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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Temperature dependence of the photoluminescence polarization of ordered III-V semiconductor alloys

We studied the linear polarization of the photoluminescence (PL) emission of atomically ordered GaInAsP and GaInP alloys with different ordering parameters in the temperature range from 10 to 300 K. The epitaxial layers of these alloys were grown on GaAs and Ge (001) substrates by metal organic vapor phase epitaxy. The polarization of the PL emission propagating along different crystallographic axes depends on the value of biaxial strain in the layer and changes with temperature. We calculated the PL polarization patterns for different propagation directions as a function of biaxial strain using an existing model developed for ternary atomically ordered III-V alloys. Comparing the calculated PL polarization patterns with those obtained experimentally, we separated the variation of the PL polarization due to change of biaxial strain with temperature.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

GDGT cyclization proteins identify the dominant archaeal sources of tetraether lipids in the ocean

Glycerol dibiphytanyl glycerol tetraethers (GDGTs) are distinctive archaeal membrane-spanning lipids with up to eight cyclopentane rings and/or one cyclohexane ring. The number of rings added to the GDGT core structure can vary as a function of environmental conditions, such as changes in growth temperature. This physiological response enables cyclic GDGTs preserved in sediments to be employed as proxies for reconstructing past global and regional temperatures and to provide fundamental insights into ancient climate variability. Yet, confidence in GDGT-based paleotemperature proxies is hindered by uncertainty concerning the archaeal communities contributing to GDGT pools in modern environments and ambiguity in the environmental and physiological factors that affect GDGT cyclization in extant archaea. To properly constrain these uncertainties, a comprehensive understanding of GDGT biosynthesis is required. Here in this paper, we identify 2 GDGT ring synthases, GrsA and GrsB, essential for GDGT ring formation in Sulfolobus acidocaldarius . Both proteins are radical S-adenosylmethionine proteins, indicating that GDGT cyclization occurs through a free radical mechanism. In addition, we demonstrate that GrsA introduces rings specifically at the C-7 position of the core GDGT lipid, while GrsB cyclizes at the C-3 position, suggesting that cyclization patterns are differentially controlled by 2 separate enzymes and potentially influenced by distinct environmental factors. Finally, phylogenetic analyses of the Grs proteins reveal that marine Thaumarchaeota, and not Euryarchaeota, are the dominant source of cyclized GDGTs in open ocean settings, addressing a major source of uncertainty in GDGT-based paleotemperature proxy applications.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Carrier Localization and Spontaneous Formation of Two-Dimensional Polarization Domain in Halide Perovskites

Halide perovskites are known for their rich phase diagram and superior performance in diverse optoelectronics applications. The latter property is often attributed to the long electron-hole recombination time, whose underlying physical mechanism has been a long-standing controversy. In this Letter, we investigate the transport and localization properties of electron and hole carriers in a prototypical halide perovskite (CsPbBr 3 ), through ab initio tight-binding nonadiabatic dynamics approach for large-scale (tens of nm size) supercell calculations, to simulate electron and ion dynamics on the same footing. Here, we found distinct structural, lattice polarization, and electron-phonon coupling properties at low (below 100 K) and high temperatures, consistent with experimental observations. In particular, at low temperature we find spontaneous formation of polar grain boundaries in the nonpolar bulk systems, which result in two-dimensional polarization patterns that serve to localize and separate electrons and holes. We reveal phonon-assisted variable-range hopping mostly responsible for low-temperature transport, and their characteristic frequency correlates with temperature-dependent phonon power spectrum and energy oscillation frequency in nonadiabatic dynamics. We answer the critical questions of long electron-hole recombination lifetime at low temperature and offer the correlation among polarization domains, electron-phonon couplings, and photocarrier dynamics.

