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At least 217 records · Page 12

Refined Analysis of CO2 Emissions in Urban Air Mobility Networks

In this study, we examine the environmental impact of Urban Air Mobility (UAM) operations as measured via carbon dioxide (CO2) emissions by leveraging a computational model from previous studies that has been refined and expanded. Several scenarios are examined in which total transportation emissions for a representative day in a metro area are distributed differently among vehicle types and transportation modes. Specifically, we investigate the use of electric air vehicles in a UAM network; the increasing presence of electric ground vehicles for ground transportation; the impacts from implementing ridesharing in the UAM mode; and the effects of varying the electricity grid emissions. Results for a case study in the Chicago, IL metro area indicate that incorporating electric ground vehicles and UAM ridesharing can both lead to reduced CO2 emissions. These preliminary results indicate that carbon emissions from a UAM system leveraging ridesharing and all-electric aircraft may not be a practical operational limit on UAM, though further improvements to the modeling are warranted.

advanced air mobility↗

Refined Analysis of CO2 Emissions in Urban Air Mobility Networks

In this study, we examine the environmental impact of Urban Air Mobility (UAM) operations as measured via carbon dioxide (CO2) emissions by leveraging a computational model from previous studies that has been refined and expanded. Several scenarios are examined in which total transportation emissions for a representative day in a metro area are distributed differently among vehicle types and transportation modes. Specifically, we investigate the use of electric air vehicles in a UAM network; the increasing presence of electric ground vehicles for ground transportation; the impacts from implementing ridesharing in the UAM mode; and the effects of varying the electricity grid emissions. Results for a case study in the Chicago, IL metro area indicate that incorporating electric ground vehicles and UAM ridesharing can both lead to reduced CO2 emissions. These preliminary results indicate that carbon emissions from a UAM system leveraging ridesharing and all-electric aircraft may not be a practical operational limit on UAM, though further improvements to the modeling are warranted.

advanced air mobility↗

Chevron Natural Gas Carbon Capture Technology Testing Project (Final Technical Report)

The objective of this project was to design, construct, commission, and operate an engineering scale post combustion carbon capture system to validate the technical maturity, operability, and scalability of Svante’s VeloxoTherm™ solid sorbent carbon capture technology under representative flue gas conditions. The project was executed at Chevron’s Kern River oil field in the San Joaquin Valley of California and evaluated carbon capture performance using slipstream flue gas from natural gas fired once through steam generators (OTSG), including indicative coal and natural gas combined cycle (NGCC) operating scenarios.

03 NATURAL GAS↗

High Inlet Temperature Combustor for Direct-Fired Supercritical Oxy-Combustion

It is envisioned that supercritical CO 2 (sCO 2 ) electric power plant efficiencies can exceed 52% with 99% carbon capture using direct-fired oxy-combustion. Such efficiencies would be competitive with Natural Gas Combined Cycles (NGCC) and operate with nearly zero carbon emissions. To achieve high plant efficiencies, turbine inlet conditions must approach 1,200 °C at 250 bar. Such conditions, while desirable from a systems perspective, exceed the current state of the art in turbine design and materials qualification. The team of Southwest Research Institute ® (SwRI ® ), Georgia Institute of Technology (Georgia Tech), Spectral Energies, LLC (Spectral), GE Global Research (GE-GRC), and the University of Central Florida (UCF) sought to demonstrate an intermediate step toward these high efficiency plants with the development of a 1 MWth, subscale direct-fired oxy-fuel combustor. The efforts focused largely on the development of an auto-ignition based combustion system capable of providing the targeted 1200 °C and the pilot-scale plant to operate the combustor. While the project was stopped short of the commissioning and demonstration work, the advances made in this effort will reduce risks associated with chemical kinetics, thermal management, water separation, flue gas cleanup, materials selection, and corrosion in future demonstration efforts for the direct-fired oxy-fuel combustion cycles. The following report documents the design, analysis, and installation efforts completed during the project periods of performance.

