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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Differences between ERBE and CERES Tropical Mean Fluxes: ENSO, Climate Change or Calibration?

Verner E. Soumi was the father of radiation budget measurements from space. He directed the team at the University of Wisconsin that developed the first radiation budget measurements on the Iota (Explorer VII) coverage) spacecraft in 1959. The first data published was from hand calculations of night-time long-wave fluxes, with absolute accuracy estimated as better than 10 percent, and the data shown as hand drawn maps with lines of equal "long-wave radiation loss, in Langleys per minute X 10(exp -3) (isolangleys)". The first comparisons of the new radiation data with nephanalyses showed that clouds dominated the radiation patterns. Soumi immediately proposed using the radiation fields to help understand the atmospheric heat sources necessary to drive the atmospheric circulation. This early work already pointed to the relationship between the outgoing longwave radiation at the top of the atmosphere and the vertical flux divergence of infrared radiation within the atmosphere. In the next 30 years, global satellite observations of the radiation balance of the planet have advanced both in accuracy, stability, and in their ability to address cause and effect in the climate system. The purpose of the present paper is to examine early results of the new Clouds and the Earth's Radiant Energy System (CERES) data on Tropical Rainfall Measuring System (TRMM) which started data collection in January, 1998. CERES is a direct descendant of the legacy of Soumi's foresight on understanding the global energetics using satellite observations of broadband radiation.

Wielicki, Bruce A.↗
DOE OSTI2025

Criegee Intermediates Compete Well with OH as a Cleaning Agent for Atmospheric Amides

Elucidating the chemical kinetics of stabilized Criegee intermediates (sCIs) in the atmosphere is critically important for climate modeling. Here, we report a class of very rapid bimolecular reactions of two sCIs, namely, CH 2 OO and syn-CH 3 CHOO, with amides. We used electronic structure calculations and kinetics calculations to elucidate a universal mechanism by which the oxygen atom of the carbonyl group in an amide is added to the carbon atom of the COO group in the sCI with simultaneous transfer of the amide hydrogen to the terminal oxygen atom of the carbonyl oxide of the sCI. The barriers for the mechanism are submerged below reactants by ∼9 kcal/mol, which means that the tight transition state is not the rate-determining step, and the rate constants are determined by loose free energy bottlenecks between the reactants and the precursor complexes. We calculate the rate constants due to these loose and barrierless transition states by variable-reaction-coordinate variational transition-state theory. We find that bimolecular reactions of sCIs with amides are very rapid, with rate constants 1 to 5 × 10 –10 cm 3 molecule –1 s –1 , which is a factor of 2 faster than the rate constants of carboxylic acids with sCIs and 10 2 faster than the rate constants of OH reactions with amides. This has the consequence that, under a wide range of conditions, sCIs are the major sink for atmospheric amides, in contrast to the usual assumption that OH radicals are the dominant sinks.

Amides↗
DOE OSTI2022

Sustainable Conversion of Carbon Dioxide and Shale Gas to Green Acetic Acid via a Thermochemical Cyclic Redox Scheme (Final Report)

The large-scale production of commodity chemicals relies heavily on the combustion of fossil fuels. As a result, enormous amounts of carbon dioxide (CO 2 ) are emitted which severely affects the global climate. The challenges for CO 2 utilization reside in the high stability of CO 2 molecules relative to the products, which requires the addition of significant external energy and overcoming slow and/or unfavorable reaction kinetics/thermodynamics. Chemical looping dry reforming of methane (CLDRM), also known as a hybrid redox process (HRP), is a promising alternative that allows the utilization of CO 2 and domestic shale gas resources to produce commodity chemicals. HRP works in two steps: In the first step, a redox catalyst reacts with methane to yield synthesis gas with a H 2 /CO ratio near 2:1, which is suitable for methanol and Fischer–Tropsch synthesis. The reduced redox catalyst then reacts with an oxidizing agent, such as CO 2 , to yield CO. In comparison to conventional thermochemical CO 2 splitting approaches, the use of methane as the reducing agent in HRP can significantly lower the operating temperature for CO 2 splitting.

03 NATURAL GAS↗
DOE OSTI2024

Active Layer Depth and Permafrost Temperatures at the Teller 47 Field Site, Seward Peninsula, Alaska, 2022

With extreme climate warming in the Arctic, there is increasing focus on mapping permafrost stability and improving understanding of the impacts of thawing permafrost. Summer active layer depths and temperatures at the top of the permafrost were collected at the Teller 47 field site on the Seward Peninsula, Alaska to better understand permafrost thermal state in areas of discontinuous permafrost. Measurements were taken between August 14th and August 20th, 2022. Active layer depths were measured with a 120 cm thaw probe, and temperature measurements were taken with a SpotOn Temperature probe at the top of permafrost and at a maximum depth of XYZ, when no near-surface permafrost (within 120 cm of the surface) was present. Measurements were co-located with ground surface displacement measurements, which can be found in the associated dataset, NGA254. Precise location data were collected at each observation point using a GNSS RTK GPS unit. This dataset contains a *.csv file of permafrost temperature and active layer depths and a *.kml file of measurement locations.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy’s Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy’s Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2013

Fast Atmosphere-Ocean Model Runs with Large Changes in CO2

How does climate sensitivity vary with the magnitude of climate forcing? This question was investigated with the use of a modified coupled atmosphere-ocean model, whose stability was improved so that the model would accommodate large radiative forcings yet be fast enough to reach rapid equilibrium. Experiments were performed in which atmospheric CO2 was multiplied by powers of 2, from 1/64 to 256 times the 1950 value. From 8 to 32 times, the 1950 CO2, climate sensitivity for doubling CO2 reaches 8 C due to increases in water vapor absorption and cloud top height and to reductions in low level cloud cover. As CO2 amount increases further, sensitivity drops as cloud cover and planetary albedo stabilize. No water vapor-induced runaway greenhouse caused by increased CO2 was found for the range of CO2 examined. With CO2 at or below 1/8 of the 1950 value, runaway sea ice does occur as the planet cascades to a snowball Earth climate with fully ice covered oceans and global mean surface temperatures near 30 C.

