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At least 217 records · Page 12

Chemical and structural characterization of EUV photoresists as a function of depth by standing-wave x-ray photoelectron spectroscopy

The success in the miniaturization of the electronic device constituents depends mostly on the photolithographic techniques. Recently, to achieve patterning at the sub-10-nm node, extreme ultraviolet (EUV) lithography has been introduced into high volume production. Continued scaling of EUV via increased numerical aperture to achieve nodes at 3-nm and below requires the development of fundamentally new patterning materials and new characterization methods. Current EUV-resist film thicknesses are in the 20- to 40-nm range, and further thickness reduction is required for the next generation. Therefore, interfaces become exceedingly important, and the properties of the resist film would be dominated by top and bottom interfacial effects. X-ray photoelectron spectroscopy (XPS) combined with standing-wave excitation (SW-XPS), a fairly new method in the EUV lithography field, previously had been largely applied in multilayers and superlattices for characterizing the composition and electronic structure of buried layers and interfaces as a function of depth. We applied the SW-XPS method to organic/inorganic photoresists to provide depth-selective information on their structural and chemical conditions of as a function of temperature, EUV exposure, different underlayers, and other fundamental parameters. As a first attempt, we perform an SW-XPS feasibility study on self-assembled monolayer (SAM) films after exposure to an electron beam. By SW-XPS, we determined that the interface between the Al 2 O 3 underlayer and the SAMs is smooth, with a mean roughness of about 0.2 nm. Moreover, we determined that the SAM chains are, on average, tilted by 1/430 deg off the sample normal. The SW-XPS results also suggest that the SAM is not a perfectly aligned and uniform monolayer, with some areas having thickness higher than a single monolayer. We demonstrated that SW-XPS can provide useful information on ultrathin materials with high potential for being used as a characterization method of organic/inorganic photoresists.

36 MATERIALS SCIENCE↗

Visualizing heterogeneous dipole fields by terahertz light coupling in individual nano-junctions

The challenge underlying superconducting quantum computing is to remove materials bottleneck for highly coherent quantum devices. The nonuniformity and complex structural components in the underlying quantum circuits often lead to local electric field concentration, charge scattering, dissipation and ultimately decoherence. Here we visualize interface dipole heterogeneous distribution of individual Al/AlO$_{x}$/Al junctions employed in transmon qubits by broadband terahertz scanning near-field microscopy that enables the non-destructive and contactless identification of defective boundaries in nano-junctions at an extremely precise nanoscale level. Our THz nano-imaging tool reveals an asymmetry across the junction in electromagnetic wave-junction coupling response that manifests as hot (high intensity) vs cold (low intensity) spots in the spatial electrical field structures and correlates with defected boundaries from the multi-angle deposition processes in Josephson junction fabrication inside qubit devices. The demonstrated local electromagnetic scattering method offers high sensitivity, allowing for reliable device defect detection in the pursuit of improved quantum circuit fabrication for ultimately optimizing coherence times.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Swift and extensive Omicron outbreak in China after sudden exit from ‘zero-COVID’ policy

In late 2022, China transitioned from a strict ‘zero-COVID’ policy to rapidly abandoning nearly all interventions and data reporting. This raised great concern about the presumably-rapid but unreported spread of the SARS-CoV-2 Omicron variant in a very large population of very low pre-existing immunity. By modeling a combination of case count and survey data, we show that Omicron spread extremely rapidly, at a rate of 0.42/day (95% credibility interval: [0.35, 0.51]/day), translating to an epidemic doubling time of 1.6 days ([1.6, 2.0] days) after the full exit from zero-COVID on Dec. 7, 2022. Consequently, we estimate that the vast majority of the population (97% [95%, 99%], sensitivity analysis lower limit of 90%) was infected during December, with the nation-wide epidemic peaking on Dec. 23. Overall, our results highlight the extremely high transmissibility of the variant and the importance of proper design of intervention exit strategies to avoid large infection waves.

