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Experiment design for the neutron irradiation of $\mathrm{PM-HIP}$ alloys for nuclear reactors

Here, this article describes the design of an Advanced Test Reactor (ATR) drop-in neutron irradiation experiment aiming to directly compare the performance of nuclear structural alloys fabricated by powder metallurgy with hot isostatic pressing (PM-HIP) against conventional casting or forging. There is growing interest in PM-HIP alloys for nuclear applications because of their microstructural uniformity, superior mechanical properties, and reduced dependence on welding and machining, compared to cast/forged alloys. Nuclear code-qualification of PM-HIP alloys requires neutron irradiation testing to demonstrate performance under relevant conditions. In this experiment, six nuclear structural alloys were irradiated: Ni-based alloys 625 and 690, Grade 91 ferritic steel, SA508 pressure vessel steel, and 304L and 316L austenitic stainless steels. The experiment is assembled into seven capsules in four test trains and irradiated in three ATR inboard A positions. Both the PM-HIP and cast/forged versions of each alloy were irradiated under nearly identical conditions for comparative purposes, to target doses of 1 ± 0.2 and 3 ± 0.2 dpa at temperatures of 300 ± 50 °C and 400 ± 50 °C. A thorough description of the experiment design and thermal, structural and neutronic analyses performed to ensure the targeted irradiation conditions are met is provided. Specimens were configured as small disks, compact tension specimens and tensile bars to facilitate post-irradiation examination (PIE) that will include mechanical testing, microstructure characterization, and fracture toughness testing. Given the considerations for ASTM standardized mechanical testing, comparative fluence and temperature across specimen pairs, and comprehensive PIE planning herein, this work serves as a template for future nuclear materials qualification experiment designs.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Considerations for Managing DOE Standard Canisters within an Over-canister as Part of an Integrated Waste Management System PPT

To better enable informed decision making regarding the back-end of the nuclear fuel cycle, the Integrated Waste Management Program within the U.S. Department of Energy, Office of Nuclear Energy (DOE-NE) has been sponsoring research into a comprehensive integrated waste management system (IWMS) that considers all major back-end aspects of the nuclear fuel cycle (i.e., transportation, storage, and disposal). An important aspect of the IWMS is DOE-managed Spent Nuclear Fuel (SNF). DOE and its predecessor agencies have generated, transported, received, stored, and reprocessed SNF at DOE facilities nationwide, and DOE is responsible for managing the SNF currently in its possession. These fuels come from a wide range of reactor types that employ various cladding materials, fuel materials, and enrichments. To enable interim, road-ready dry storage (RRDS) of the wide variety of SNF types found in the DOE inventory, a standardized canister system (i.e., the DOE Standard Canister) was proposed for the packaging demonstration. This robust, welded canister system is designed to confine radionuclides, prevent criticality by precluding content moderation, and satisfy other requirements as part of a larger storage, transportation, and disposal system. While SNF has yet to be loaded into a DOE Standard Canister, DOE Standard Canister designs were included in past storage facility and disposal facility design licensing endeavors. In a renewed effort to evaluate packaging SNF at Idaho National Laboratory (INL) in a RRDS configuration, researchers are planning the RRDS Packaging Demonstration. This demonstration is supplemented by analytical structural, criticality, and material compatibility evaluations that support management of SNF in DOE Standard Canisters, taking advantage of past analysis work to the extent possible. One of the largest differences between the current Packaging Demonstration and past analytical evaluations is the inclusion of an over-canister containing multiple DOE Standard Canisters. For the Packaging Demonstration, DOE Standard Canisters loaded with SNF are planned to be placed in a larger diameter over-canister. The sealed over-canister could then be placed in a storage overpack for onsite storage, or in a transportation overpack for shipment to an offsite storage location or disposal site once one becomes available. This paper examines the relevant considerations and provides a preliminary evaluation of integrating the over-canister configuration into the storage, transportation, and disposal processes of the overall waste management system. For storage and transportation, the over-canister can be considered analogous to a multi-purpose canister (MPC) for commercial SNF. For disposal, the DOE Standard Canisters could be removed from the over-canister and placed in a co-disposal waste package with canisters containing vitrified high-level radioactive waste (HLW) similar to configurations examined previously, or the sealed over-canisters might be capable of direct disposal in a waste package.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Novel Geochemistry Determined from High Pressure, High Temperature Simulation Experiments of Hydraulic Fracture Test Site 2

