Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “ions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Helium Ion Microscopy with Secondary Ion Mass Spectrometry for Nanoscale Chemical Imaging and Analysis of Polyolefins

To date, chemical imaging of polymers and polymer blends has been primarily accomplished using time-of-flight secondary ion mass spectrometry (ToF-SIMS) to directly visualize the distribution of components in a complex material with spatial resolution ranging from 100 nm to 5 μm. However, in many cases, this resolution falls far short of visualizing interfaces directly. To overcome these limitations, recent work has focused on developing a SIMS detection system based on a helium ion microscope (HIM) enabling chemical imaging with a demonstrated ~14 nm spatial resolution. Here, we utilize HIM-SIMS for differentiation between the olefin-based polymers of polyethylene (PE) and polypropylene (PP). We illustrate both analyses for separating PE and PP using specific mass fragment ratios as well as demonstrate spatially resolved imaging of phase-separated domains within PE. Altogether, we demonstrate the abilities of HIM-SIMS as a multimodal chemical technique for imaging and quantification of polyolefin interfaces, which could be more broadly applied to the analysis of more complex polymeric systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Impact of Ionic Liquid on Lithium Ion Battery with a Solid Poly(Ionic Liquid) Pentablock Terpolymer as Electrolyte and Separator

In this work, a ternary blend solid polymer electrolyte (SPE) consisting of a poly(ionic liquid) (PIL) multiblock polymer, lithium salt, and ionic liquid (IL) was investigated with the goal of understanding the influence of IL concentration on ion transport mechanisms and electrochemical stability. The physical, transport, mechanical, morphological, and electrochemical properties of the ternary blend SPE were systematically investigated as a function of IL concentration (r = [IL]/[PIL] mole ratio between 0.1 and 0.7). The results indicate that with increasing IL concentration, the continuous conductive domain increases along with the polymer chain segmental mobility, as well as facilitate ionic conductivity, while the mechanical modulus exhibits a percolation threshold (from 52.17 MPa to 0.55 MPa at r = 0.2 to 0.3). Surprisingly, at higher IL concentrations, there is a reduction in the lithium cation mobility (i.e., 9.3 × 10-12 m2 s-1 versus 3.8 × 10-12 m2 s-1 for r = 0.2 versus r = 0.5, respectively) as evidenced by pulsed-field gradient nuclear magnetic resonance (PFG-NMR), which coincides with an increased overpotential (i.e., 50 mV versus 150 mV for r = 0.2 versus r = 0.5, respectively) evidenced by lithium metal stripping and plating. This work provides valuable insights into the impact of IL on lithium ion conducting PIL block polymers, which may enable the design of new SPEs with both high ionic conductivity and improved stability for the future lithium ion batteries.

Chen, Tzu-Ling↗
DOE OSTI2023

Characterizing the Mechanisms of Ca and Mg Carbonate Ion-Pair Formation with Multi-Level Molecular Dynamics/Quantum Mechanics Simulations

The carbonate minerals of Ca and Mg are abundant throughout the lithosphere and have recently garnered significant research interest as possible long-term carbon sinks in the sequestration of atmospheric carbon dioxide. Nonetheless, an understanding of the atomic-level processes comprising their mineralization remains limited. Furthermore, we characterize and contrast the mechanisms of contact ion-pair formation in aqueous Ca and Mg carbonate systems, which represents the most fundamental step leading to the formation of their mineral solids. Utilizing multilevel embedded correlated wavefunction-based ab initio molecular dynamics/quantum mechanics simulations, we characterize not only the dynamics of these processes but also factors arising from the electronic structure of the involved species, revealing further details of the fundamentally different mechanisms for the interconversion between the contact ion-pairs and solvent-shared ion-pairs of Ca versus Mg carbonate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Quantum Sensing of Electric Fields Using Spin-Correlated Radical Ion Pairs