03 NATURAL GAS↗

Validation of Carbon Trace Gas Profile Retrievals from the NOAA-Unique Combined Atmospheric Processing System for the Cross-Track Infrared Sounder

This paper provides an overview of the validation of National Oceanic and Atmospheric Administration (NOAA) operational retrievals of atmospheric carbon trace gas profiles, specifically carbon monoxide (CO), methane (CH4) and carbon dioxide (CO2), from the NOAA-Unique Combined Atmospheric Processing System (NUCAPS), a NOAA enterprise algorithm that retrieves atmospheric profile environmental data records (EDRs) under global non-precipitating (clear to partly cloudy) conditions. Vertical information about atmospheric trace gases is obtained from the Cross-track Infrared Sounder (CrIS), an infrared Fourier transform spectrometer that measures high resolution Earth radiance spectra from NOAA operational low earth orbit (LEO) satellites, including the Suomi National Polar-orbiting Partnership (SNPP) and follow-on Joint Polar Satellite System (JPSS) series beginning with NOAA-20. The NUCAPS CO, CH4, and CO2 profile EDRs are rigorously validated in this paper using well-established independent truth datasets, namely total column data from ground-based Total Carbon Column Observing Network (TCCON) sites, and in situ vertical profile data obtained from aircraft and balloon platforms via the NASA Atmospheric Tomography (ATom) mission and NOAA AirCore sampler, respectively. Statistical analyses using these datasets demonstrate that the NUCAPS carbon gas profile EDRs generally meet JPSS Level 1 global performance requirements, with the absolute accuracy and precision of CO 5% and 15%, respectively, in layers where CrIS has vertical sensitivity; CH4 and CO2 product accuracies are both found to be within ±1%, with precisions of ≈1.5% and ⪅0.5%, respectively, throughout the tropospheric column.

satellite cal/val; error analysis; greenhouse gase↗

As assessment of power system vulnerability to release of carbon fibers during commercial aviation accidents

The vulnerability of a power distribution system in Bedford and Lexington, Massachusetts to power outages as a result of exposure to carbon fibers released in a commercial aviation accident in 1993 was examined. Possible crash scenarios at Logan Airport based on current operational data and estimated carbon fiber usage levels were used to predict exposure levels and occurrence probabilities. The analysis predicts a mean time between carbon fiber induced power outages of 2300 years with an expected annual consequence of 0.7 persons losing power. In comparison to historical outage data for the system, this represents a 0.007% increase in outage rate and 0.07% increase in consequence.

Larocque, G. R.↗

ROTA-CAP™: An Intensified Carbon Capture System Using Rotating Packed Beds (Final Scientific/Technical Report)

GTI Energy and Carbon Clean Solutions Limited successfully designed, constructed, and operated an integrated ROTA-CAP carbon capture skid. ROTA-CAP™ is a process intensification technology, applied for post-combustion carbon capture, which utilizes the centrifugal forces generated from rotation of rotating packed beds as well as advanced solvents to achieve increased mass transfer rates 1-2 orders of magnitude higher than conventional columns while substantially decreasing footprint. The test skid, which consisted of a dual stage RPB absorber with external interstage cooling and a single stage RPB regenerator, was operated at capacities up to 0.5 tonne/day of CO 2 capture with flue gas concentrations ranging from 4% to 22% CO 2 by vol. CO 2 removal rates greater than 95% were achieved, with CO 2 product purity also exceeding 95% by vol. Over 1,600 hours of operation were accumulated throughout the project, including over 1,000 hours of operation of the with real flue gas containing at least 9.8% CO 2 by vol. The skid was operated continuously for 24 hours per day and 7 days per week over the course of 7 long-term test campaigns, with the campaigns ranging from approximately 2-4 weeks per campaign. A techno-economic analysis was performed, and a cost of capture of $\$$41.18/tonne CO 2 was calculated for the ROTA-CAP process, compared to $\$$45.75/tonne for a Cansolv-based process. These results show a cost reduction of approximately 10% compared to the Cansolv-based process. Although this still exceeds the target cost of capture of $\$$30/tonne specified for this project, GTI expects that the cost of capture can be further reduced through further optimization of the design and technology. GTI also performed an engineering design review to determine the scale-up potential of the technology, with the results of the preliminary assessment indicating that it appears to be feasible to scale up the RPB technology to 4,000 TPD. It was also determined that both horizontal and vertical rotor orientations are feasible, though there are mechanical advantages to the vertical orientation.

