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At least 217 records · Page 12

Ozone and aerosol distributions over the Amazon Basin during the wet season

Results are presented of O3 and aerosol measurements made in the lower troposphere from April 13 through May 10, 1987, as part of the wet season field experiment. Aircraft flights on the NASA Electra were conducted in the vicinity of Manaus, Brazil and between Manaus and the mouth of the Amazon River. Airborne O3 measurements were made in situ and with a lidar system pointed below the aircraft in nadir mode of operation. Data collection and results concerning the distributions of O3 and aerosols observed during the wet season from within the mixed layer to the middle troposphere over the central Amazon basin and between Manaus and Belem are discussed, and these observations are compared to the measurements obtained in the 1985 dry season. Ozone mixing ratio values are found to be lower than those of the 1985 dry season by 6-8 ppbv, indicating a strong removal process near the surface during wet season. It is also found that within the mixed layer O3 levels appeared to be lower over the forest compared to over the ocean.

Browell, Edward V.↗

Impact of Soil Moisture Assimilation on Land Surface Model Spin-Up and Coupled LandAtmosphere Prediction

Advances in satellite monitoring of the terrestrial water cycle have led to a concerted effort to assimilate soil moisture observations from various platforms into offline land surface models (LSMs). One principal but still open question is that of the ability of land data assimilation (LDA) to improve LSM initial conditions for coupled short-term weather prediction. In this study, the impact of assimilating Advanced Microwave Scanning Radiometer for EOS (AMSR-E) soil moisture retrievals on coupled WRF Model forecasts is examined during the summers of dry (2006) and wet (2007) surface conditions in the southern Great Plains. LDA is carried out using NASAs Land Information System (LIS) and the Noah LSM through an ensemble Kalman filter (EnKF) approach. The impacts of LDA on the 1) soil moisture and soil temperature initial conditions for WRF, 2) land-atmosphere coupling characteristics, and 3) ambient weather of the coupled LIS-WRF simulations are then assessed. Results show that impacts of soil moisture LDA during the spin-up can significantly modify LSM states and fluxes, depending on regime and season. Results also indicate that the use of seasonal cumulative distribution functions (CDFs) is more advantageous compared to the traditional annual CDF bias correction strategies. LDA performs consistently regardless of atmospheric forcing applied, with greater improvements seen when using coarser, global forcing products. Downstream impacts on coupled simulations vary according to the strength of the LDA impact at the initialization, where significant modifications to the soil moisture flux- PBL-ambient weather process chain are observed. Overall, this study demonstrates potential for future, higher-resolution soil moisture assimilation applications in weather and climate research.

soil moisture↗

Technical Report Series on Global Modeling and Data Assimilation: A Comparison of GEOS Assimilated Data with FIFE Observations - Volume 14

First ISLSCP Field Experiment (FIFE) observations have been used to validate the near-surface proper- ties of various versions of the Goddard Earth Observing System (GEOS) Data Assimilation System. The site- averaged FIFE data set extends from May 1987 through November 1989, allowing the investigation of several time scales, including the annual cycle, daily means and diurnal cycles. Furthermore, the development of the daytime convective planetary boundary layer is presented for several days. Monthly variations of the surface energy budget during the summer of 1988 demonstrate the affect of the prescribed surface soil wetness boundary conditions. GEOS data comes from the first frozen version of the assimilation system (GEOS-1 DAS) and two experimental versions of GEOS (v. 2.0 and 2.1) with substantially greater vertical resolution and other changes that influence the boundary layer. This report provides a baseline for future versions of the GEOS data assimilation system that will incorporate a state-of-the-art land surface parameterization. Several suggestions are proposed to improve the generality of future comparisons. These include the use of more diverse field experiment observations and an estimate of gridpoint heterogeneity from the new land surface parameterization.