Quantum sensing affords the possibility of using quantum entanglement to probe electromagnetic fields with exquisite sensitivity. In this work, we show that a photogenerated spin-correlated radical ion pair (SCRP) can be used to sense an electric field change created at one radical ion of the pair using molecular recognition. The SCRP is generated within a covalent donor–chromophore–acceptor system PXX–PMI–NDI, 1, where PXX = peri-xanthenoxanthene, PMI = 1,6-bis(p-t-butylphenoxy)perylene-3,4-dicarboximide, and NDI = naphthalene-1,8:4,5-bis(dicarboximide). The electron-rich PXX donor in 1 acts as a guest molecule that can be encapsulated selectively by a tetracationic cyclophane ExBox4+ host to give a supramolecular complex 1 ⊂ ExBox 4+ . Selective photoexcitation of the PMI chromophore results in ultrafast generation of the PXX •+ –PMI–NDI •– SCRP. When PXX is encapsulated by ExBox 4+ , the cyclophane generates an electric field that repels the positive charge on PXX •+ within PXX •+ –PMI–NDI •– , reducing the SCRP distance, i.e., the distance between the centers-of-charge on the donor and acceptor. Pulse-EPR measurements are used to measure the coherent oscillations created primarily by the electron–electron dipolar coupling in the SCRP, which yields the distance between the two charges (spins) of PXX •+ –PMI–NDI •– . Here, the experimental results show that the distance between PXX •+ and NDI •– decreases when ExBox 4+ encapsulates PXX •+ , which demonstrates that the SCRP can function as a quantum sensor to detect electric field changes in the vicinity of the radical ions.

Anions↗
DOE OSTI2020

Improvements to the Faraday cup fast ion loss detector and magnetohydrodynamic induced fast ion loss measurements in Joint European Torus plasmas

Upgrades to electronic hardware and detector design have been made to the JET thin-foil Faraday cup fast ion loss detector in anticipation of the upcoming deuterium–tritium (DT) campaign. An improved foil stack design has been implemented, which greatly reduces the number of foil-to-foil shorts, and triaxial cabling has mitigated ambient noise pickup. Initial tests of 200 kHz digitizers, as opposed to the original 5 kHz digitizers, have provided enhanced analysis techniques and direct coherence measurements of fast ion losses with magnetohydrodynamic activity. Here, we present recent loss measurements in JET deuterium plasmas correlated with kink modes, fishbone modes, edge-localized modes, and sawteeth. Sources of systematic noise are discussed with emphasis on capacitive plasma pickup. Overall, the system upgrades have established a diagnostic capable of recording alpha particle losses due to a wide variety of resonant fast ion transport mechanisms to be used in future DT-experiments and modeling efforts.

47 OTHER INSTRUMENTATION↗
DOE OSTI2024

Comparison of Mg-based liquid metal ion sources for scalable focused-ion-implantation doping of GaN

We compare the suitability of various magnesium-based liquid metal alloy ion sources (LMAISs) for scalable focused-ion-beam (FIB) implantation doping of GaN. We consider GaMg, MgSO 4 $\bullet$7H 2 O, MgZn, AlMg, and AuMgSi alloys. Although issues of oxidation (GaMg), decomposition (MgSO 4 $\bullet$7H 2 O), and excessive vapor pressure (MgZn and AlMg) were encountered, the AuMgSi alloy LMAIS operating in a Wien-filtered FIB column emits all Mg isotopes in singly and doubly charged ionization states. We discuss the operating conditions to achieve <20 nm spot size Mg FIB implantation and present Mg depth profile data from time-of-flight secondary ion mass spectrometry. We also provide insight into implantation damage and recovery based on cathodoluminescence spectroscopy before and after rapid thermal processing. Prospects for incorporating the Mg LMAIS into high-power electronic device fabrication are also discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Demonstration of closed shell breeding of cesium ions with an electron beam ion source

An electron beam ion source serves as a charge breeder for the Californium Rare Isotope Breeder Upgrade (CARIBU) at the Argonne Tandem Linac Accelerator System (ATLAS). The source accepts radioactive beams of 1+ or 2+ ions and raises their charge state for post-acceleration by ATLAS. The efficiency of this process impacts the length of each experiment and, hence, the type and number of experiments that can be run in each program cycle. Recent efforts to improve the charge breeding efficiency for the 80 < A < 160 species typical of CARIBU have focused on utilizing the closed shell breeding technique. Here, with this technique, the electron beam energy is manipulated to take advantage of the large gap in ionization energies at shell closures and selectively populate a single charge state. Charge breeding studies with stable cesium ions have demonstrated an absolute efficiency of 72% for Cs 27+ and a total efficiency of 93%. The Cs 27+ efficiency result represents a factor of 3 improvement over the previous best charge breeding result of 23% for Cs 27+ .

