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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Bench-Scale Development of a Novel Direct Air Capture Technology Using High-Capacity Structured Sorbents

The work performed under this project has resulted into development of a DAC technology utilizing a structured sorbent to capture CO 2 from ambient air with a key innovation of direct Joule heating of the sorbent for CO 2 desorption. A working SMA, fully integrated with an electrically resistive heating layer, high surface area support, and high CO 2 capacity sorbent coated onto a commercial ceramic monolithic substrate, was successfully developed and demonstrated over >200 adsorption-desorption cycles in a high-fidelity bench test unit directly using ambient air. A cordierite-based monolith was selected as a substrate owing to its high surface area, low bulk density, low heat capacity, and commercial availability. Reaction kinetics study conducted during this project led to development of a promoter for the base Na 2 CO 3 sorbent that could be incorporated into the sorbent to enhance to achieve higher CO 2 adsorption/desorption rates, greater working capacity, and reduced regeneration temperature. An accelerated aging study was conducted in a TGA to determine sorbent stability and no degradation in the sorbent performance was observed even after 250 adsorption-desorption cycles. An electrically resistive heating layer was developed with tunable electrical properties. The heating layer was coated onto the selected cordierite substrate. Aging studies performed showed the electrical properties and heating performance was stable after 500 heating and cooling cycles. The collective findings on the selected cordierite substrate, robust heating layer, promoter and sorbent selection were used to synthesize a full, 6”x6” SMA for bench-scale testing. The bench-scale DAC system was constructed to test full size SMAs using real ambient air for adsorption and joule heating for regeneration. After completing shakedown and commissioning of the 1 kg/day of CO 2 capacity DAC bench unit, an extended operation was performed to complete over 230 cycles with the full size SMA. This testing showed no observable degradation in sorbent performance. A detailed process model, TEA and LCA were developed for a conceptual 100,000 TPY CO 2 removal DAC facility. The LCA results show the net CO 2 e emissions from the DAC system are highly dependent on the electricity source. All other factors, including SMA manufacturing, materials for facility enclosure, etc., are minor cost contributors compared to the energy consumption required for CO 2 removal. With the successful development and validation of the SMA for the sustained performance for CO 2 removal from ambient air with joule heated regeneration in this project, a fully integrated 1 TPY bench-scale DAC system is currently in development with the support of DOE/FECM (DE-FE0032243). The project objective is to demonstrate the engineering design of the DAC system to produce a continuous, high purity CO 2 stream from ambient air. This project will address and validate key engineering features of the DAC system including the gas sealing mechanism and panels, enclosure and air contactor design, and automation sequence to achieve continuous CO 2 production.

42 ENGINEERING↗
DOE OSTI2022

LiNi 0.8 Fe 0.1 Al 0.1 O 2 as a Cobalt-Free Cathode Material with High Capacity and High Capability for Lithium-Ion Batteries

Obtaining cathode materials with high capacity and cycle stability is one of the main challenges regarding the success of electric vehicle technologies. However, most of the widely used materials with these properties involve the use of toxic and expensive cobalt as the active material. To overcome this challenge, this work proposes a novel cobalt-free cathode material, synthesized for the first time using a solid-state reaction, whose general formula is LiNi 0.8 Fe 0.1 Al 0.1 O 2 (NFA). This class of materials offers high capacity and reduces the battery costs by removing cobalt, without jeopardizing the structural stability and safety of the NFAs. The morphology and the structural properties of the obtained NFA cathode material were characterized using different techniques, e.g., scanning electronic microscopy, X-ray diffraction, X-ray fluorescence, and infrared and Raman spectroscopies. The electrochemical activity and diffusivity of the Li-ion during lithium removal and its insertion into the bulk of the NFA cathode demonstrated high-yield specific capacities of ≈180 mAh g –1 at 0.1C, along with a reasonable rate capability and cycling stability, with a capacity retention of ≈99.6% after 100 charge/discharge cycles at a rate of C/2, and whose operando X-ray diffraction experiments have been used to study the crystallographic transitions during the lithiation–delithiation reaction.

