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Results for “conditional neutrality”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12

Use of a Multiple Hydride Donor To Achieve an n-Doped Polymer with High Solvent Resistance

We report the ability to insolubilize doped semiconducting polymer layers can help enable the fabrication of efficient multilayer solution-processed electronic and optoelectronic devices. Here, we present a promising approach to simultaneously n-dope and largely insolubilize conjugated polymer films using tetrakis[{4-(1,3-dimethyl-2,3-dihydro-1H-benzo[d]imidazol-2-yl)phenoxy}methyl]methane (tetrakis-O-DMBI-H), which consists of four 2,3-dihydro-1H-benzoimidazole (DMBI-H) n-dopant moieties covalently linked to one another. Doping a thiophene-fused benzodifurandione-based oligo(p-phenylenevinylene)-co-thiophene polymer (TBDOPV-T) with tetrakis-O-DMBI-H results in a highly n-doped film with bulk conductivity of 15 S cm –1 . Optical absorption spectra provide evidence for film retention of ~93% after immersion in o-dichlorobenzene for 5 min. The optical absorption signature of the charge carriers in the n-doped polymer decreases only slightly more than that of the neutral polymer under these conditions, indicating that the exposure to solvent also results in negligible dedoping of the film. Moreover, thermal treatment studies on a tetrakis-O-DMBI-H-doped TBDOPV-T film in contact with another undoped polymer film indicate immobilization of the molecular dopant in TBDOPV-T. This is attributed to the multiple electrostatic interactions between each dopant tetracation and up to four nearby anionic doped polymer segments.

36 MATERIALS SCIENCE↗

Deep Learning for Subgrid‐Scale Turbulence Modeling in Large‐Eddy Simulations of the Convective Atmospheric Boundary Layer

Abstract In large‐eddy simulations, subgrid‐scale (SGS) processes are parameterized as a function of filtered grid‐scale variables. First‐order, algebraic SGS models are based on the eddy‐viscosity assumption, which does not always hold for turbulence. Here we apply supervised deep neural networks (DNNs) to learn SGS stresses from a set of neighboring coarse‐grained velocity from direct numerical simulations of the convective boundary layer at friction Reynolds numbers Re τ up to 1243 without invoking the eddy‐viscosity assumption. The DNN model was found to produce higher correlation between SGS stresses compared to the Smagorinsky model and the Smagorinsky‐Bardina mixed model in the surface and mixed layers and can be applied to different grid resolutions and various stability conditions ranging from near neutral to very unstable. The DNN model can capture key statistics of turbulence in a posteriori (online) tests when applied to large‐eddy simulations of the atmospheric boundary layer.

54 ENVIRONMENTAL SCIENCES↗

Enhanced pedestal H-mode at low edge ion collisionality on NSTX

The Enhanced Pedestal (EP) H-mode regime is an attractive wide-pedestal high-βp scenario for the National Spherical Torus Experiment Upgrade (NSTX-U) and next-step devices as it achieves enhanced energy confinement (H98y,2 > 1.5), large normalized pressure (βN > 5), and significant bootstrap fraction (fBS > 0.6) at Ip/BT = 2 MA/T. This regime is realized when the edge ion collisionality becomes sufficiently small that a positive feedback interaction occurs between a reduction in the ion neoclassical energy transport and an increase in the particle transport from pressure-driven edge instabilities. The EP H-mode was most often observed as a transition following a large edge-localized mode in conditions with low edge neutral recycling. It is hypothesized that the onset of pressure-driven instabilities prior to the full recovery of the neutral density leads to a temporary period with an elevated ion temperature gradient that triggers the transition to EP H-mode. Linear CGYRO and M3D-C1 calculations are compared to beam emission spectroscopy and magnetic spectroscopy in order to describe the evolution of the edge particle transport mechanisms during the ELM recovery and the saturated EP H-mode state. The observations are consistent with the hypothesis that the onset of pressure-driven edge instabilities, such as the kinetic ballooning mode and kink-peeling mode, can be responsible for the increased particle transport in EP H-mode.

