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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Interfacial effects on the behavior of partially bonded metal matrix composite properties

A novel computational method developed at NASA-Lewis in order to predict the behavior of unidirectional composites has been used to explore the effects of partial debonding and fiber fracture on the behavior of room temperature and high temperature metal-matrix composites. Attention is presently given to the influence of disbonding, which occurs with fractured fibers, on the ply properties of metal-matrix composites with orthotropic fibers, in the case of a graphite fiber-reinforced copper-matrix composite. It is shown that, for small amounts of partial bonding on fractured fibers, composite material properties are not significantly affected.

Caruso, J. J.↗
NASA NTRS1985

Effect of fiber and matrix maximum strain on the energy absorption of composite materials

Static crushing tests were conducted on graphite composite tubes to examine the influence of fiber and matrix maximum strain at failure on the energy absorption capability of graphite reinforced composite material. Fiber and matrix maximum strain at failure were determined to significantly effect energy absorption. The higher strain at failure composite material system, AS-4/5245, exhibited superior energy absorption capability compared to AS-4/934, T300/5245 or T300/934 composite material. Results of this investigation suggest that to achieve maximum energy absorption from a composite material a matrix material that has a higher strain at failure than the fiber reinforcement should be used.

Farley, G. L.↗
NASA NTRS1993

Thermal stability relationships between PMR-15 resin and its composites

A study was conducted to investigate the relationship between the thermo-oxidative stability of PMR-15 matrix resin and the stability of graphite-fiber-reinforced composites that contain this resin as the matrix material. Three areas were investigated. The first was the effect of fiber/matrix interfacial bond strength on the isothermal aging weight loss of composites. By using type-A graphite fibers produced by Hercules, it was possible to study composites reinforced with fibers that were processed to receive different surface treatments. One of the fibers was untreated, a second fiber was treated by oxidation to enhance fiber/matrix bonding, and the third type of fiber was coated with an epoxy sizing. These treatments produced three significantly different interfacial bond strengths. The epoxy sizing on the third fiber was quickly oxidized from the bare fiber surfaces at 288, 316, and 343 C. The weight loss due to the removal of the sizing was constant at 1.5 percent. This initial weight loss was not observed in thermo-oxidative stability studies of composites. The PMR-15 matrix satisfactorily protected the reinforcemnt at all three temperatures.

Bowles, Kenneth J.↗
DOE OSTI2020

Laser writing of nitrogen-doped silicon carbide for biological modulation

Conducting or semiconducting materials embedded in insulating polymeric substrates can be useful in biointerface applications; however, attainment of this composite configuration by direct chemical processes is challenging. Laser-assisted synthesis has evolved as a fast and inexpensive technique to prepare various materials, but its utility in the construction of biophysical tools or biomedical devices is less explored. Here, we use laser writing to convert portions of polydimethylsiloxane (PDMS) into nitrogen-doped cubic silicon carbide (3C-SiC). The dense 3C-SiC surface layer is connected to the PDMS matrix via a spongy graphite layer, facilitating electrochemical and photoelectrochemical activity. We demonstrate the fabrication of arbitrary two-dimensional (2D) SiC-based patterns in PDMS and freestanding 3D constructs. To establish the functionality of the laser-produced composite, we apply it as flexible electrodes for pacing isolated hearts and as photoelectrodes for local peroxide delivery to smooth muscle sheets.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1973

Stress wave calculations in composite plates using the fast Fourier transform.

The protection of composite turbine fan blades against impact forces has prompted the study of dynamic stresses in composites due to transient loads. The mathematical model treats the laminated plate as an equivalent anisotropic material. The use of Mindlin's approximate theory of crystal plates results in five two-dimensional stress waves. Three of the waves are flexural and two involve in-plane extensional strains. The initial value problem due to a transient distributed transverse force on the plate is solved using Laplace and Fourier transforms. A fast computer program for inverting the two-dimensional Fourier transform is used. Stress contours for various stresses and times after application of load are obtained for a graphite fiber-epoxy matrix composite plate. Results indicate that the points of maximum stress travel along the fiber directions.

