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At least 217 records · Page 12

In situ synchrotron investigation of degenerate graphite nodule evolution in ductile cast iron

Ductile cast irons (DCIs) are of increasing importance in the renewable energy and transportation sectors. The distribution and morphology of the graphite nodules, in particular the formation of degenerate features during solidification, dictate the mechanical performance of DCIs. In situ high-speed synchrotron X-ray tomography was used to capture the evolution of graphite nodules during solidification of DCI, including degenerate features and the effect of the carbon concentration field. The degeneration of nodules is observed to increase with re-melting cycles, which is attributed to Mg-loss. The dendritic primary austenite and carbon concentration gradients in the surrounding liquid phase were found to control nodule morphology by locally restricting and promoting growth. A coupled diffusion-mechanical model was developed, confirming the experimentally informed hypothesis that protrusions form through liquation cracking of the austenite shell and subsequent localised growth. In conclusion, these results provide valuable insights into the solidification kinetics of cast irons, supporting the design of advanced alloys.

36 MATERIALS SCIENCE↗

Mechanistic nuclear fuel performance modeling of uranium nitride

Uranium mononitride (UN) is a nuclear fuel candidate for advanced reactor designs and an alternative being considered for light water reactors due to its higher thermal conductivity and uranium density than UO 2 . As with any nuclear fuel, swelling and fission gas release are important factors for safety, while also being some of the hardest phenomena to predict with a high degree of confidence. Getting a grasp on the gas swelling behavior and release is crucial to lower the barrier for UN utilization. An accelerated swelling rate at high temperatures observed experimentally, sometimes referred to as “breakaway swelling,” further complicates the prediction of fuel performance of UN. A mechanistic model has been developed using a multiscale approach to describe the intragranular and intergranular fission gas behavior. Lower-length-scale calculations have been employed to inform models of the gas and self-diffusion behavior, resolution rate, and bubble shape. Leveraging previous work on high burnup UO 2 , two populations of intragranular bubbles are considered; small bulk bubbles and larger bubbles located along dislocations. The dislocation bubbles were found to be crucial to the overall swelling behavior, and the breakaway swelling transition was associated with the transition in the gas atom diffusion mechanism from an irradiation-induced athermal diffusion regime at lower temperatures to an intrinsic thermal equilibrium regime at higher temperatures, accelerating the growth of the dislocation bubbles. Similarly, the threshold for fission gas release was associated with the grain boundary vacancy diffusivity surpassing the gas atom diffusivity at sufficiently high temperatures, allowing the over-pressurized grain boundary bubble to grow in size and interconnect. Using thermo-mechanical models with the fission gas model, two integral fuel pin assessment cases were simulated. Finally, this work demonstrates the ability of a multiscale approach to accelerate the understanding of advanced fuel forms when experimental data is limited.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Laser-Induced Spectral Diffusion of T Centers in Silicon Nanophotonic Devices

Color centers in silicon are emerging as spin-photon interfaces operating at telecommunication wavelengths. The nanophotonic device integration of silicon color centers via ion implantation leads to significant optical-linewidth broadening, which makes indistinguishable photon generation challenging. Here, we study the optical spectral diffusion of T centers in a silicon photonic crystal cavity. We investigate the linewidth-broadening timescales and origins by measuring the temporal correlations of the resonance frequency under different conditions. Spectral hole-burning measurements reveal no spectral broadening at short timescales from 102 ns to 725 ns. We probe broadening at longer timescales using a check pulse to herald the T-center frequency and a probe pulse to measure the frequency after a wait time. The optical resonance frequency is stable up to 3 ms in the dark. Laser pulses below the silicon band gap applied during the wait time lead to linewidth broadening. Our observations establish laser-induced processes as the dominant spectral-diffusion mechanism for T centers in devices and inform materials and feedback strategies for indistinguishable photon generation.

