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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Gaseous fuel engine system and operating strategy for limiting crankcase fuel accumulation

Operating a gaseous fuel engine system includes controlling at least one of a delivery location, a delivery timing, or in situ mixing of a gaseous fuel with air, based on at least one engine system parameter upon the basis of which a blowby amount of a gaseous fuel to a crankcase varies. Crankcase accumulation of the gaseous fuel is maintained below a flammability limit. Related apparatus and control logic is also disclosed.

Singh, Jaswinder↗
DOE OSTI2021

Recent Advances in Electrocatalysts for Proton Exchange Membrane Fuel Cells and Alkaline Membrane Fuel Cells

The rapid progress of proton exchange membrane fuel cells (PEMFCs) and alkaline exchange membrane fuel cells (AMFCs) has boosted the hydrogen economy concept via diverse energy applications in the past decades. For a holistic understanding of the development status of PEMFCs and AMFCs, recent advancements in electrocatalyst design and catalyst layer optimization, along with cell performance in terms of activity and durability in PEMFCs and AMFCs, are summarized in this report. The activity, stability, and fuel cell performance of different types of electrocatalysts for both oxygen reduction reaction and hydrogen oxidation reaction are discussed and compared. Research directions on the further development of active, stable, and low-cost electrocatalysts to meet the ultimate commercialization of PEMFCs and AMFCs are also discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Techno-economic Analysis and Life-Cycle Analysis of Renewable Diesel Fuels Produced with Waste Feedstocks

Wet waste feedstocks represent an important category of resources that could be utilized to produce biofuels. Diversion of the wet waste resources from going through conventional waste management practices to utilization as feedstocks for energy production also benefits from avoided cost and pollutant emissions of waste management and disposal. This study investigates the economic and environmental implications of producing bio-blendstocks for mixing controlled compression ignition (MCCI) engines from two waste-to-fuel pathways: hydroprocessed esters and fatty acids (HEFA) from yellow grease, and swine manure hydrothermal liquefaction (HTL) followed by biocrude upgrading. Detailed process models were developed for both pathways, which informed the techno-economic analysis (TEA) and life-cycle analysis (LCA). Conventional swine manure management practice was also modeled in detail as the business-as-usual (BAU) scenario for the swine manure HTL pathway. The estimated minimum fuel selling prices (MFSP) were $4.47/gasoline gallon equivalent (GGE) and $3.57/GGE for the yellow grease to HEFA and swine manure HTL pathways, respectively. The life-cycle greenhouse gas (GHG) emissions of the two pathways were 11.2 and -33.3 g CO2e/MJ, respectively, for the yellow grease to HEFA and swine manure HTL pathways. The credits of avoided emissions from conventional swine manure management were the main reason for the negative GHG emissions of the swine manure HTL pathway. The marginal GHG emissions abatement costs were estimated to be $100 – $253/tonne CO2e and $5 – $103/tonne CO2e for the yellow grease HEFA and swine manure HTL pathways, respectively, for a diesel price ranging between $2.0/GGE and $3.5/GGE. Since the yellow grease HEFA pathway is already commercialized, it can benefit from the $200/tonne carbon credit in the California Low Carbon Fuel Standard (LCFS) market, which could help the yellow grease HEFA pathway to achieve near-zero marginal GHG emissions abatement cost.

renewable diesel, techno economic analysis, life c↗
DOE OSTI2021

Correlating Nanoscale Secondary Ion Mass Spectrometry and Atom Probe Tomography Analysis of Uranium Enrichment in Metallic Nuclear Fuel

Distribution and enrichment of 235U within nuclear fuels are essential to material performance and reactor safety. With the development of metallic U fuels, understanding 235U homogeneity has become increasingly important, however, it is difficult to map with high spatial, and mass resolution to analyze both matrix and secondary phase precipitates. Here, we analyze 235U enrichment in matrix and carbide phases in LEU-Mo via two chemical imaging modalities: nanoscale secondary ion mass spectrometry (nanoSIMS) and atom probe tomography (APT). NanoSIMS and APT provided consistent results, with no statistically significant difference between measured and nominal enrichment (19.75 % 235U).