Moon, F. C.↗
NASA NTRS1979

Mechanical and thermophysical properties of graphite/polyimide composite materials

An on-going program to characterize advanced composites for up to 50,000 hours of exposure to simulated supersonic cruise environments is summarized. Results are presented for up to 25,000 hours of thermal exposure and 10,000 hours of flight simulation at temperatures up to 560K (550 F) with emphasis on HTS/710 graphite/polyimide composite material. Results to date indicate that the maximum use temperature for HTS/710 may be reduced to 505K (450 F) for long-time (1000 hours) application such as the supersonic transport. Preliminary thermophysical properties data for HTS/PMR15 graphite/polyimide were generated. These data include thermal conductivity, thermal expansion, and specific heat from 115K (-252 F) to 590K (600 F) and emittance at room temperature and 590K (600 F). The purpose in generating these data was to validate use of state-of-the-art property measurement methods for advanced graphite fiber reinforced resin matrix composites. Based on results to this point, thermal expansion measurements for composites are most difficult to perform. A high degree of caution in conducting thermal expansion tests and analyzing results is required to produce reliable data.

Rummler, D. R.↗
NASA NTRS1983

Resin characterization in cured graphite fiber reinforced composites using diffuse reflectance-FTIR

The feasibility of using diffuse reflectance in combination with Fourier transform infrared spectroscopy to obtain information on cured graphite fiber reinforced polymeric matrix resin composites was investigated. Several graphite/epoxy, polysulfone, and polyimide composites exposed to thermal or radiation environments were examined. An experimental polyimide-sulfone adhesive tape was also studied during processing. In each case, significant changes in resin molecular structure was observed due to environmental exposure. These changes in molecular structure were correlated with previously observed changes in material properties providing new insights into material behavior.

Young, P. R.↗
NASA NTRS1986

Composite tubes for the Space Station truss structure

The reference configuration of NASA's Space Station includes a large truss structure to support the various modules and solar arrays. This truss structure will be constructed from tubular members approximately 2 in. in diameter and up to 23 ft in length. The important design considerations for this structure are light weight, high stiffness, dimensional stability, and long-term durability. Continuous graphite fiber reinforced polymer matrix composite materials can meet the structural requirements, and are leading candidates for the tubular truss members. However, there are concerns regarding the durability of composites during the long-term exposure to atomic oxygen and thermal cycling that will be encountered during the Space Station service life. This paper discusses space environmental factors and their effect on composite materials, and provides estimates of the changes in mechanical and thermal properties of composites exposed to long-term Space Station conditions. The effect of low velocity impact and handling damage on composite tube properties is also discussed.

Bowles, David E.↗
NASA NTRS1986

Thermal expansion behavior of graphite/glass and graphite/magnesium

The thermal expansion behavior of n (+/- 8)s graphite fiber reinforced magnesium laminate and four graphite reinforced glass-matrix laminates (a unidirectional laminate, a quasi-isotropic laminate, a symmetric low angle-ply laminate, and a random chopped-fiber mat laminate) was determined, and was found, in all cases, to not be significantly affected by thermal cycling. Specimens were cycled up to 100 times between -200 F and 100 F, and the thermal expansion coefficients determined for each material as a function of temperature were found to be low. Some dimensional changes as a function of thermal cycling, and some thermal-strain hysteresis, were observed.

Tompkins, Stephen S.↗
NASA NTRS1988

Novel polyamide-imines

An account is given of tough, thermally stable linear polyimides containing amide linkages that recommend themselves for use in high temperature-resistant films and coatings as well as matrix resins for graphite-reinforced structures. Four such polymers were synthesized from unsubstituted amide diamines, and two others from N-substituted amide diamines. High inherent viscosities and glass transition temperatures were obtained. The films exhibit good resistance to organic solvents. Films of the 4,4-prime-isomer polyamide-imide yielded exceptionally high modulus and toughness during impact evaluation.

Dezern, James F.↗
NASA NTRS1988

Interpenetrating polymer network approach to tougher and more microcracking resistant high temperature polymers. I - LaRC-RP40

Interpenetrating polymer networks in the form of the LaRC-RP40 resin, prepared by the in situ polymerization of a thermosetting imide prepolymer and thermoplastic monomer reactants, are presently used to obtain toughness and microcracking resistance in a high-temperature polymer. Attention is presently given to the processing, physical, and mechanical properties, as well as the thermooxidative stability, of both the neat resin and the resin as a graphite fiber-reinforced matrix. Microcracking after thermal cycling was also tested. LaRC-RP40 exhibits significant resin fracture toughness improvements over the PMR-15 high-temperature matrix resin.