Bosilovich, Michael G.↗

Groundwater and Terrestrial Water Storage

Most people think of groundwater as a resource, but it is also a useful indicator of climate variability and human impacts on the environment. Groundwater storage varies slowly relative to other non-frozen components of the water cycle, encapsulating long period variations and trends in surface meteorology. On seasonal to interannual timescales, groundwater is as dynamic as soil moisture, and it has been shown that groundwater storage changes have contributed to sea level variations. Groundwater monitoring well measurements are too sporadic and poorly assembled outside of the United States and a few other nations to permit direct global assessment of groundwater variability. However, observational estimates of terrestrial water storage (TWS) variations from the GRACE satellites largely represent groundwater storage variations on an interannual basis, save for high latitude/altitude (dominated by snow and ice) and wet tropical (surface water) regions. A figure maps changes in mean annual TWS from 2009 to 2010, based on GRACE, reflecting hydroclimatic conditions in 2010. Severe droughts impacted Russia and the Amazon, and drier than normal weather also affected the Indochinese peninsula, parts of central and southern Africa, and western Australia. Groundwater depletion continued in northern India, while heavy rains in California helped to replenish aquifers that have been depleted by drought and withdrawals for irrigation, though they are still below normal levels. Droughts in northern Argentina and western China similarly abated. Wet weather raised aquifer levels broadly across western Europe. Rains in eastern Australia caused flooding to the north and helped to mitigate a decade long drought in the south. Significant reductions in TWS seen in the coast of Alaska and the Patagonian Andes represent ongoing glacier melt, not groundwater depletion. Figures plot time series of zonal mean and global GRACE derived non-seasonal TWS anomalies (deviation from the mean of each month of the year) excluding Greenland and Antarctica. The two figures show that 2010 was the driest year since 2003. The drought in the Amazon was largely responsible, but an excess of water in 2009 seems to have buffered that drought to some extent. The drying trend in the 25-55 deg S zone is a combination of Patagonian glacier melt and drought in parts of Australia.

Rodell, Matthew↗

Ultrasonic techniques for aircraft ice accretion measurement

Results of tests to measure ice growth in natural (flight) and artificial (icing wind tunnel) icing conditions are presented. Ice thickness is measured using an ultrasonic pulse-echo technique. Two icing regimes, wet and dry ice growth, are identified and the unique ultrasonic signal characteristics associated with these different types of ice growth are described. Ultrasonic measurements of ice growth on cylinders and airfoils exposed to artificial and natural icing conditions are presented. An accuracy of plus or minus 0.5 mm is achieved for ice thickness measurement using the pulse-echo technique. The performance of two-probe type ice detectors is compared to the surface mounted ultrasonic system. The ultrasonically measured ice accretion rates and ice surface condition (wet or dry) are used to compare the heat transfer characteristics for flight and icing wind tunnel environments. In general the heat transfer coefficient is inferred to be higher in the wind tunnel environment, not likely due to higher freestream turbulence levels. Finally, preliminary results of tests to measure ice growth on airfoil using an array of ultrasonic transducers are described. Ice profiles obtained during flight in natural icing conditions are shown and compared with mechanical and stereo image measurements.

Hansman, R. John, Jr.↗

Capillary Channel Flow (CCF) EU2-02 on the International Space Station (ISS): An Experimental Investigation of Passive Bubble Separations in an Open Capillary Channel

It would be signicantly easier to design fluid systems for spacecraft if the fluid phases behaved similarly to those on earth. In this research an open 15:8 degree wedge-sectioned channel is employed to separate bubbles from a two-phase flow in a microgravity environment. The bubbles appear to rise in the channel and coalesce with the free surface in much the same way as would bubbles in a terrestrial environment, only the combined effects of surface tension, wetting, and conduit geometry replace the role of buoyancy. The host liquid is drawn along the channel by a pump and noncondensible gas bubbles are injected into it near the channel vertex at the channel inlet. Control parameters include bubble volume, bubble frequency, liquid volumetric flow rate, and channel length. The asymmetrically confined bubbles are driven in the cross-flow direction by capillary forces until they at least become inscribed within the section or until they come in contact with the free surface, whereupon they usually coalesce and leave the flow. The merging of bubbles enhances, but does not guarantee, the latter. The experiments are performed aboard the International Space Station as a subset of the Capillary Channel Flow experiments. The flight hardware is commanded remotely and continuously from ground stations during the tests and an extensive array of experiments is conducted identifying numerous bubble flow regimes and regime transitions depending on the ratio and magnitude of the gas and liquid volumetric flow rates. The breadth of the publicly available experiments is conveyed herein primarily by narrative and by regime maps, where transitions are approximated by simple expressions immediately useful for the purposes of design and deeper analysis.

fluid dynamics↗

Unraveling the Origin of Photocatalytic Deactivation in CeO 2 /Nb 2 O 5 Heterostructure Systems during Methanol Oxidation: Insight into the Role of Cerium Species

