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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Screening Metal Halide Perovskite Solar Modules for Premature Field Failures

Developing metal halide perovskite (MHP) photovoltaic (PV) devices into reliable large-area solar modules could accelerate global solar energy deployment. Many MHP devices are susceptible to degradation under light and elevated temperature (LT). Published research on LT testing is limited at the module level, and LT testing has not yet been developed for qualification testing of commercial PV products. This report assesses whether results of LT testing at moderately elevated temperatures correlate with those of field-tested modules from the same batch. Six batches of samples from four manufacturers are assessed. It is shown that modules with a robust package that can maintain over 80% of their peak efficiency during LT testing at 55 °C for 100 h are more likely to retain over 80% of their peak efficiency during outdoor operation for 10 weeks. This finding is a step towards developing a validated test protocol that could be incorporated into a qualification standard for the commercialization of MHP PV technologies.

14 SOLAR ENERGY↗
NASA NTRS1978

Graphite-fiber-reinforced polyimide liners of various compositions in plain spherical bearings

Composites made of graphite-fiber-reinforced polyimide (GFRPI) with a fiber-resin ratio (by weight) of about 1 were evaluated as molded outer-race liners in plain spherical bearings. Several compositions were examined: two types of polyimide (addition and condensation polymers), two types of graphite fiber (high and low modulus) and four powder additives (CdO, CdI2, (CF1.1)n, and MoS2). Friction and wear were measured during oscillation at 25, 200, and 315 C. It is shown that all compositions provided good lubrication in dry air, that neither type of polyimide or graphite fiber nor the additives gave a clear advantage, and that wear rates were always higher during run-in, before conditions stabilized. It is concluded that GFRPI composites are self-lubricating under all but the most extreme moisture-free conditions at 25 C. The additives are helpful only with very high loads or extremely dry environments.

Sliney, H. E.↗
NASA NTRS2021

Evidence that Horizontal Moisture Advection Regulates the Ubiquitous Amplification of Rainfall Variability over Tropical Oceans

The column moist static energy (MSE) budget equation approximates the processes associated with column moistening and drying in the tropics, and is therefore predictive of precipitation amplification and decay. We use ERA-Interim (ERA-I) and TRMM 3B42 data to investigate day-to-day convective variability and distinguish the roles of horizontal MSE (or moisture) advection versus vertical advection, sources, and sinks. Over tropical convergence zones, results suggest that horizontal moisture advection is a primary driver of day-to-day precipitation fluctuations; when drying via horizontal moisture advection is smaller (greater) than Chikira’s “column process,” precipitation tends to amplify (decay). In the absence of horizontal moisture advection, precipitation tends to increase spontaneously almost universally through a positive column process feedback. This bulk positive feedback is characterized by negative effective gross moist stability (GMS), which is maintained throughout the tropical convergence zones. How this positive feedback is achieved varies geographically, depending on the shape of vertical velocity (omega) profiles. In regions where omega profiles are top-heavy, the effective GMS is negative primarily owing to strong feedbacks between convection and diabatic MSE sources (radiative and surface fluxes). In these regions, vertical MSE advection stabilizes the atmosphere (positive vertical GMS). Where omega profiles are bottom-heavy, by contrast, a positive feedback is primarily driven by import of MSE through a shallow circulation (negative vertical GMS). The diabatic feedback and vertical GMS are in a seesaw balance, offsetting one another. Our results suggest that ubiquitous convective variability is amplified by the same mechanism as moisture-mode instability.

horizontal moisture advection↗
NASA NTRS2012

Moisture Fluxes Derived from EOS Aqua Satellite Data for the North Water Polynya Over 2003-2009

