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At least 217 records · Page 12

Thermal-chemical instabilities in CO clouds

The stability of interstellar clouds containing CO is analyzed taking account of formation processes for CO. Two such processes are examined: O(+) charge exchange and C(+) radiative association. It is found that the C(+) radiative-association chemistry leads to low-temperature instabilities which influence the evolution of clouds. It is also found that instability may set in if CO production increases sufficiently with density, that the O(+) charge-exchange chemistry leads to instability associated with attenuation of the interstellar radiation field by grains, and that thermal instabilities will also result if grain formation, rather than ion-molecule chemistry, dominates CO production. It is suggested that such instabilities play a role in the fragmentation of interstellar clouds and in the formation of protostellar objects.

Glassgold, A. E.↗

A flux-limited treatment for the conductive evaporation of spherical interstellar gas clouds

In this work, we present and analyze a new analytic solution for the saturated (flux-limited) thermal evaporation of a spherical cloud. This work is distinguished from earlier analytic studies by allowing the thermal conductivity to change continuously from a diffusive to a saturated form, in a manner usually employed only in numerical calculations. This closed form solution will be of interest as a computational benchmark. Using our calculated temperature profiles and mass-loss rates, we model the thermal evaporation of such a cloud under typical interstellar medium (ISM) conditions, with some restrictions. We examine the ionization structure of the cloud-ISM interface and evaluate column densities of carbon, nitrogen, oxygen, neon, and silicon ions toward the cloud. In accord with other investigations, we find that ionization equilibrium is far from satisfied under the assumed conditions. Since the inclusion of saturation effects in the heat flux narrows the thermal interface relative to its classical structure, we also find that saturation effects tend to lower predicted column densities.

Dalton, William W.↗

Laboratory Studies of Stabilities of Heterocyclic Aromatic Molecules: Suggested Gas Phase Ion-Molecule Routes to Production in Interstellar Gas Clouds

Several ring compounds have been detected in interstellar gas clouds, ISC, including the aromatic, benzene. Polycyclic aromatic hydrocarbons, PAHs, have been implicated as carriers of diffuse interstellar bands (DIBs) and unidentified infrared (UIR) bands. Heterocyclic aromatic rings of intermediate size containing nitrogen, possibly PreLife molecules, were included in early searches but were not detected and a recent search for Pyrimidine was unsuccessful. Our laboratory investigations of routes to such molecules could establish their existence in ISC and suggest conditions under which their concentrations would be maximized thus aiding the searches. The stability of such ring compounds (C5H5N, C4H4N2, C5H11N and C4H8O2) has been tested in the laboratory using charge transfer excitation in ion-molecule reactions. The fragmentation paths, including production of C4H4(+), C3H3N(+) and HCN, suggest reverse routes to the parent molecules, which are presently under laboratory investigation as production sources.

Adams, Nigel G.↗

Interstellar molecules

Progress in the discovery and study of interstellar molecules is summarized. The 36 molecular species thus far identified in interstellar space are listed in several groups which include simple hydrides, oxides, and sulfides, various derivatives of ammonia, molecules involving linear carbon chains, cyanides, and molecules related in structure to formaldehyde, alcohols, or ethers. Several free radicals are described, the discovery of molecules in external galaxies is discussed, and possible mechanisms for molecular formation are noted. Methods for examining relative isotopic abundances by measuring molecules in interstellar clouds are outlined, mechanisms for the excitation of interstellar molecules are reviewed, and values are presented for the C-12/C-13 abundance ratio in a number of interstellar clouds. The detection of interstellar masers is discussed along with pumping mechanisms and masing transitions in H2CO, CH, OH, and SiO. The nature of dense interstellar clouds is examined in terms of several simple and complex cloud models, with emphasis on multiple condensation models.