The study provides deep insight into the origin of photocatalytic deactivation of Nb 2 O 5 after modification with ceria. Of particular interest was to fully understand the role of ceria species in diminishing the photocatalytic performance of CeO 2 /Nb 2 O 5 heterostructures. For this purpose, ceria was loaded on niobia surfaces by wet impregnation. The as-prepared materials were characterized by powder X-ray diffraction, nitrogen physisorption, UV-visible spectroscopy, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, and photoluminescence measurements. Photocatalytic activity of parent metal oxides (i.e., Nb 2 O 5 and CeO 2 ) and as-prepared CeO 2 / Nb 2 O 5 heterostructures with different ceria loadings were tested in methanol photooxidation, a model gas-phase reaction. Deep insight into the photocatalytic process provided by operando-IR techniques combined with results of photoluminescence studies revealed that deactivation of CeO 2 /Nb 2 O 5 heterostructures resulted from increased recombination of photo-excited electrons and holes. The main factor contributing to more efficient recombination of the charge carriers in the heterostructures was the ultrafine size of the ceria species. The presence of such highly dispersed ceria species on the niobia surface provided a strong interface between these two semiconductors, enabling efficient charge transfer from Nb 2 O 5 to CeO 2 . However, the ceria species supported on niobia exhibited a high defect site concentration, which acted as highly active recombination centers for the photo-induced charge carriers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

GaAs solar cells grown on acoustically spalled GaAs substrates with 27% efficiency

Acoustic spalling presents a potentially low-cost reuse pathway for III–V epitaxial growth substrates via exfoliation of device layers with recovery and reuse of the substrate. However, surface features formed during spalling can reduce the performance of subsequently grown devices. Here, we develop an understanding of how the surface morphology of acoustically spalled substrates affects GaAs solar cell performance and develop strategies to mitigate these impacts. We demonstrate that minor planarization of the surface by wet chemical etching and/or epitaxial growth, or the redesign of the device structure to thicken critical layers, prevents performance degradation. Using these strategies, we demonstrate a 0.25 cm 2 single-junction GaAs device with 26.9% ± 0.2% photovoltaic conversion efficiency under the AM1.5G spectrum grown on an acoustically spalled substrate. These results enable the growth of high-performance III–V devices on non-traditional substrates with the potential for significantly reduced device costs.

14 SOLAR ENERGY↗

Spontaneous imbibition in a square tube with corner films: theoretical model and numerical simulation

Spontaneous imbibition in an angular tube with corner films is a fundamental problem in many scientific and engineering processes. In this paper, a modified interacting capillary bundle model is developed to describe the liquid imbibition dynamics in a square tube with corner films. The square tube is decomposed into several interacting sub-capillaries and the local capillary pressure in each sub-capillary is derived based on the specific shape of its meniscus. The conductance of each sub-capillary is calculated using single-phase lattice Boltzmann simulation. The modified interacting capillary bundle model and color-gradient lattice Boltzmann method are used to simulate the liquid imbibition dynamics in the square tube with different fluid properties. The predictions by the modified interacting capillary bundle model match well with the lattice Boltzmann simulation results for different conditions, demonstrating the accuracy and robustness of the interacting capillary bundle model to describe the imbibition dynamics with corner films. In addition, the interacting capillary bundle model is helpful to investigate the mechanisms during spontaneous imbibition and the influences of fluid viscosity, surface tension, wetting phase contact angle and gravity on imbibition dynamics. Finally, a universal scaling law of imbibition dynamics for the main meniscus is developed and the scaling law for arc meniscus is also analyzed.