A standard method in unconventional oil and gas production is the process of hydraulic fracturing followed by a shut-in period, during which the fracture fluid remains pressurized in the reservoir for up to three weeks before production begins. Despite this widely used process, very little is known about what occurs in the reservoir during this shut-in process. In order to properly delineate potential reservoir reactions that may occur during shut-in that would lead to corrosion and scaling events, experiments were conducted in high pressure, high temperature reactors to simulate conditions of the Wolfcamp Formation in the Delaware Basin. Experimental design allowed the assessment of the effect of proppant, microbiology, and time on the mineralogy and fluid chemistry in the reservoir. Results suggest the biggest impact on fluid chemistry and shale mineralogy during shut-in is time. Analyses demonstrate dissolution of the shale material, with maximum dissolved ions occurring after 7 days of the shut-in period. After 21 days, results suggest precipitation occurs. The Delaware Basin is demonstrated to be high in sulfate content, which further increases in the fluid due to dissolution reactions during shut-in. The pressure vessel experiments suggest there was no significant contribution to reactions from microbiology during the shut-in period. Furthermore, early production samples demonstrate a significant selection of the microorganism Caminicella, a genus of which has previously been correlated to corrosion and sulfide production. Results suggest shut-in conditions may provide high sulfate concentrations that could later be utilized by a shifted microbial community to drive potential well infrastructure failure. This is the first study to incorporate microbiology, mineralogy, and fluid chemistry to investigate the fundamental geochemical reactions that occur during shut-in and early phase production of the Delaware Downloaded from http://onepetro.org/URTECONF/proceedings-pdf/21URTC/2-21URTC/D021S032R001/2477425/urtec-2021-5219-ms.pdf/1 by Carol Worster on 28 February 2022 Basin. Results from this study can complement observations from the Hydraulic Fracture Test Site 2 observations

58 GEOSCIENCES↗

Engineered Solutions Group's SMR Containment Cable and Electrical Penetration Assembly System

GAIN Project CRADA Number NFE-21-08839, entitled “SMR Containment Cable and EPA System” was initiated by the partnership of Oak Ridge National Laboratory (ORNL) and Engineered Solutions Group (ESG) to test an ESG-designed Electrical Penetration Assembly and Containment Cabling System Qualified for not only legacy LWR designs, but also Small Modular Reactors designs currently being designed by several different suppliers. This project was undertaken to fill the equipment gap of EPA and Cabling Systems that require much more severe environmental requirements than legacy plant applications present due to their smaller containment volumes that result in high energy densities compared to legacy designs. This high energy density results in severe accident environments and more severe normal operating conditions as well. We developed two approaches to qualify Electrical Penetration Assembly (EPA) and Containment Cabling Systems for SMRs and Advanced Reactors. We take into consideration the more severe environmental parameters found with SMR designs. The system will need to meet a qualification test program addressing wear/cyclic aging, potential radiation exposure, thermal aging, vibration aging, thermal cycling, seismic qualification, electrical fault testing (per IEEE 317) and accident simulation. The equipment must meet the requirements of 10CFR50.49, GDC 50 in 10CFR50 Appendix A, and 10CFR50 Appendix J. NRC Regulatory Guides (RGs) identify an acceptable way of meeting regulatory requirements. RGs frequently endorse a standard for meeting these requirements. Specific to this review, equipment would be qualified in accordance with the following IEEE Standards. • IEEE 317-2013 (Electrical Penetration Assemblies), which is endorsed by RG 1.63, Rev. 3, • IEEE 323-2003 and the more current IEC/IEEE 60780-323 (Environmental Qualification of 1E Equipment) which is endorsed by RG 1.89. IEEE 323-2003 is endorsed by RG 1.209, • IEEE 344-2020 (Seismic Qualification. The 2013 version endorsed by RG 1.100, Rev. 4, with exceptions), • IEEE 383-2015 (Electrical Cables) (which is endorsed by RG 1.189 Rev. 4 and the -2003 version endorsed by RG 1.211 rev. 0), • IEEE 572-2019 (Electrical Connectors and Assemblies), which is endorsed by 1.156 Rev 1, and • [IEEE 1202 (endorsed by RG 1.189) would normally be applicable but the advanced cable designs are impervious to this cable flame test.] The primary goal of such a program is to provide an EPA design that can meet the qualification requirements for all legacy light water reactor plants currently operating as well as new plant designs including light water Small Modular Reactors. Thus, these requirements are applicable to plants licensed under 10CFR50 and 10CFR52. Other reactor designs may be evaluated, and this test system and qualification method applied to those applications if the requirements would satisfy the requirements of the intended plant. A secondary benefit of this work is to document some of the history and background in these requirements as there have been recent delays in an SMR licensing process due to NRC Requests for Additional Information in this subject matter area.