Satellite data were applied to calculate the moisture flux from the North Water polynya during a series of events spanning 2003-2009. The fluxes were calculated using bulk aerodynamic formulas with the stability effects according to the Monin-Obukhov similarity theory. Input parameters were taken from three sources: air relative humidity, air temperature, and surface temperature from the Atmospheric Infrared Sounder (AIRS) onboard NASA's Earth Observing System (EOS) Aqua satellite, sea ice concentration from the Advanced Microwave Scanning Radiometer (AMSR-E, also onboard Aqua), and wind speed from the ECMWF ERA-Interim reanalysis. Our results show the progression of the moisture fluxes from the polynya during each event, as well as their atmospheric effects after the polynya has closed up. These results were compared to results from studies on other polynyas, and fall within one standard deviation of the moisture flux estimates from these studies. Although the estimated moisture fluxes over the entire study region from AIRS are smaller in magnitude than ERA-Interim, they are more accurate due to improved temperature and relative humidity profiles and ice concentration estimates over the polynya. Error estimates were calculated to be 5.56 x10(exp -3) g/sq. m/ s, only 25% of the total moisture flux, thus suggesting that AIRS and AMSR-E can be used with confidence to study smaller scale features in the Arctic sea ice pack and can capture their atmospheric effects. These findings bode well for larger-scale studies of moisture fluxes over the entire Arctic Ocean and the thinning ice pack.

Boisvert, Linette N.↗
NASA NTRS1984

Delineating mid- and low-level water vapor patterns in pre-convective environments using VAS moisture channels

Infrared and visible imagery from VAS are used to delineate mid- and lower-tropospheric moisture fields for a variety of severe storm cases in the southern and central United States. The ability of sequences of images to isolate areas of large negative vertical moisture gradients and apparent convective instability prior to the onset of convective storms is assessed. A variety of image combination procedures are used to deduce the stability fields which are then compared with the available radiosonde data. The results for several severe storm cases indicate that VAS can detect mid- and low-level mesoscale water vapor fields as distinct radiometric signals. The VAS imagery shows a strong tendency for thunderstorms to develop along the edges of bands of midlevel dryness as they overtake either preexisting or developing low-level moisture maxima. Image sequences depict the speed with which deep moist and dry layers can develop and move.

Petersen, R. A.↗
NASA NTRS1981

Thermal expansion of composites: Methods and results

The factors controlling the dimensional stability of various components of large space structures were investigated. Cyclic, thermal and mechanical loading were identified as the primary controlling factors of the dimensional stability of cables. For organic matrix composites, such as graphite-epoxy, it was found that these factors include moisture desorption in the space environment, thermal expansion as the structure moves from the sunlight to shadow in its orbit, mechanical loading, and microyielding of the material caused by microcracking of the matrix material. The major focus was placed on the thermal expansion of composites and in particular the development and testing of a method for its measurement.

Bowles, D. E.↗
NASA NTRS1990

Effect of hydrogen on the strength and microstructure of selected ceramics

Ceramics in monolithic form and as composite constituents in the form of fibers, matrices, and coatings are currently being considered for a variety of high-temperature applications in aeronautics and space. Many of these applications involve exposure to a hydrogen-containing environment. The compatibility of selected ceramics in gaseous high-temperature hydrogen is assessed. Environmental stability regimes for the long term use of ceramic materials are defined by the parameters of temperature, pressure, and moisture content. Thermodynamically predicted reactions between hydrogen and several monolithic ceramics are compared with actual performance in a controlled environment. Morphology of hydrogen attack and the corresponding strength degradation is reported for silicon carbide, silicon nitride, alumina, magnesia, and mullite.

Herbell, Thomas P.↗
NASA NTRS1991

Effect of hydrogen on the strength and microstructure of selected ceramics

Ceramics in monolithic form and as composite constituents in the form of fibers, matrices, and coatings are currently being considered for a variety of high-temperature applications in aeronautics and space. Many of these applications involve exposure to a hydrogen-containing environment. The compatibility of selected ceramics in gaseous high-temperature hydrogen is assessed. Environmental stability regimes for the long term use of ceramic materials are defined by the parameters of temperature, pressure, and moisture content. Thermodynamically predicted reactions between hydrogen and several monolithic ceramics are compared with actual performance in a controlled environment. Morphology of hydrogen attack and the corresponding strength degradation is reported for silicon carbide, silicon nitride, alumina, magnesia, and mullite.

