Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Charging Experience”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

The Mu2e Experiment and Progress in the Year 2024

The Mu2e Experiment is a search for Charged Lepton Flavor Violation (CLFV) in the process of a coherent neutrinoless mu- N -> e- N transition. This process is allowed under the Standard Model in the presence of neutrino mixing; albeit, at unobservable rates (branching ratio below 10-50). The sensitivity of the Mu2e experiment is a factor of 104 improvement over the current limit. This search both compliments and extends current searches for muon to electron+gamma at MEG and new physics searches at the LHC. Another interesting process that Mu2e will search for is the neutrionless conversion of stopped negative muons into positrons: mu- N -> e+ N'. This process violates both lepton flavor and lepton number (LNV) and would provide proof that neutrinos are Majorana particles. Progress has been made in many areas in preparation for beam. A description of the Mu2e Experiment and a synopsis of this experiment s progress in the year 2024 towards data collection will be presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Geometrical control of topological charge transfer in Shakti-Cairo colloidal ice

Lattice transformations that preserve the system topology, but not its geometry, are common in condensed matter systems. However, how geometric constrains influence the topological properties of the lattices is still unclear. Here we show that a geometric transformation between two mixed coordination lattices, from Shakti to Cairo in an artificial colloidal ice, leads to a breakdown of the ice rule in all but one specific geometry. We observe a transfer of topological charge among sublattices which can be controlled in sign and intensity, vanishing at the ice-rule point. These unusual topological effects are absent in magnetic spin ices and they are due to collective, non-local geometric frustration in the particle ice. By merging numerical simulations, theory and experiments, we demonstrate how the charge transfer occurs in the Cairo geometry. The broader implication of our results is that we demonstrate how geometric constraints can control the topological properties of a mesoscopic colloidal system.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

A New Concept for Kilotonne Scale Liquid Argon Time Projection Chambers

We develop a novel Time Projection Chamber (TPC) concept suitable for deployment in kilotonne-scale detectors, with a charge-readout system free from reconstruction ambiguities, and a robust TPC design that reduces high-voltage risks while increasing the coverage of the light-collection system and maximizing the active volume. This novel concept could be used as a far detector module in the Deep Underground Neutrino Experiment (DUNE). For the charge-readout system, we used the charge-collection pixels and associated application-specific integrated circuits currently being developed for the liquid argon (LAr) component of the DUNE Near Detector design, ArgonCube. In addition, we divided the TPC into a number of shorter drift volumes, reducing the total voltage used to drift the ionization electrons, and minimizing the stored energy per TPC. Segmenting the TPC also contains scintillation light, allowing for precise trigger localization and a more expansive light-readout system. Furthermore, the design opens the possibility of replacing or upgrading components. These augmentations could substantially improve the reliability and the sensitivity, particularly for low-energy signals, in comparison to traditional monolithic LArTPCs with projective-wire charge readouts.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2026

Modulating the Lattice Stability in Sodium-Layered Oxide Cathodes through Inductive Effect

Stability and safety of sodium layered oxide cathodes relative to lithium analogs remain a critical concern, yet its fundamental origin remains poorly understood. Here, we examine the role of sodium – oxygen bond ionicity in governing outgassing by introducing 5% lithium (Li), potassium (K), or both into layered NaNiO 2 (NNO), yielding Na 0.95 Li 0.05 NiO 2 , Na 0.95 K 0.05 NiO 2 , and Na 0.90 Li 0.05 K 0.05 NiO 2 . Online electrochemical mass spectrometry at 4.3 V reveals that K substitution increases gas evolution with similar charge capacity, whereas Li substitution reduces gas evolution by nearly 80% with only a 16% capacity decrease. Capacity-controlled experiments show that NNO must be charged to only 3.8 V (144 mA h g -1 ) to achieve gas evolution comparable to Na 0.95 Li 0.05 NiO 2 charged to 4.3 V (175 mA h g -1 ). These results demonstrate that tuning alkali-metal–oxygen bond ionicity through the inductive effect regulates Ni–O covalency, lattice oxygen stability, and interfacial reactivity, providing design guidance for safer sodium layered oxide cathodes.