Townes, C. H.↗

Molecules in celestial objects. III - Study of CO in interstellar diffuse clouds

The absorption lines corresponding to the A-X transition of CO have been looked for in the IUE spectra of 14 stars with varying values of the colour excess, E(B-V) and found to be present in the spectra of nine stars with E(B-V) at least 0.28. The column density of CO has been determined towards these nine stars and its upper limit towards the rest of the stars. The curve of growth analysis has been found to show that the contribution to CO absorption is possibly from a single interstellar cloud for stars with E(B-V) less than 0.4 and from more than one cloud for stars with E(B-V) greater than 0.4. The observed column density of CO as a function of E(B-V) has been found to be in good agreement with that expected from the theory of ion-molecular chemistry.

Tarafdar, S. P.↗

Distribution of hot stars and hydrogen in the Large Magellanic Cloud

Far-UV brightness distribution data for the face of the Large Magellanic Cloud (LMC) are derived from calibrated electrographic imagery in the 1050-1600 and 1250-1600 A ranges, and far-UV fluxes for individual hot-star groupings in the LMC are compared with H-alpha measurements and with a 21-cm survey. It is found that large clouds of interstellar hydrogen contain smaller concentrations revealed by H-alpha emission and other clear regions where hot O-B stars excite no H II regions. Either (1) four of these associations lie behind the large interstellar clouds, or (2) the clouds may be very diffuse and extended in the line of sight. Six other peaks in far-UV flux not previously cataloged are also indicated.

Page, T.↗

Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula

Detailed study of the first interstellar hydrocarbon ring, cyclopropenylidene (C3H2), is continuing. The singly deuterated isotope of this molecule, C3HD, was observed in several cold interstellar clouds. The results of a large survey for C3H2 in galactic sources of various types will soon be completed. It appears that cyclopropenylidene is present in virtually all interstellar clouds of at least moderate density. In order to make the first determinations of the CO2/CO abundance ratio in interstellar sources, observations of protonated CO2 were pursued. The spectrum from 18.5 to 22 GHz for several interstellar clouds is being systematically measured. Particular attention is being given to the cold, dark clouds TMC-1 and L124N, which may be formation sites for solar mass stars. The phenomena of maser emission from molecules of methanol is being studied in certain interstellar clouds. A comparison of 1 millimeter continuum emission from dust with the column density of carbon monoxide as determined from the rare C(18)O isotope for 4 molecular clouds in the Galaxy is nearing completion. Papers published during the period of this report are listed.

Irvine, William M.↗

Atomic and molecular gas in interstellar cirrus clouds

The dust, atomic gas, and molecular gas content of a sample of 26 of isolated, degree-sized infrared clouds are compared. Half of the clouds have an infrared excess indicating the presence of H2, and 14 contain compact CO-emitting regions. Complete, high angular resolution H I and CO maps of one cloud, G236+39, resolve the transition between atomic and molecular H, as well as the location of CO formation. Assuming the infrared emission traces the total column density, H2 is inferred to be much more widely distributed than the CO. The CO rotational levels are subthermally excited, and the (2 - 1)/(1 - 0) line ratios suggest a density n(H2) approximately 200/cm(exp 3) where CO was detected. A model of H2 formation on grain surfaces balanced by self-shielded photodissociation fits the variation of infrared brightness with H I column density. Assuming a temperature of 80 K, typical of diffuse H2 (Savage et al. 1977), the H2 chemistry requires an average density n(H + 2H2) approximately 50/cm(exp 3). For G236+39, if the distance is 100 pc, the H I and H2 masses are estimated to be 90 and 70 solar mass, respectively. High-resolution H I and infrared maps of a smaller cloud, G249.0+73.7, reveal no evidence for molecular gas, which is likely due to the low total column density through this cloud. These results suggest the H2 and H I content are comparable for some interstellar cirrus clouds with column densities N(H I) greater than 4 x 10(exp 20)/cm(exp 2), even where CO was not detected.