Vondrasek, R. [Argonne National Laboratory (ANL), ↗
DOE OSTI2026

Experimental demonstration of accelerating a beam with a large transverse emittance ratio in the relativistic heavy ion collider for the electron-ion collider

The electron-ion collider (EIC), to be constructed at Brookhaven National Laboratory, will collide polarized high-energy electron beams with hadron beams, achieving luminosities of up to 1.0 × 10 34 cm −2 s −1 in the center-of-mass energy range of 20–140 GeV. To reach such high luminosity, the EIC will employ small, flat beams at the interaction point. According to the design of the EIC hadron storage ring (HSR), hadron beams with a large transverse emittance ratio of 11:1 will be generated at the injection energy using an electron cooling technique and then accelerated to high energies for collisions. Accelerating hadron beams with such a large emittance ratio had never been demonstrated elsewhere—until our recent beam experiment at the relativistic heavy ion collider (RHIC). In this experiment, we successfully generated a large transverse emittance ratio of 13:1 with a gold-ion beam at 31 GeV/nucleon using stochastic cooling. We then accelerated this beam, with a transverse emittance ratio of 11:1, from 31 to 100 GeV/nucleon. Thanks to RHIC’s high-performance orbit, tune, and decoupling feedback systems, the large emittance ratio was well maintained throughout the 5-min-long acceleration process. This experiment fully validated the EIC/HSR design assumptions—namely, that large-emittance-ratio hadron beams can be generated at injection energy and then accelerated to high energies for collisions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Experimental Demonstration of a Large Transverse Emittance Ratio 11 : 1 in the Relativistic Heavy Ion Collider for the Electron-Ion Collider

The Electron-Ion Collider (EIC), to be constructed at Brookhaven National Laboratory, will collide polarized high-energy electron beams with hadron beams, achieving luminosities of up to 1.0 × 10 34 cm –2 s –1 in the center-of-mass energy range of 20–140 GeV. In order to achieve such high luminosity, the EIC will employ small and flat beams at the interaction point. In the hadron storage ring of the EIC, the ratio of horizontal to vertical emittances is approximately 11:1. In contrast, in previous or existing hadron colliders, the horizontal and vertical emittances are typically similar or closely matched. At the Relativistic Heavy Ion Collider (RHIC), we experimentally demonstrated a large transverse emittance ratio of 11:1 with gold ion beams at a particle energy of 100 GeV per nucleon, thanks to stochastic cooling and fine decoupling. Furthermore, we demonstrated collisions with flat beams, featuring a transverse beam size ratio of 3:1 for the first time at the RHIC.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Anti-Coulomb ion-ion interactions: A theoretical and computational study

The free energy of ion solvation can be decomposed into enthalpic and entropic contributions. This helps one to understand the connection between the dielectric properties and the underlying forces. We present a simple linear-response model of screened charge interactions that provides an alternative understanding of solvation barriers. Moreover, it explains the “anti-Coulomb” interactions (attraction between like-charged ions and repulsion between opposite-charged ions) observed in both simulations and experiments. We show that this is a universal behavior associated to the nonlocal response function of any dielectric or metallic systems. Published by the American Physical Society 2024

Wills, Alec (ORCID:0000000280184692)↗
DOE OSTI2022

Ion Chromatography and Combustion Ion Chromatography Analysis of Fuel Cell Effluent Water During Open Circuit Voltage

Open circuit voltage tests were conducted on sixteen 3M Ionomer and eight Nafion™ NR211 membranes. Lifetime distributions were determined, and ion chromatography (IC) techniques were used to measure fluoride, sulfate, trifluoro acetate, and oxalate ions. Combustion Ion Chromatography (CIC) was used to determine the total organic fluoride (TOF) associated with water soluble membrane degradation fragments. The ratio of these products relative to the fluoride release rates were used to infer the likely degradation mechanism for each membrane. Peroxide attack at the sulfonic acid side chain was determined to be the least relevant reaction pathway while the long-proposed polymer chain end unzipping appears to be the dominant mechanism. Abstraction of the tertiary fluorine in the NR211 backbone and side chain is evident by organic fluoride release rates higher than can be explained by unzipping alone.

25 ENERGY STORAGE↗
DOE OSTI2022

Dynamic Structure Discovery Applied to the Ion Transport in the Ubiquitous Lithium-ion Battery Electrolyte LP30

The electrolytes of the today omnipresent lithium-ion batteries (LIBs) have for more than 25 years been based upon 1 M LiPF 6 in a 50:50 EC:DMC mixture—commonly known as LP30. The success of the basic design of the LP30 electrolyte, with many variations and additions made over the years, is unchallenged. Yet, some molecular level fundamentals of LP30 are surprisingly elusive: the structure of the first solvation shell of the Li + cation is still a topic of current debate; the details of the dynamics are not fully understood; the interpretation of structural and dynamic properties is highly dependent on the analysis methods used; the contributions by different species to the ion transport and the energetics involved are not established. We here apply dynamic structure discovery analysis as implemented in CHAMPION to molecular dynamics simulation trajectories to bring new light on the structure and dynamics within LP30 and especially the (Li + ) ion transport to rationalize further development of LIB electrolytes.

25 ENERGY STORAGE↗