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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Characteristics of advanced hydrogen maser frequency standards

Measurements with several operational atomic hydrogen maser standards have been made which illustrate the fundamental characteristics of the maser as well as the analysability of the corrections which are made to relate the oscillation frequency to the free, unperturbed, hydrogen standard transition frequency. Sources of the most important perturbations, and the magnitude of the associated errors, are discussed. A variable volume storage bulb hydrogen maser is also illustrated which can provide on the order of 2 parts in 10 to the 14th power or better accuracy in evaluating the wall shift. Since the other basic error sources combined contribute no more than approximately 1 part in 10 to the 14th power uncertainty, the variable volume storage bulb hydrogen maser will have net intrinsic accuracy capability of the order of 2 parts in 10 to the 14th power or better. This is an order of magnitude less error than anticipated with cesium standards and is comparable to the basic limit expected for a free atom hydrogen beam resonance standard.

Peters, H. E.↗
NASA NTRS1976

Ultraviolet absorption experiment MA-059

The ultraviolet absorption experiment performed during the Apollo Soyuz mission involved sending a beam of atomic oxygen and atomic nitrogen resonance radiation, strong unabsorbable oxygen and nitrogen radiation, and visual radiation, all filling the same 3 deg-wide field of view from the Apollo to the Soyuz. The radiation struck a retroreflector array on the Soyuz and was returned to a spectrometer onboard the Apollo. The density of atomic oxygen and atomic nitrogen between the two spacecraft was measured by observing the amount of resonance radiation absorbed when the line joining Apollo and Soyuz was perpendicular to their velocity with respect to the ambient atmosphere. Information concerning oxygen densities was also obtained by observation of resonantly fluorescent light. The absorption experiments for atomic oxygen and atomic nitrogen were successfully performed at a range of 500 meters, and abundant resonance fluorescence data were obtained.

Donahue, T. M.↗
NASA NTRS1985

The production of glow precursors by oxidative erosion of spacecraft surfaces

Erosion rates of organic materials are measured during a recent flight of the shuttle (STS-8). Several forms of carbon and a variety of thermosetting and thermoplastic polymers are exposed to the ram beam of atomic oxygen. Arrhenius energies of about 1000 to 2000 cal/mole were measured from the rate dependencies on temperature. If some simple assumptions are made about the chemical nature of the desorbed species, the data can be used to estimate production rates at surfaces in orbit under different conditions of temperature, oxygen atom flux, and material surface conditions.

Gregory, J. C.↗
NASA NTRS1987

Electron stimulated desorption of atomic oxygen from silver

The electron stimulated desorption (ESD) of neutral oxygen atoms from polycrystalline silver and of oxygen ions from Ag(110) has been studied. Polycrystalline Ag charged with (16)O2 and (18)O2 and bombarded by low-energy electrons (approx 100 eV) under ultrahigh vacuum (UHV) conditions emitted O atom flux levels of 1 x 10 to the 12th power/sq cm/s at a Ag temperature of 300 C. The flux was detected with a quadrupole mass spectrometer operating in the appearance potential mode. The neutral cross section at about 100 C was determined to be 7 x 10 to the -19 sq cm. Ancillary experiments conducted in a UHV chamber equipped with a cylindrical mirror analyzer and rigged for ion energy distribution and ion angular distribution were used to study O ions desorbed from Ag(110). Two primary O(+) energies of 2.4 and 5.4 eV were detected from the Ag(110) after having been dosed with 2500 L of (16)O2. It also appears that in both experiments there was strong evidence for directionality of the emitted flux. The results of this study serve as a proof of concept for the development of a laboratory atomic oxygen beam generator that simulates the gas flux environment experienced by orbiting vehicles.

Outlaw, R. A.↗
NASA NTRS1987

Dynamics of atom-surface interactions

Scattering techniques currently being used to examine the dynamics and energetics of gas-surface energy exchange processes and gas-surface reaction mechanisms are reviewed. In particular, recent inelastic scattering measurements are highlighted which are revealing the microscopic basis for collision-induced gas-surface energy exchange, e.g., which surface vibrational modes actively participate in translational energy accommodation. Reactive scattering and laser desorptive experiments which examine energy disposal in volatile products are also discussed. Finally, an efficient atomic oxygen beam source is described which is suitable for terrestrial studies of gas-surface interactions.

Sibener, Steven J.↗
NASA NTRS1990

The effect of atomic oxygen on altered and coated Kapton surfaces for spacecraft applications in low earth orbit

A commercially applied silicon oxide coating on Kapton and an alternative material with Si groups on the surface were evaluated for durability with respect to atomic oxygen in both a random plasma and a directed atomic oxygen beam system. It is found that the alternative to Kapton, DuPont 93-1, is not adequately protecting to last 15 years in LEO, the desired operation time of the Space Station Freedom. The coated Kapton is considered to be promising due to the adherence of the coating and lack of extensive tearing at undercut defect sites. Fewer defects in the coating and elimination of long scratches and uncoated areas would substantially improve the durability of this material.