Reach, William T.↗

A high-resolution survey of interstellar Na I D1 lines

We present high-resolution (0.5 km/s) spectra, obtained with the McDonald Observatory 2.7 m coude echelle spectrograph, of interstellar Na I D1 absorption toward 38 bright stars. Numerous narrow, closely blended absorption components, showing resolved Na I hyperfine structure, are evident in these spectra; such narrow components appear in both low halo and quite local gas, as well as in gas toward more distant disk stars. We have used the method of profile fitting in an attempt to determine column densities, line widths, and velocities for the individual interstellar clouds contributing to the observed absorption lines. The resulting sample of 276 clouds is significantly larger, and likely more complete, than several previous samples of 'individual' interstellar clouds, and allows more precise investigation of various statistical properties. We find that the cloud column density (N) and line width parameter (b) are not correlated, for 0.3 km/s approximately less than b approximately less than 1.5 km/s and 10.0/sq cm approximately less than log (N(Na I)) approximately less than 11.6/sq cm. The median b is about 0.73 km/s, the median log N is about 11.09/sq cm, and the median separation between adjacent components is about 2.0 km/s. All these are overestimates of the true median values, however, due to our inability to completely resolve all the component structure present in some cases; even at a resolution of 0.5 km/s, we may have discerned only 60% of the full number of individual components actually present. The one-dimensional dispersion of component velocities, in the local standard of rest, is approximately 8.6 km/s; the distribution of velocities is broader and displaced to more negative velocities for the weaker components. If 80 K is a representative temperature for the interstellar clouds seen in Na I absorption, then at least 38% (and probably the majority) of the clouds have subsonic internal turbulent motions. The range in N(H I) observed at a given N(Na I) increases as N(Na I) decreases below about 10(exp 11)/sq cm, so that N(Na I) becomes a less reliable predictor of N(H I) at low column densities. These spectra will be quite useful in future detailed studies of these lines of sight with the Hubble Space Telescope (HST) Goddard High Resolution Spectrograph (GHRS) echelle -- to determine accurate velocities and to reveal the detailed interstellar component structures that cannot be discerned at the 3.5 km/s resolution available with the GHRS.

Welty, Daniel E.↗

The ratio of carbon monoxide to molecular hydrogen in interstellar dark clouds

LTE (C-13)O column densities are compared with the corresponding values of beam-convolved visual extinction at more than 100 locations within 38 different interstellar dark clouds. A roughly linear correlation is found to exist between these two quantities for visual extinctions in the range from about 1.5 to 5 mag. It is argued that this correlation can be extended up to about 10 mag and that the standard gas-to-extinction ratio can be expected to remain valid in the sources studied. The correlation of LTE (C-13)O column density with visual extinction is used to obtain an equation for the H2 column density associated with a given (C-13)O column density. It is shown that if the clouds studied are assumed to be chemically homogeneous, the equation obtained implies that at least 12% of all gas-phase carbon is in the form of CO. Comparison of the observational data with various theories proposed for molecule formation in dark clouds indicates that Langer's (1977) ion-molecule scheme accounts well for the observations when the fractionation channel of Watson et al. (1976) is included.

Dickman, R. L.↗

Theoretical, observational, and isotopic estimates of the lifetime of the solar nebula