Pater, Ruth H.↗
NASA NTRS1989

The effect of processing on autohesive strength development in thermoplastic resins and composites

In the present investigation of processing effects on the autohesive bond strength of neat polysulfone resin and graphite-reinforced polysulfone-matrix composites measured resin bond strength development in precracked compact tension specimens 'healed' by heating over a contact period at a given temperature. The critical strain energy release rate of refractured composite specimens did not exhibit the strong time or temperature dependence of the neat resin tests; only 80-90 percent of the undamaged fracture energy is recoverable.

Howes, Jeremy C.↗
NASA NTRS1991

Polyamide-Imides Made From BTDA

New synthesis results in improved class of tough, thermally stable polyimides containing amide linkages. Linear, aromatic, polyimide/amides synthesized from isomers of DABA with 3, 3', 4, 4'- BTDA. Mechanical properties better than those of LARC-TPI polyimide. Potentially useful as matrix resins in graphite-reinforced structures, and as fibers or coating films withstanding high temperatures.

Dezern, James F.↗
NASA NTRS1991

Advanced materials for space nuclear power systems

The overall philosophy of the research was to develop and characterize new high temperature power conversion and radiator materials and to provide spacecraft designers with material selection options and design information. Research on three candidate materials (carbide strengthened niobium alloy PWC-11 for fuel cladding, graphite fiber reinforced copper matrix composites for heat rejection fins, and tungsten fiber reinforced niobium matrix composites for fuel containment and structural supports considered for space power system applications is discussed. Each of these types of materials offers unique advantages for space power applications.

Titran, Robert H.↗
NASA NTRS1991

Advanced materials for space nuclear power systems

The overall philosophy of the research was to develop and characterize new high temperature power conversion and radiator materials and to provide spacecraft designers with material selection options and design information. Research on three candidate materials (carbide strengthened niobium alloy PWC-11 for fuel cladding, graphite fiber reinforced copper matrix composites for heat rejection fins, and tungsten fiber reinforced niobium matrix composites for fuel containment and structural supports) considered for space power system applications is discussed. Each of these types of materials offers unique advantages for space power applications.

Titran, Robert H.↗
NASA NTRS1990

Applications of high thermal conductivity composites to electronics and spacecraft thermal design

Recently, high thermal conductivity continuous graphite fiber reinforced metal matrix composites (MMC's) have become available that can save much weight over present methods of heat conduction. These materials have two or three times higher thermal conductivity in the fiber direction than the pure metals when compared on a thermal conductivity to weight basis. Use of these materials for heat conduction purposes can result in weight savings of from 50 to 70 percent over structural aluminum. Another significant advantage is that these materials can be used without the plumbing and testing complexities that accompany the use of liquid heat pipes. A spinoff of this research was the development of other MMC's as electronic device heat sinks. These use particulates rather than fibers and are formulated to match the coefficient of thermal expansion of electronic substrates in order to alleviate thermally induced stresses. The development of both types of these materials as viable weight saving substitutes for traditional methods of thermal control for electronics packaging and also for spacecraft thermal control applications are the subject of this report.

Sharp, G. Richard↗
NASA NTRS1992

Effect of space environment on composite materials and thermal coatings (A0138-9)

This paper presents an experiment within the FRECOPA project on composite materials, adhesives, and thermal coatings. The aging of the specimens was limited because of the canister closing, the location on the trailing edge and the arrangement of the specimens inside the canister. The results show no evidence of change for several graphite fiber reinforced epoxy matrix composite materials as well as for two adhesives. Minor changes can be found on some second surface mirrors.

Parcelier, Michel↗
NASA NTRS1993

Styrene-Terminated Polysulfone Oligomers As Matrix Materials

Report summarizes preliminary experimental study and evaluation of styrene-terminated polysulfone oligomers as matrix materials in graphite-fiber/matrix composites. Composites evaluated in terms of methods of fabrication and of mechanical properties.

Bowles, Kenneth J.↗