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At least 235 records · Page 13

Testing of Composite Fan Vanes With Erosion-Resistant Coating Accelerated

The high-cycle fatigue of composite stator vanes provided an accelerated life-state prior to insertion in a test stand engine. The accelerated testing was performed in the Structural Dynamics Laboratory at the NASA Glenn Research Center under the guidance of Structural Mechanics and Dynamics Branch personnel. Previous research on fixturing and test procedures developed at Glenn determined that engine vibratory conditions could be simulated for polymer matrix composite vanes by using the excitation of a combined slip table and electrodynamic shaker in Glenn's Structural Dynamics Laboratory. Bench-top testing gave researchers the confidence to test the coated vanes in a full-scale engine test.

Bowman, Cheryl L.↗

Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing - Part 2

Evaluation of metals to predict service life of metal-based structures in corrosive environments has long relied on atmospheric exposure test sites. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions similar to those of the corrosive environment. Their reliability to correlate to atmospheric exposure test results is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated corrosion testing has yet to be universally accepted as a useful tool in predicting the long-term service life of a metal, despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard, and their use is crucial, a method that correlates timescales from accelerated testing to atmospheric exposure would be very valuable. This paper presents work that began with the characterization of the atmospheric environment at the Kennedy Space Center (KSC) Beachside Corrosion Test Site. The chemical changes that occur on low carbon steel, during atmospheric and accelerated corrosion conditions, were investigated using surface chemistry analytical methods. The corrosion rates and behaviors of panels subjected to long-term and accelerated corrosion conditions, involving neutral salt fog and alternating seawater spray, were compared to identify possible timescale correlations between accelerated and long-term corrosion performance. The results, as well as preliminary findings on the correlation investigation, are presented.

Montgomery, Eliza L.↗

Reliability study of opto-coupled semiconductor devices and Light Emitting Diodes (LED)

Opto-coupler and light emitting diode (LED) failure mechanisms and associated activation energies were determind from the results of environmental and accelerated lift tests of over 2,400 devices. The evaluation program included LED phototransistor opto-couplers from three sources, LED photoamplifier opto-couplers from a single source, and discrete infrared emitting LEDs from two sources. Environmental tests to evaluate device mechanical integrity included power cycling (10,000 cycles), temperature cycling (500 cycles) and a sequence of monitored shock, monitored vibration and constant acceleration. Multiple temperature operating life tests were conducted at ambient temperatures between 25 C and 200 C. Opto-couplers were operated in both the 'on' and 'off' states during life testing.

Maurer, R. C.↗

Long life nickel electrodes for a nickel-hydrogen cell. III - Results of an accelerated test and failure analyses

Nineteen different designs of nickel electrodes were tested in Ni/H2 boiler plate cells in an accelerated low earth orbit cycle regime to the end of their life. The failure analyses of these cells showed that the major performance changes due to the cycling was a severe reduction of their high rate discharge capability rather than an absolute capacity reduction. Many physical changes of the nickel electrodes were observed after the cycling test. These changes include dimensional expansion, sinter rupture, loose black powdering of the active material, morphology changes, active material migration, increase of pore volume, change of pore distribution, and increase of surface area. All of these were caused by active material expansion with cycling. Among these changes, the morphology change which involves migration of active material away from the current collecting nickel sinter appears to be that most responsible for the reduction of the rate capability.

Lim, H. S.↗

NiCd battery reliability for shuttle serviced spacecraft

Data from life-cycle testing of 22-cell NiCd batteries designed for shuttle-service spacecrafts are analyzed, first by averaging battery cycle lives as a function of temperature and depth of discharge, and then by calculating single cell failure and survival probabilities as a function of temperature, depth of discharge, and number of operating cycles. The single cell data are used to calculate battery survival probabilities. A mathematical failure model which is a function of the quantity of charge through the battery and the temperature is characterized, suggesting a predictive capability for accurate estimation of energy storage subsystem life and performance of accelerated tests. The failure mechanism described is apparently independent of most charge-discharge parameters and common to most cell sizes.

Eliason, J.↗

The Clouds and the Earth's Radiant Energy System Elevation Bearing Assembly Life Test

The Clouds and the Earth's Radiant Energy System (CERES) elevation scan bearings lubricated with Pennzane SHF X2000 and 2% lead naphthenate (PbNp) were life tested for a seven-year equivalent Low Earth Orbit (LEO) operation. The bearing life assembly was tested continuously at an accelerated and normal rate using the scanning patterns developed for the CERES Earth Observing System AM-1 mission. A post-life-test analysis was performed on the collected data, bearing wear, and lubricant behavior.