42 ENGINEERING↗

Status Report on ASME Code Development for Nonmetallic Core Components in 2020

The purpose of this report is to provide a status update on the progress and ongoing activities of the current ASME Boiler Pressure Vessel (BPV) Code Section III, Division 5, on nonmetallic core components and assemblies which includes the design rules for graphite and ceramic composite materials. Section III is concerned with the design and construction of nuclear reactor components and Division 5 focuses on high temperature reactors (HTR). The ASME Section III Committee’s function for nuclear items other than pressure-retaining components, is to establish rules of safety related to structural integrity. The term “construction” refers to the all-inclusive effort comprising of materials, design, fabrication, examination, inspection, testing, certification, and pressure relief. The Department of Energy (DOE) supports industry codes and standards development through focused research providing the technical basis for new or modified codes and standards and the participation of subject matter experts in codes and standards committees. The activities for the nonmetallic core components and assemblies committees are the pursuit of two working groups that meet quarterly during ASME BPV Code Week meetings. The two working groups are General Requirements for Graphite and Ceramic Composite Core Components and Assemblies (GR GCCCCA) and Nonmetallic Design and Materials (NDM). The rules on general requirements for nonmetallic core components are discussed in the articles of Subsection HA subpart B. Ceramic composites were recently incorporated within the rules, and the GR GCCCCA working group is now in the process of aligning the requirements with the subsections and articles of ASME BPV Code Section III NCA, the general requirements for Division 1 and 2 of the code. The NDM working group is concerned with the design rules for graphite and composite materials for core components and assemblies discussed in Subsection HH (Class SN Nonmetallic Core Components) subpart A and subpart B which reference graphite and composite materials respectively. The bulk of the progress and work is done within this working group. A significant undertaking, with discussion that started in 2015, is to gain endorsement of ASME Section III, Division 5, by the U.S. Nuclear Regulatory Commission (NRC). In June 2018, ASME formally recommended endorsement to the NRC. The NRC has since initiated the endorsement review process, which is to be concluded early in 2021. ASME task groups on metallic structures and components, as well as non-metallic core support structures, have been formed to define potential pathways and schedules for NRC endorsement of Division 5. NRC determined to perform a review on the 2017 edition of Section III Division 5 as a baseline. As a result, the use of graphite as nonmetallic core components formed part of the review, but it excluded composite materials (which were first introduced in the 2019 edition). This report documents progress in FY 2020 directed toward ASME’s efforts to develop design codes for graphite and composites. Progress includes a major code review by NRC, the first code enquiry, and its solution, an overhaul of the treatment of Weibull Statistics, and the addition of Nonmandatory Appendices to the composites code relating to carbon-carbon composite materials.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A ranking methodology for the coupling of pressurized water nuclear reactors and molten salt thermal energy storage

Thermal energy storage (TES) systems are a proposed solution to electricity market demand fluctuations and can be coupled to nuclear power plants to enable load following. Here, this work focuses on developing a methodology for evaluating potential designs for integrating a TES system into an existing pressurized water nuclear power plant. The proposed ranking methodology allows a group of experts to postulate and weigh designs based on ranking criteria derived from literature. The methodology developed in this study can aid in the final selection of a TES design for an existing nuclear power plant. The same process could be used to analyze other TES and nuclear reactor designs. The determined optimum design from this methodology was to place the TES system after the steam generator and to utilize the steam generated from the nuclear power plant to heat a molten salt TES unit. Another conclusion of this research was that human bias is prevalent during design selection, and actions such as standardized ranking criteria and large groups of experts should be used to minimize this error.