Zhang, Xueyue↗

Multi-Physics Simulations of Molten Chloride Fast Reactor using Nek5000 and PROTEUS-NODAL

This report documents the FY20 work to demonstrate a specific multi-physics capability within NEAMS tools to model molten chloride fast reactors (MCFR). Specifically, the CFD code Nek5000 and the neutronics code PROTEUS-NODAL were coupled off-line to calculate the delayed neutron precursor distribution within the flowing fuel salts in an MCFR core. An MCFR benchmark problem and a 3D test problem based on a conceptual MSR design were successfully solved through the coupled simulation of Nek5000 and PROTEUS-NODAL. In the coupled simulations for these test problems, Nek5000 provided high-quality flow field information, and PROTEUS-NODAL performed the neutron diffusion calculation along with the precursor drift model. The impact of precursor drift on the core status was also investigated. Additionally, the precursor drift model implemented in PROTEUS-NODAL was verified by making use of the reference precursor distribution generated from Nek5000. Results of these test problems suggest that the multi-physics capability of Nek5000 and PROTEUS-NODAL was properly developed for tracking delayed neutron precursor drift.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Data-Driven Method for Groundwater-Level Mapping and Monitoring-Well Network Optimization at Hanford

This report summarizes the initial results and outcomes of a physics-informed, data-driven groundwater level (GWL) mapping capability for the Hanford Site. GWL mapping at Hanford is typically conducted annually and requires a significant amount of computational and expert resources, and it does not allow assessment of the informational value of specific monitoring wells. The proposed method produces spatially and temporally resolved fields consistent with sparse, irregularly sampled, and nonuniformly distributed well measurements. Implemented successfully, this capability will allow rapid mapping of groundwater levels and provide an opportunity to optimize monitoring activities (both location and sampling frequency) based on data information value evaluation. The approach integrates a diffusion-based generative model – trained on MODFLOW simulation data from the Plateau-to-River (P2R) model – with score-based data assimilation (SDA), allowing observation-conditioned mapping without retraining for each monitoring-network layout.

54 ENVIRONMENTAL SCIENCES↗

Visual Attention to Radar Displays

A model is described which predicts the allocation of attention to the features of a radar display. It uses the growth of uncertainty and the probability of near collision to call the eye to a feature of the display. The main source of uncertainty is forgetting following a fixation, which is modelled as a two dimensional diffusion process. The model was used to predict information overload in intercept controllers, and preliminary validation obtained by recording eye movements of intercept controllers in simulated and live (practice) interception.

Moray, N.↗

IUE/IRAS studies of metal abundances and infrared cirrus

A survey is reported of interstellar densities, abundances, and cloud structure in the Galaxy, using the IUE and IRAS satellites. Heavy element depletions are discussed along with their correlations with mean density, reddening, and galactic location. Interesting correlations between the Fe/Si abundance ratio and the infrared diffuse cirrus is also reported, which may provide information on the history and formation of grains in the galactic halo.

Vansteenberg, M. E.↗

Experimental simulations of oxidizing conditions and organic decomposition on the surface of Mars

One important scientific objective of a Mars Rover Sample Return mission would be to look for traces of living and extinct life on Mars. An instrument to search for organic carbon may be the simplest instrument that could screen samples which are interesting from a biological point of view. An experimental program is described which would help to understand the nature of the oxidizing soil on Mars and the mechanism responsible for organic degradation on the Martian surface. This is approached by lab simulations of the actual conditions that occur on Mars, particularly the oxidant production by atmospheric photochemistry, and the combined effects of UV light and oxidants in decomposing organic compounds. The results will be used to formulate models of the photochemistry of the atmospheric, the atmosphere-soil interaction, and the diffusion of reactive compounds into the soils. This information will provide insights and constraints on the design of a sampling strategy to search for organic compounds on Mars.