Brown, Phillip L.↗

Understanding How Kurtosis Is Transferred from Input Acceleration to Stress Response and Its Influence on Fatigue Llife

High cycle fatigue of metals typically occurs through long term exposure to time varying loads which, although modest in amplitude, give rise to microscopic cracks that can ultimately propagate to failure. The fatigue life of a component is primarily dependent on the stress amplitude response at critical failure locations. For most vibration tests, it is common to assume a Gaussian distribution of both the input acceleration and stress response. In real life, however, it is common to experience non-Gaussian acceleration input, and this can cause the response to be non-Gaussian. Examples of non-Gaussian loads include road irregularities such as potholes in the automotive world or turbulent boundary layer pressure fluctuations for the aerospace sector or more generally wind, wave or high amplitude acoustic loads. The paper first reviews some of the methods used to generate non-Gaussian excitation signals with a given power spectral density and kurtosis. The kurtosis of the response is examined once the signal is passed through a linear time invariant system. Finally an algorithm is presented that determines the output kurtosis based upon the input kurtosis, the input power spectral density and the frequency response function of the system. The algorithm is validated using numerical simulations. Direct applications of these results include improved fatigue life estimations and a method to accelerate shaker tests by generating high kurtosis, non-Gaussian drive signals.

Kihm, Frederic↗

Quaternary FeCoNiMn-Based Nanocarbon Electrocatalysts for Bifunctional Oxygen Reduction and Evolution: Promotional Role of Mn Doping in Stabilizing Carbon

The intrinsic instability of carbon largely limits its use for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as a bifunctional catalyst in reversible fuel cells or water electrolyzers. In this paper, we discovered that Mn doping has a promotional role in stabilizing nanocarbon catalysts for the ORR/OER in alkaline media. Stable nanocarbon composites are derived from an inexpensive carbon/nitrogen precursor (i.e., dicyandiamide) and quaternary FeCoNiMn alloy via a template-free carbonization process. In addition to FeCoNiMn metal alloys/oxides, the carbon composites comprise substantial carbon tube forests growing on a thick and dense graphitic substrate. The dense carbon substrate with high degree of graphitization results from Mn doping, while active nitrogen-doped carbon tubes stem from FeCoNi. Catalyst structures and performance are greatly dependent on the doping content of Mn. Various accelerated stress tests (AST) and life tests verify the encouraging ORR/OER stability of the nanocarbon composite catalyst with optimal Mn doping. Extensive characterization before and after ASTs elucidates the mechanism of stability enhancement resulting from Mn doping, which is attributed to (i) hybrid carbon nanostructures with enhanced resistance to oxidation and (ii) the in situ formation of the β-MnO 2 and FeCoNi-based oxides capable of preventing carbon corrosion and promoting activity. Note that the improvement in stability due to Mn doping is accompanied by a slight activity loss due to a decrease in surface area. Finally, this work provides a strategy to stabilize carbon catalysts by appropriately integrating transition metals and engineering carbon structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Accelerated Creep Testing of Inconel 718 Using the Stepped Isostress Method (SSM)

This paper demonstrates the stepped isostress method (SSM); an accelerated creep test (ACT) for the rapid assessment of metallic materials. The SSM test is based on the time-temperature-stress superposition principle (TTSSP) where temperature and/or stress are step increased to accelerate the time-to-rupture. The SSM test has proven successful for the ACT of polymers and polymeric composites but has yet to be proven for metallic materials. In this study, new test matrix design rules for the SSM of metals are established based on deformation mechanism, time-temperature transformation, and time-temperature precipitation maps. A test matrix of SSM and conventional creep tests (CCTs) are executed for alloy Inconel 718 at 750°C (1382°F) with stress levels ranging from 100 to 350 MPa. Validation CCT data is gathered from the Japan National Institute of Material Science (NIMS). Material constants for the Sine-hyperbolic (Sinh) constitutive model are calibrated using the SSM data and employed to predict the conventional creep response. Here, when blindly compared to the CCT data, the SSM calibrated Sinh model can accurately predict the conventional creep response across logarithmic decades and thus accelerate the capture of conventional creep data. Fractography indicates ductile fracture by transgranular microvoid coalescence (TMVC) with the same fracture mode observed in both SSM and CCT specimens. Creep cavitation is indicated by the population, smoothness, and size of microvoids.