20 FOSSIL-FUELED POWER PLANTS↗

Performance comparisons of Navy jet mix and MIL-F-5624A (JP-3) fuels in tubular and annular combustors / Richard J. McCafferty

The performances of Navy Jet Mix and MIL-F-5624A (JP-3) fuels were compared in J33, J47, and NACA experimental annular combustion chambers. Combustion efficiencies, altitude operational limits, and carbon-forming tendencies wer determined and discussed. The results indicate that Jet Mix fuel can be utilized satisfactorily in a number of current turbojet engines over the normal operating range. Small differences in combustion efficiences and altitude operational limits existed between the two fuels but these differences depended on the particular combustor and simulated altitude and rotor speed condition. Excessive carbon deposition is not predicted for Jet Mix fuel, although this property may be marginal.

Mccafferty, Richard J↗

Economic and Jobs Impacts of Point-Source Carbon Capture in Cement Industry – Case Study

The cement industry accounts for an estimated 8% of global CO2 emissions, which surpasses that of the entire aviation sector. In contrast with other industries, where CO2 emissions can be drastically reduced via electrification or fuels substitution, cement production releases CO2 as part of its process, during the calcination of carbonates to yield oxides. Thus, point-source carbon capture has become a key technology in the cement industry’s decarbonization. Apart from the expected environmental benefits, point-source carbon capture in the cement industry can yield important economic benefits and create jobs. The objective of this study was to perform a preliminary assessment of the economic and workforce impacts associated with the construction and operation of a point-source carbon capture retrofit of an existing cement production facility, using as a basis the data from a front-end engineering design (FEED) study to install a 3.9 million metric tons per year (Mtpy) CO2 capture facility at Holcim Ste Genevieve cement plant in Missouri, United States of America. The advanced carbon capture technology used in this FEED study was Air Liquide’s Cryocap™ FG carbon capture technology. The study evaluated the direct, indirect, and induced economic impacts of the construction, operation, and maintenance activities of the project over its lifespan. It also covered how the project will generate new jobs, their nature, and quantity, along with strategies to prepare the workforce. To perform this study, construction, operation, and maintenance cost estimates, as well as construction and operation staffing plans from the FEED study were input into IMPLAN version 7.5 software, licensed by IMPLAN Group LLC (Huntersville, VC), to predict the direct, indirect and induced economic impacts of the project using industry multipliers from the software. Additionally, recruitment strategies were developed for hiring individuals who belong to groups that are historically underserved or underrepresented, as well as anticipated recruitment of workers from the local community (whether training will be required or if the skills are associated with an existing labor force). The analysis estimated that the construction and operation of the carbon capture at Holcim Ste. Genevive will result in over 24 thousand work-years of job opportunities, close to USD 10 billion of economic impacts, including over USD 460 million of tax revenue. These results encompass the direct, indirect, and induced effects. A strategy to maximize hiring from the project and neighboring counties was developed, leveraging training agreements with local trade groups and universities. The result of this study can be used for a strategic preliminary assessment of the potential regional economic and job impacts of retrofitting existing cement plants with point source carbon systems, and its methodology can be replicated to individual projects to aid in planning and workforce development.

01 COAL, LIGNITE, AND PEAT↗

A Review of Well Integrity Based on Field Experience at Carbon Utilization and Storage Sites

Maintaining well integrity is critical to the success of geologic carbon storage (GCS) and carbon dioxide enhanced oil recovery (CO 2 -EOR) operations. Wells that experience leakage because of integrity issues can potentially become a risk to the environment or human health if they release previously captured CO 2 back into the atmosphere or into freshwater aquifers. There are many GCS and CO 2 -EOR sites in operation around the world. However, well integrity experiences at these sites are not widely documented in the public domain. This study details findings from a survey of well integrity experiences elicited from operators of GCS and CO 2 -EOR sites. The goal of the survey was to obtain information about site characteristics and operator experiences with well integrity, monitoring methods, and risk assessment of legacy wells. Literature relevant to the survey questions was also reviewed and summarized to provide context for survey responses and identify areas where field experiences with well integrity do and do not align with the current state of research. We highlight the current state-of-practice, identify research needs, and provide context for future interactions between researchers, operators, and regulators on issues related to well integrity.