Herbell, Thomas P.↗
NASA NTRS2009

Dynamics and Predictability of Hurricane Humberto (2007) Revealed from Ensemble Analysis and Forecasting

This study uses short-range ensemble forecasts initialized with an Ensemble-Kalman filter to study the dynamics and predictability of Hurricane Humberto, which made landfall along the Texas coast in 2007. Statistical correlation is used to determine why some ensemble members strengthen the incipient low into a hurricane and others do not. It is found that deep moisture and high convective available potential energy (CAPE) are two of the most important factors for the genesis of Humberto. Variations in CAPE result in as much difference (ensemble spread) in the final hurricane intensity as do variations in deep moisture. CAPE differences here are related to the interaction between the cyclone and a nearby front, which tends to stabilize the lower troposphere in the vicinity of the circulation center. This subsequently weakens convection and slows genesis. Eventually the wind-induced surface heat exchange mechanism and differences in landfall time result in even larger ensemble spread. 1

Sippel, Jason A.↗
DOE OSTI2025

From Structured Solvents to Hybrid Materials (SS2HM) for Chemically Selective Capture and Electromagnetic Release of CO 2 : Mechanisms, Stability and Interfaces (Final Report)

The goal of this research program was to develop high capacity sorbents amenable for alternative regeneration approaches for direct air capture (DAC) of CO 2 . In particular, the research aimed to develop an understanding of CO 2 binding mechanism, thermal and oxidative stability, and regeneration energetics of functionalized ionic liquids (ILs), deep eutectic solvents (DESs), and porous materials. ILs and DESs are high-dielectric solvents with structural tunability that permits the rational-design for energy-efficient regeneration approaches based on electromagnetic (EM) field and moisture-swing. By further incorporating these solvents into polymeric capsules and other structural supports, multi-scale interfaces for targeted CO 2 and energy transfers were achieved. Aspects related to CO 2 capacity, selectivity, stability, dielectric properties, and binding energies were examined through experimental and computational design to identify molecular descriptors to inform future design of structured solvents and hybrid materials for DAC. Enclosed final report details the key findings, science advancements, and workforce development efforts from this project.

36 MATERIALS SCIENCE↗
NASA NTRS1975

The Severe Storms Observation Satellite /SSOS/

The objective of the Severe Storms Observation Satellite (SSOS) is to continuously observe meteorological phenomena from geosynchronous altitude and to acquire data whose analysis will lead to a better understanding, early detection, and prediction of severe storms and other significant mesoscale events such as dust storms. Details are discussed as to the Advanced Atmospheric Sounding and Imaging Radiometer designed for SSOS, the use of a special spacecraft for an R&D mission, data acquisition, and data processing and analysis. The required accurate vertical temperature and moisture profiles as well as high temporal and spatial resolution images can best be obtained by a three-axis stabilized system, which offers approximately an order of magnitude sensing improvement over a comparable spinning system due to its capability to continuously view the earth. A block diagram of the severe storm analysis system is included.

Shenk, W. E.↗
DOE OSTI2022

Conversion of Phenolic Oil from Biomass Pyrolysis into Phenyl Esters

Bio-oil is among the most economical approaches for advanced biofuel production. However, bio-oil faces several challenges including high acidity and viscosity, poor storage, and thermal stability. This study focuses on the upgradation of lignocellulosic (corn stover and yellow pine) bio-oil derived phenolic oil (PO), produced by the autothermal fast pyrolysis, through acid-catalyzed esterification reaction. Our strategy exploits a little recognized chemistry: the Fischer esterification of PO and carboxylic acids into carboxylic acid phenyl esters (CAPE) using Dean Stark distillation. Analyses by the Folin–Ciocalteu method, Karl Fischer titration, gas chromatography flame ionization detector, and the molecular weight determination by gel permeation chromatography suggest the conversion of 50 wt% added phenolics to their corresponding CAPE. The Fourier transform infrared spectroscopy analysis confirmed the formation of new C=O and two C–O stretching bands and decrease in the intensity of phenolic-OH bands in the CAPE. The 13 C NMR analysis supports the formation of CAPE together with some unreacted precursors. A base-catalyzed ester hydrolysis experiment and mass balance calculation show an excellent agreement (within 5% range) of the equivalent weight between the produced ester and the phenyl hexanoate. Brookfield analysis indicates that CAPE has 330-fold lower viscosity than starting PO. Heating values of CAPE were higher than PO, from which they were derived (42.2 and 43.6%, respectively, for PO from pyrolysis of corn stover and yellow pine), while moisture content decreased by 98.3 and 98.7%, respectively. The CAPE, which is a phenolic analogue of methyl esters used in biodiesel, has improved stability compared to PO from which it was derived.