36 MATERIALS SCIENCE↗

Efficient Reversible Operation and Stability of Novel Solid Oxide Cells

This project aims to develop and test novel Reversible Solid Oxide Cells (ReSOCs) specifically designed to yield low area specific resistance, as required to achieve high round trip efficiency in reversible operation at high current density. A key objective is to improve long-term reversible SOC durability; mechanistic degradation models will be used to predict long-term durability using input data from accelerated testing that combines electrochemical life testing with quantitative microstructural and chemical evaluation. The modeling tasks seek to design low-loss, low-cost ReSOC systems using input data from the experimental cell studies. A key challenge is to develop a thermal management strategy that maintains thermally self-sustaining operation while operating the stack at a potential lower than the thermo-neutral steam electrolysis voltage of ~1.3 V, to maintain high efficiency.

08 HYDROGEN↗

Long Life Technology Work at Rockwell International Space Division

This paper presents highlights of long-life technology oriented work performed at the Space Division of Rockwell International Corporation under contract to NASA. This effort included evaluation of Saturn V launch vehicle mechanical and electromechanical components for potential extended life capabilities, endurance tests, and accelerated aging experiments. A major aspect was evaluation of the components at the subassembly level (i.e., at the interface between moving surfaces) through in-depth wear analyses and assessments. Although some of this work is still in progress, preliminary conclusions are drawn and presented, together with the rationale for each. The paper concludes with a summary of the effort still remaining.

D K Huzel↗

Corrosion of metal particle and metal evaporated tapes

Very high coercivity metal particle (MP) and metal evaporated (ME) tapes are being used in 8mm video and digital audio tape applications, and more recently in digital data recording applications. In view of the inherent susceptibility of such media to environmental corrosion, a number of recent studies have addressed their long term stability and archivability. These studies have used an accelerated corrosion test based either on elevated temperature-humidity or polluting gas atmospheres known as Battelle tests. A comparison of the Battelle test results performed at different laboratories reveals a large variation from one location to another, presumably due to incorrect replication of the Battelle condition. Furthermore, when the Battelle tests are performed on enclosed cartridges, it is quite possible that diffusion limits the penetration of the extremely low concentration polluting gaseous species to the inner layers of the tapes during the short time of the accelerated test, whereas in real life these diffusion limitations may not apply. To avoid this uncertainty, the corrosion behavior of commercial 8mm MP and ME tapes when cassettes without their external plastic cases were exposed to 50 deg C and 80 percent RH for 7.5 weeks is investigated.

Speliotis, Dennis E.↗

Nondestructive Characterization and Accelerated UV Testing of Browned Field-Aged PV Modules

Encapsulant browning is one of the most common degradation modes found in crystalline silicon field-aged photovoltaic modules. Browning, usually undetected unless severe, reduces the short-circuit current (Isc) produced by a module. Therefore, field-aged browned modules have been subjected to accelerated UV testing to obtain true end-of-life activation energy for the encapsulant browning mechanism. A novel time- and resource-saving accelerated UV exposure testing method simultaneously allowing multiple module temperatures to be maintained in a single chamber run is presented. Six field-aged crystalline silicon modules of glass/backsheet construction (three each from BP Solar/Solarex MSX 60 and Siemens M55) with similar glass and encapsulant formulation were exposed to a UV dosage of 450 kWh/m2 . Through passive heating, the average module temperatures for the BP Solar/Solarex modules were 60 degrees C, 77 degrees C, and 85 degrees C and those of Siemens M55 were 75 degrees C, 80 degrees C, and 837 degrees C. To study UV browning, the modules were intermittently characterized through visual imaging, UV fluorescence imaging, electroluminescence imaging, quantum efficiency measurements, module, and cell-level light I-V measurements. An Isc decrease corroborated the increased extent of browning with increased module temperature. For the BP Solar/Solarex modules, the Low T, Mid T, and the High T modules showed a 1.37%, 2.48%, and 3.26% Isc drop, respectively. The Siemens modules showed a 4.11%, 5.65%, and 6.95% Isc drop. The multiple cell-level Isc data points obtained for each module temperature increased provided statistical significance. Activation energy for encapsulant browning was calculated as 0.44 and 0.72 eV for MSX 60 and M55 modules, respectively.