25 ENERGY STORAGE↗

Fast Reactor Physics Model Verification Studies using ARC and PyARC Workflows

PyARC was recently developed at Argonne National Laboratory to automate many of the tasks required in the ARC (Argonne Reactor Computation) fast reactor simulation workflow, from input file generation, code execution, data transfer between ARC codes, and output postprocessing. PyARC will likely be the path forward to train new users of the ARC codes with the goal of wide adoption by the national laboratories, academia, and industry. In particular, for the ANL-JAEA collaboration under the Civil Nuclear Working Group (CNWG) project agreement NE-01, PyARC will be used to model the Joyo and EBR-II reactors for comparisons with measured data and calculated results from JAEA (Task 3: Fast Reactor Fuel and Core). As an additional avenue for verification and validation, this report investigates the use of PyARC towards a variety of existing ARC-based reactor models, in order to understand its efficacy in replicating the behavior of base ARC codes and better understand any limitations within modeling realistic fast reactor problems. To this end, PyARC was used to model the Joyo MKI, RBEC Benchmark-M, PRISM Mod-B, and EBR-II Run 138B cores, and its results were compared to those from existing ARC-based models. It was found that for hexagonal-based geometries PyARC was able to replicate the behavior of ARC codes to within 10 pcm for small reactor cores, and ~150pcm difference in eigenvalue for larger cores. These discrepancies are attributed primarily to differences in local mesh refinement options between ARC and PyARC, which currently cannot be resolved with PyARC’s latest version (1.6.0). In some of these cases, PyARC was used to model steady-state problems with initial core compositions originating from a prior REBUS depletion calculation. While PyARC was not designed to support such steady-state calculations, workarounds were applied to replicate the behavior of ARC-based calculations as closely as possible. Thus, these results demonstrate the wide extent to which they can be applied to fast reactor problems while still providing immense benefit to the user in terms of automating and standardizing common routines within the fast reactor analysis workflow. This study concluded that PyARC will be suitable for modeling the steady-state conditions of the EBR-II and Joyo fast reactors as part of the CNWG project agreement.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Validation of Robustness in TCR Design Strategies

Advanced Manufacturing (AM) has been identified as one of key pathways in accelerating deployment of next generation of nuclear power plants. The nuclear industry continues to predominately rely on fabrication techniques and materials that their codes and standards were approved decades ago. This legacy approach in the highly regulated nuclear sector has brought uncertainty to commercial viability of nuclear energy in the U.S. The Transformational Challenge Reactor (TCR), sought to utilize AM methods for fabrication of a High Temperature Gas Reactor (HTGR). The program sought to leverage AM to construct a non-conventional geometry made up of TRISO fuel and hydride moderator in SiC matrix. This project objective was to provide independent analysis of the core configuration with separate set of tools and approaches than utilized by the TCR team in a 2-year time frame. This NEUP project also tackled a question: Can AM be a cost-effective tool in changing the commercial paradigm of nuclear. We investigated this question in-context of a micro HTGR. While respecting the inherit uncertainty in our input parameters, overall we saw that AM has potential in improving economic competitiveness of nuclear energy when employed on multiple fronts (i.e. few percentage cost improvement per component). Given realizing AM requires mass orders and large R&D investment for commercial utilization, Department of Energy should focus its support on few key enabling technologies and support their codes and standards development and qualification cost (including irradiation as applicable) rather than taking a diluted approach.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Developmental Efforts of an Electrochemical Oxygen Recovery System for Advanced Life Support