25 ENERGY STORAGE↗
DOE OSTI2024

Energy Level Gradients from Surface to Bulk in Hybrid Metal-Halide Perovskite Thin Films

Variations in local strain, defect densities, and composition of hybrid metal-halide perovskites have been reported to create heterogeneous energy landscapes in thin films, which impact charge-carrier diffusion and recombination dynamics. Here, we employ one- and two-photon transient absorption spectroscopy to selectively probe the dynamics of charge carriers from surface and bulk regions of methylammonium lead bromide thin films. Differences in the transient absorption spectra indicate that an energy gradient of approximately 100 meV is formed between the higher band-gap surface and lower band-gap bulk regions. Thus, during their lifetime, photoexcited carriers move away from the surface to recombine in the bulk, where our experiments detect long-lived charge populations despite the significant band splitting that has conventionally been assumed to inhibit efficient radiative recombination. Supported by first-principles calculations, we demonstrate that bright emission can still arise from the bulk with states that occupy a wide range of momenta in the vicinity of the band extrema, which show strong dipole transitions. Our results report that photoexcitations in the hybrid perovskites avoid defect-rich surface regions, and that particularly strong emission is generated from accumulated excitation populations in the bulk. Published by the American Physical Society 2024

Bourelle, Sean A.↗
DOE OSTI2025

Robust quantification of the diamond nitrogen-vacancy center charge state via photoluminescence spectroscopy

Nitrogen vacancy (NV) centers in diamond are at the heart of many emerging quantum technologies, all of which require control over the NV charge state. Hence, methods for quantification of the relative photoluminescence intensities of the NV 0 and NV − charge states, i.e., a charge state ratio, are vital. Several approaches to quantify NV charge state ratios have been reported but are either limited to bulk-like NV diamond samples or yield qualitative results. We propose an NV charge state quantification protocol based on the determination of sample- and experimental setup-specific NV 0 and NV − reference spectra. The approach employs blue (400–470 nm) and green (480–570 nm) excitation to infer pure NV 0 and NV − spectra, which are then used to quantify NV charge state ratios in subsequent experiments via least squares fitting. We test our dual excitation protocol (DEP) for a bulk diamond NV sample and 20 and 100 nm nanodiamond particles and compare results with those obtained via other commonly used techniques such as zero-phonon line fitting and non-negative matrix factorization. We find that DEP can be employed across different samples and experimental setups and yields consistent and quantitative results for NV charge state ratios that are in agreement with our understanding of NV photophysics. By providing robust NV charge state quantification across sample types and measurement platforms, DEP will support the development of NV-based quantum technologies.

Color center laser spectroscopy↗
DOE OSTI2021

An unprecedented quinoid–donor–acceptor strategy to boost the carrier mobilities of semiconducting polymers for organic field-effect transistors

Quinoidal–aromatic conjugated polymers hold great application potential in organic field-effect transistors (OFETs). However, the development of high mobility quinoidal–aromatic conjugated polymers still lags behind the more popular donor–acceptor (D–A) conjugated polymers, mainly owing to the lack of a rational design strategy and efficient building block. Herein, a novel quinoid–donor–acceptor (Q–D–A) strategy is demonstrated to modulate the energy-level and boost the charge carrier transport mobility of conjugated polymers as opposed to the D–A system. On the basis of this strategy, a quinoidal–aromatic conjugated polymer, namely PAQM-BT, is designed and synthesized. With the combined use of quinoid, donor and acceptor units in the backbone, the resulting Q–D–A polymer PAQM-BT displays the narrowest bandgap with the deepest-lying lowest unoccupied molecular orbital (LUMO) energy level, highest backbone coplanarity, enhanced thin-film crystallinity and smallest effective hole mass ($m^*_h$) in comparison with the corresponding D–A polymer PT3B1 and quinoid–donor (Q–D) polymer PAQM-3T. Benefitting from the more effective intra- and inter-chain charge transport, as corroborated by experiment and theoretical calculations, OFET devices based on PAQM-BT exhibit a highly boosted hole mobility of up to 5.10 cm 2 V -1 s -1 , which is one and four orders of magnitude higher than that of PAQM-3T and PT3B1, respectively, and is among the highest for quinoidal–aromatic conjugated polymers. Finally, the potent Q–D–A strategy not only allows the energy level to be modulated but also leads to effective charge carrier transport, opening up possibilities to the development of high mobility quinoidal–aromatic conjugated polymers based on a variety of quinoids, donors, and acceptors.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Comparison of Single-Event Transients in an Epitaxial Silicon Diode Resulting from Heavy Ion-, Focused X-Ray-, and Pulsed Laser-Induced Charge Generation