14 SOLAR ENERGY↗

Lifetimes of fiber composites under sustained tensile loading

Results are presented for a study intended to summarize lifetime data on several fiber/epoxy composite materials subjected to sustained uniaxial tensile loading, to report preliminary results of an accelerated test method for predicting the life of simple composites, and to describe related work in progress on pressure vessels and other filament-wound structures. The lifetime performance of the tested composites was compared by plotting the percent of ultimate strength (applied fiber stress normalized with respect to fiber failure stress in a composite) versus lifetime. In terms of performance in long-term tensile applications, the tested composites are ranked in the following order: graphite/epoxy, Be wire/epoxy, Aramid/epoxy, and S-glass/epoxy. The accelerated test using temperature and stress to simulate the passage of time proves to be encouraging, at least in the case of the Aramid/epoxy composite. The potential of a statistical analysis based on Weibull distribution analyses or a power law relationship is demonstrated.

Chiao, T. T.↗

Solid Propulsion Systems, Subsystems, and Components Service Life Extension

The service life extension of solid propulsion systems, subsystems, and components will be discussed based on the service life extension of the Space Transportation System Reusable Solid Rocket Motor (RSRM) and Booster Separation Motors (BSM). The RSRM is certified for an age life of five years. In the aftermath of the Columbia accident there were a number of motors that were approaching the end of their five year service life certification. The RSRM Project initiated an assessment to determine if the service life of these motors could be extended. With the advent of the Constellation Program, a flight test was proposed that would utilize one of the RSRMs which had been returned from the launch site due to the expiration of its five year service life certification and twelve surplus Chemical Systems Division BSMs which had exceeded their eight year service life. The RSRM age life tracking philosophy which establishes when the clock starts for age life tracking will be described. The role of the following activities in service life extension will be discussed: subscale testing, accelerated aging, dissecting full scale aged hardware, static testing full scale aged motors, data mining industry data, and using the fleet leader approach. The service life certification and extension of the BSMs will also be presented.

Hundley, Nedra H.↗

Experimental Considerations for Estimating Degradation in PV Modules

Carefully controlled laboratory experiments and measurements can enable the determination of acceleration factors suitable for extrapolation to durability and performance of a fielded PV module. Ideally, a single mechanism can be identified with appropriate acceleration factors for extrapolation to the field. However, even with a single mechanism, the inherent uncertainty in these factors leads to uncertainty in the extrapolation which is greater the higher the acceleration factor. This course will explain how because of the wide range of acceleration factors for a given degradation mode, utilizing acceleration factors greater than about 10x will typically lead to unacceptable uncertainty in the results. Therefore, if even just a rank ordering of materials is desired, acceleration factors must be minimized which requires a good general understanding of the scale of the different acceleration factors for the degradation mode of interest. In this tutorial we will discuss what the different purposes are for many of the accelerated stress tests used today. E.g., what is a qualification test, a highly accelerated stress test, a rank ordering test, or a service life prediction test. We will discuss how one can understand the relationship between test results and expected field performance. A single accelerated stress test condition cannot duplicate outdoor exposure for all possible degradation pathways; therefore, one must use targeted evaluation of material properties at different stress levels to determine the relevant acceleration factors and fit it to a model. We will also discuss how to interpret the results of experiments understanding what is relevant/not relevant, or not e valuated in a test. There are many common error people make in their test interpretations because they push the stress levels to be too harsh. This creates biases and can mask the relevant failure modes and mechanisms or will erroneously lead one to over design materials against things that aren't relevant. Several case studies will be presented to illustrate appropriate interpretation of accelerated stress testing results.

degradation↗

Magnetic Shielding of the Acceleration Channel Walls in a Long-Life Hall Thruster

In a Qualification Life Test (QLT) of the BPT-4000 Hall thruster that recently accumulated greater than 10,000 h it was found that the erosion of the acceleration channel practically stopped after approximately 5,600 h. Numerical simulations of this thruster using a 2-D axisymmetric, magnetic field-aligned-mesh (MFAM) plasma solver reveal that the process that led to this significant reduction of the erosion was multifaceted. It is found that when the channel receded from its early-in-life geometry to its steady-state configuration several changes in the near-wall plasma and sheath were induced by the magnetic field that, collectively, constituted an effective shielding of the walls from any significant ion bombardment. Because all such changes in the behavior of the ionized gas near the eroding surfaces were caused by the topology of the magnetic field there, we term this process "magnetic shielding."

life modeling↗