Battaglia, D. J. (ORCID:0000000188979740)↗

Enhanced Pedestal H-mode at low edge ion collisionality on NSTX

The Enhanced Pedestal (EP) H-mode regime is an attractive wide-pedestal ELM-free high-betap scenario for NSTX-U and next-step devices as it achieves enhanced energy confinement (H98y,2 > 1.5), large normalized pressure (betaN > 5) and significant bootstrap fraction (f_BS > 0.6) at I_p/B_T = 2 MA/T. This regime is realized when the edge ion collisionality becomes sufficiently small that a positive feedback interaction occurs between a reduction in the ion neoclassical energy transport and an increase in the particle transport from pressure-driven edge instabilities. EP H-mode was most often observed as a transition following a large ELM in conditions with low edge neutral recycling. It is hypothesized that the onset of pressure-driven instabilities prior to the full recovery of the neutral density leads to a temporary period with elevated ion temperature gradient that triggers the transition to EP H-mode. Linear CGYRO and M3D-C1 calculations are compared to beam emission spectroscopy (BES) and magnetic spectroscopy in order to describe the evolution of the edge particle transport mechanisms during the ELM recovery and the saturated EP H-mode state. The observations are consistent with the hypothesis that the onset of pressure-driven edge instabilities, such as the KBM and kink-peeling, can be responsible for the increased particle transport in EP H-mode.

edge and boundary physics↗

Collisionless solar wind. II - Variable electron temperature.

Examination of a two-component ?model' for the solar wind, in which the protons become collisionless beyond a distance from the solar center equal to or greater than 10 solar radii, where they are already highly supersonic. The proton temperatures are found from the double adiabatic equation of state. The electrons are highly subsonic, and their temperature profile is prescribed ad hoc. The momentum equations for the electrons and protons are solved subject to the conditions of quasi-neutrality and zero charge efflux from the sun. Some of the principal results are: (1) the proton thermal anisotropy is substantially reduced when solar rotation is considered; (2) solar rotation leads to significantly lower mean proton temperatures; and (3) the electron temperature profile in the supersonic region is the primary parameter determining flow acceleration there.

Hollweg, J. V.↗

Stable boundary layer wind shear model for aircraft flight hazard definition

It is pointed out that wind shear, particularly at the lower altitudes in the terminal area, has been identified as being hazardous to aircraft operations. Accurate and reliable wind profiles are required for use in fast time and manned flight simulation studies aimed at fully defining and understanding the wind shear hazard. A description is presented of wind speed profiles for neutral and stable atmospheric conditions developed for the simulation studies to improve the safety and reliability of operations in the terminal area. The wind shear is mathematically modeled and the mathematical scenarios are presented in a format for direct application to wind shear hazard/flight simulation studies.

Frost, W.↗

Charge neutralization as studied experimentally and theoretically

Problems regarding an isolated sphere which emits negative charge are considered. Such a sphere could charge up to large potentials which would inhibit the electron beam from leaving the vicinity of the body. In order to avoid charging to high potentials, a vehicle must attract a return current equal to the emitted current. The present investigation is concerned with theoretical models of some processes believed to be important for the vehicle neutralization problem under various conditions. Attention is given to general time-scale considerations, the low-altitude regime, the high-altitude regime, vehicle-induced discharge, and beam-plasma discharge. The general pattern which emeres as a result of measurements is that below altitudes of approximately 125 + or - 5 km the vehicle potential rarely rises more than several tens of volts.

Linson, L. M.↗

The inviscid stability of supersonic flow past axisymmetric bodies

The supersonic flow past a sharp cone is studied. The associated boundary layer flow (i.e., the velocity and temperature field) is computed. The inviscid linear temporal stability of axisymmetric boundary layers in general is considered, and in particular, a so-called 'triply generalized' inflection condition for 'subsonic' nonaxisymmetric neutral modes is presented. Preliminary numerical results for the stability of the cone boundary layer are presented for a freestream Mach number of 3.8. In particular, a new inviscid mode of instability is seen to occur in certain regimes, and this is shown to be related to a viscous mode found by Duck and Hall (1988).

Duck, Peter W.↗

Thermal Infrared Emission Spectroscopy of Synthetic Allophane and its Potential Formation on Mars

Allophane is a poorly-crystalline, hydrous aluminosilicate with variable Si/Al ratios approx.0.5-1 and a metastable precursor of clay minerals. On Earth, it forms rapidly by aqueous alteration of volcanic glass under neutral to slightly acidic conditions [1]. Based on in situ chemical measurements and the identification of alteration phases [2-4], the Martian surface is interpreted to have been chemically weathered on local to regional scales. Chemical models of altered surfaces detected by the Mars Exploration Rover Spirit in Gusev crater suggest the presence of an allophane-like alteration product [3]. Thermal infrared (TIR) spectroscopy and spectral deconvolution models are primary tools for determining the mineralogy of the Martian surface [5]. Spectral models of data from the Thermal Emission Spectrometer (TES) indicate a global compositional dichotomy, where high latitudes tend to be enriched in a high-silica material [6,7], interpreted as high-silica, K-rich volcanic glass [6,8]. However, later interpretations proposed that the high-silica material may be an alteration product (such as amorphous silica, clay minerals, or allophane) and that high latitude surfaces are chemically weathered [9-11]. A TIR spectral library of pure minerals is available for the public [12], but it does not contain allophane spectra. The identification of allophane on the Martian surface would indicate high water activity at the time of its formation and would help constrain the aqueous alteration environment [13,14]. The addition of allophane to the spectral library is necessary to address the global compositional dichotomy. In this study, we characterize a synthetic allophane by IR spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) to create an IR emission spectrum of pure allophane for the Mars science community to use in Martian spectral models.