Carrier generation & recombination↗
DOE OSTI2010

First-principles Computational Study of Defect Clustering in Solid Solutions of ThO 2 with Trivalent Oxides

The energetics of mixing and defect ordering in solid solutions of fluorite-structured ThO 2 with oxides of trivalent cations (Sc, In, Y, Nd, and La) are investigated by electronic density-functional theory (DFT). Through DFT calculations of structures enumerated by lattice-algebra techniques, we identify the lowest energy patterns for defect clustering for four separate dopant concentrations. The most stable structures are characterized by a repulsive interaction between nearest-neighbor vacancies on the oxygen sublattice. The enthalpies of formation with respect to constituent oxides are positive for all dopants considered, and show a tendency to decrease in magnitude as the size and electronegativity of the trivalent dopant decrease. Due to the small positive formation enthalpies and low oxygen-vacancy binding energy with La dopants, La O 3 -ThO 2 solid solutions are predicted to have relatively high ionic conductivities relative to those for the other aliovalent dopants considered. Our results are compared with those for the more widely studied ZrO 2 and CeO{sub 2} fluorite-structured solid solutions with trivalent cations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Flatbands and Perfect Metal in Trilayer Moiré Graphene

We investigate the electronic structure of a twisted multilayer graphene system forming a moiré pattern. We consider small twist angles separating the graphene sheets and develop a low-energy theory to describe the coupling of Dirac Bloch states close to the K point in each individual plane. Extending beyond the bilayer case, we show that, when the ratio of the consecutive twist angles is rational, a periodicity emerges in quasimomentum space with moiré Bloch bands even when the system does not exhibit a crystalline lattice structure in real space. For a trilayer geometry, we find flatbands in the spectrum at certain rotation angles. Performing a symmetry analysis of the band model for the trilayer, we prove that the system is a perfect metal in the sense that it is gapless at all energies. Furthermore, this striking result originates from the three Dirac cones which can only gap in pairs and produce bands with an infinite connectivity. It also holds quite generally for multilayer graphene with an odd number of planes under the condition of C 2z T symmetry.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Mycorrhizal nutrient acquisition strategies shape tree competition and coexistence dynamics

Mycorrhizal fungi with different nutrient acquisition strategies influence plant species performance and physiology, thereby defining their trophic niche. This might drive resource competition dynamics that cumulatively impact tree species coexistence, but few manipulative experiments have directly tested this. Combining surveys and experiments in a modern coexistence theory framework, we tested how variation in mycorrhizal strategies and nutrient conditions affects plant competitive outcomes. We focused on two genera of co-occurring tree species with different mycorrhizal states: Acer (arbuscular mycorrhizal, AM) and Populus (dual mycorrhizal, but often considered predominantly ectomycorrhizal, EM). The EM and AM fungal responsiveness in Populus species varied with latitude and nitrogen (N) limitation. Host-specific soil microbiome conditioning and inorganic N fertilization combined to qualitatively affect coexistence outcomes. Lower N conditions favoured Populus over Acer trees, and N fertilization reversed this outcome for southern species, aligning with regional-scale forest mycorrhizal transitions. Results from the coexistence experiment also predict competitive exclusion between the tree species pairs, which could arise, in part, from their mycorrhizal differences and is consistent with alternative stable states in dominant forest mycorrhizal strategies. Such bistability appears in natural systems as a bimodal distribution of Populus vs. Acer tree species dominance using long-term forest inventory data. Synthesis: The magnitude and outcome of microbially mediated competition between Populus and Acer depends on soil nutrient availability, which likely relates to their mycorrhizal differentiation. These findings support the importance of mycorrhizal symbioses for contributing to large-scale biogeographical patterns of tree species trophic niche separation across soil resource gradients and bistability in forest mycorrhizal structure.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2011

Separate determination of the amplitude of thermal vibrations and static atomic displacements in titanium carbide by neutron diffraction

The amplitude of thermal (dynamic) atomic vibrations and meansquare static atomic displacements in titanium carbide TiC{sub x} (x = 0.97, 0.88, 0.70) have been separately determined by measuring neutron diffraction patterns at two temperatures (T{sub 1} = 300 K and T{sub 2} = 80 K). The static lattice distortions in stoichiometric titanium carbide are experimentally found to be negligible. In the TiC{sub x} homogeneity range, the amplitude {radical}u{sup 2}{sub dyn} of thermal atomic vibrations significantly increases with a decrease in the carbon concentration. The Debye temperature has been determined for the first time in the TiC{sub x} homogeneity range at both room and liquid-nitrogen temperatures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Smart Refractory Sensors Development for Corrosion and Erosion Monitoring in High Temperature Systems

