be related to an insufficient representation of land surface heterogeneity, including peatlands, in the study area.

Jonas Mortelmans↗