Rampe, E. B.↗

In Situ Analysis of Organics with a Portable Mass Spectrometer

The search for extra-terrestrial life starts at home. In order to find life on other planets, we start by examining life processes we understand on the earth. Though it may not be possible to see the life in the form of macroscopic organisms, telltale signs of life can exist in the form of small organic molecules such as peptides and amino acids. Our overall goal is to test a portable mass spectrometer (MS) system, the Mini 10.5, for astrobiological applications including in situ hydrocarbon analysis and sediments analysis using an additional automated sample processing system (ASPS). The collaborative research focuses on two current projects in the field of astrobiology. Both projects are geared towards examining organics distributed in extreme environments. One portion of study attempts to qualitatively analyze the effect of volatile organic compounds (VOC) produced by diesel exhaust on lichens growing in the desert. This requires measurements to be taken by bringing the instrument to the Mojave Desert and monitoring atmospheric composition of VOCs in situ. The second project is to evaluate the miniature MS system as a detector for the ASPS extraction system. A major obstacle of any chemometric in situ analysis is the suppression of analyte signal by concomitant signal from the surrounding environment. The ASPS extraction device has been developed at JPL to extract amino acids from sediment samples and elute them in solution. The solution is eluted at a high pH and needs to be conditioned to a more neutral pH so that dissolved amino acids can be readily protonated and subsequently analyzed by electrospray MS.

astrobiology↗

Tropospheric Temperature

The 2020 annual global lower tropospheric temperature (LTT) tied with 2016 as the highest on record. The annual average LTT was 0.49°–0.72°C above the 1981–2010 average, depending on dataset, and 10%–16% of Earth’s surface experienced record high temperatures (Plate 2.1e). Such expansive and record warmth is notable because it occurred even though the ENSO exhibited neutral or La Niña conditions throughout the year (Fig. 2.7a) and is thus consistent with the background upward trend since 1958.

54 ENVIRONMENTAL SCIENCES↗

A Graphics Processing Unit (GPU) Approach to Large Eddy Simulation (LES) for Transport and Contaminant Dispersion

Recent advances in the development of large eddy simulation (LES) atmospheric models with corresponding atmospheric transport and dispersion (AT&D) modeling capabilities have made it possible to simulate short, time-averaged, single realizations of pollutant dispersion at the spatial and temporal resolution necessary for common atmospheric dispersion needs, such as designing air sampling networks, assessing pollutant sensor system performance, and characterizing the impact of airborne materials on human health. The high computational burden required to form an ensemble of single-realization dispersion solutions using an LES and coupled AT&D model has, until recently, limited its use to a few proof-of-concept studies. An example of an LES model that can meet the temporal and spatial resolution and computational requirements of these applications is the joint outdoor-indoor urban large eddy simulation (JOULES). A key enabling element within JOULES is the computationally efficient graphics processing unit (GPU)-based LES, which is on the order of 150 times faster than if the LES contaminant dispersion simulations were executed on a central processing unit (CPU) computing platform. JOULES is capable of resolving the turbulence components at a suitable scale for both open terrain and urban landscapes, e.g., owing to varying environmental conditions and a diverse building topology. In this paper, we describe the JOULES modeling system, prior efforts to validate the accuracy of its meteorological simulations, and current results from an evaluation that uses ensembles of dispersion solutions for unstable, neutral, and stable static stability conditions in an open terrain environment.

54 ENVIRONMENTAL SCIENCES↗

Pressure anisotropy and radial stress balance in the Jovian neutral sheet

By examining particle and magnetic field data from the Voyager 1 and 2 spacecraft, signatures were found indicating that the (greater than about 28 keV) particle pressure parallel to the magnetic field is greater than the pressure perpendicular to the field within the nightside neutral sheet (three nightside neutral sheet crossings, with favorable experimental conditions, were used). By incorporating the pressure anisotropy into the calculation of radial forces within the hightside neutral sheet, it is found that (1) force balance is approximately achieved and (2) the anisotropy force term provides the largest contribution of the other particle forces considered (pressure gradients and the corotation centrifugal force). With regard to the problem of understanding the balance of radial forces within the dayside neutral sheet (McNutt, 1984; Mauk and Krimigis, 1987), the nightside pressure anisotropy force is larger than the dayside pressure gradient forces at equivalent radial distances; however, a full accounting of the dayside regions remains to be achieved.