42 ENGINEERING↗
DOE OSTI2025

Crystal Growth Scale-Up and Stability of RbSr 2 X 5 :Eu Scintillators

The discovery and development of new scintillation materials support national security needs. In these applications, large volumes of scintillator crystals are needed to achieve efficient screening for contraband. Therefore, one important step in the discovery of new scintillator compositions is testing their feasibility for scale-up and their stability. In this work, high-quality Ø22 mm crystals of two new scintillators RbSr 2 Br 5 :Eu and RbSr 2 I 5 :Eu were grown via the Vertical Bridgman method, and their scintillation properties were characterized. Here, the Ø22 mm RbSr 2 I 5 :Eu crystals could be grown with fast translation rates up to 3.5 mm/h. Both RbSr 2 Br 5 :Eu and RbSr 2 I 5 :Eu had high scintillation performance, including light yields of 46,000 and 61,000 ph/MeV, respectively, for Ø22 × 35 mm crystals. Additionally, properties related to physical stability were investigated, including the coefficients of thermal expansion via high-temperature X-ray diffraction (HTXRD) as well as moisture sensitivity. HTXRD confirmed the absence of solid–solid phase transitions and showed that RbSr 2 Br 5 had minimal thermal expansion anisotropy compared to RbSr 2 I 5 and some other inorganic metal halide scintillators, which favors the growth of large-sized crystals.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Quantifying Dynamic Water Storage in Unsaturated Bedrock with Borehole Nuclear Magnetic Resonance

Quantifying the volume of water that is stored in the subsurface is critical to studies of water availability to ecosystems, slope stability, and water-rock interactions. In a variety of settings, water is stored in fractured and weathered bedrock as rock moisture. However, few techniques are available to measure rock moisture in unsaturated rock, making direct estimates of water storage dynamics difficult to obtain. Here, we use borehole nuclear magnetic resonance (NMR) at two sites in seasonally dry California to quantify dynamic rock moisture storage. Additionally, we show strong agreement between NMR estimates of dynamic storage and estimates derived from neutron logging and mass balance techniques. The depths of dynamic storage are up to 9 m and likely reflect the depth extent of root water uptake. To our knowledge, these data are the first to quantify the volume and depths of dynamic water storage in the bedrock vadose zone via NMR.

58 GEOSCIENCES↗
DOE OSTI2024

Improving Low‐Cloud Fraction Prediction Through Machine Learning

Abstract In this study, we evaluated the performance of machine learning (ML) models (XGBoost) in predicting low‐cloud fraction (LCF), compared to two generations of the community atmospheric model (CAM5 and CAM6) and ERA5 reanalysis data, each having a different cloud scheme. ML models show a substantial enhancement in predicting LCF regarding root mean squared errors and correlation coefficients. The good performance is consistent across the full spectrums of atmospheric stability and large‐scale vertical velocity. Employing an explainable ML approach, we revealed the importance of including the amount of available moisture in ML models for representing spatiotemporal variations in LCF in the midlatitudes. Also, ML models demonstrated marked improvement in capturing the LCF variations during the stratocumulus‐to‐cumulus transition (SCT). This study suggests ML models' great potential to address the longstanding issues of “too few” low clouds and “too rapid” SCT in global climate models.

Geology↗
DOE OSTI2020

Analysis of the Impurity MgOHCl in Molten Chloride Salts Toward its Electrochemical Removal from CSP Plants During Operation

The work presented here is a study of the impurity MgOHCl in molten chloride salts, toward the eventual goal of electrochemically removing it from operational molten-chloride-based concentrating solar power (CSP) plants.1,2 Implementation of molten chloride salts as a heat transfer fluid is among the most promising pathways for decreasing the levelized cost of energy (LCOE) of CSP systems because its high thermal stability allows higher operating temperatures, and thus, greater efficiency. However, this impurity - formed when MgCl2 salts are exposed to air and moisture - cause significant corrosion of containment alloys.1 Therefore, we have developed and validated in a laboratory setting: 1) a method for the formation of MgOHCl for controlled impurity spike in molten salt for its further sensing, evaluation, and reduction; 2) evaluated its diffusion in the molten salt, and 3) began assessing its electrochemical properties. Our findings allow us to propose solutions for efficiently and instantly removing MgOHCl from an operational CSP plant.