To optimize the operation and functioning of high temperature systems such as slagging gasifiers, coal boilers and glass/steel melters, it is important to monitor corrosion and erosion of refractory used in such systems. Corrosion test strategies are generally based on continuous gravimetric and chemical reactivity monitoring at operational temperatures (750°-1500°C). Both thermocouples and failure sensors and arrays would be useful to monitor the health of any refractory or coatings in these systems. Many of such type of sensors are installed into the systems through open access ports within the refractory; however, there are some disadvantages of this approach where corrosive/erosive gas and molten materials can penetrate and compromise the system. The current work presents the development and performance demonstration of smart refractory with embedded high temperature sensors such as thermocouples, thermistors, and various spallation/crack monitoring sensors, which may be used within a variety of refractory brick in different high temperature processes and applications. The main feature of this technology is that electroceramic based sensors are embedded into smart refractory without significantly impact to the intrinsic properties of the refractory. This technology circumvents the need to insert an isolated monolithic, stand-alone sensor into the refractory via an access port. This technological approach guarantees the integrity and the chemical stability of the materials used in the sensor fabrication within the harsh environment and does not introduce molten material (such as slag) penetration pathways within the refractory. One interesting and important aspect of this innovation is that these embedded sensors can be used to in situ monitoring processes such as chemical reactions and at the same time give information and a deeper understanding of the corrosion and erosion process of the refractory within the system. As stated above, the objective of our work is to develop high-temperature sensors composed of electroceramic materials that are chemically stable at high temperatures (750°-1500°C) and high pressures (up to 1000 psi) that can be used in monitoring corrosion and erosion process in refractory used in high energy systems. The high-temperature sensors investigated in this work were composed of various oxide composites directly embedded into the refractory oxides. The composites used for this work were synthesized by a mixed-oxide route. Metal oxides were inserted within a matrix material composed of refractory oxides (Al2O3, ZrO2, etc.). The physical and electrical properties were specifically manipulated by altering the level of percolation of the conductive species (metal oxides) within the refractory constituent (refractory oxide). Prior to the development of the high-temperature sensors, the oxides composites developed in this study were sintered up to 1600°C under oxidizing atmosphere in order to investigate densification, microstructural evolution, phase development, and their thermoelectrical performance as a function of the composition. The 4-point DC conductivity measurements were performed between 100°-1500°C. The sensors were fabricated from the composite materials by 3D-printing or screen-printing methods into the refractory brick during the consolidation process. An example of one of these embedded sensors consisted of an electroceramic-based thermocouple fabricated with two separate oxide composite compositions which were patterned to produce a couple within the interior of a refractory matrix. The thermocouple successfully displayed thermoelectric voltage trend (as a function of temperature), and the voltage was 220.0 mV around 1400 °C. Corrosion tests on the refractory embedded sensors were performed. To evaluate corrosion in the refractory brick an in-house glass composition was prepared and pressed into pellets and delivered into a pre-cut cavity in the brick. Corrosion experiments results showed the glass penetrated the brick over a 90 h period, and the penetration of the glass through the brick could be monitored by both an amperometric and voltametric based sensor. With this experiment, it was demonstrated that the embedded sensor could dynamically monitor the corrosion process.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2023

Oxide Semiconductor Sensors for Monitoring Advanced Energy Conversion and Manufacturing Processes at High Temperature

To optimize the operation and functionality of high temperature systems such as slagging gasifiers, coal boilers and glass/steel smelters, it is important to monitor temperature, corrosion and erosion of the refractory used in such systems. Both thermocouple and failure sensors (and arrays of these) would be useful to monitor the health of any refractory or coatings in these systems. Many of such type of sensors are installed into the systems through open access ports within the refractory; however, there are some disadvantages of this approach where corrosive/erosive gas and molten materials can penetrate and compromise the system. The current work presents the development and performance of refractory with embedded high temperature sensors such as thermocouples, thermistors, and various spallation/crack monitoring sensors, which may be used within a variety of refractory brick in different high temperature processes and applications. The objective of our work is to develop high-temperature sensors composed of electroceramic materials that are chemically stable at high temperatures (750°-1500°C) and high pressures (up to 1000 psi) that can be used in monitoring temperature, corrosion and erosion process in refractory used in high energy systems. The high-temperature sensors investigated in this work were composed of various oxide composites directly embedded into the refractory oxides. The composites used for this work were synthesized by a mixed-oxide route. Metal oxides were inserted within a matrix material composed of refractory oxides (Al2O3, ZrO2, etc.). The physical and electrical properties were specifically manipulated by altering the level of percolation of the conductive species (metal oxides) within the refractory constituent (refractory oxide). An example of one of these embedded sensors consisted of an electroceramic-based thermocouple fabricated with two separate oxide composite compositions which were patterned to produce a couple within the interior of a refractory matrix. The thermocouple successfully displayed thermoelectric voltage trend (as a function of temperature), and the voltage was 220.0 mV near 1400 °C. In addition, corrosion tests on the refractory embedded sensors were performed. To evaluate corrosion in the refractory was exposed to high-temperature glass compositions over a 90 h period. The penetration of the glass through the refractory could be monitored by both an amperometric and voltametric based sensor. With this experiment, it was demonstrated that the embedded sensor could dynamically monitor the corrosion process, and thus, provide real-time feedback on both temperature and the refractory health.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2021