54 ENVIRONMENTAL SCIENCES↗

Abatement cost curve analysis of freight rail decarbonization alternatives

This paper investigates decarbonization alternatives for the freight rail industry, considering economic, environmental, and operational aspects. The study compares battery-electric and hydrogen fuel cell locomotives, drop-in fuels including biofuels and e-fuels, and overhead catenary electrification through abatement cost analyses. Scenario analysis identifies the cost-effectiveness of each of the technologies at different stages of decarbonization in the US Class 1 freight railroad network. We show that though battery locomotives offer a lower-cost decarbonization option in the considered scenarios, green hydrogen fuel-powered locomotives become more attractive when battery charging delays are considered. We introduce the concept of the technology margin to cater for uncertainties in battery charging operations and hydrogen fuel production for cases where carbon taxes are imposed on railroad operations. In conclusion, the study provides valuable insights for policymakers and rail operators, contributing to sustainable freight rail operations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Assessment of risk to Boeing commerical transport aircraft from carbon fibers

The possible effects of free carbon fibers on aircraft avionic equipment operation, removal costs, and safety were investigated. Possible carbon fiber flow paths, flow rates, and transfer functions into the Boeing 707, 727, 737, 747 aircraft and potentially vulnerable equipment were identified. Probabilities of equipment removal and probabilities of aircraft exposure to carbon fiber were derived.

Clarke, C. A.↗

Techno-economic life cycle assessment of CO 2 -EOR operations towards net negative emissions at farnsworth field unit

Optimizations of CO 2 Water Alternating Gas(WAG)- systems with multi-objectives of incremental recovery and maximization of CO 2 storage are challenging. Here, the incorporation of a total Greenhouse gas (GHG) life cycle assessment is mostly ignored leading to inaccurate estimation of overall net carbon emissions of their operations. In this study, the effect of a total GHG life cycle assessment on a multi-objective CO 2 -WAG optimization with integrated techno-economic assessment (TEA) which factors carbon tax credit is conducted. A life cycle assessment (LCA) was conducted utilizing a 20 -year optimized post history matched data from a high fidelity reservoir simulation model. Using data generated from the optimum result, a techno-economic life cycle analysis was further conducted. The first scenario classified as the base model had an estimated 81% of purchased CO 2 sequestered. The results through a comprehensive techno-economic LCA model yielded a net estimate of 73% of purchased CO 2 . The optimized forecasted model which considered key operational and reservoir factors such as WAG ratio, injection rates and periods, and well specification resulted in an improved sequestration of 92% of purchased CO 2 . However, this also dropped to 84% after taking it through LCA. These results clearly indicate a significant amount of net CO 2 is not accounted for when operations are not analyzed through LCA. From the LCA, direct flaring volumes of CO 2 , energy consumption and efficiency of unit equipment were noticed to be the major causes of these reductions. Considering ten main sources of energy as source of energy generation, a comparative techno-eco LCA was conducted. The results confirmed a lower net volume and NPV for energy sources with higher carbon footprints and vice versa. Thus, a total LCA of CO 2 -WAG greatly influences net storage factor of purchased CO 2 and hence project NPV where tax credit/incentives per ton of CO 2 sequestered is considered. Although operational conditions are optimized for best results, there are significant factors that leads to minimization of net storage factor. This study therefore provides an insightful information for optimizing CO 2 -WAG multi-objectives to achieve minimum GHG emission.