Heavy ion, focused x-ray, and pulsed laser single event transient experiments are performed on a silicon epitaxial diode. Collected charge, transient rise times, and transient fall times are calculated and compared between the different sources. It is observed that these transient shape characteristics depend on the source (ion, x-ray, or laser), even when similar amounts of charge are generated. Finally, the observed differences are examined and explained in terms of basic charge collection mechanisms.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Assessing the Effect of Explicit Polarizability on Models of Carbon Dioxide Solvation in Ionic Liquids

Ionic liquids are an important possible carbon capture material because of their anomalously high sorption selectivity for carbon dioxide over other gases common in air. Many research groups have investigated the molecular origins of this property and provided important insights, including using 1D and 2D-IR spectroscopy. Molecular dynamics simulations have been indispensable to the interpretation of these experiments. In prior molecular dynamics simulation work, charge-scaled force fields have typically been used to provide a mean-field treatment of effects vital to ionic liquid systems such as charge transfer and polarization. Here, we compare models of carbon dioxide solvated in ionic liquids with explicit polarization to models of the same with implicit polarizability through charge-scaling. We calculate structural, dynamical, and spectroscopic properties, and make comparisons to the same items measured in experiment. In this study, we focus on two ionic liquids: 1-butyl-3- methylimidazolium (BMIM + ) paired with bis(trifluoromethane sulfonyl imide) (Tf 2 N − ) and 1-butyl-3-methylimidazolium (BMIM+) paired with hexafluorophosphate (PF 6 − ). We find that many structural, dynamical, and spectroscopic properties are changed when polarization is modeled explicitly. We also find that explicit polarizability softens local ion cages around the carbon dioxide and that the long-time diffusion of the carbon dioxide is gated by the reorganization of the ionic liquid molecules. Comparisons to experiment show modest improvement of many observables compared with experiment for the explicitly polarizable model over the charge-scaled model. Overall, our results show that charge-scaled force fields are likely sufficient to compute spectroscopic properties of carbon dioxide in ionic liquids and suggest some interpretive rules for understanding their structural and dynamical properties. Those using charge-scaled force fields should generally assume that the ion cages around solutes such as carbon dioxide are too stiff and cation-rich in their models and adjust their interpretations and predictions accordingly.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Nucleon Mass and Charges with Lattice Quantum Chromodynamics

Neutrino oscillation experiments are designed to measure neutrino masses and mixing parameters by scattering them off nuclei such as carbon, oxygen, and argon in detectors. Predictions of neutrino-nuclei cross sections from the Standard Model are needed to extract these parameters, but their theoretical uncertainties remain large due to the complexity of nuclear and hadronic physics. This situation needs to be improved in order to satisfy the precision needs of future experiments.In this dissertation, we focus on working towards a first-principles calculation of the nucleon axial form factor with lattice quantum chromodynamics (QCD). Nucleon axial form factor, which parametrizes the weak responses of a proton or neutron, is difficult to measure experimentally, and it is a dominant uncertainty in neutrino-nuclei cross-section calculations for incoming neutrino energies at around 1 GeV. So a theoretical calculation with lattice QCD provides a non-ambiguous determination of the form factor that could help reducing the uncertainty.The notorious signal-to-noise problem renders calculations of nucleon observables computationally intensive in lattice QCD. In this work, we investigate the use of staggered fermions in nucleon calculations. Staggered fermions are the most computationally efficient fermion discretization in lattice field theory, but certain theoretical issues have so far prevented their applications to nucleon physics. As a stepping stone towards a full calculation of the nucleon axial form factor, this dissertation provides a comprehensive theoretical framework on how to calculate the nucleon mass, vector charge, and axial charge with staggered fermions, together with numerical results demonstrating the methodology. This framework can be generalized to the form factor calculation that will appear in the near future.