There are a variety of isotopic data for meteorites which suggest that the protostellar nebula existed and was involved in making planetary materials for some 10(exp 7) yr or more. Many cosmochemists, however, advocate alternative interpretations of such data in order to comply with a perceived constraint, from theoretical considerations, that the nebula existed only for a much shorter time, usually stated as less than or equal to 10(exp 6) yr. In this paper, we review evidence relevant to solar nebula duration which is available through three different disciplines: theoretical modeling of star formation, isotopic data from meteorites, and astronomical observations of T Tauri stars. Theoretical models based on observations of present star-forming regions indicate that stars like the Sun form by dynamical gravitational collapse of dense cores of cold molcular clouds in the interstellar clouds in the interstellar medium. The collapse to a star and disk occurs rapidly, on a time scale of the order 10(exp 5) yr. Disks evolve by dissipating energy while redistributing angular momentum, but it is difficult to predict the rate of evolution, particularly for low mass (compared to the star) disks which nonetheless still contain enough material to account for the observed planetary system. There is no compelling evidence, from available theories of disk structure and evolution, that the solar nebula must have evolved rapidly and could not have persisted for more than 1 Ma. In considering chronoloically relevant isotopic data for meteorites, we focus on three methodologies: absolute ages by U-Pb/Pb-Pb, and relative ages by short-lived radionuclides (especially Al-26) and by evolution of Sr-87/Sr-86. Two kinds of meteoritic materials-refractory inclusions such as CAIs and differential meteorites (eucrites and augrites) -- appear to have experienced potentially dateable nebular events. In both cases, the most straightforward interpretations of the available data indicate nebular events spanning several Ma. We also consider alternative interpretations, particularly the hypothesis of radically heterogeneous distribution of Al-26, which would avoid these chronological interpretations. The principal impetus for such alternative interpretations seems to be precisely the obviation of the chronological interpretation (i.e., the presumption rather than the inference of a short (less than or equal to 1 Ma) lifetime of the nebula). Astronomical observations of T Tauri stars indicate that the presence of dusty disks is a common if not universal feature, that the disks are massive enough to accomodate a planetary system such as ours, and that at least some persist for 110(exp 7) yr or more. The results are consistent with the time scales inferred from the meteoritic isotopic data. They cannot be considered conclusive with regard to solar nebula time scales, however, in part because it is difficult to relate disk observations to processes that affect meteorites, and in part because the ages assigned for these stars could be wrong by a factor of several in either direction. We conclude that the balance of available evidence favors the view that the nebula existed and was active for at least several Ma. However, because the evidence is not definitive, it is important that the issue be perceived to be an open question, whose answer should be sought rather than presumed.

Podosek, Frank A.↗

Search for H2COH+ and H2(13)CO in dense interstellar molecular clouds

We have searched for the 2 mm transitions of H2COH+ (2(02) - 1(01)) and H2(13)CO (2(02) - 1(01), 2(12) - 1(11), and 2(11) - 1(10)) toward the dense interstellar molecular clouds Orion A, TMC-1 and L134N using the FCRAO 14m telescope. None of the transitions have been detected except the H2(13)CO transitions toward Orion-KL. We set upper limits for the abundances of the protonated formaldehyde ion (H2COH+), which are close to the abundances expected from ion-molecule chemistry.

NASA Discipline Exobiology↗

Theory of collapse and protostar formation

Interstellar clouds must increase in density by a factor of more than 10 to the 20th in order to form stars. Because observations of the phases intermediate between dense interstellar clouds and pre-main-sequence stars are difficult, theoretical solutions presently provide the primary means for exploring the collapse phase of protostellar formation. The mathematical formulation of the protostellar collapse problem is presented, and various methods employed in solving the equations are outlined. This tutorial emphasizes the numerical approach to the study of the nonlinear time-dependent evolution of collapsing interstellar clouds, including self-gravitation, rotation, and radiative transfer. Results are summarized for the restricted cases of spherical and axisymmetric symmetry, as well as for fully three-dimensional evolutions, and briefly compared to observations of star formation.

Boss, A. P.↗

Molecular hydrogen in interstellar dark clouds

A simplified H2 formation mechanism is proposed in which small interstellar grains furnish the reaction sites. This mechanism results in a maximum value for the rate constant of about 2 by 10 to the -18th power per cu cm/sec for dark clouds at 10 K. Also, the nascent molecules are ejected in excited states, in qualitative agreement with Copernicus observations. A time-dependent treatment of the chemical evolution of a dark cloud with little or no ionizing radiation shows that the clouds require more than 10 million years to achieve chemical equilibrium. The observed residual atomic hydrogen in several dark clouds suggests that the clouds are 1 to 10 million years old. Other consequences of the temporal cloud model are in accord with astronomical observations.