25 ENERGY STORAGE↗
NASA NTRS1974

Yield analysis of large capacity magnetic bubble circuits with redundancy design

The fabrication yield of an on-chip modifiable redundant circuit design for a 100M bit serial shift register is evaluated. The yield model is a redundancy design in which there is a primary loop and a set of secondary loops which can be enabled/disabled without introducing blanks to the data stream. This function has a finite yield, the loop-modification yield factor, which must be greater than 0.9 to make the system more economical than the simple nonredundant design. It is further established that small loop capacities greatly degrade the yield because of the effect of the modification yield factor, while large loop capacities degrade the yield because of defects in the operating area. As the modification yield increases the optimum loop capacity decreases. An optimum value for the number of redundant loops exists for each loop capacity. Other factors that affect the yield are the garnet film and the processed circuit.

Bailey, R. F.↗
NASA NTRS1984

Factors Affecting Nickel-oxide Electrode Capacity in Nickel-hydrogen Cells

The nickel-oxide electrode common to the nickel hydrogen and nickel cadmium cell is by design the limiting or capacity determining electrode on both charge and discharge. The useable discharge capacity from this electrode, and since it is the limiting electrode, the useable discharge capacity of the cell as well, can and is optimized by rate of charge, charge temperature and additives to electrode and electrolyte. Recent tests with nickel hydrogen cells and tests performed almost 25 years ago with nickel cadmium cells indicate an improvement of capacity as a result of using increased electrolyte concentration.

Ritterman, P. F.↗
NASA NTRS1984

The capacity of digital links in tandem

The present investigation is concerned with the error control strategy used in connection with digital data networks, taking into account the capacity of the end-to-end channel. It is assumed that the only source of noise is Gaussian and that bandwidth limitation on capacity can be ignored. Attention is given to L links in tandem with binary repeaters, the asymptotic capacity with a large number of links, some alternative repeater strategies, and approaches for lowering the bit error probability. Numerical results are presented, taking into consideration capacity versus link error probability for various numbers of links.

Posner, E. C.↗
NASA NTRS1987

The capacity of the Hopfield associative memory

Techniques from coding theory are applied to study rigorously the capacity of the Hopfield associative memory. Such a memory stores n-tuple of + or - 1s. The components change depending on a hard-limited version of linear functions of all other components. With symmetric connections between components, a stable state is ultimately reached. By building up the connection matrix as a sum-of-outer products of m fundamental memories, it may be possible to recover a certain one of the m memories by using an initial n-tuple probe vector less than a Hamming distance n/2 away from the fundamental memory. If m fundamental memories are chosen at random, the maximum asymptotic value of m in order that most of the m original memories are exactly recoverable is n/(2 log n). With the added restriction that every one of the m fundamental memories be recoverable exactly, m can be no more than n/(4 log n) asymptotically as n approaches infinity. Extensions are also considered, in particular to capacity under quantization of the outer-product connection matrix. This quantized memory-capacity problem is closely related to the capacity of the quantized Gaussian channel.

Mceliece, Robert J.↗
NASA NTRS1988

On the stability, storage capacity, and design of nonlinear continuous neural networks

The stability, capacity, and design of a nonlinear continuous neural network are analyzed. Sufficient conditions for existence and asymptotic stability of the network's equilibria are reduced to a set of piecewise-linear inequality relations that can be solved by a feedforward binary network, or by methods such as Fourier elimination. The stability and capacity of the network is characterized by the post synaptic firing rate function. An N-neuron network with sigmoidal firing function is shown to have up to 3N equilibrium points. This offers a higher capacity than the (0.1-0.2)N obtained in the binary Hopfield network. Moreover, it is shown that by a proper selection of the postsynaptic firing rate function, one can significantly extend the capacity storage of the network.

