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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Electrolytic Etching of Germanium Substrates with Hydrogen Peroxide

Anodic electrolytic etching of germanium has been performed in hydrogen peroxide etchants with controlled external conditions. In-situ current and ex-situ etch-depths were measured and tracked with respect to etchant composition and stir rates. Gas bubbles formed during the etching process were found to cause non-uniformity in etch-current and surface quality. The effects were minimized in specific composition spaces. Quantitative analysis revealed a linear correlation of the number of electrons transferred during germanium oxidation with the number of surface atoms removed. Experimental results of 2.77 electrons/atom deviate significantly from 4 electrons/atom previously reported for silicon. The conclusion is that etching mechanisms for germanium are sufficiently different from those for silicon which invalidates the direct transfer of processing techniques between the two materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Variation in Heat Transfer During Transient Heating of a Hemisphere at a Mach Number of 2

Convective heat-transfer tests were made on a 5-inch-diameter hemisphere to determine the variation of Stanton number with the ratio of wall temperature to total temperature. The tests were made at a nominal Mach number of 2 for stagnation temperatures of 760 deg R, 1,030 deg R, and 1,380 deg R. The model was constructed so that radiation effects and also streamwise conduction effects within the model skin were minimized. The results of the tests verified that these effects were small. Tests which were made with different masses of air inside the model to check for conduction effects to the internal air cavity showed these effects to be negligible. For laminar flow on the hemisphere, the Stanton number remained essentially constant as the ratio of wall temperature to total temperature increased. However, for fully established turbulent flow, the Stanton number at some stations decreased on the order of 50 percent as the ratio of wall temperature to total temperature increased. A theory which agreed fairly well with the trend of this decrease is shown for comparison.

English, Roland D.↗

Ion transport in composites of binary electrolyte and single ion conductor—A chronoamperometry study

Composite electrolytes for lithium batteries typically combine materials with very different mechanical properties and ionic transport mechanisms and the degree to which these two phases affect each other is not well understood. In this work we used numerical simulations and experiments to investigate the transport in composite electrolytes consisting of polyethylene oxide (PEO) with Lithium bis-triuoromethanesulfonimide (LiTFSI) and Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) lithium ion conducting glass-ceramic particles. In particular we are interested in how the introduction of a single ion conductor (SIC) changes the salt concentration gradients in the polymer electrolyte (PE) under applied potential. To study this, we performed numerical simulations and chronoamperometry experiments in electrolytes with different arrangements of the SIC and PE phases, i.e. layers and particulate composites. The results show that the particulate composites have the highest concentration gradients and take the longest time to reach steady state current. Furthermore, the high concentration gradient can be exacerbated by a high SIC/PE interfacial resistance. Finally, the best arrangement appears to have a layer of SIC impenetrable to anions in the polymer phase within the electrolyte membrane.

25 ENERGY STORAGE↗

Reduced-Order Modeling Method for Phase-Change Thermal Energy Storage Heat Exchangers

Thermal energy storage can facilitate the effective utilization of renewable energy. To speed up the design process of thermal energy storage devices, it is critical to develop fast and accurate modeling methods for phase change material embedded heat exchangers (PCM HXs). This study developed and compared two approximation-assisted reduced-order PCM HX models for the simulation of thermal storage components and systems, which were verified against a validated finite-volume model. They are a pure black-box model, and a grey-box model based on the Number of Transfer Units (or effectiveness-NTU) approach. We used the reduced-order models to predict the performance of standalone PCM HX for 1000 cases with different fluid inlet conditions and HX designs. We also integrated the models with a vapor compression system to predict the compressor energy consumption and total charging time under various conditions. The results show that overall, the black-box model gave more accurate results than the grey-box model. On average, the mean absolute deviation in the PCM HX fluid outlet temperature was 0.05 K and 0.1 K for the black-box model and grey-box model, respectively. The grey-box model gave larger temperature deviation toward the end of the phase change process, due to the simplified two-node PCM representation. On the system level, the mean absolute deviation in compressor energy consumption was 0.2% and 0.3% for the black-box model and grey-box model, respectively. Their mean absolute deviation in total charging time was 1.1% and 2.6%, respectively. In terms of computation efficiency, the system simulation speedup ratio gained by using the reduced-order models was 11 to 57. System simulation time was decreased from an average of 1465 s to an average of 59 s. This shows that the proposed reduced-order modeling methods can be used to predict system performance of PCM HXs with less than 3% accuracy penalty, and 25 times less computational time than finite-volume models, enabling faster design and evaluation of PCM thermal storage devices.