60 APPLIED LIFE SCIENCES↗

Photometric detection of internal gravity waves in upper main-sequence stars

Massive stars are predicted to excite internal gravity waves (IGWs) by turbulent core convection and from turbulent pressure fluctuations in their near-surface layers. These IGWs are extremely efficient at transporting angular momentum and chemical species within stellar interiors, but they remain largely unconstrained observationally. In this work, we aim to characterise the photometric detection of IGWs across a large number of O and early-B stars in the Hertzsprung–Russell diagram, and explain the ubiquitous detection of stochastic variability in the photospheres of massive stars. Furthermore, we combined high-precision time-series photometry from the NASA Transiting Exoplanet Survey Satellite with high-resolution ground-based spectroscopy of 70 stars with spectral types O and B to probe the relationship between the photometric signatures of IGWs and parameters such as spectroscopic mass, luminosity, and macroturbulence.

79 ASTRONOMY AND ASTROPHYSICS↗

The Extraordinary March 2022 East Antarctica “Heat” Wave. Part II: Impacts on the Antarctic Ice Sheet

Abstract Between 15 and 19 March 2022, East Antarctica experienced an exceptional heat wave with widespread 30°–40°C temperature anomalies across the ice sheet. In Part I, we assessed the meteorological drivers that generated an intense atmospheric river (AR) that caused these record-shattering temperature anomalies. Here, we continue our large collaborative study by analyzing the widespread and diverse impacts driven by the AR landfall. These impacts included widespread rain and surface melt that was recorded along coastal areas, but this was outweighed by widespread high snowfall accumulations resulting in a largely positive surface mass balance contribution to the East Antarctic region. An analysis of the surface energy budget indicated that widespread downward longwave radiation anomalies caused by large cloud-liquid water contents along with some scattered solar radiation produced intense surface warming. Isotope measurements of the moisture were highly elevated, likely imprinting a strong signal for past climate reconstructions. The AR event attenuated cosmic ray measurements at Concordia, something previously never observed. Last, an extratropical cyclone west of the AR landfall likely triggered the final collapse of the critically unstable Conger Ice Shelf while further reducing an already record low sea ice extent. Significance Statement Using our diverse collective expertise, we explored the impacts from the March 2022 heat wave and atmospheric river across East Antarctica. One key takeaway is that the Antarctic cryosphere is highly sensitive to meteorological extremes originating from the midlatitudes and subtropics. Despite the large positive temperature anomalies driven from strong downward longwave radiation, this event led to huge amounts of snowfall across the Antarctic interior desert. The isotopes in this snow of warm airmass origin will likely be detectable in future ice cores and potentially distort past climate reconstructions. Even measurements of space activity were affected. Also, the swells generated from this storm helped to trigger the final collapse of an already critically unstable Conger Ice Shelf while further degrading sea ice coverage.

Wille, Jonathan D.↗

Using AI to build a hydrobiogeochemical soil model

Soil water content is a function of inputs from precipitation and outputs via evaporation, transpiration, lateral flow, and vertical percolation, and is sensitive to biogeochemical processes. As such, soils serve as an ideal integrator of atmospheric, hydrological, and biogeochemical processes affecting the water cycle. In addition, soil water retention capacity, infiltration rates, and hydraulic conductivity can buffer or exacerbate the effects of extreme precipitation events (e.g., flooding, runoff, subsurface transport, erosion, greenhouse gas emissions) and mitigate the impact of droughts and heat waves on land systems (e.g., fire, crop failure). However, integrating water cycle measurements spanning different land atmosphere compartments across scales is a fundamental barrier for numerical model predictability. A significant challenge is that each domain (soil, hydrology, biology, and atmosphere) typically collects different sets of data at different temporal and spatial frequencies/scales, and even different dimensionalities (2D vs 3D). To implement soil as an integrator of the water cycle in land models, we suggest that novel machine learning (ML) tools can be developed to effectively simulate complex landscapes across various domains and scales, extended to regions with sparse or no data. The ultimate goals are to improve predictive understanding of land-atmosphere interactions and to extend the predictability of current Earth System Models (ESMs) through better integration of hydrological and biogeochemical data. We envision a framework in which: (1) ML-aided data reconstructions enable the merger of data sources into a unified geospatial product; (2) automated detection techniques are used to improve the knowledge of complex soil processes and interactions; and (3) this knowledge is leveraged and incorporated into models through AI-based emulators to distinctly connect the land and atmospheric compartments of the water cycle in models.

