Species separation in polystyrene shock release evidenced by molecular-dynamics simulations and laser-drive experiments
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The dynamics of laser-driven shock propagation in solid ablator material, along with the concomitant processes of shinethrough and blowoff plasma plume expansion, at conditions relevant to laser-direct-drive fusion are measured using a tabletop system capable of supporting rapid dataset development with significantly higher resolution compared to existing methods. The experimental results are directly compared with current radiation-hydrodynamic simulations using the two-dimensional code . Discrepancies between experiments and simulations are evidenced and attributed to limitation of simulation to account for important processes involved in the solid-to-plasma transition. Published by the American Physical Society 2024
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Length-temperature measurements for several polymers and mixtures for detection of transitions and determination of location and magnitude of expansion coefficient changes
Technique facilitates purification of vaccines and production of immunoadsorption columns exhibiting relatively long stability. Information interests biochemists, medical researchers, and pharmaceutical manufacturers.
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Three large-particle-size monodisperse latexes (3.44, 4.08, and 4.98 micron diameter) were prepared in an automated four-reactor apparatus on the third orbital mission of the 'Columbia' begun on March 22. Comparison with ground-based controls showed that the 4.98 micron-size flight sample was the more uniform; the uniformity at the other two sizes was about the same. The rates of polymerization in microgravity and on earth were the same within experimental error, demonstrating that radical-initiated vinyl addition polymerizations are unaffected by the weightless environment.
The creeping flow of a dilute (0.025 wt%) monodisperse polystyrene/polystyrene Boger fluid through a 4:1:4 axisymmetric contraction/expansion is experimentally observed for a wide range of Deborah numbers. Pressure drop measurements across the orifice plate show a large extra pressure drop that increases monotonically with Deborah number above the value observed for a similar Newtonian fluid at the same flow rate. This enhancement in the dimensionless pressure drop is not associated with the onset of a flow instability, yet it is not predicted by existing steady-state or transient numerical computations with simple dumbbell models. It is conjectured that this extra pressure drop is the result of an additional dissipative contribution to the polymeric stress arising from a stress-conformation hysteresis in the strong non-homogeneous extensional flow near the contraction plane. Such a hysteresis has been independently measured and computed in recent studies of homogeneous transient uniaxial stretching of PS/PS Boger fluids. Flow visualization and velocity field measurements using digital particle image velocimetry (DPIV) show large upstream growth of the corner vortex with increasing Deborah number. At large Deborah numbers, the onset of an elastic instability is observed, first locally as small amplitude fluctuations in the pressure measurements, and then globally as an azimuthal precessing of the upstream corner vortex accompanied by periodic oscillations in the pressure drop across the orifice.
Modeling approach to simulate both mesoscale and microscopic forces acting in a typical AFM experiment is presented. At mesoscale level interaction between the cantilever tip and the sample surface is primarily described by the balance of attractive Van der Waals and repulsive forces. The model of cantilever oscillations is applicable to both non-contact and "tapping" AFM. This model can be farther enhanced to describe nanoparticle manipulation by cantilever. At microscopic level tip contamination and details of tip-surface interaction can be simulated using molecular dynamics approach. Integration of mesoscale model with molecular dynamic model is discussed.
The effect of incorporating an organic linking group, 1,6-bis(trimethoxysilyl)hexane (BTMSH), into the underlying silica structure of a styrene cross-linked silica aerogel is examined. Vinyltrimethoxysilane (VTMS) is used to provide a reactive site on the silica backbone for styrene polymerization. Replacement of up to 88 mol 1 of the silicon from tetramethoxyorthosilicate with silicon derived from BTMSH and VTMS during the making of silica gels improves the elastic behavior in some formulations of the crosslinked aerogels, as evidenced by measurement of the recovered length after compression of samples to 251 strain. This is especially true for some higher density formulations, which recover nearly 100% of their length after compression to 251 strain twice. The compressive modulus of the more elastic monoliths ranged from 0.2 to 3 MPa. Although some of these monoliths had greatly reduced surface areas, changing the solvent used to produce the gels from methanol to ethanol increased the surface area in one instance from 6 to 220 sq m2/g with little affect on the modulus, elastic recovery, porosity, or density.
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