Paranicas, C. P.↗

Simulation of Liquid Lithium Divertor Geometry Using SOLPS-ITER

Here, plasma-facing component (PFC) geometries are evaluated for a Fusion Nuclear Science Facility (FNSF) design to find solutions that are compatible with flowing liquid lithium components while satisfying requirements from the perspective of plasma and neutral particle transport. Flowing liquid metal (LM) divertor systems offer important advantages due to continual regeneration of the surface material, but may require modifications from standard optimized tokamak divertor designs. Scrape Off Layer Plasma Simulator for the International Thermonuclear Experimental Reactor (SOLPS-ITER) simulations are used to compare standard vertical target, open, and balanced baffled geometries. It is found that the open geometry offers little control of neutral particles and has narrow operating windows where the divertor fluxes can be lowered to acceptable levels, while maintaining the required upstream density. The addition of neutral baffles allows greater control over the divertor conditions with less impact on the upstream density. The divertor neutral pressure in the baffled geometry is slightly higher than the open divertor, but not as large with a vertical target. A first-pass coupling of the SOLPS solution with sheath and implantation/erosion models to compute the lithium emission shows that the lithium is largely confined to the near-surface region due to the small ionization mean free path and large main ion flow toward the surface. The lithium source was varied by three orders of magnitude. At the highest rate, when the sourced lithium approaches the level of the main ion recycling flux, a high core lithium concentration (~10%) is observed with only moderate power dissipation to affect the divertor plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Preliminary Test Results for Stability and Control Characteristics of a Generic T-Tail Transport Airplane at High Angle of Attack

Tests of a generic T-tail transport airplane, in flaps-up configuration, were conducted using two wind tunnels, a water tunnel, and computational fluid dynamics. Static force and moment testing, forced oscillation testing and dye flow visualization test techniques were used. The purpose of the testing was to obtain stability and control characteristics for development of a research flight simulator aerodynamic database. The purpose of that database was for assessment of aerodynamic model fidelity requirements to train airline pilots to recognize and recover from full stall conditions. Preliminary results, at initial stall conditions, include: an unstable stall pitch break, and near-neutral roll damping. Preliminary results, at deep stall conditions, include: a potential static longitudinal trim condition at approximately 35 degrees angle of attack, large aerodynamic asymmetries, and localized unstable dynamic stability.

Cunningham, Kevin↗

Main bearing response in a waked 15-MW floating wind turbine in below-rated conditions

Increased wind turbine size raises unknowns related to structural flexibility. Moreover, moving to deeper waters, component reliability becomes more critical. This work investigates main bearing response dependence on drivetrain flexibility and wake impingement in a two-turbine wind farm. A 15-MW floating direct-drive turbine is considered. Large eddy simulations (LES) are employed to model neutral, stable and unstable atmospheric conditions at below-rated mean wind speed, while the engineering codes OpenFAST and FAST.Farm simulate turbine and wake behavior. Results indicate significant sensitivities in fatigue estimates to lateral distance between the upstream and downstream turbine. The trends are most substantial in stable conditions, where the waked downwind main bearing sees twice the fatigue damage estimates of the upstream turbine for one position and 50% for another. Main bearing fatigue sensitivity to drivetrain flexibility is minor, while properly including generator rotor inertia loads is important for the axial forces of the locating (axially fixed) bearing, especially in stable conditions.

17 WIND ENERGY↗

Analysis of an extended period of earthward plasma sheet flow at about 220 R(E) - CDAW 8

The interpretation of the ISEE 3 earthward flow events observed during an extended period on January 29, 1983 is addressed in terms of a neutral line moving beyond roughly 220 earth radii. This concept was tested for consistency with current magnetospheric and solar wind observations. A broad range of additional data including Dynamics Explorer auroral imaging and a wide variety of ground-based measurements from the eighth Coordinated Data Analysis Workshop (CDAW 8) was available. The distant neutral line location within the context of the distant tail, geostationary orbit, auroral zone, and associated solar wind data is analyzed, based on an extended version of the Coraniti and Kennel (1972) flaring tail theory. It is concluded, from known solar wind conditions that, for a typical neutral line location at about 135 earth radii, an increase of about 30 percent of the near-earth lobe field strength would be required to cause the distant neutral line to move tailward beyond 220 earth radii. The question of why substorms did not terminate the growth phase earlier is also addressed.

Schindler, K.↗

Neutral elastic deformations

Elastic bodies or systems may not require external energy for certain finite and continuous deformations. Conditions providing these kinds of effortless, or neutral, deformations are discussed.

Durum, M. M.↗