The current State of Art (SOA) Environmental Control and Life Support System (ECLSS) oxygen recovery system onboard the International Space Station (ISS) is complex, heavy, and power consuming system that recovers approximately 50% of the oxygen (O2) from metabolic carbon dioxide (CO2). For future long-duration missions, O2 recovery systems will need to be highly reliable, efficient, and recover maximum metabolic CO2. A minimum of 75% O2 recovery is required for future O2 recovery systems. Investigations into various technologies to help meet these requirements for exploration are ongoing; however, most of these proposed technologies ultimately result in a more complex system. A Macrofluidic Electrochemical Reactor (MFECR) is one proposed technology development effort currently underway at NASA Marshall Space Flight Center (MSFC) that has the potential to significantly reduce the complexity of ECLSS O2 recovery system. The MFECR operates at standard conditions, giving it an advantage over other technologies being investigated, which require high temperatures resulting in heavy reactors and high power consumption. The MFECR would replace three pieces of hardware for future ECLSS architectures: the current Carbon Dioxide Reduction Assembly (Sabatier reactor), the Plasma Pyrolysis Assembly (PPA), and the Oxygen Generation Assembly (OGA). It is designed to interface directly with the Carbon Dioxide Removal Assembly (CDRA) and the Water Processor Assembly (WPA). This allows for a less complex system and higher reliability than the current SOA as well as reduced power, weight and H2O consumption of ECLSS. Here, we will discuss the current technology development efforts of the MFECR and how this technology may aide in the advancement of future long-duration life support systems.

Brown, Brittany R.↗

Developmental Efforts of an Electrochemical Oxygen Recovery System for Advanced Life Support

The current State of Art (SOA) Environmental Control and Life Support System (ECLSS) oxygen recovery system onboard the International Space Station (ISS) is a complex, heavy, and power consuming system that recovers approximately 50% of the oxygen (O2) from metabolic carbon dioxide (CO2). For future long-duration missions, O2recovery systems will need to be highly reliable, efficient, and recover maximum metabolic CO2. Investigations into various technologies to help meet these requirements for exploration are ongoing; however, most of these proposed technologies ultimately result in a more complex system. A Macrofluidic Electrochemical Reactor (MFECR) is one proposed technology development effort currently underway at NASA Marshall Space Flight Center (MSFC) that has the potential to significantly reduce the complexity of ECLSSO2recovery system. The MFECR operates at standard conditions, giving it an advantage over other technologies being investigated, which require high temperatures resulting in heavy reactors and high power consumption. The MFECR would replace three pieces of hardware for future ECLSS architectures: the current Carbon Dioxide Reduction Assembly (Sabatier reactor), the Plasma Pyrolysis Assembly (PPA), and the Oxygen Generation Assembly(OGA). It is designed to interface directly with the Carbon Dioxide Removal Assembly (CDRA) and the Water Processor Assembly (WPA). This allows for a less complex system and higher reliability than the current SOA as well as reduced power, weight and H2Oconsumption of ECLSS. Here, we will discuss the current development efforts of the MFECR and how this technology may aide in the advancement of future long-duration life support systems.

Brittany R Brown↗

Design Optimization for Printed Melt Wire Arrays Encapsulation

As part of the Nuclear Energy Enabling Technology (NEET) Advanced Sensor and Instrumentation (ASI) Program, Idaho National Laboratory (INL) has recently established in-house capabilities to fabricate and test new advanced-manufactured sensors for measuring peak irradiation temperature within a nuclear test reactor. Although methods of real-time temperature monitoring, such as thermocouples, may be used, the complexity of feedthroughs and attachments to collect real-time measurements greatly increases the cost of the experiment. Instead, passive monitoring techniques may be used for peak- temperature measurement that exploit the melting point of well-characterized materials (standard melt wires) to infer peak reactor temperatures. However, limited available space for instrumentation during experiments introduces an additional challenge. To accommodate this, INL has expanded its temperature- detection instrumentation capabilities to include advanced manufactured (AM) melt wires for peak irradiation temperature measurements. These melt wires can determine peak temperatures while also accommodate space limitations in irradiation experiments. In an effort to improve performance reliability of AM meltwire capabilities, a process was developed and tested to identify the significance of entrapping a high purity inert atmosphere within the packaging of printed melt wire arrays. The materials used in this study were aluminum, zinc, and tin encapsulated in high purity helium within a stainless steel (SS) 316 container. Tin, with a low melting point of approximately 230°C, Zn with a mid-melting point of approximately 420°C, and Al with a high melting point of approximately 660°C. This report describes the design, fabrication process, furnace testing and X-ray Computed Tomography (XCT) evaluation. Results show a successful outcome in creating an inert gas encapsulation and high-resolution evaluation methods.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Considerations for Improving the Technoeconomic Viability of Heat Pipe Microreactors by Employing a Functional Containment Approach