U-10Mo, atom probe tomography, nanoscale secondary↗
DOE OSTI2024

Evaluating Impacts of Sustainable Aviation Fuel Production with CO2-to-Fuels Technologies on High Renewable Share Power Grid

This paper investigates the impact of Sustainable Aviation Fuel (SAF) production using CO 2 -to-Fuels technologies on a future power grid with a high share of renewable energy. We focus on understanding the implications of the 2050 SAF production goal on the U.S. power system's long-term planning, encompassing generation, transmission, and cost analysis. Via the Regional Energy Deployment System (ReEDS) model, we developed a detailed SAF electricity demand model based on a low-temperature electrolysis-syngas fermentation-ethanol pathway. Four SAF target scenarios which aim to meet 10%, 15%, 20%, and 27% of SAF demand by 2050. These scenarios are exhaustively simulated to assess their impact on the power grid. Our results reveal that increasing SAF demand will result in higher electricity requirements, as well as expanded generator and transmission capacities, leading to an overall rise in system costs. However, these impacts are manageable within the broader context of U.S. capacity expansion plans. This study provides valuable insights into incorporating the CO 2 -to-Fuels electricity demand model and other carbon capture technologies into power system planning, emphasizing their significance in shaping a sustainable energy future.

capacity expansion model↗
DOE OSTI2022

Approach to Analyzing VTR Core Performance Sensitivities to Fuel Manufacturing Uncertainties and Application to Fuel Slug Diameter

This report documents the initial effort to characterize sensitivity of VTR core performance to fuel manufacturing uncertainties. The effects of variation in the as-fabricated fuel slug diameter on VTR neutronics performance are evaluated, using both high-fidelity Monte Carlo (OpenMC) and the main core design solver (DIF3D) for all cases. This work and follow-on work will inform the VTR Project’s fuel manufacturing processes and associated acceptable criteria, as well as detailed uncertainty analysis in later stages of VTR development and deployment. In addition, this work demonstrates the approach to performing such evaluations and provides a basis for reducing the scope of calculations in future sensitivity analysis.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Fuel Specification for Uranium Monocarbide FAST Fuel Specimens

This specification outlines the fabrication requirements for kernel compact uranium monocarbide (UC) fuel to be fabricated at General Atomics (GA) and is already issued in EDMS and is going thru LRS so that it can be shared with the Vendor. The UC fuel will be irradiated in the Advanced Test Reactor (ATR) using the Irradiation System for High-Throughput Acquisition (ISHA-1). The primary objective of the ISHA-1 capsule design is to deliver to Idaho National Lab (INL) a semi-universal drop-in capsule that can facilitate the irradiation of both fissile and structural materials in a variety of ATR positions. This irradiation experiment will support the need for development of Accelerated Fuel Qualification (AFQ) methods.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Quantifying the effect of CO 2 gasification on pulverized coal char oxy-fuel combustion

Previous research has provided strong evidence that CO 2 and H 2 O gasification reactions can provide non-negligible contributions to the consumption rates of pulverized coal (pc) char during combustion, particularly in oxy-fuel environments. Fully quantifying the contribution of these gasification reactions has proven to be difficult, due to the dearth of knowledge of gasification rates at the elevated particle temperatures associated with typical pc char combustion processes, as well as the complex interaction of oxidation and gasification reactions. Gasification reactions tend to become more important at higher char particle temperatures (because of their high activation energy) and they tend to reduce pc oxidation due to their endothermicity (i.e. cooling effect). The work reported here attempts to quantify the influence of the gasification reaction of CO 2 in a rigorous manner by combining experimental measurements of the particle temperatures and consumption rates of size-classified pc char particles in tailored oxy-fuel environments with simulations from a detailed reacting porous particle model. The results demonstrate that a specific gasification reaction rate relative to the oxidation rate (within an accuracy of approximately +/- 20% of the pre-exponential value), is consistent with the experimentally measured char particle temperatures and burnout rates in oxy-fuel combustion environments. Conversely, the results also show, in agreement with past calculations, that it is extremely difficult to construct a set of kinetics that does not substantially overpredict particle temperature increase in strongly oxygen-enriched N2 environments. This latter result is believed to result from deficiencies in standard oxidation mechanisms that fail to account for falloff in char oxidation rates at high temperatures.