Guez, Allon↗
NASA NTRS1989

Nickel-hydrogen capacity loss on storage

A controlled experiment evaluating the capacity loss experienced by nickel electrodes stored under various conditions of temperature, hydrogen pressure, and electrolyte concentration was conducted using nickel electrodes from four different manufacturers. It was found that capacity loss varied with respect to hydrogen pressure, and storage temperature as well as with respect to electrode manufacturing processes. Impedance characteristics were monitored and found to be indicative of electrode manufacturing processes and capacity loss. Cell testing to evaluate state-of-charge effects on capacity loss were inconclusive as no loss was sustained by the cells tested in this experiment.

Manzo, Michelle A.↗
NASA NTRS1989

On Gaussian feedback capacity

Pinsker and Ebert (1970) proved that in channels with additive Gaussian noise, feedback at most doubles the capacity. Cover and Pombra (1989) proved that feedback at most adds half a bit per transmission. Following their approach, the author proves that in the limit as signal power approaches either zero (very low SNR) or infinity (very high SNR), feedback does not increase the finite block-length capacity (which for nonstationary Gaussian channels replaces the standard notion of capacity that may not exist). Tighter upper bounds on the capacity are obtained in the process. Specializing these results to stationary channels, the author recovers some of the bounds recently obtained by Ozarow.

Dembo, Amir↗
NASA NTRS1989

Determination of the heat capacities of Lithium/BCX (bromide chloride in thionyl chloride) batteries

Heat capacities of twelve different Lithium/BCX (BrCl in thionyl chloride) batteries in sizes AA, C, D, and DD were determined. Procedures and measurement results are reported. The procedure allowed simple, reproducible, and precise determinations of heat capacities of industrially important Lithium/BCX cells, without interfering with performance of the cells. Use of aluminum standards allowed the accuracy of the measurements to be maintained. The measured heat capacities were within 5 percent of calculated heat capacity values.

Kubow, Stephen A.↗
NASA NTRS1990

Nickel-hydrogen capacity loss on storage

A controlled experiment evaluating the capacity loss experienced by nickel electrodes stored under various conditions of temperature, hydrogen pressure, and electrolyte concentration was conducted using nickel electrodes from four different manufacturers. It was found that capacity loss varied with regard to hydrogen pressure and storage temperature, as well as with regard to electrode manufacturing processes. Impedance characteristics were monitored and found to be indicative of electrode manufacturing processes and capacity loss. Cell testing to evaluate state-of-charge effects on capacity loss were inconclusive as no loss was sustained by the cells tested in this experiment.

Manzo, Michelle A.↗
NASA NTRS1989

Global change and carrying capacity: Implications for life on Earth

Determining the long-term number of people that the planet can support without irreversibly reducing its ability to support people in the future, i.e., the carrying capacity of the Earth, is an exceedingly complex problem. About all that is known for certain is that, with present and foreseeable technologies, the human population has already exceeded the capacity. The reduction in carrying capacity that can be expected to result from direct human impacts on resources and the environment and from our indirect impacts of the climate system is discussed. Global warming and modeling global change and food security are also discussed with respect to carrying capacity.

Ehrlich, Paul R.↗
NASA NTRS1991

Optimal control of systems with capacity: Related noises

In the ordinary theory of optimal control (LQR and Kalman filter), the variances of the actuators and the sensors are assumed to be known (not related to the capacities of the devices). This assumption is not true in practice. Generally, a device with greater capacity to exert actuating forces and a sensor capable of sensing greater sensing range will generate noise of greater power spectral density. When the ordinary theory of optimal control is used to estimate the errors of the outputs in such cases it will lead to faulty results, because the capacities of such devices are unknown before the system is designed. The performance of the system designed by the ordinary theory will not be optimal as the variances of the sensors and the actuators are neither known nor constant. The interaction between the control system and structure could be serious because the ordinary method will lead to greater feedback (Kalman gain) matrices. Methods which can optimize the performance of systems when noises of the actuators and the sensors are related to their capacities are developed. These methods will result in smaller feedback (Kalman gain) matrix.