54 ENVIRONMENTAL SCIENCES↗

Multimessenger Characterization of Markarian 501 during Historically Low X-Ray and γ-Ray Activity

We study the broadband emission of Mrk 501 using multiwavelength observations from 2017 to 2020 performed with a multitude of instruments, involving, among others, MAGIC, Fermi's Large Area Telescope (LAT), NuSTAR, Swift, GASP-WEBT, and the Owens Valley Radio Observatory. Mrk 501 showed an extremely low broadband activity, which may help to unravel its baseline emission. Nonetheless, significant flux variations are detected at all wave bands, with the highest occurring at X-rays and very-high-energy (VHE) γ-rays. A significant correlation (>3σ) between X-rays and VHE γ-rays is measured, supporting leptonic scenarios to explain the variable parts of the emission, also during low activity. This is further supported when we extend our data from 2008 to 2020, and identify, for the first time, significant correlations between the Swift X-Ray Telescope and Fermi-LAT. We additionally find correlations between high-energy γ-rays and radio, with the radio lagging by more than 100 days, placing the γ-ray emission zone upstream of the radio-bright regions in the jet. Furthermore, Mrk 501 showed a historically low activity in X-rays and VHE γ-rays from mid-2017 to mid-2019 with a stable VHE flux (>0.2 TeV) of 5% the emission of the Crab Nebula. The broadband spectral energy distribution (SED) of this 2 yr long low state, the potential baseline emission of Mrk 501, can be characterized with one-zone leptonic models, and with (lepto)-hadronic models fulfilling neutrino flux constraints from IceCube. We explore the time evolution of the SED toward the low state, revealing that the stable baseline emission may be ascribed to a standing shock, and the variable emission to an additional expanding or traveling shock.

79 ASTRONOMY AND ASTROPHYSICS↗

Understanding the effects of radiative preheat and self-emission from shock heating on equation of state measurement at 100s of Mbar using spherically converging shock waves in a NIF hohlraum

Over the last six years many experiments have been done at the National Ignition Facility to measure the Hugoniot of materials, such as CH plastic at extreme pressures, up to 800 Mbar. The “Gbar” design employs a strong spherically converging shock launched through a solid ball of material using a hohlraum radiation drive. Here, the shock front conditions are characterized using x-ray radiography. In this paper we examine the role of radiation in heating the unshocked material in front of the shock to understand the impact it has on equation of state measurements and how it drives the measured data off the theoretical Hugoniot curve. In particular, the two main sources of radiation heating are the preheating of the unshocked material by the high-energy kilo-electron-volt x-rays in the hohlraum and the heating of the material in front of the shock, as the shocked material becomes hot enough to radiate significantly. Using our model, we estimate that preheating can reach 4 eV in unshocked material, and that radiation heating can begin to drive data off the Hugoniot significantly, as pressures reach above 400 Mb.

Equations of state↗

Multi-criteria thermal resilience certification scheme for indoor built environments during heat waves

With climate change, the indoor built environment is expected to significantly influence the occupant's safety and well-being. A novel multi-criteria thermal resilience certification scheme for indoor built environments during extreme heat events is proposed in this paper. The certification scheme considers overheating, thermal comfort, heat stress, and hygrothermal discomfort in built environments. These criteria are quantified using key performance indicators like indoor overheating degree, hours of exceedance, wet-bulb globe temperature, and heat index, respectively. This scheme is developed based on existing best practices like standards, rating systems, and literature. The scheme is implemented on a benchmark building energy performance model for detached post-World War II dwellings in Belgium as a case study using weather data measured from the City of Brussels. The indoor overheating in the reference dwelling is assessed with a static threshold of 27 °C for the bedrooms and adaptive thresholds for other areas. The analysis found that the building performance is within the defined threshold levels throughout the heat wave duration for all criteria. Therefore, the reference dwelling got a maximum attainable score of four points and is rated five-star for thermal resilience during heat waves. The proposed certification scheme is intended as a standardized framework and highlights the need for further revisions in building performance policies and guidelines.