Lin, Yin↗
DOE OSTI2023

First Measurement of Inclusive Muon Neutrino Charged Current Triple Differential Cross Section on Argon

The field of accelerator neutrino experiments is entering an era of precision oscillation measurements where the remaining unknown neutrino measurements will be determined. The upcoming DUNE and Hyper-K experiments aim to determine the neutrino mass hierarchy and degree of Charge-Parity (CP) violation in the neutrino sector, providing potential insight on the matter-antimatter imbalance observed in the universe. However, these experiments require highly accurate measurements, and neutrino cross section modeling uncertainties may limit their capabilities. Cross section measurements at current- generation experiments can aid the development of neutrino interaction models to reduce these uncertainties. This is especially true for measurements of neutrino energy, as it drives neutrino oscillations and is of key importance to oscillation experiments. The MicroBooNE experiment uses a Liquid Argon Time Projection Chamber (LArTPC) to produce neutrino-argon cross sections as one of its physics goals. The MicroBooNE detector’s fully active volume, precision reconstruction, and calorimetry information are leveraged in the Wire-Cell analysis to produce a muon neutrino selection that is 92% pure while maintaining 68% efficiency. A reconstruction chain featuring a fully 3D charge reconstruction and a graph-based particle trajectory fit are used to produce accurate measurements of lepton kinematics as well as visible hadronic energy produced in a neutrino interaction. This thesis presents the first neutrino-argon triple-differential cross section measurement, targeting inclusive charged-current final states. Wiener SVD unfolding is used to produce a measurement over neutrino energy, muon momentum, and muon scattering angle. A series of constrained goodness of fit tests are used to demonstrate the validity of MicroBooNE’s model in describing the distribution of reconstructed kinematics seen in data to ensure the accuracy of unfolding. The validated unfolding to neutrino energy represents a step forward in the field of neutrino cross sections, and demonstrates the capabilities of the LArTPC detector.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Measuring Charged Current Muon Neutrino Cross Sections on Oxygen with the Accelerator Neutrino Neutron Interaction Experiment

The Accelerator Neutrino Neutron Interaction Experiment (ANNIE) is a $26$-ton gadolinium-doped water Cherenkov detector on-axis of the Booster Neutrino Beam (BNB) at Fermilab. With ANNIE, this dissertation provides the first results of a high statistics muon neutrino charged current cross section on oxygen at a short baseline on axis. This thesis explains the necessity of the measurements and details how the measurements are performed. Focus is given on the physics behind the models used to predict neutrino cross sections. The measurements include the CC inclusive and CC$0\pi$ cross section channels. This thesis details the processes of event selection, reconstruction, handling systematics, and unfolding as part of cross section measurements. A data unblinding procedure is documented and acts as the first implementation of data unblinding in ANNIE. These results provide additional constraints on existing neutrino interaction models and are the necessary steps for a joint analysis with liquid Argon experiments also on the BNB line.

Minock, James [Rutgers U., Piscataway (main)]↗
DOE OSTI2022

Experimental observations of multiple modes of filamentary structures in the magnetized dusty plasma experiment (MDPX) device

Due to the small charge-to-mass ratio of dust particles, it is often necessary to use large magnetic fields of B ≥ 1 T, in order to observe the influence of magnetic forces in laboratory dusty plasmas. However, when experiments are performed at high magnetic fields in capacitively coupled, radio frequency discharges used for these dusty plasma experiments, the plasma is often observed to form filamentary structures between the electrodes that are aligned to the external magnetic field which disrupt the uniformity of the plasma and adversely impact some of our dusty plasma experiments. Recent experiments performed in the Magnetized Dusty Plasma Experiment device seek to identify and characterize these filamentary structures. This paper discusses the morphology of several distinct filamentary modes that are formed in low temperature argon plasmas. Three different spatial modes of filaments that appear to be strongly dependent on the magnetic field and neutral pressure are identified. There is strong evidence that each spatial mode has a threshold condition that is dependent on the ion Hall parameter. The criteria for the formation of the filaments are shown to be consistent with predictions of recent numerical simulations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

Charged-hadron identification at Belle II

The Belle II experiment’s ability to identify particles critically affects the sensitivity of its measurements. We describe Belle II’s algorithms for identifying charged particles and evaluate their performance in separating pions, kaons, and protons using $426\,\text {fb}^{-1}$ of data collected at the energy-asymmetric $e^{+}e^{-}$ collider SuperKEKB in 2019–2022 at center-of-mass energies at and near the mass of the $\Upsilon$ (4S).