Ruan, Milfang↗
NASA NTRS1991

Measurement of the cooling capacity of an RMC-Cryosystems Model LTS 4.5-025 closed-cycle helium refrigerator

The cooling capacity of a recently purchased RMC-Cryosystems Model LTS 4.5-025 closed-cycle He refrigerator was measured over the range 4-35 K. It is found that the nominal cooling capacity of 250 mW is only met or exceeded over a narrow temperature range around 4.3 + or - 0.5 K, and that, above this range, there exists a considerable region of much lower cooling capacity, not exceeding about 100 mW. It is believed that this behavior results from use of a fixed-aperture Joule-Thompson expansion valve, and might be alleviated if the J-T valve could be adjusted to compensate for changing flow within the 5-20 K temperature range. Present performance may severely limit or prevent effective use in applications where an irreducible heat inflow exists which is greater than about 100 mW, yet substantially less than the quoted capacity at about 4 K.

De Zafra, R. L.↗
NASA NTRS1992

Bulk thermal capacity determination for Li/BCX and Li/SOClN2 cells

The bulk heat capacities of Li/BCX and Li/SOClN2 cells were determined at 0 and 100 percent depth-of-discharge for 2.0 V cut-off voltage, in the temperature range 0 to 60 C by a method that did not involve the destruction of the cell nor the contact of cell with a liquid. The heat capacities are found to be dependent on state-of-charge, increasing with depth-of-discharge. The Li/BCX DD-cell has a lower heat capacity than a high rate Li/SOCl2 D-cell. The results obtained by this method compare favorably well with results reported in the literature through other methods. The bulk heat capacities of the cells did not change significantly in the temperature range 0 to 60 C.

Kalu, E. E.↗
NASA NTRS1993

Mechanisms for capacity fading in the NiH2 cell and its effects on cycle life

During recent years there have been a number of instances where the capacity of nickel hydrogen battery cells has proven to be unstable during storage. The capacity losses seen after periods of cell or battery storage have typically varied from only a small amount of fading, up to about 30 percent of the total cell capacity. Detailed studies into the root causes for such fading have been carried out in a number of instances. This report provides an overview of the different mechanisms that have been found to be responsible for such capacity fading in nickel hydrogen cells, and summarizes the presently available data on how each responsible mechanism affects ultimate cell cycle life.

Zimmerman, Albert H.↗
NASA NTRS1993

Characteristics of storage related capacity loss in Ni/H2 cells

The changes in the capacity, voltage and pressure profile of flight configuration Ni/H2 cells when they are stored for extended periods is examined. The Ni/H2 cells exhibit capacity fade phenomenon regardless of their design when they are stored at room temperature. Capacity loss also occurs if old cells (5 years old) are stored in a very low rate trickle charge (C/200 rate) condition. A periodic recharge technique leads to pressure rise in the cells. Conventional trickle charge (C/100 rate) helps in minimizing or eliminating the second plateau which is one of the characteristics of the capacity fade phenomenon.

Vaidyanathan, Hari↗
NASA NTRS1991

Robo-line storage: Low latency, high capacity storage systems over geographically distributed networks

Rapid advances in high performance computing are making possible more complete and accurate computer-based modeling of complex physical phenomena, such as weather front interactions, dynamics of chemical reactions, numerical aerodynamic analysis of airframes, and ocean-land-atmosphere interactions. Many of these 'grand challenge' applications are as demanding of the underlying storage system, in terms of their capacity and bandwidth requirements, as they are on the computational power of the processor. A global view of the Earth's ocean chlorophyll and land vegetation requires over 2 terabytes of raw satellite image data. In this paper, we describe our planned research program in high capacity, high bandwidth storage systems. The project has four overall goals. First, we will examine new methods for high capacity storage systems, made possible by low cost, small form factor magnetic and optical tape systems. Second, access to the storage system will be low latency and high bandwidth. To achieve this, we must interleave data transfer at all levels of the storage system, including devices, controllers, servers, and communications links. Latency will be reduced by extensive caching throughout the storage hierarchy. Third, we will provide effective management of a storage hierarchy, extending the techniques already developed for the Log Structured File System. Finally, we will construct a protototype high capacity file server, suitable for use on the National Research and Education Network (NREN). Such research must be a Cornerstone of any coherent program in high performance computing and communications.

Katz, Randy H.↗