Climate change↗

Time-Domain Extreme-Ultraviolet Diffuse Scattering Spectroscopy of Nanoscale Surface Phonons

Here, we report the observation of dynamic fringe patterns in the diffuse scattering of extreme ultraviolet light from surfaces, following femtosecond optical excitation. At each point on the detector, the diffuse scattering intensity exhibits oscillations at well-defined frequencies that correspond to surface phonons with wave vectors determined by the scattering geometry, indicating that the optical excitation generates coherent surface phonons propagating in all directions and spanning a wavelength range from 60 to 300 nm. This phenomenon is observed on a variety of samples, including single-layer and multilayer metal films, as well as bulk semiconductors. The measured surface phonon dispersions show good agreement with theoretical calculations. By comparing signal amplitudes from samples with different surface morphologies, we find that the excitation mechanism is linked to the natural surface roughness of the samples. However, the signal is still detectable on extremely smooth surfaces with subnanometer roughness. Our findings demonstrate a simple and effective method for optically exciting coherent surface phonons with nanoscale wavelengths on a wide range of solid samples and establish a foundation for surface phonon spectroscopy in a wave vector range well beyond the limit of conventional surface Brillouin scattering.

Capotondi, F. [Elettra-Sincrotrone Trieste (Italy)↗

Conceptual design of the LHCD system on CFETR

With the capability of saving flux consumption in the current ramp up phase, controlling the safety factor (q) profile, providing the required off-axis current drive (CD), a lower hybrid current drive (LHCD) system was eventually determined to be used on the China Fusion Engineering Test Reactor (CFETR). Here, in this paper, a 20 MW/4.6 GHz system composed of 40 units of 500 kW continuous wave (CW) klystron amplifier is preliminarily designed. The feasibility of the frequency choice of 4.6 GHz in the physical aspect is discussed. In order to minimize the transmission loss, a TE01 over-mode of circular waveguide will be used in the transmission system. Although previous calculations indicates that high field side (HFS) launcher location results in waves damping at inner region than low field side (LFS) launcher, which is favorable for plasma stability, HFS launcher will be extremely difficult in engineering due to the limited space. Calculations show that the tritium breeding ratio (TBR) will be decreased by ~ 1.5% with HFS launcher, while it will be decreased by ~ 0.22% only with LFS launcher. As a result, the LH power will be coupled to plasma from the top port at LFS. The designed passive active multi-junction (PAM) launcher is arranged in an array of 5 rows and 8 columns with the height of 1181 mm and the width of 794 mm. A shielding block with a thickness of 20 cm will be equipped around the feeding waveguides to protect the feeding waveguides and to prevent neutron leakage. A preliminary scheme of the remote maintenance for the LFS launcher is given. The modeling results shows that the density for optimum coupling is ~ 1.8 × 10 17 /m 3 , lower than the 4.6 GHz cut-off density n e_co = 2.6 × 10 17 /m 3 . Around this density, the power directivity (D p ) can be high as 71%.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Machine learning based algorithms for uncertainty quantification in numerical weather prediction models

Complex numerical weather prediction models incorporate a variety of physical processes, each described by multiple alternative physical schemes with specific parameters. The selection of the physical schemes and the choice of the corresponding physical parameters during model configuration can significantly impact the accuracy of model forecasts. There is no combination of physical schemes that works best for all times, at all locations, and under all conditions. It is therefore of considerable interest to understand the interplay between the choice of physics and the accuracy of the resulting forecasts under different conditions. This paper demonstrates the use of machine learning techniques to study the uncertainty in numerical weather prediction models due to the interaction of multiple physical processes. The first problem addressed herein is the estimation of systematic model errors in output quantities of interest at future times, and the use of this information to improve the model forecasts. The second problem considered is the identification of those specific physical processes that contribute most to the forecast uncertainty in the quantity of interest under specified meteorological conditions. In order to address these questions we employ two machine learning approaches, random forests and artificial neural networks. The discrepancies between model results and observations at past times are used to learn the relationships between the choice of physical processes and the resulting forecast errors. Numerical experiments are carried out with the Weather Research and Forecasting (WRF) model. The output quantity of interest is the model precipitation, a variable that is both extremely important and very challenging to forecast. The physical processes under consideration include various micro-physics schemes, cumulus parameterizations, short wave, and long wave radiation schemes. The experiments demonstrate the strong potential of machine learning approaches to aid the study of model errors.