Rutledge, Sharon K.↗
NASA NTRS1990

High emittance surfaces for high temperature space radiator applications

Surface modification techniques are evaluated for emittance enhancement of radiator surfaces. These techniques include acid etching, heat treating, abrasion, sputter texturing, electrochemical texturing, arc texturing, and atomic oxygen beam texturing. Candidate radiator surface materials under consideration include Nb-1 pct Zr, Cu, Ti, Ti-6 pct Al-4 pct V, 304 stainless steel, Al6061-T6, Mo, W, and Ta.

Banks, Bruce A.↗
NASA NTRS1993

Atomic research

Work performed by the University of Alabama in Huntsville's (UAH) Center for Applied Optics (CAO) entitled Atomic Research is documented. Atomic oxygen (AO) effects on materials have long been a critical concern in designing spacecraft to withstand exposure to the Low Earth Orbit (LEO) environment. The objective of this research effort was to provide technical expertise in the design of instrumentation and experimental techniques for analyzing materials exposed to atomic oxygen in accelerated testing at NASA/MSFC. Such testing was required to answer fundamental questions concerning Space Station Freedom (SSF) candidate materials and materials exposed to atomic oxygen aboard the Long-Duration Exposure Facility (LDEF). The primary UAH task was to provide technical design, review, and analysis to MSFC in the development of a state-of-the-art 5eV atomic oxygen beam facility required to simulate the RAM-induced low earth orbit (LEO) AO environment. This development was to be accomplished primarily at NASA/MSFC. In support of this task, contamination effects and ultraviolet (UV) simulation testing was also to be carried out using NASA/MSFC facilities. Any materials analysis of LDEF samples was to be accomplished at UAH.

Hadaway, James B.↗
NASA NTRS1995

Effects of Surface Treatments on Secondary Electron Emission from CVD Diamond Films

Secondary electron emission (SEE) properties of polycrystalline diamond films grown by chemical vapor deposition (CVD) were measured. The total secondary yield (sigma) from as-grown samples was observed to be as high as 20 at room temperature and 48 while heating at 700 K in vacuum. Electron-beam-activated, alkali-terminated diamond films have shown stable values of sigma as high as 60 when coated with CsI and similarly high values when coated with other alkali halides. Diamond coated with BaF2 had a stable sigma of 6, but no enhancement of the SEE properties was observed with coatings of Ti or Au. Hydrogen was identified to give rise to this effect in as-grown films. However, electron beam exposure led to a reduction in sigma values as low as 2. Exposure to a molecular hydrogen environment restored sigma to its original value after degradation, and enabled stable secondary emission during electron beam exposure. Atomic hydrogen and hydrogen plasma treatments were performed on diamond/Mo samples in an attempt to increase the near-surface hydrogen concentration which might lead to increased stability in the secondary emission. Raman scattering analysis, scanning electron microscopy, and Auger electron spectroscopy (AES) confirmed that hydrogen plasma and atomic hydrogen treatments improved the quality of the CVD diamond significantly. Elastic recoil detection (ERD) showed that heating as-grown diamond targets to 7OO K, which was correlated with an increase in sigma, removed contaminants from the surface but did not drive hydrogen from the diamond bulk. ERD showed that the hydrogen plasma treatment produced an increase in the hydrogen concentration in the near-surface region which did not decrease while heating in vacuum at 700 K, but no improvement in the SEE properties was observed.

Mearini, G. T.↗
NASA NTRS1998

Monte Carlo Computational Modeling of the Energy Dependence of Atomic Oxygen Undercutting of Protected Polymers

A Monte Carlo computational model has been developed which simulates atomic oxygen attack of protected polymers at defect sites in the protective coatings. The parameters defining how atomic oxygen interacts with polymers and protective coatings as well as the scattering processes which occur have been optimized to replicate experimental results observed from protected polyimide Kapton on the Long Duration Exposure Facility (LDEF) mission. Computational prediction of atomic oxygen undercutting at defect sites in protective coatings for various arrival energies was investigated. The atomic oxygen undercutting energy dependence predictions enable one to predict mass loss that would occur in low Earth orbit, based on lower energy ground laboratory atomic oxygen beam systems. Results of computational model prediction of undercut cavity size as a function of energy and defect size will be presented to provide insight into expected in-space mass loss of protected polymers with protective coating defects based on lower energy ground laboratory testing.

Banks, Bruce A.↗
NASA NTRS2000

Modeling and Observations of Phase-Mask Trapezoidal Profiles with Grating-Fiber Image Reproduction

We report on an investigation of the trapezoidal design and fabrication defects in phase masks used to produce Bragg reflection gratings in optical fibers. We used a direct visualization technique to examine the nonuniformity of the interference patterns generated by several phase masks. Fringe patterns from the phase masks are compared with the analogous patterns resulting from two-beam interference. Atomic force microscope imaging of the actual phase gratings that give rise to anomalous fringe patterns is used to determine input parameters for a general theoretical model. Phase masks with pitches of 0.566 and 1.059 microns are modeled and investigated.

Lyons, Donald R.↗