The economic cost of a microreactor is being investigated by leveraging MARVEL cost information in conjunction with some simplified design and analysis activities to present a hypothetical, yet feasible, option for investigation. This bottom-up cost estimate for a hypothetical commercial microreactor will be used to provide guidance to the industry and research communities regarding where priorities should be set to improve the viability of broad microreactor deployment. To support the design and analysis activities required to present a feasible option, some understanding of maximum accidental radionuclide releases and consequences is needed to provide bounding estimates on containment or confinement systems for radionuclide retention. To estimate fission product barrier and retention performance, a gaussian plume dose and dispersion model is employed, with isotopic inventories being propagated between barriers assuming conservative fractional release rates. Demonstrably conservative meteorological assumptions are also assumed. Standard reference release rates are assumed where safety requirements could be easily and economically employed. Results are provided in units of total effective dose equivalent as a function of distance from the release (i.e., the reactor). Initial results indicate that the hypothetical microreactor will likely need to credit the fuel cladding and at least one other barrier, or combination of barriers, to ensure public health and safety as required during a postulated accident. This approach is referred to as “functional containment,” since no single barrier will be relied upon for satisfying regulatory requirements and fundamental safety functions for radionuclide retention. Finally, a set of barrier options are provided so that future economic analyses can select the most viable design path.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Safeguards Considerations for Coated Particle Fuel Fabrication Facilities

This study aims to identify where existing fuel fabrication safeguards are limited in application to coated particle fuel fabrication facilities; perform a review of techniques that may be appropriate to address these limitations; and identify where further study is required. The purpose is to ensure the necessary technology and safeguards developments are established to facilitate safeguards-by-design for coated particle fuel fabrication facilities, analogous to the research and development (R&D) efforts in the advanced reactor space, including those requiring coated particle fuels and progress to higher technology readiness levels. Finally, this study will also help meet high priority objectives set forth by the IAEA in establishing safeguards R&D precedence and measurement/procedural standards at emerging fuel fabrication facilities. To achieve these objectives, the report is formatted to (1) distill relevant background information on fuel fabrication of oxide and coated particle fuels; (2) provide an overview of the fuel fabrication techniques for a reference oxide fuel fabrication facility and two selected TRISO fuel fabrication facilities; (3) develop facility models of safeguards approaches for the reference facility and the two TRISO facilities; and (4) identify any observed technology needs or gaps from this analysis.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

PROSPECT: A Precision Reactor Oscillation and Spectrum Experiment

Nuclear reactors are a source of copious amounts of electron antineutrinos. They are emitted in the beta decays of the fission products and their energies depend on the isotopic composition of the reactor. In recent years a number of reactor antineutrino experiments including Daya Bay, Double Chooz, and RENO reported a deficit in the measured flux of antineutrinos from reactors compared to expectation and a spectral deviation in the measured energy spectra compared to model predictions. These observations led to the hypothesis of sterile neutrino oscillation as an explanation of the flux deficit. New physics or incomplete nuclear models may explain the origin of the spectral deviation. PROSPECT, the Precision Reactor Oscillation and Spectrum Experiment, is a novel neutrino experiment at the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) designed to address two major scientific objectives: 1. Perform a search for eV-scale sterile neutrinos independent of reactor neutrino models by searching for the oscillation signature of massive, sterile neutrino states beyond the 3 known active neutrino species. The discovery of sterile neutrinos would indicate a new form of matter and require physics beyond the Standard Model. 2. Perform the first modern precision measurement of the antineutrino spectrum from a Highly Enriched Uranium (HEU) 235 U reactor to benchmark our understanding of the neutrino emission from nuclear reactors and to understand the isotopic origin of spectral deviations observed in previous reactor neutrino experiments.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

ECAR-7517 Rev 1 MARVEL I&C Failure Modes and Effects Analysis

The purpose of this document is to perform a single-failure analysis through the use of a Failure Modes and Effects Analysis (FMEA) for the Safety Related components of the MARVEL Instrumentation and Control (I&C) System. The intent is that this document will meet the requirements for a single-failure analysis described in IEEE-379, “IEEE Standard for Application of the Single-Failure Criterion to Nuclear Power Generating Station Safety Systems”, to verify that this design does indeed meet the single failure criterion. Principles of IEEE-352, “IEEE Guide for General Principles of Reliability Analysis of Nuclear Power Generating Station Safety Systems” are followed to ensure the analysis is consistent with industry standards.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

