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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Supersonic meteorology of Io - Sublimation-driven flow of SO2

The horizontal flow of SO2 gas from the day side to the night side of IO is calculated on the basis of a hydrodynamic model. The flow speed is found to be supersonic for all realistic values of the parameters. The surface pressure follows the frost vapor pressure within a factor of 2 in spite of day-night pressure ratios of 10,000 or more. Atmospheric temperature is generally below the surface temperature due to decompression in the expanding flow. The greatest sensitivity of the solution is connected with the frost temperature at the subsolar point. The quantities that involve the mass of the atmosphere (density, pressure, mass transport, and condensation rate) all vary as the vapor pressure of the frost, which is a sensitive function of frost temperature.

Ingersoll, A. P.↗
NASA NTRS1985

The reactions of cobalt, iron and nickel in SO2 atmospheres Similarities and differences

The reactions of cobalt, iron and nickel in SO2 atmospheres are reviewed and compared. A mixed oxide-sulfide product layer is observed in all cases. Cobalt and nickel exhibit similar behavior. The observed rates are near the sulfidation rates, and the reaction rate is strongly influenced by the outward diffusion of metal through an interconnected sulfide network. A continuous interconnected sulfide is not observed in the oxide-sulfide scales formed on iron, and the reaction rates are more difficult to summarize. The differences and similarities among the three metals are explained in terms of the absence of scale-gas equilibrium and the ratio of the metal diffusivity in the corresponding oxide and sulfide.

Jacobson, N. S.↗
NASA NTRS1987

Parametrization of electron impact ionization cross sections for CO, CO2, NH3 and SO2

The electron impact ionization and dissociative ionization cross section data of CO, CO2, CH4, NH3, and SO2, measured in the laboratory, were parameterized utilizing an empirical formula based on the Born approximation. For this purpose an chi squared minimization technique was employed which provided an excellent fit to the experimental data.

Srivastava, Santosh K.↗
NASA NTRS1987

SO2 absorption cross sections in the near U.V.

In order to understand data measured by the TOMS instrument on Nimbus 7 after the eruption of El Chichon, absorption cross sections are measured in SO2 between 3000 and 3240 A at 295 and 210 K. Errors for these measurements range from less than 2 percent to about 10 percent. Measurements in the 3175 + or 5 A spectral region observed by TOMS indicate that there is a 9 percent reduction in the average cross section at 210 K compared to room-temperature data. Peak cross sections measured at low temperature show increases up to 20 percent over room-temperature data, while cross-section decreases are measured at low temperatures in the areas between the strong features.

Mcgee, Thomas J.↗
NASA NTRS1989

Differential elastic electron scattering cross sections for SO2

Differential cross sections for elastic electron scattering by SO2 were measured by utilizing a modulated, crossed-beam method and calibration against He. The energy and angular ranges were from 5 to 50 eV and from 12 to 156 deg, respectively. The present results are compared with earlier data of Orient et al. (1982), and it is suggested that their cross section values should be increased by about a factor of two.

Trajmar, Sandor↗
NASA NTRS1991

Laser stark spectroscopy of SO2 with the HCN laser

The far infrared laser Stark spectrum of SO2 was investigated using the 337-micron line of the HCN laser. Two distinct families, one originating at low field and the other at high field, were observed. The high field transition is identified. A significant fourth-order Stark shift was observed for this transition in the presence of a large second-order Stark shift. The zero-field frequency of the assigned transition was obtained by accounting for the fourth-order contribution.

Sarker, J. C.↗
NASA NTRS1992

The complete UV spectrum of SO2 by electron impact. I - The vacuum ultraviolet spectrum

Measurements of the VUV emission cross sections of SO2 from 40 to 200 nm in the laboratory in a crossed beam experiment are reported. The wavelength range comprised the EUV spectrum, from 40 to 120 nm, and the FUV spectrum, from 120 to 200 nm. The studies included the measurement of excitation functions of the strongest multiplets from 0 to 1 keV impact energy and the identification of dissociation processes from the analysis of the threshold excitation function. It is shown that the FUV emission cross sections for dissociative excitation of atomic multiplets are generally much larger in the FUV than in the EUV. The emission cross sections measured are important for the preparation and data analysis of spacecraft observations of Io to be obtained for the 1990s.