Stoker, C. R.↗

Igneous fractionation and subsolidus equilibration of diogenite meteorites

Diogenites are coarse-grained orthopyroxenite breccias of remarkably uniform major element composition. Most diogenites contain homogeneous pyroxene fragments up to 5 cm across of Wo2En74Fs24 composition. Common minor constituents are chromite, olivine, trolite and metal, while silica, plagioclase, merrillite and diopside are trace phases. Diogenites are generally believed to be cumulates from the eucrite parent body, although their relationship with eucrites remains obscure. It has been suggested that some diogenites are residues after partial melting. I have performed EMPA and INAA for major, minor and trace elements on most diogenites, concentrating on coarse-grained mineral and lithic clasts in order to elucidate their igneous formation and subsequent metamorphic history. Major element compositions of diogenites are decoupled from minor and trace element compositions; the latter record an igneous fractionation sequence that is not preserved in the former. Low equilibration temperatures indicate that major element diffusion continued long after crystallization. Diffusion coefficients for trivalent and tetravalent elements in pyroxene are lower than those of divalent elements. Therefore, major element compositions of diogenites may represent means of unknown portions of a cumulate homogenized by diffusion, while minor and trace elements still yield information on their igneous history. The scale of major element equilibration is unknown, but is likely to be on the order of a few cm. Therefore, the diogenite precursors may have consisted largely of cm-sized, igneously zoned orthopyroxene grains, which were subsequently annealed during slow cooling, obliterating major element zoning but preserving minor and trace incompatible element zoning.

Mittlefehldt, David W.↗

NASA/DOD Aerospace Knowledge Diffusion Research Project. Use of Communications Sources: An Intercultural Investigation of Practices in the US and Russia

The purpose of this paper is to investigate the impact of U.S./Russian cultural differences in communications among scientists and engineers in applied technology industries. This is important because the advent of perestroika, the breakup of the Soviet Union, and massive moves toward privatization make Russia a potential partner in economic endeavors and, at the same time, a possible competitor in the international arena. Unfortunately the results of U.S./Soviet collaborative endeavors have not always met with expectations. Since 1987, when the former USSR adopted a law on joint ventures, evidence has emerged as to the causes of many failures of these cooperative arrangements. While international strategic alliances face many structural barriers, failures of these cooperative ventures have often resulted from a lack of understanding of the more intangible barrier of major differences in cultural environments between the partners (Cattaneo, 1992). Cultural differences not only affect business operations but also raise questions for scholars and practitioners who have advocated that U.S. management theories apply abroad. Boyacigiller and Adler (1991), Doktor, Tung, and Von Glinow (1991), and Hofstede (1993) observed that most U.S. scholars have continued to export management concepts and practices abroad assuming the concepts were universally valid despite the fact that Western organizational theory has placed little emphasis on factors such as history, social setting, culture, and government (Boyacigiller & Adler, 1991). High technology industries such as aerospace, which includes the cormmercial aviation segment, have characteristics that make the industry an excellent platform to study cultural implications for technical communications. The investigation of this group is worthwhile for several reasons. First, high technology industries are becoming more international and more engaged in collaborative endeavors. Second, the industries are highly dependent on effective innovation diffusion which, according to Fischer (1979), is essentially information exchange. And, third, studies of innovative project management have found that information availability was a critical factor in project success or failure (e.g., Link & Zmud, 1987; Tushman, 1978, 1979). We propose that a gap in the literature exists that centers on whether U.S. paradigms of commnunications behavior apply to other cultures. First, we will explore early findings in the U.S. that held that the choice of an information source was a function of the 'law of least effort' rather than quality (e.g., Allen, 1977; Cuinan, 1983; DeWhirst, 1971; Hardy, 1982; O'Reilly, 1982; Rosenberg, 1967). Second, we will explore the contingency approaches such as that of Tushman (1979) and the later work of Daft and Lengel (1984, 1987), Huber and Daft (1987) and Lengel and Daft (1988) who held that information choice was a function of the nature of the task at hand. A third issue to be addressed is the confounding problem of presumed differences between scientists and engineers in information gathering behavior (Allen, 1977). Finally, we will investigate whether cultural differences cast doubt on the applicability of findings from U.S. situations to other cultures.