02 PETROLEUM↗

Optical Characterization of Component Wear and Near-Field Plasma of the Hermes Thruster

Optical emission spectral (OES) data are presented which correlate trends in sputtered species and the near-field plasma with the Hall-Effect Rocket with Magnetic Shielding (HERMeS) thruster operating condition. The relative density of singly-ionized xenon (Xe II) is estimated using a collisional-radiative model. OES data were collected at three radial and several axial locations downstream of the thruster's exit plane. These data were deconvolved to show the structure for the near-field plasma as a function of thruster operating condition. The magnetic field is shown to have a much greater affect on plasma structure than the discharge voltage with the primary ionization/acceleration zone boundary being similar for all nominal operating voltages at constant power. OES measurement of sputtered boron shows that the HERMeS thruster is magnetically shielded across its operating envelope. Preliminary assessment of carbon sputtered from the keeper face suggest it increases significantly with operating voltage, but the uncertainty associated with these measurements is very high.

Electric Propulsion↗

Pistons and Cylinders Made of Carbon-Carbon Composite Materials

An improved reciprocating internal combustion engine has a plurality of engine pistons, which are fabricated from carbon-carbon composite materials, in operative association with an engine cylinder block, or an engine cylinder tube, or an engine cylinder jug, all of which are also fabricated from carbon-carbon composite materials.

Rivers, H. Kevin↗

Pistons and Cylinders Made of Carbon-Carbon Composite Materials

An improved reciprocating internal combustion engine has a plurality of engine pistons, which are fabricated from carbon---carbon composite materials, in operative association with an engine cylinder block, or an engine cylinder tube, or an engine cylinder jug, all of which are also fabricated from carbon-carbon composite materials.

H. Kevin Rivers↗

A study of Sabatier reactor operation in zero 'G'

The results of zero-g computer model simulation of the operation of a Sabatier reactor, which relies on the effects of buoyant forces, are presented. The reactor was also operated in an experiment with inlet flow rates of carbon dioxide that correspond to continuous operation of the reactor at three, five, eight, and ten-man loading conditions; the three and five-man conditions are noted to be within the design capabilities of the reactor. The loss of carbon dioxide conversion predicted by the model for zero-g environment is noted to be substantial, ranging from 12 to 18.2 percent for five-man to ten-man loading. The simulated normal-gravity values are within 0.9 percent of the experimental conversions. Finally, the results indicate a much hotter operation of the reactor in zero-g due to the loss of natural convective cooling effect.

Forsythe, R. K.↗

The GeoCarb Mission: One Tool in the Evolving Understanding of Methane and Carbon Monoxide Budgets

NASA plans to operate an instrument in geostationary orbit over the Americas beginning in 2022. This mission allows a coordinated study of climate-determining carbon species. Prime focus is on CO2 fluxes, but the reactive species CO and CH4 are particularly relevant to IGAC. Measurements of solar-induced fluorescence will describe plant photosynthesis contemporaneous with emissions. To outline the technology: Grating mapping spectrometery, using a single slit and four focal planes set at 0.76, 1.60, 2.07, and 2.32 microns and ~17000 resolving power. Retrieval profiting from the rich heritage of OCO-2, GOSAT, TropOMI, and GOME/SCIAMACHY. Column concentrations of CO2, CH4, and CO, with finest resolution at 3 km x 6 km. A selection of scans allowing appreciable refinement in fluxes of CO2 and CH4. Rapid re-pointing allowing at least one synoptic observation of all North and South America daily, and 3 observations through the day for selected areas.This presentation is an appeal to IGAC community to use GeoCarb to help improve the attribution of fluxes by sector and by geography. Cost constraints allow GeoCarb only limited listed goals. For example, GeoCarb aspires to constrain CH4 emissions for the whole US, closing the ~60% gap between US EPA estimation and 3-d models. Detailed CO measurements should also aid photochemical and aerosol studies. NASA's TEMPO (UV-Vis geostationary) instrument will overlap GeoCarb. Consequently, HCHO, NO2, aerosol, and CO may be intercompared, allowing elucidation of chemical sources and also transformation timescales. We expect that Sentinel-5P's TropOMI will lead the way here; geostationary imaging will allow diurnal views and reduced cloud obscuration of interesting areas. Analysis of current data suggests interesting questions: (a) puzzling XCH4 diel variations in the Amazonian rainforest; (b) time-varying CO/NO2 relationships in urban plumes. We also urge the suite of airborne and small-sat measurements needed to complete the story at fine scales.

Chatfield, Robert B.↗