Adachi, I. (ORCID:0000000322870173)↗
DOE OSTI2020

Reconstruction of neutral-triggered charged recoil jets in √ s = 200 GeV p+p collisions at the STAR experiment

Jets — collimated sprays of hadrons — are produced by hard-scattered partons during the early stages of heavy ion collisions. Hence, they provide a valuable probe of the complex multi-particle dynamics within the hot, dense medium produced in such collisions. In particular, the study of jets recoiling from direct photons (γ dir +jet) and those recoiling from energetic π 0 (π 0 +jet) may shed light on the path-length and initial flavor (quark vs. gluon) dependence of the energy-loss experienced by a parton as it traverses the medium. We present here measurements of the yields of charged recoil jets tagged by γ dir and π 0 in p+p collisions at √S = 200 GeV. These measurements will serve as a vacuum fragmentation reference for an upcoming measurement in Au + Au collisions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Particle-hole asymmetry in the dynamical spin and charge responses of corner-shared 1D cuprates

Although many experiments imply that oxygen orbitals play an essential role in the high-temperature superconducting cuprates, their precise role in collective spin and charge excitations and superconductivity is not yet fully understood. Here, we study the doping-dependent dynamical spin and charge structure factors of single and multi-orbital (pd) models for doped one-dimensional corner-shared spin-chain cuprates using several numerically exact methods. In doing so, we determine the orbital composition of the collective spin and charge excitations of cuprates, with important implications for our understanding of these materials. For example, we observe a particle-hole asymmetry in the orbital-resolved charge excitations, which is directly relevant to resonant inelastic x-ray scattering experiments and not captured by the single-band Hubbard model. Our results imply that one must explicitly include the oxygen degrees of freedom in order to fully understand some experimental observations on cuprate materials.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Origin of layered perovskite device efficiencies revealed by multidimensional time-of-flight spectroscopy

Mixtures of layered perovskite quantum wells with different sizes form prototypical light-harvesting antenna structures in solution-processed films. Gradients in the bandgaps and energy levels are established by concentrating the smallest and largest quantum wells near opposing electrodes in photovoltaic devices. Whereas short-range energy and charge carrier funneling behaviors have been observed in layered perovskites, our recent work suggests that such light-harvesting processes do not assist long-range charge transport due to carrier trapping at interfaces between quantum wells and interstitial organic spacer molecules. Here, we apply a two-pulse time-of-flight technique to a family of layered perovskite systems to explore the effects that interstitial organic molecules have on charge carrier dynamics. In these experiments, the first laser pulse initiates carrier drift within the active layer of a photovoltaic device, whereas the second pulse probes the transient concentrations of photoexcited carriers as they approach the electrodes. The instantaneous drift velocities determined with this method suggest that the rates of trap-induced carrier deceleration increase with the concentrations of organic spacer cations. Overall, our experimental results and model calculations suggest that the layered perovskite device efficiencies primarily reflect the dynamics of carrier trapping at interfaces between quantum wells and interstitial organic phases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Multiband Fermi surface in $1T–$$\mathrm{VSe_2}$ and its implication for the charge density wave phase

Angle-resolved photoemission spectroscopy experiments reveal a surprisingly richer surface electronic structure in $1T–$$\mathrm{VSe_2}$ than previously predicted or probed. Earlier claims supporting a charge density wave phase in this material are reexamined in terms of these findings and are found to be untenable. Here, the Fermi surface is found to be gapless, while band warping effects, currently attributed to three-dimensional lattice distortion, result from the simultaneous dispersion of the closely lying multiple bands. Based on these findings, a charge density wave scenario in $1T–$$\mathrm{VSe_2}$ is unlikely. On the other side, the presence of multiple states crossing the Fermi level should constitute relevant constraints for any viable microscopic model of the structural phase transition of $\mathrm{VSe_2}$.

36 MATERIALS SCIENCE↗