Pinelli, Thomas E.↗

Singularities in nearly uniform one-dimensional condensates due to quantum diffusion

Dissipative systems often exhibit wavelength-dependent loss rates. One prominent example is Rydberg polaritons formed by electromagnetically induced transparency, which have long been a leading candidate for studying the physics of interacting photons and also hold promise as a platform for quantum information. In this system, dissipation is in the form of quantum diffusion, i.e., proportional to k 2 (k being the wavevector) and vanishing at long wavelengths as k→0. Here, we show that one-dimensional condensates subject to this type of loss are unstable to long-wavelength density fluctuations in an unusual manner: after a prolonged period in which the condensate appears to relax to a uniform state, local depleted regions quickly form and spread ballistically throughout the system. We connect this behavior to the leading-order equation for the nearly uniform condensate—a dispersive analog to the Kardar-Parisi-Zhang equation—which develops singularities in finite time. Furthermore, we show that the wavefronts of the depleted regions are described by purely dissipative solitons within a pair of hydrodynamic equations, with no counterpart in lossless condensates. We close by discussing conditions under which such singularities and the resulting solitons can be physically realized.

74 ATOMIC AND MOLECULAR PHYSICS↗

Localization of fluorescent targets in deep tissue with expanded beam illumination for studies of cancer and the brain

Imaging fluorescence through millimeters or centimeters of tissue has important in vivo applications, such as guiding surgery and studying the brain. Often, the important information is the location of one of more optical reporters, rather than the specifics of the local geometry, motivating the need for a localization method that provides this information. We present an optimization approach based on a diffusion model for the fast localization of fluorescent inhomogeneities in deep tissue with expanded beam illumination that simplifies the experiment and the reconstruction. We show that the position of a fluorescent inhomogeneity can be estimated while assuming homogeneous tissue parameters and without having to model the excitation profile, reducing the computational burden and improving the utility of the method. We perform two experiments as a demonstration. First, a tumor in a mouse is localized using a near infrared folate-targeted fluorescent agent (OTL38). This result shows that localization can quickly provide tumor depth information, which could reduce damage to healthy tissue during fluorescence-guided surgery. Second, another near infrared fluorescent agent (ATTO647N) is injected into the brain of a rat, and localized through the intact skull and surface tissue. This result will enable studies of protein aggregation and neuron signaling.

60 APPLIED LIFE SCIENCES↗

Effects of buoyancy on gas jet diffusion flames

The objective of this effort was to gain a better understanding of the fundamental phenomena involved in laminar gas jet diffusion flames in the absence of buoyancy by studying the transient phenomena of ignition and flame development, (quasi-) steady-state flame characteristics, soot effects, radiation, and, if any, extinction phenomena. This involved measurements of flame size and development, as well as temperature and radiation. Additionally, flame behavior, color, and luminosity were observed and recorded. The tests quantified the effects of Reynolds number, nozzle size, fuel reactivity and type, oxygen concentration, and pressure on flame characteristics. Analytical and numerical modeling efforts were also performed. Methane and propane flames were studied in the 2.2 Second Drop Tower and the 5.18-Second Zero-Gravity Facility of NASA LeRC. In addition, a preliminary series of tests were conducted in the KC-135 research aircraft. Both micro-gravity and normal-gravity flames were studied in this program. The results have provided unique and new information on the behavior and characteristics of gas jet diffusion flames in micro-gravity environments.

Bahadori, M. Yousef↗

Relating Geometric Nanoconfinement and Local Molecular Environment to Diffusion in Ionic Polymer Membranes

Understanding structure-diffusion relationships in ionic polymer membranes not only illuminates fundamental mechanisms for membrane transport, but also informs further membrane development. In this study, we employ NMR diffusometry and molecular dynamics (MD) simulations to investigate diffusion coefficients and activation energies of diffusion (Ea) for both a lithium-form perfluorosulfonic acid membrane and aqueous solutions of lithium triflate. NMR shows that, at high water/ion molar ratio (?), Ea for water diffusion is slightly lower in the membrane than in solution. Conversely, membrane transport exhibits much higher Ea at low hydration as compared to solutions. MD simulations of a model system consisting of carbon nanotubes with varying diameter reveal that Ea of diffusion clearly relates to both the geometric nanoconfinement of the hydrophilic pathways in the membrane as well as the local molecular environment. These results demonstrate that Ea of diffusion can serve as a revelatory tool for the study of molecular transport processes and the coupling of morphology with transport at the nanoscale. This study thus provides new insights and new experimental and computational models for understanding transport in a wide range of polymer membranes, such as those used in molecular separations applications.