42 ENGINEERING↗

Occurrence of Warm Freezing Rain: Observation and Modeling Study

Freezing rain has been normally considered to be composed of supercooled raindrops when the 2 m air temperature (hereafter T as ) is below freezing. However, according to a statistical survey of freezing rain observations in China from 2000 to 2019, we find that there were 656 events that occurred at T as greater than 0°C (hereafter warm freezing rain and denoted by WFR), which account for 7% of the total freezing rain observations. Additionally, nearly 3% (266 observations) of freezing rain events occurred when the near-surface wet-bulb temperature was greater than 0°C. The modeling and sensitivity experiments on the nonequilibrium raindrop temperature (hereafter T r ) how that the temperature difference between raindrops and the atmosphere is the main cause of WFR. The magnitudes of the Δ T ar (difference between raindrop temperature T r and air temperature T a ) and Δ T ur (difference between T r and wet-bulb temperature T w ) are determined by the raindrop diameter D, temperature lapse rate $\Gamma$, and relative humidity RH. Increases of D and $\Gamma$, and a decrease of RH enhance Δ T ar and Δ T ur and thus the occurrence of WFR. Further simulations of 4 idealized and 370 real sounding profiles reveal that either the T a or the T w cannot properly distinguish the WFR events. When considering the temperature difference between raindrops and the atmosphere, the WFR can form by the “melting of solid hydrometeors” or “supercooled warm rain process.” This study can also deepen our understanding of the conditions of WFR and freezing rain formation at different altitudes.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric pressure plasmas interacting with wet and dry microchannels: reverse surface ionization waves

Atmospheric pressure plasma jets (APPJs) are increasingly being used to functionalize polymers and dielectric materials for biomedical and biotechnology applications. Once such application is microfluidic labs-on-a-chip consisting of dielectric slabs with microchannel grooves hundreds of microns in width and depth. The periodic channels, an example of a complex surface, present challenges in terms of directly and uniformly exposing the surface to the plasma. In this paper, we discuss results from computational and experimental investigations of negative APPJs sustained in Ar/N 2 mixtures flowing into ambient air and incident onto a series of microchannels. Results from two-dimensional plasma hydrodynamics modeling are compared to experimental measurements of electric field and fast-camera imaging. The propagation of the plasma across dry microchannels largely consists of a sequence of surface ionization waves (SIWs) on the top ridges of the channels and bulk ionization waves (IWs) crossing over the channels. The IWs are directed into electric field enhanced vertices of the next ridge. The charging of these ridges produce reverse IWs responsible for the majority of the ionization. The propagation of the plasma across water filled microchannels evolve into hopping SIWs between the leading edges of the water channels, regions of electric enhancement due to polarization of the water. Positive, reverse IWs follow the pre-ionized path of the initial negative waves.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Crystallization in one-step solution deposition of perovskite films: Upward or downward?

Despite the fast progress of perovskite photovoltaic performances, understanding the crystallization and growth of perovskite films is still lagging. One unanswered fundamental question is whether the perovskite films are grown from top (air side) to bottom (substrate side) or from bottom to top despite 10 years of development. Here, by using grazing incidence x-ray diffraction and morphology characterizations, we unveil that the perovskite films prepared by one-step solution processes, including antisolvent-assisted spin coating and blade coating, follow the downward growth from intermediate phase during thermal annealing. Such a top-to-bottom downward growth is initialized by the evaporation of residual solvent from the top surface of “wet” films and is less sensitive to perovskite compositions and the wettability of underlying substrates. Addressing this fundamental question is important to understand the heterogeneity of perovskite films along the vertical direction, which markedly affects the efficiency and stability of perovskite solar cells.

36 MATERIALS SCIENCE↗

Bioadhesive polymer semiconductors and transistors for intimate biointerfaces

The use of bioelectronic devices relies on direct contact with soft biotissues. For transistor-type bioelectronic devices, the semiconductors that need to have direct interfacing with biotissues for effective signal transduction do not adhere well with wet tissues, thereby limiting the stability and conformability at the interface. Here we report a bioadhesive polymer semiconductor through a double-network structure formed by a bioadhesive brush polymer and a redox-active semiconducting polymer. The resulting semiconducting film can form rapid and strong adhesion with wet tissue surfaces together with high charge-carrier mobility of ~1 square centimeter per volt per second, high stretchability, and good biocompatibility. Further fabrication of a fully bioadhesive transistor sensor enabled us to produce high-quality and stable electrophysiological recordings on an isolated rat heart and in vivo rat muscles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Preliminary Thermal-Hydraulic Analysis of the UTA–2 Subcritical Linear Accelerator–Driven System