Ajello, Joseph M.↗
NASA NTRS1992

High resolution spectroscopy of the Martian atmosphere - Study of seasonal variations of CO, O3, H2O, and T on the north polar cap and a search for SO2, H2O2, and H2CO

An overview is presented of an observational campaign which will measure (1) the seasonal variations of the CO mixing ratio on the Martian polar cap due to accumulation and depletion of CO during the condensation and evaporation of CO2, as well as (2) the early spring ozone and water vapor of the Martian north polar cap, and (3) the presence of H2CO, H2O2, and SO2. The lines of these compounds will be measured by a combined 4-m telescope and Fourier-transform spectrometer 27097.

Krasnopolsky, V. A.↗
NASA NTRS1993

Satellite measurements of the backscattered ultraviolet to determine ozone trends, volcanic SO2, and nitric oxide

Measurements of the atmospheric backscattered UV albedo have been used from satellites for more than 20 years to measure ozone. The longest continuous record has been from the Solar Backscattered Ultraviolet instrument (SBUV) and TOMS on the Nimbus 7 satellite, which have been in operation since November of 1978. Because of degradation in space of the diffuser plate used to measure extraterrestrial solar flux, it has been necessary to develop new techniques to maintain the calibration of these instruments. Calibration is maintained by requiring that ozone measured by different wavelength pairs be consistent, and by requiring that ozone measured at different solar zenith angles be consistent. This technique of using a geophysical quantity, ozone, as a transfer standard for wavelength calibration is very powerful. The recalibrated data have been used to measure total ozone trends to an accuracy of +/- 1.3 percent 2(sigma) error over ten years. No significant trends are found near the equator, but significant trends larger than predicted by homogeneous chemistry are found at middle to high latitudes in both hemispheres. In addition, UV albedo data have been used to measure SO2 using band structure in the 300-310 nm range, and to measure nitric oxide in the upper stratosphere and mesosphere using the (10) and (02) NO gamma band fluorescence features.

Mcpeters, Richard↗
NASA NTRS1994

Long path monitoring of tropospheric O3, NO2, H2CO and SO2

Concentrations of tropospheric O3, NO2, H2CO, and SO2 have been measured on the Campus of the 'Universite Libre de Bruxelles' on a routine basis since October 1990. The long path system consists of a source lamp, a first 30 cm f/8 Cassegrain type telescope which collimates the light onto a slightly parabolic mirror placed on the roof of a building situated 394 m away from the laboratory. The light is sent back into a second 30 cm Cassegrain telescope. This telescope has been modified so that the output beam is a 5 cm diameter parallel beam. This beam is then focused onto the entrance aperture of the BRUKER IFS120HR fourier transform spectrometer. The two telescopes are mounted on alignment devices and the external mirror is equipped with a driving system operated from the laboratory. The choice of the light source (either a 1000 W high pressure 'ozone free' xenon lamp or a 250 W tungsten filament) and of the detector (either a solar blind UV-diode or a silicon diode) depended on the spectral region studied. These regions lie respectively from 26,000 cm(exp -1) to 30,000 cm(exp -1) (260-380 nm) and from 14,000 cm(exp -1) to 30,000 cm(exp -1) (330-700 nm). The spectra have been recorded at the resolution of 16 cm(exp -1) and with a dispersion of 7.7 cm(exp -1). They have been measured during the forward and the backward movements of the mobile mirror, in double sided mode; each spectrum is an average of 2000 scans. The time required to record a spectrum is about 45 minutes. The shape of the raw spectra in the two investigated regions are represented.

Vandaele, A. C.↗
NASA NTRS1996

Laboratory Measurement of the Temperature Dependence of Gaseous Sulfur Dioxide (SO2) Microwave Absorption with Application to the Venus Atmosphere

High-accuracy laboratory measurements of the temperature dependence of the opacity from gaseous sulfur dioxide (SO2) in a carbon dioxide (CO2) atmosphere at temperatures from 290 to 505 K and at pressures from 1 to 4 atm have been conducted at frequencies of 2.25 GHz (13.3 cm), 8.5 GHz (3.5 cm), and 21.7 GHz (1.4 cm). Based on these absorptivity measurements, a Ben-Reuven (BR) line shape model has been developed that provides a more accurate characterization of the microwave absorption of gaseous S02 in the Venus atmosphere as compared with other formalisms. The developed BR formalism is incorporated into a radiative transfer model. The resulting microwave emission spectrum of Venus is then used to set an upper limit on the disk-averaged abundance of gaseous S02 below the main cloud layer. It is found that gaseous S02 has an upper limit of 150 ppm, which compares well with previous spacecraft in situ measurements and Earth-based radio astronomical observations.