Optimizing Ammonia Separation via Reactive Absorption for Sustainable Ammonia Synthesis

Metal halide salts such as magnesium chloride have been shown to be promising candidates for ammonia storage materials for energy storage and agriculture applications due to their ability to incorporate several moles of ammonia per mole of salt. Ammonia exiting a synthesis reactor can be separated from nitrogen and hydrogen by absorption into magnesium chloride. Such an absorption can be more complete and hotter than separation via ammonia condensation, the current standard in the Haber–Bosch process. Here, we discuss the optimal conditions for the cyclic uptake and release of ammonia from the supported magnesium chloride absorbents. An automated system was designed for measuring the nonequilibrium working capacity of the absorbent, as well as the impact of important operating conditions such as absorption and desorption temperature, pressure, and desorption time. Measurements of absorption and desorption kinetics provide insight into the mechanisms involved. The temperatures and pressures during absorption and desorption were designed to use minimal energy input to maximize the uptake and release of ammonia within a reasonable amount of time. In a laboratory-scale bed, absorption has a small unused bed length, so it is largely independent of mass transfer; it is dominated by how fast ammonia is fed to the bed. Yet, desorption is restricted both by the speed of heating the bed and by diffusion out of the absorbent. These measurements provide guidelines for ammonia separations and cycling sorbent materials on a larger scale.

10 SYNTHETIC FUELS↗

Neural network-based classification and regression of magnetohydrodynamic modes in tokamaks

We present a machine learning-based magnetohydrodynamic (MHD) classifier and regressor that utilizes real or complex-valued 3D magnetic sensor array data to determine neoclassical tearing mode (NTM) onset times in tokamaks with millisecond accuracy. The input dataset consists of poloidal profiles of complex Fourier amplitudes with an n = 1 toroidal mode number from 144 human-labeled ITER Baseline Scenario discharges in the DIII-D tokamak, spanning both tearing-dominated and sawtooth-dominated regimes. Since m, n = 2,1 NTMs frequently emerge alongside sawteeth at the same frequency in this scenario, the focus is on isolating the m = 1 and m = 2 components of the n = 1 MHD mode near the tearing onset. To improve model regularization and prediction stability, singular value decomposition was applied to balance the sawtooth and tearing datasets. The enriched datasets facilitated training neural networks that learn the key distinguishing features of sawtooth and tearing modes in the poloidal profiles of their magnetic amplitude and phase. When the modes occur independently, the networks achieve perfect classification due to the modes’ distinct characteristics and low measurement noise. In the more experimentally relevant case where both modes coexist, the networks maintain exceptional performance across key metrics. Tests on synthetic data with known ground truth demonstrate the superior accuracy of the neural network trained on complex-valued input compared to models using real amplitude, phase, or pseudo-complex data, achieving both a mean time delay and standard deviation below 1 ms. Notably, standard linear regression methods fitting the dominant singular modes to the data closely match the neural network’s performance. Applying these methods across a broad range of H-mode scenarios will enable future studies to systematically identify dominant NTM triggers as scenario-specific variables, paving the way for more effective tearing mode avoidance strategies in future fusion reactor designs.

machine learning↗

Film condensation with high heat fluxes and scaled experiments using pure steam for reactor containment cooling

Condensation tests were performed using a newly developed test facility for scaling the passive containment cooling system (PCCS) to a small modular reactor (SMR). The PCCS of the SMR plays a pivotal role in ensuring greater safety, reliability, and compactness than what is afforded by traditional reactors. Therefore, a well-designed PCCS is essential to SMRs. However, previous studies and test data were unsuitable for scaling, due to high variation in the test geometry and operating conditions. This study intends to close this research gap by using a novel designed scaled test facility consisting of vertical condensing test sections featuring 1-, 2-, and 4-inch-diameter condensing tubes with annular water cooling, and by applying superheated and saturated steam with different steam mass flow ranges of 5–25 g/s. Further, the primary test data, including axial temperatures, mass flow rates, and pressures, were used in conjunction with a standard data reduction method to estimate critical parameters such as heat fluxes, heat transfer coefficients, and condensation rates. These scaled test data would support improving empirical correlations and validating condensation models to identify scaling distortion for SMR PCCSs.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