The National Nuclear Security Administration’s mission includes establishing a reliable supply of 99 Mo without highly enriched uranium. Oak Ridge National Laboratory (ORNL) supports this objective through collaborative research and development with industrial partners. Niowave Inc., a current partner, is currently designing a subcritical linear accelerator-driven system (ADS) and preparing for the US Nuclear Regulatory Commission’s licensing process. Niowave’s system has the potential to efficiently supply medical radioisotopes. The technology includes a superconducting electron accelerator and a pile of both natural and low-enriched uranium (LEU) targets. The process fissions uranium and many valuable isotopes can then be extracted from the targets. Niowave is currently iterating through conceptual and detailed design processes for several system sizes. This report discusses UTA–2, which is at the demonstration stage. UTA–2 will validate numerical modeling results with experimental measurements before progressing to the detailed design of UTA–3, the commercial-sized ADS. The thermal-hydraulic behavior of the UTA–2 core design was numerically investigated using STAR-CCM+, as described in this report. STAR-CCM+, a state-of-the-art computational fluid dynamics (CFD) software that was commercially developed by Siemens, has an extensive user base and a set of validation studies. It is also compliant with the American Society of Mechanical Engineers’ Nuclear Quality Assurance 1 standard. Three cases are investigated in this report. Case 1 quantified the temperature field within the UTA–2 assembly and water tank using only conduction as the method of thermal energy transport. This simplified approach was overly conservative and yielded wetted cladding temperatures above the coolant saturation temperature. In this case, the maximum temperature of the wetted cladding surface of the highest power rod exceeded the saturation temperature of water by 63.8°C. Because of the overly conservative approach taken in Case 1 and its negative subcooled margin, buoyancy-driven natural circulation flow physics were implemented in Case 2. Adding coolant motion significantly distributed the thermal energy of the system through convective heat transfer. This relatively small amount of convective heat transfer significantly reduced system temperatures and increased the subcooled margin from –63.8 to 61.3°C. This margin confirmed that no boiling was expected during normal operation of UTA–2 at 230 W. Case 3 had no additional physics models but considered an overpower event during which the power of each LEU and natural uranium rod was at its respective peak values. This resulted in a study with the total assembly power equal to 176% of the nominal power of 230 W considered in Cases 1 and 2. The resulting natural circulation flows were slightly enhanced. The subcooled margin decreased slightly to 46.3°C, which is still a significant margin to local boiling of the water within the tank. This margin confirmed that no boiling was expected during an abnormal operation of UTA–2 at 406 W.

07 ISOTOPE AND RADIATION SOURCES↗

SAIL Supermicron Bioaerosol (SSB) Field Campaign Report

The Surface Atmosphere Integrated Field Laboratory (SAIL) Supermicron Bioaerosol (SSB) study was designed to complement the larger Atmospheric Radiation Measurement (ARM) SAIL science goals to understand aerosol processes and aerosol-cloud interactions in the Colorado River’s East River Watershed Basin. Supermicron aerosol, particles larger than one micron in diameter, and bioaerosols, primary particles containing biological material, are important for understanding atmospheric processes and sources within high mountainous terrain. For example, they can interact with clouds and the water cycle such as by serving as nuclei for cloud droplets and ice crystals that can eventually result in precipitation events. These particles can also be recycled back to the surface via wet and dry deposition, where they can alter plant and microbial growth and/or be reemitted again, forming a positive feedback loop within the Earth system known as bioprecipitation.

54 ENVIRONMENTAL SCIENCES↗

On the remote measurement of evaporation rates from bare wet soil under variable cloud cover

Evaporation rates from a natural wet soil surface are calculated from an energy balance equation at 0.1-hour intervals. A procedure is developed for calculating the heat flux through the soil surface from a harmonic analysis of the surface temperature curve. The evaporation integrated over an entire 24-hour period is compared with daily evaporation rates obtained from published models.

Auer, S.↗

Recent Progress Towards Predicting Aircraft Ground Handling Performance

The significant progress which has been achieved in development of aircraft ground handling simulation capability is reviewed and additional improvements in software modeling identified. The problem associated with providing necessary simulator input data for adequate modeling of aircraft tire/runway friction behavior is discussed and efforts to improve this complex model, and hence simulator fidelity, are described. Aircraft braking performance data obtained on several wet runway surfaces is compared to ground vehicle friction measurements and, by use of empirically derived methods, good agreement between actual and estimated aircraft braking friction from ground vehilce data is shown. The performance of a relatively new friction measuring device, the friction tester, showed great promise in providing data applicable to aircraft friction performance. Additional research efforts to improve methods of predicting tire friction performance are discussed including use of an instrumented tire test vehicle to expand the tire friction data bank and a study of surface texture measurement techniques.

Yager, T. J.↗