Suleiman, Shady H.↗
NASA NTRS2000

A Compact Airborne System for SO2 and DMS Measurements for Use on Future GTE Missions Aboard the P-3 or DC-8

This project involved the design and construction of a new instrument for airborne measurement of DMS and SO2. The instrument is intended for use on field missions to study the global atmospheric sulfur cycle. The ultimate scientific goal is to provide insight into the mechanisms of atmospheric transport and transformations impacting both natural and anthropogenic sulfur emissions. This report summarizes the progress made to date and the goals for future work on the project. The PI's for this project have recently relocated from the University of Miami to the University of California, Irvine, and a request has been made to transfer remaining funds to UCI. All equipment associated with this project has been transferred to UCI. The instrument design goal was to develop an instrument roughly one quarter the size and weight of currently available airborne instrumentation used for DMS and S02 measurements. Another goal was full automation, to allow unattended operation for the duration of a P-3 or DC-8 flight. The original performance design specifications for the instrument are given.

Saltzman, Eric S.↗
NASA NTRS2001

Dynamics and Evolution of SO2 Gas Condensation Around Prometheus-like Volcanic Plumes on Io as Seen by the Near Infrared Mapping Spectrometer

Near Infrared Mapping Spectrometer data acquired during the I24, 25, and 27 Io's Fly-bys by Galileo are analyzed to map the SO2 frost abundance and granularity. This allows a better understanding of the dynamics and evolution of gas condensation around volcanic plumes. Additional information is contained in the original extended abstract.

Doute, S.↗
NASA NTRS1998

Atomization Energies of SO and SO2; Basis Set Extrapolation Revisted

The addition of tight functions to sulphur and extrapolation to the complete basis set limit are required to obtain accurate atomization energies. Six different extrapolation procedures are tried. The best atomization energies come from the series of basis sets that yield the most consistent results for all extrapolation techniques. In the variable alpha approach, alpha values larger than 4.5 or smaller than 3, appear to suggest that the extrapolation may not be reliable. It does not appear possible to determine a reliable basis set series using only the triple and quadruple zeta based sets. The scalar relativistic effects reduce the atomization of SO and SO2 by 0.34 and 0.81 kcal/mol, respectively, and clearly must be accounted for if a highly accurate atomization energy is to be computed. The magnitude of the core-valence (CV) contribution to the atomization is affected by missing diffuse valence functions. The CV contribution is much more stable if basis set superposition errors are accounted for. A similar study of SF, SF(+), and SF6 shows that the best family of basis sets varies with the nature of the S bonding.

Bauschlicher, Charles W., Jr.↗
NASA NTRS2002

UV photoabsorption cross sections of CO, N2, and SO2 for studies of the ISM and planetary atmospheres

We report high-resolution laboratory measurements of photoabsorption cross sections of CO, N2, and SO2 in the wavelength range 80 to 320 nm. The motivation is to provide the quantitative data that are needed to analyze observations of absorption by, and to model photochemical processes in, the interstellar medium and a number of planetary atmospheres. Because of the high resolution of the spectrometers used, we can minimize distortion of the spectrum that occurs when instrument widths are greater than the widths of spectral features being measured. In many cases, we can determine oscillator strengths of individual rotational lines - a unique feature of our work.

Smith, Peter L.↗
NASA NTRS2003

Io's Thermal Regions and Non-SO2 Spectral Features

Several absorptions have been identified in the Galileo NIMS spectra of Io that are not related to SO2. [1,2]. These absorptions have band centers at 2.97, 3.15, 3.85, and 3.91 microns. There are also broad absorptions in the regions 1-1.3 and 3- 3.4 microns. Patterning noise in wavelength registration, arising from the pushbroom imaging and grating motion of the NIMS instrument have previously inhibited reliable mapping of weak absorptions. Recent improvements in techniques to remove the coherent pattern noise from the NIMS dataset have been made by Soderblom. This greatly improves the signal to noise ratio and enables mapping of weak spectral signatures such as the 3.15 micron absorption on Io.

Smythe, W. D.↗