Propagation of Cryogenic Thermal Fractures from Unconfined PMMA Boreholes

In cryogenic fracturing, a rock surface exposed to cryogenic fluids undergoes a large thermal gradient, and the resultant local tensile stress overcomes rock strength and initiates fractures. This study investigates the development of cracks generated from the cryogenic treatment of a borehole under no external confining stress on specimens. The experiments were performed on transparent PMMA specimens to observe fracture proliferation around boreholes. Liquid nitrogen was flowed through the boreholes to cool the borehole surface. The results show that initial fracture growth is characterized by abrupt starts and stops, and as the fracture propagates outward, the growth appears more continuous. In an early stage, horizontal/radial fractures and vertical fractures are the defining patterns. Horizontal fractures tend to be separated by a specific exclusion distance (i.e., spacing between cracks). While distinct horizontal/vertical fractures and exclusion distance manifest themselves at an early stage, fractures resulting from fracture interactions and curvatures can develop into complex shapes at later stages. Cryogenic thermal loading induces distinctively curved fractures. The tendency of curvature may prevent greater penetration. An increase in the borehole pressure during liquid nitrogen flow, however, can lessen fracture tortuosity and facilitate radial propagation. A high flow pressure and rate are also advantageous in that they accelerate cooling and fracture propagation.

42 ENGINEERING↗
NASA NTRS1973

Feasibility study of full-reactor gas core demonstration test

Separate studies of nuclear criticality, flow patterns, and thermodynamics for the gas core reactor concept have all given positive indications of its feasibility. However, before serious design for a full scale gas core application can be made, feasibility must be shown for operation with full interaction of the nuclear, thermal, and hydraulic effects. A minimum sized, and hence minimum expense, test arrangement is considered for a full gas core configuration. It is shown that the hydrogen coolant scattering effects dominate the nuclear considerations at elevated temperatures. A cavity diameter of somewhat larger than 4 ft (122 cm) will be needed if temperatures high enough to vaporize uranium are to be achieved.

Kunze, J. F.↗
NASA NTRS1982

Impingement of an oblique shock wave on a cylinder

This paper presents a numerical simulation of impingement of an oblique shock wave on a cylinder. The study was undertaken to understand the three-dimensional shock wave and boundary-layer interactions occurring on problems such as the impingement of the bow shock wave from the Shuttle nose on an external tank, and store-carriage interference on a supersonic tactical aircraft. A thin-layer approximation of the Navier-Stokes equations is solved by a mixed explicit-implicit scheme for a supersonic Mach 4 flow with an incident shock angle of 25 deg. Both laminar and turbulent flows are investigated. Surface pressures show large extents of upstream influence, except near windward plane. Based on plots of velocity at the first mesh points above the cylinder body, a conjectured limiting-streamline pattern is constructed. Three-dimensional separation is studied, and the role of crossflow is discussed.

Hung, C. M.↗
NASA NTRS1982

Cultural and environmental influences on temporal-spectral development patterns of corn and soybeans

A technique for evaluating crop temporal-spectral development patterns is described and applied to the analysis of cropping practices and environmental conditions as they affect reflectance characteristics of corn and soybean canopies. Typical variations in field conditions are shown to exert significant influences on the spectral development patterns, and thereby to affect the separability of the two crops.

Crist, E. P.↗
NASA NTRS1985

Evaluation of existing and proposed computer architectures for future ground-based systems

Parallel processing architectures and techniques used in current supercomputers are described and projections are made of future advances. Presently, the von Neumann sequential processing pattern has been accelerated by having separate I/O processors, interleaved memories, wide memories, independent functional units and pipelining. Recent supercomputers have featured single-input, multiple data stream architectures, which have different processors for performing various operations (vector or pipeline processors). Multiple input, multiple data stream machines have also been developed. Data flow techniques, wherein program instructions are activated only when data are available, are expected to play a large role in future supercomputers, along with increased parallel processor arrays. The enhanced operational speeds are essential for adequately treating data from future spacecraft remote sensing instruments such as the Thematic Mapper.