25 ENERGY STORAGE↗

Viewing convection as a solar farm phenomenon broadens modern power predictions for solar photovoltaics

We report heat mitigation for large-scale solar photovoltaic (PV) arrays is crucial to extend lifetime and energy harvesting capacity. PV module temperature is dependent on site-specific farm geometry, yet common predictions consider panel-scale and environmental factors only. Here, we characterize convective cooling in diverse PV array designs, capturing combined effects of spatial and atmospheric variation on panel temperature and production. Parameters, including row spacing, panel inclination, module height, and wind velocity, are explored through wind tunnel experiments, high-resolution numerical simulations, and operating field data. A length scale based on fractal lacunarity encapsulates all aspects of arrangement (angle, height, etc.) in a single value. When applied to the Reynolds number Re within the canonical Nusselt number heat transfer correlation, lacunarity reveals a relationship between convection and farm-specific geometry. This correlation can be applied to existing and forthcoming array designs to optimize convective cooling, ultimately increasing production and PV cell life.

14 SOLAR ENERGY↗

General Applications for Hamilton Vantage (GenApps for Vantage) v0.6.1

General applications for Hamilton Vantage is a flexible liquid handling method used to automate the most widely applicable types of automated liquid transfers. General applications can also be used as a tool to onboard new fully-automated workflows by breaking them down step by step into single transfers. The goal of General Applications is to make using the Hamilton Vantage liquid handler as easy & practical as using a handheld pipette for the end user. The software supports plate-to-plate transfers for a variety of method types including: Stamp: One-to-One, Stamp: One-To-Many, Split, Combine, Hitpick, and Qtray plating. General Applications eliminates the need for automation engineers to customize individual methods for each new workflow that gets onboarded. Steps can be customized within GenApps according to the needs of the researcher. The software utilizes a GUI to prompt the users to input variables – Allowing for flexible control over plate types, transfer volumes, number of replicates, tip types, liquid classes, mixing steps, aspiration/dispense heights and more. General Applications also generates a deck image and setup instructions to guide the researcher on how to load the deck and start the instrument.

Yoder, Sam↗

Parametric study of relaminarization of turbulent boundary layers on nozzle walls

By means of comparisons between theoretical predictions and experimental data, the accuracy of a boundary procedure to predict the effect of large streamwise accelerations upon initially turbulent boundary layers is assessed. The boundary layer procedure is based upon simultaneous solution of the boundary layer partial differential equations and the integral turbulence kinetic energy equation. The results of the present investigation show the ability of the procedure to accurately predict properties of boundary layers subjected to large streamwise accelerations. The procedure is used to conduct a parametric study of the effect of free stream turbulence, heat transfer, Reynolds number, acceleration, and Mach number on boundary layers in supersonic nozzles to assist in the design of a quiet tunnel. Results of the investigation show that, even in the presence of moderate free-stream turbulence levels, the boundary layer in the approach section of the quiet tunnel nozzle relaminarizes and becomes thin enough to be removed by a small slot in the nozzle wall. Furthermore, the calculations indicate that it should be possible to maintain a laminar boundary layer for the entire length of the supersonic portion of the quiet tunnel nozzle.

Kreskovsky, J. P.↗

Optimal solar sail spiral to escape

A solar sail is being considered for various solar system missions, such as a comet rendezvous and a planetary sample return. Such missions might include a planetocentric escape or capture trajectory segment. This paper considers a method for calculating time optimal planetocentric solar sail spiral trajectories to near escape and orbit to orbit transfers. A number of examples illustrate trajectories generated with a computer program, SUNSPOT, based on this analysis.

Sackett, L. L.↗

Oscillatory flow with heat transfer in a square cavity

A computational study is presented for the flow inside an oscillatory cavity. The numerical scheme employs a semi-implicit, time-splitting method to integrate the two-dimensional full Navier-Stokes equations satisfying continuity to machine accuracy. The efficient use of direct solvers for the uncoupled momentum and pressure equations is demonstrated. The oscillatory cavity flow is studied considering the effects of heat transfer, Reynolds number, and oscillatory Stokes number.

Biringen, S.↗

Oscillatory flow with heat transfer in a square cavity

A computational study is presented for the flow inside an oscillatory cavity. The numerical scheme employs a semiimplicit, time-splitting method to integrate the two-dimensional full Navier-Stokes equations satisfying continuity to machine accuracy. The efficient use of direct solvers for the uncoupled momentum and pressure equations is demonstrated. The oscillatory cavity flow is studied considering the effects of heat transfer, Reynolds number and oscillatory Stokes number.

Danabasoglu, G.↗

Overcoming obstacles to IPv6 on WLCG

The transition of the Worldwide Large Hadron Collider Computing Grid (WLCG) storage services to dual-stack IPv6/IPv4 is almost complete; all Tier-1 and 94% of Tier-2 storage are IPv6 enabled. While most data transfers now use IPv6, a significant number of IPv4 transfers still occur even when both endpoints support IPv6. This paper presents the ongoing efforts of the HEPiX IPv6 working group to steer WLCG toward IPv6-only services by investigating and fixing the obstacles to the use of IPv6 and identifying cases where IPv4 is used when IPv6 is available. Removing IPv4 use is essential for the long-term agreed goal of IPv6-only access to resources within WLCG, thus eliminating the complexity and security concerns associated with dual-stack services. We present our achievements and ongoing challenges as we navigate the final stages of the transition from IPv4 to IPv6 within WLCG.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