97 MATHEMATICS AND COMPUTING↗

Resilience assessment and planning in power distribution systems: Past and future considerations

High impact low probability (HILP) events such as hurricanes, heat waves, and floods have instigated widespread power outages and blackouts around the globe in the past decade. With the increasing challenges concerning the threats to the power distribution systems and the growing need to mitigate the impacts of the HILP events, resilience has become a crucial requirement for the power grid infrastructures. Numerous efforts have been made to define, measure, and characterize the resilience of power distribution systems. This study thoroughly reviews the state-of-the-art methods on the existing resilience evaluation framework and metrics. Here, the desirable characteristics of resilience metrics are highlighted, and the challenges associated with formulating, developing, and calculating such metrics are discussed. Next, we detail the state-of-the-art literature on planning solutions to ensure distribution system resilience. This paper aims to extract a deep insight into this challenging and critical research area and envision future opportunities that can guide the power distribution system operators/planners to formulate more effective mitigation strategies to enhance the resilience of power distribution systems.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Forecasting Tropical Annual Maximum Wet-Bulb Temperatures Months in Advance From the Current State of ENSO

Humid heatwaves, characterized by high temperature and humidity combinations, challenge tropical societies. Extreme wet-bulb temperatures (TW) over tropical land are coupled to the warmest sea surface temperatures by atmospheric convection and wave dynamics. Here, we harness this coupling for seasonal forecasts of the annual maximum of daily maximum TW (TW max ). We develop a multiple linear regression model that explains 80% of variance in tropical mean TW max and significant regional TW max variances. The model considers warming trends and El Niño and Southern Oscillation indices. Looking ahead, the strong-to-very-strong El Niño at the end of 2023, with an Oceanic Niño Index of ~2.0, suggests a 2024 tropical land mean TW max of 26.2°C (25.9–26.4°C), and a 68% chance (24%–94%) of breaking existing records. This method also predicts regional TW max in specific areas.

54 ENVIRONMENTAL SCIENCES↗

Energy density and spectrum of single-cycle and sub-cycle electromagnetic pulses

Based on the exact solution of the Maxwell equations in the form of a collapsing spherical vector wave specified by an arbitrary function of time, we have calculated the maximum energy density that can be achieved when focusing extremely short pulses of various shapes. It is shown that our earlier formula expressing the maximum energy density in terms of the spectrum parameters for Gaussian quasi-monochromatic pulses is approximately (with an accuracy of ±40 %) valid for the main types of extremely short pulses. (extremely short laser pulses)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Superconductivity at carrier density 10 17 cm – 3 in quasi-one-dimensional Li 0.9 Mo 6 O 17

Superconductivity is a fascinating phenomenon that involves an attractive interaction by which electrons are paired and can move without electrical resistance below a critical temperature T c . A paradigm for understanding superconductive pairing, the successful “BCS” theory, developed more than 65 years ago, is challenged by certain classes of materials for which parameters (e.g. the value of T c , the density of electrons, etc.) fall outside the range for which BCS theory is applicable. The study of such materials is important because new physics may be revealed and because superconductivity has many potential applications in sensing and electronics. Superconductivity at very low carrier density is a rare and fascinating phenomenon that is of considerable importance and interest in condensed matter physics. The conditions of high density of states and effective screening of Coulomb repulsion, both key ingredients of stable Cooper pairing in the BCS theory, may not be met at low carrier density. Thus, such systems may also harbor unconventional electron pairing (e.g. non-phononic) or pairing without phase coherence as a precursor to Bose-Einstein condensation. An intriguing route toward extreme low-density (and possibly unconventional) superconductivity may be found in quasi-one-dimensional metals for which density-wave instabilities compete for the ground state and can lead to gapping of substantial portions of the Fermi surface (FS), leaving a residual (reconstructed) FS comprising a very small carrier density. Our work highlights a novel material in this unusual category: Li 0.9 Mo 6 O 17 (T c =2 K) (also known as "lithium purple bronze" or "LiPB"). We present both electrical and thermoelectric magnetotransport measurements that reveal superconductivity to occur at carrier density 2 x10 17 cm -3 , among the lowest known for any superconductor, and four orders of magnitude lower than is expected from its chemical valence and band structure. With its exceptionally large ratio of superconducting to Fermi temperature, T c /TF ≳ 0.1, LiPB is properly placed at the top of a very small group of superconductors (including cuprates, heavy-fermion and Fe-based superconductors) for which this ratio falls in the BCS-BEC crossover regime and for which pairing is believed to be spin mediated.