Zhang, Rui↗

Measurement of the longitudinal diffusion of ionization electrons in the MicroBooNE detector

Accurate knowledge of electron transport properties is vital to understanding the information provided by liquid argon time projection chambers (LArTPCs). Ionization electron drift-lifetime, local electric field distortions caused by positive ion accumulation, and electron diffusion can all significantly impact the measured signal waveforms. This paper presents a measurement of the effective longitudinal electron diffusion coefficient, D L , in MicroBooNE at the nominal electric field strength of 273.9 V/cm. Historically, this measurement has been made in LArTPC prototype detectors. This represents the first measurement in a large-scale (85 tonne active volume) LArTPC operating in a neutrino beam. This is the largest dataset ever used for this measurement. Using a sample of ~70,000 through-going cosmic ray muon tracks tagged with MicroBooNE's cosmic ray tagger system, we measure D L = 3.74 +0.28 -0.29 cm 2 /s.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The diffuse galactic gamma ray emission

The EGRET (Energetic Gamma-Ray Experiment Telescope) detector will provide a much more detailed view of the diffuse galactic gamma ray intensity in terms of higher resolution, greater statistical significance, and broader energy range than earlier missions. These observations will furnish insight into a number of very important questions related to the dynamics and structure of the Galaxy. A diffuse emission model is being developed that incorporates the latest information on matter distribution and source functions. In addition, it is tailored to the EGRET instrument response functions. The analysis code of the model maintains flexibility to accommodate the quality of the data that is anticipated. The discussion here focuses on the issues of the distributions of matter, cosmic rays, and radiation fields, and on the important source functions that enter into the model calculation of diffuse emission.

Bertsch, David L.↗

CARETS: A prototype regional environmental information system. Volume 7: Land use information and air quality planning

The pilot national land use information system developed by the U.S. Geological Survey in the Central Atlantic Regional Ecological Test Site project has provided an improved technique for estimating emissions, diffusion, and impact patterns of sulfur dioxide (S0 2 ) and particulate matter. Implementation of plans to control air quality requires land use information, which, until this time, has been inadequate. The pilot system, however, provided data for updating information on the sources of point and area emissions of S0 2 and particulate matter affecting the Norfolk--Portsmouth area of Virginia for the 1971-72 winter (Dec.-Jan.-Feb.) and the annual 1972 period, and for a future annual period--1985. This emission information is used as input to the Air Quality Display Model of the Environmental Protection Agency to obtain diffusion and impact patterns for the three periods previously mentioned. The results are: (1) During the 1971-72 winter, estimated SO 2 amounts over an area with a SW-NE-axis in the central section of Norfolk exceeded both primary and secondary levels; (2) future annual levels of SO 2 , estimated by anticipated residential development and point-source changes, are not expected to cause serious deterioration of the region's present air quality; and (3) for the 1971-72 winter and annual 1972 period the diffusion results showed that both primary and secondary standards for particulate matter are regularly exceeded in central Norfolk and Portsmouth. In additions on the bas is of current control programs, the 1985 levels of particulate matter are expected to exceed the presently established secondary air quality standards throughout central Norfolk and Portsmouth and in certain areas of Virginia Beach. The land use information can be used to estimate emissions for inputs to diffusion models and to interpret the implications of diffusion patterns for: (1) Implementing various control strategies (2) selecting sites of air sampling stations, and (3) predicting the effects that proposed changes in land use might have on emission patterns and air quality.

Remote sensing↗

Matrix Resin Characterization in Cured Graphite Composites Using Diffuse Reflectance-Ftir

The chemical characterization of cured graphite fiber reinforced polymer matrix composites is complicated by the fact that the resins are insoluble and the composites are apaque. Standard analyses which depend either on the ability to dissolve the sample or to detect transmitted radiation are impossible. As a result, data reported on environmentally exposed composites primarily concern macroscopic information such as weight loss or changes in selected mechanical properties. Diffuse reflectance in combination with fourier transform infrared spectroscopy was developed to gain a basic chemical understanding of composite and adhesive behavior. Several composite and adhesive materials were characterized before and after environmental exposure. In each case significant changes in resin molecular structure were observed and correlated with changes in mechanical properties, providing new insights into material performance.

Young, P. R.↗