42 ENGINEERING↗
DOE OSTI2020

Chapter 8. Hybrid Biological–Inorganic Systems for CO 2 Conversion to Fuels

The biological reduction of CO 2 into organic carbon is integral to the formation and maintenance of all life on earth. An urgent need to mitigate the effects of CO 2 on our atmosphere has provided an imperative to exploit biological CO 2 fixation for the conversion of CO2 into valuable and energy rich fuels. Photosynthesis uses only sunlight, water, and CO2 as starting materials to form all biomass.

CO2 Conversion to Fuels↗
DOE OSTI2021

Pitch Variation Experiments in Water-Moderated Square-Pitched U(6.90)O 2 Fuel Rod Lattices with Fuel to Water Volume Ratios Spanning 0.08 to 0.67

The twenty-seven critical experiments in this series were performed in 2020 in the SCX at the Sandia Pulsed Reactor Facility. The experiments are grouped by fuel rod pitch. Case 1 is a base case with a pitch of 0.8001 cm and no water holes in the array. Cases 2 through 6 have the same pitch as Case 1 but contain various configurations with water holes, providing slight variations in the fuel-to-water ratio. Similarly, Case 7 is a base case with a pitch of 0.854964 cm and no water holes in the array. Cases 8 through 11 have the same pitch as Case 7 but contain various configurations with water holes. Cases 12 through 15 have a pitch of 1.131512 cm and differ according to the number of water holes in the array, with Case 12 having no water holes. Cases 16 through 19 have a pitch of 1.209102 cm and differ according to number of water holes in the array, with Case 16 having no water holes. Cases 20 through 23 have a pitch of 1.6002 cm and differ according to number of water holes in the array, with Case 20 having no water holes. Cases 24 through 27 have a pitch of 1.709928 cm and differ according to number of water holes in the array, with Case 24 having no water holes. As the experiment case number increases, the fuel-to-water volume ratio decreases.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

Development of a Fuel Cell for the Perhydrodibenzyltoluene / Dibenzyltolluene Fuel Pair

An experimental study of the performance of an LFC with H-DBT and other cyclic hydrogenated aromatic fuels was carried out, along with a characterization of the fuel cell conversion products. A technoeconomic analysis (TEA) of the LFC operating in a class 8 truck powertrain using the H-DBT / DBT fuel pair was completed to determine the total cost of ownership (TCO), comparing LFC vehicles (LFCVs) to HFC vehicles (HFCVs), battery electric vehicles (BEVs), and diesel trucks on a pro-forma basis assuming the LFC could be developed to HFC benchmarks.

08 HYDROGEN↗
DOE OSTI2025

Dusty Gas Model for Solid Oxide Fuel Cell Fuel Electrode

This model applies the Dusty Gas Model simulate multi-component species transport in SOFC (solid oxide fuel cell) anodes which considers the pressure gradient across the fuel electrode. This studyhas been verified with the analytical solution for different fuel electrode thicknesses and with literature values. The model was developed using the VoronoiFVM platform in Julia which is a built in implicit and semi implicit solver that integrates electrochemical behavior, microstructural effects, and transient analysis for accurate prediction of species transport under varying conditions.