Allen, M.↗

Interstellar Antifreeze: Ethylene Glycol

Interstellar ethylene glycol (HOCH2CH2,OH) has been detected in emission toward the Galactic center source Sagittarius B2(N-LMH) by means of several millimeter-wave rotational torsional transitions of its lowest energy conformer. The types and kinds of molecules found to date in interstellar clouds suggest a chemistry that favors aldehydes and their corresponding reduced alcohols-e.g., formaldehyde (H2CO)/methanol (CH3OH), acetaldehyde (CH3CHO)/ethanol (CH3CH2OH). Similarly, ethylene glycol is the reduced alcohol of glycolaldehyde (CH2OHCHO), which has also been detected toward Sgr B2(N-LMH). While there is no consensus as to how any such large complex molecules are formed in the interstellar clouds, atomic hydrogen (H) and carbon monoxide (CO) could form formaldehyde on grain surfaces, but such surface chemistry beyond that point is uncertain. However, laboratory experiments have shown that the gas-phase reaction of atomic hydrogen (H) and solid-phase CO at 10-20 K can produce formaldehyde and methanol and that alcohols and other complex molecules can be synthesized from cometary ice analogs when subject to ionizing radiation at 15 K. Thus, the presence of aldehyde/ reduced alcohol pairs in interstellar clouds implies that such molecules are a product of a low-temperature chemistry on grain surfaces or in grain ice mantles. This work suggests that aldehydes and their corresponding reduced alcohols provide unique observational constraints on the formation of complex interstellar molecules.

Hollis, J. M.↗

A new class of solutions for interstellar magnetohydrodynamic shock waves

An analysis is presented of the equations of motion for steady MHD shock waves proopagating in interstellar clouds, for boundary conditions that preclude C shocks. In addition to J shocks, in which the neutral fluid component becomes subsonic at an adiabatic jump front, the equations admit a new class of solutions, called C-asterisk shocks, in which the transition to subsonic flow occurs continuously at a sonic point. Numerical methods are developed for computing the structure of J and C-asterisk shocks propagating in diffuse interstellar clouds. The effects of chemical, ionization, and recombination processes are included in this treatment. An alternative numerical method, which uses artificial viscosity to facilitate integration through sonic points, is analyzed and shown to be invalid. A set of exemplary solutions, computed for realistic shock parameters, shows that C-asterisk shocks occur for a broad range of conditions relevant to diffuse interstellar clouds.

Roberge, W. G.↗

An isolated, well-defined infrared cirrus cloud

High spatial resolution H I measurements of a high-latitude FIR cirrus cloud (l = 9 deg, b = 51 deg) were obtained with the Arecibo 310 m telescope. The cloud is well isolated spatially and has a velocity well-separated from other H I clouds, providing an ideal laboratory for studying diffuse interstellar clouds. The Iv(100)/N(H) and Iv(60)/Iv(100) ratios are consistent with the Draine and Anderson model which includes a distribution of grain sizes down to 3 A. The small grains undergo transient heating and affect the 60 micron FIR continuum emission. Current models, however, underpredict Iv(12)/Iv(100) and Iv(25)/Iv(100) by more than a factor of 2. The effects small grains have on the thermal equilibrium of diffuse interstellar clouds are discussed.

Herter, T.↗

Production and transfer of UV photons in non-homogeneous spherical clouds

Due to screening by dust particles, the UV radiation field of interstellar origin is practically inexistent within very dense interstellar clouds. However, it appears possible that the cosmic-ray excitation of the Lyman and Werner systems of the hydrogen molecule could originate a chemically-significant flux of UV photons even within such dense clouds. Computations of photon fluxes were carried out for two different models of radial density distribution inside the cloud (gas and dust densities were assumed to have the same density distribution). The result strongly support the suggestion that the low energy cosmic rays may generate inside dense interstellar clouds UV radiation fields that may significantly contribute to the gas and dust evolution.

Aiello, Santi↗