36 MATERIALS SCIENCE↗

Ultra-High Vacuum Outgassing Characterization of Thermally Processed Low-Carbon Steel for Advanced Particle Accelerator and Gravitational Wave Detector Applications

This dissertation investigated AISI 1020 low-carbon steel as an alternative vacuum chamber material to conventional stainless steel for ultra-high vacuum (UHV) and extreme-high vacuum (XHV) applications. After a 400 °C/48 h bake, AISI 1020 tube chambers achieved a hydrogen outgassing rate of 2.4 × 10¿¹6 Torr·L·s¿¹·cm¿², approximately 2,300 times lower than the prebaked 316L stainless-steel comparator, among the lowest hydrogen outgassing rates ever reported for an uncoated metallic vacuum chamber. Bare and magnetite-coated AISI 1020 chambers were then compared using throughput and rate-of-rise methods. The magnetite coating yielded 5× lower water outgassing at room temperature, but this advantage disappeared after 80 °C baking. After full thermal conditioning (400 °C/48 h prebake followed by 150 °C/96 h and 200 °C/110 h), bare steel achieved 25× lower hydrogen outgassing than the magnetite-coated chamber (9.6 × 10¿¹6 Torr·L·s¿¹·cm¿²) and >99% H2 purity with carbon species below RGA detection. Monte Carlo molecular flow simulations of a CEBAF photogun beamline (96 scenarios) showed that replacing 304L stainless steel with AISI 1020 reduces equilibrium H2 pressure by a factor of 833; a single 304L electrode contributes 98.8% of the gas load despite occupying only 9.1% of the internal surface area. A 500-m Einstein Telescope beampipe screening showed that corrugated bellows contribute 18% of the gas load from only 0.7% of the surface area. A five-model adsorption isotherm framework applied to 22 pumpdown datasets (164 fits with AR(1)-GLS correction) established that the experimental protocol, not the material, controls isotherm identifiability: Dubinin–Radushkevich wins isothermal pipe pumpdowns; Langmuir wins thermally dominated chamber bakes. Cross-dataset joint fitting of the AISI 1020 pipe pumpdowns yielded an H2 diffusion activation energy Ed = 7.24 ± 1.28 kcal·mol¿¹, consistent with trap dominated diffusion in commercial low-carbon steels. Two companion innovations were developed: a Variable Conductance Device (VCD, patent pending IDF-00723) for XHV outgassing measurement, and VacuumDesignerPro (VDP), a MATLAB-based design tool validated against LIGO benchmarks.

Al-Allaq, Aiman H [Old Dominion University]↗

Removing solar artifacts from Geostationary Lightning Mapper data to document lightning extremes

Here, we compare the performance of three different filters that identify solar artifacts in the Geostationary Lightning Mapper (GLM) data. These filters differ in their complexity and intended use. We use the most appropriate filters to document the severity of GLM solar contamination and to compute the frequency of extreme Americas lightning. Solar artifacts occur at an average rate of one every ~8 min. Due to their continuous emissions across a portion of the GLM CCD array, these events disproportionately contribute to the GLM event and group rates. Up to 40% of all events recorded between 10:00 and 12:00 local time during 2018 were solar artifacts. The frequency-domain solar filter also reveals a carrier wave at 50 to 60 Hz in some lightning flashes and solar episodes that appears to be anthropogenic in origin. Removing the relatively frequent solar artifact cases reveals rare cases of extreme lightning flashes. Exceptional flashes on the order of 500+ km in length and 10+ s in duration only occur a few times per year and are produced by storms that are predisposed for exceptional lightning rather than as single random occurrences.

54 ENVIRONMENTAL SCIENCES↗