dusty gas model (DGM)↗
DOE OSTI2020

A Hybrid Pathway to Biojet Fuel via 2,3-Butanediol

Production of biomass-derived sustainable alternative jet fuels (SAJF) has been considered as an important approach to decarbonize the aviation industry but still possesses various challenges in technology advancement, particularly in achieving high carbon efficiency. Here we report a hybrid pathway to SAJF from 2,3-butanediol (2,3-BDO), integrating biologically converting biomass to 2,3-BDO with catalytically upgrading of 2,3-BDO to jet-range hydrocarbons. This pathway is demonstrated to have a high carbon recovery to liquid hydrocarbons from corn stover (25–28%) (74–82% of the theoretical maximum efficiency). The catalytic conversion steps involve 2,3-BDO to C3+ olefins, oligomerization, and hydrogenation where the first two steps are the focus of this study. Under optimum reaction conditions (523 K, 115 kPa, 1.0 h-1 weight hourly space velocity), 2,3-BDO conversion and C3+ olefin selectivity are >97% and 94–98% during 40 h time on stream, respectively. To demonstrate the adaptability of this technology with bio-derived 2,3-BDO, we also investigated the impact of water and other organic coproducts (acetoin and acetic acid) inherited from the fermentation broth on the catalyst performance and product selectivities. We have shown that the catalyst can handle a significant amount of water in the liquid feed (40 wt% water/60 wt% 2,3-BDO) and maintain catalyst stability for ~40 h. Acetoin can be converted to similar C3+ olefins as 2,3-BDO with complete conversion of acetoin. Co-feeding 10 wt% acetoin with 2,3-BDO is found to have no impact on 2,3-BDO conversion, C3+ olefin selectivity, and catalyst stability. The utilization of organic coproduct like acetoin can help to improve overall carbon conversion efficiency when using real biomass-derived 2,3-BDO. On the other hand, the presence of 10 wt% acetic acid is shown to drastically inhibit methyl ethyl ketone (MEK) hydrogenation and butene oligomerization as revealed by the increased MEK and butene selectivities, implying the importance of separating organic acids when feeding bio-derived 2,3-BDO. The formed C3–C6 olefins from 2,3-BDO are further oligomerized over Amberlyst-36 catalyst to longer-chain hydrocarbons with >70 wt% jet-range hydrocarbons including predominantly iso-olefins/iso-paraffins. The overall carbon efficiency for the jet-range hydrocarbons is 19–22%, exceeding most of the reported biojet pathways, which makes it a promising approach for SAJF production.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2020

Aluminum Spent Fuel Performance in Dry Storage Task 4 Aluminum Oxide Sampling of ATR Dry Stored Fuel

Milestone report on sampling of long-term dry-stored ATR spent fuel elements. It describes tooling, sample acquisition methods and analysis of the aluminum oxide samples by scanning electron microscopy, thermogravimetric analysis, X-ray diffraction and transmission electron microscopy. The observations provide input to projections on controls necessary for maintaining the integrity of the fuel during extended interim storage.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Partially-Reflected Water-Moderated Square-Pitched U(6.90)O 2 Fuel Rod Lattices with 0.52 Fuel to Water Volume Ratio (0.855 CM Pitch)

The US Department of Energy (DOE) Nuclear Energy Research Initiative funded the design and construction of the Seven Percent Critical Experiment (7uPCX) at Sandia National Laboratories. The start-up of the experiment facility and the execution of the experiments described here were funded by the DOE Nuclear Criticality Safety Program. The 7uPCX is designed to investigate critical systems with fuel for light water reactors in the enrichment range above 5 % 235 U. The 7uPCX assembly is a water-moderated and -reflected array of aluminum-clad square-pitched U(6.90 %)0 2 fuel rods. Other critical experiments performed in the 7uPCX assembly are documented in LEU-COMP-THERM-078, LEU-COMP-THERM-080, LEU-COMP-THERM-096, and LEU-COMP-THERM-097.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Spent Nuclear Fuel and Reprocessing Waste Inventory: Spent Fuel and Waste Disposition

This report provides information on the inventory of spent nuclear fuel (SNF) in the United States located at Nuclear Power Reactor (NPR) and Independent Spent Fuel Storage Installation (ISFSI) sites, as well as SNF and reprocessing waste located at U.S. Department of Energy (DOE) sites and other research and development (R&D) centers as of the end of calendar year 2021. Actual or estimated quantitative values for current inventories are provided along with inventory forecasts derived from examining different future nuclear power generation scenarios, based on information available and assumptions made at the time the scenarios were developed in the spring of 2022. The report also includes select information on the characteristics associated with the wastes examined (e.g., type, packaging, heat generation rate, decay curves).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