concentrated solar power↗
NASA NTRS2011

NASA Soil Moisture Active Passive (SMAP) Mission Formulation

The Soil Moisture Active Passive (SMAP) Mission is one of the first Earth observation satellites being formulated by NASA in response to the 2007 National Research Council s Earth Science Decadal Survey [1]. SMAP s measurement objectives are high-resolution global measurements of near-surface soil moisture and its freeze-thaw state. These measurements would allow significantly improved estimates of water, energy and carbon transfers between the land and atmosphere. The soil moisture control of these fluxes is a key factor in the performance of atmospheric models used for weather forecasts and climate projections. Soil moisture measurements are also of great importance in assessing flooding and monitoring drought. Knowledge gained from SMAP s planned observations can help mitigate these natural hazards, resulting in potentially great economic and societal benefits. SMAP measurements would also yield high resolution spatial and temporal mapping of the frozen or thawed condition of the surface soil and vegetation. Observations of soil moisture and freeze/thaw timing over the boreal latitudes will contribute to reducing a major uncertainty in quantifying the global carbon balance and help resolve an apparent missing carbon sink over land. The SMAP mission would utilize an L-band radar and radiometer sharing a rotating 6-meter mesh reflector antenna (see Figure 1) [2]. The radar and radiometer instruments would be carried onboard a 3-axis stabilized spacecraft in a 680 km polar orbit with an 8-day repeating ground track. The instruments are planned to provide high-resolution and high-accuracy global maps of soil moisture at 10 km resolution and freeze/thaw at 3 km resolution, every two to three days (see Table 1 for a list of science data products). The mission is adopting a number of approaches to identify and mitigate potential terrestrial radio frequency interference (RFI). These approaches are being incorporated into the radiometer and radar flight hardware and ground processing designs.

Entekhabi, Dara↗
DOE OSTI2023

Effect of the Molecular Structure of Surface Vanadia on Activity and Regenerability of VO $x$ /In 2 O 3 Catalysts for CO 2 -Assisted Oxidative Dehydrogenation of Propane

Our recent work has reported that higher propylene selectivity and improved stability can be achieved by combining redox-active VO $x$ and basic In 2 O 3 for CO 2 -assisted oxidative dehydrogenation of propane (CO 2 -ODHP). In the present work, we continued to explore the stability and regenerability of V/In catalysts. In particular, our interest lies in identifying the effect of mono- and polyvanadate on catalytic performance and regenerability. A V/In catalyst with an increased proportion of monovanadate was prepared using the Schlenk line under moisture-free conditions (V/In–S), while the fully polymerized vanadate catalyst was prepared through a regular impregnation (V/In) for comparison. The Schlenk-line-prepared catalyst, namely, V/In–S, not only exhibits a 17–30% enhanced propylene yield at high temperatures (500–540 °C) over V/In but also presents improved stability and regenerability with nearly 88% activity recovered after regeneration in O 2 . Detailed characterizations have been performed to reveal the catalyst structure–performance relationship, including chemisorption (NH 3 /CO 2 -temperature-programmed desorption, NH 3 /CO 2 -TPD), H 2 -temperature-programmed reduction (H 2 -TPR), and spectroscopic studies [Raman spectroscopy, UV–vis diffuse reflectance spectroscopy (UV–vis DRS), near-ambient-pressure X-ray photoelectron spectroscopy (NAP-XPS), and high-sensitivity low-energy ion scattering (HS-LEIS)]. Characterization results demonstrate that compared with polyvanadates, monovanadates lead to strengthened interaction with In 2 O 3 and a more stabilized V/In surface and subsurface, as well as improved redox properties of VO $x$ . These advantages give rise to the observed enhancement in activity, stability, and regenerability. In conclusion, these findings advance the understanding of the relationship between the activity/stability and the molecular structure of surface oxide species (vanadia) and the interplay between acid–base interactions and redox properties of mixed metal-oxide catalysts for efficient CO 2 -ODHP.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