Schulbach, C.↗
NASA NTRS1991

Multiple shock-shock interference on a cylindrical leading edge

The details of an experimental study of shock wave interference heating on a cylindrical leading edge representative of the cowl of a rectangular hypersonic engine inlet are presented. This Mach 8 study has provided the first detailed pressure and heat transfer rate distributions on a cylinder resulting from a two-dimensional shockwave interference pattern created by two incident oblique shock waves intersecting the cylinder bow shock wave. The peak heat transfer rate was 38 times the undisturbed flow stagnation point level and occurred when the two oblique shock waves coalesced prior to intersecting the cylinder bow shock wave. Development of pressure deflection diagrams identified a new interference pattern consisting of concomitant supersonic jets separated from each other by a shear layer and submerged in the subsonic region between the bow shock wave and body.

Wieting, Allan R.↗
NASA NTRS1992

Ultra high bypass Nacelle aerodynamics inlet flow-through high angle of attack distortion test

A flow-through inlet test program was conducted to evaluate inlet test methods and determine the impact of the fan on inlet separation when operating at large angles of attack. A total of 16 model configurations of approximately 1/6 scale were tested. A comparison of these flow-through results with powered data indicates the presence of the fan increased separation operation 3 degrees to 4 degrees over the flow through inlet. Rods and screens located at the fan face station, that redistribute the flow, achieved simulation of the powered-fan results for separation angle of attack. Concepts to reduce inlet distortion and increase angle of attack capability were also evaluated. Vortex generators located on the inlet surface increased inlet angle of attack capability up to 2 degrees and reduced inlet distortion in the separated region. Finally, a method of simulating the fan/inlet aerodynamic interaction using blockage sizing method has been defined. With this method, a static blockage device used with a flow-through model will approximate the same inlet onset of separation angle of attack and distortion pattern that would be obtained with an inlet model containing a powered fan.

Larkin, Michael J.↗
NASA NTRS1996

Development of Semi-Span Model Test Techniques

A computational investigation was performed to support the development of a semispan model test capability in the NASA Langley Research Center's National Transonic Facility. This capability is desirable for the testing of advanced subsonic transport aircraft at full-scale Reynolds numbers. A state-of-the-art three-dimensional Navier-Stokes solver was used to examine methods to improve the flow over a semi-span configuration. First, a parametric study is conducted to examine the influence of the stand-off height on the flow over the semispan model. It is found that decreasing the stand-off height, below the maximum fuselage radius, improves the aerodynamic characteristics of the semi-span model. Next, active sidewall boundary layer control techniques are examined. Juncture region blowing jets, upstream tangential blowing, and sidewall suction are found to improve the flow over the aft portion of the semispan model. Both upstream blowing and suction are found to reduce the sidewall boundary layer separation. The resulting near surface streamline patterns are improved, and found to be quite similar to the full-span results. Both techniques however adversely affect the pitching moment coefficient.

Milholen, William E., II↗
NASA NTRS1993

Ion mobility spectrometry of hydrazine, monomethylhydrazine, and ammonia in air with 5-nonanone reagent gas

Hydrazine (HZ) and monomethylhydrazine (MMH) in air were monitored continuously using a hand-held ion mobility spectrometer equipped with membrane inlet, 63Ni ion source, acetone reagent gas, and ambient temperature drift tube. Response characteristics included detection limit, 6 ppb; linear range, 10-600 ppb; saturated response, >2 ppm; and stable response after 15-30 min. Ammonia interfered in hydrazines detection through a product ion with the same drift time as that for MMH and HZ. Acetone reagent gas was replaced with 5-nonanone to alter drift times of product ions and separate ammonia from MMH and HZ. Patterns in mobility spectra, ion identifications from mass spectra, and fragmentation cross-sections from collisional-induced dissociations suggest that drift times are governed by ion-cluster equilibria in the drift region of the mobility spectrometer. Practical aspects including calibration, stability, and reproducibility are reported from the use of a hand-held mobility spectrometer on the space shuttle Atlantis during mission STS-37.

Flight Experiment↗