ocean models↗
NASA NTRS2014

Temperature and Humidity Profiles in the TqJoint Data Group of AIRS Version 6 Product for the Climate Model Evaluation

The Atmospheric Infrared Sounder (AIRS) mission is entering its 13th year of global observations of the atmospheric state, including temperature and humidity profiles, outgoing long-wave radiation, cloud properties, and trace gases. Thus AIRS data have been widely used, among other things, for short-term climate research and observational component for model evaluation. One instance is the fifth phase of the Coupled Model Intercomparison Project (CMIP5) which uses AIRS version 5 data in the climate model evaluation. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is the home of processing, archiving, and distribution services for data from the AIRS mission. The GES DISC, in collaboration with the AIRS Project, released data from the version 6 algorithm in early 2013. The new algorithm represents a significant improvement over previous versions in terms of greater stability, yield, and quality of products. The ongoing Earth System Grid for next generation climate model research project, a collaborative effort of GES DISC and NASA JPL, will bring temperature and humidity profiles from AIRS version 6. The AIRS version 6 product adds a new "TqJoint" data group, which contains data for a common set of observations across water vapor and temperature at all atmospheric levels and is suitable for climate process studies. How different may the monthly temperature and humidity profiles in "TqJoint" group be from the "Standard" group where temperature and water vapor are not always valid at the same time? This study aims to answer the question by comprehensively comparing the temperature and humidity profiles from the "TqJoint" group and the "Standard" group. The comparison includes mean differences at different levels globally and over land and ocean. We are also working on examining the sampling differences between the "TqJoint" and "Standard" group using MERRA data.

climate model evaluation↗
NASA NTRS2023

Evaluation of EPIC Oxygen Bands Stability With Radiative Transfer Simulations Over the South Pole

The Earth Polychromatic Imaging Camera (EPIC) onboard the Deep Space Climate Observatory (DSCOVR) satellite orbiting the Sun at the Lagrange-1 point was launched without onboard calibration systems. Vicarious calibration is conducted for 8 of the 10 UV/VIS/NIR channels using other low earth orbiting satellite instruments, while its two O 2 bands (688 nm and 764nm) rely on indirect moon-view calibrations because the same narrow-band O 2 bands are not readily available from other in-flight instruments. This study compares EPIC measurements from the four O 2 bands aiming at examining sensor stability over a uniquely suited location, i.e., the permanently snow-covered South Pole. The study utilizes radiative transfer model simulations with in-situ atmospheric soundings taken at South Pole during months of December and January from 2015 to 2022. The absolute discrepancy between the model simulations and observations is less than 1.0% for the two reference bands, but 5.75% and 15.63% for the 688nm, and 764 nm absorption bands, respectively. The simulated A-band and B-band ratios are 16.09% and 4.74% higher than that from the observations. Various sensitivities are conducted to estimate possible contributions to the discrepancies from input atmospheric profiles, spectral surface albedos and surface BRDF. While none of the input uncertainties is likely to account for the large discrepancies in the oxygen absorption bands, a small shift in the instrument response function could be the main reason for these biases. On the other hand, the model simulations are able to capture systematic variations with observed angular measurements and explain the multi-year trends found in observed O 2 band ratios due to satellite orbit shifting. When model simulated contributions from the angle variations are deducted from the observed O 2 band ratios, the residual O 2 band ratios are found to be stable since 2015.

EPIC↗
NASA NTRS2013

Global Climate Change, Food Security and the U.S. Food System

Climate change influences on the major pillars of food security. Each of the four elements of food security (availability,access,utilization,andstability) is vulnerable to changes in climate. For example,reductions in production related to regional drought influence food availability at multiple scales. Changes in price influences the ability of certain populations to purchase food (access). Utilization maybe affected when production zones shift, reducing the availability of preferred or culturally appropriate types of food within a region. Stability of the food supply may be highly uncertain given an increased incidence of extreme climatic events and their influence on production patterns.

Climate↗
DOE OSTI2022

On-policy learning-based deep reinforcement learning assessment for building control efficiency and stability

Artificial intelligence technologies have emerged as a game changer not only in specific applications such as image recognition and machine translation but also in many scientific domains. In particular, as deep reinforcement learning (DRL) has shown great success in complex control problems, DRL-based control has been considered as a potential solution to efficiently control and manage building systems. However, broad assessment of DRL-based building control is still required to characterize their pros and cons in comparison with conventional building control methods (e.g., rule-based feedback controls). In this paper, we assessed DRL-based controls with on-policy learning-based algorithms and continuous control actions for cooling control of large office buildings in the summer season to minimize whole-building energy use and occupant discomfort. We compared DRL-based control methods with two baseline control methods: (1) a pre-determined schedule with supply temperature and static pressure setpoints, and (2) advanced reset method that adjusts setpoints based on heuristic rules, i.e., ASHRAE Guideline 36. We also tested the DRL algorithms to evaluate their performances in multiple climate locations. We found that DRL-based control methods outperformed the baseline control methods in terms of energy savings while maintaining a thermal comfort. DRL reduced energy use between ~4%–22% on average compared to the baseline methods, depending on climate location. We also evaluated DRL-based control in terms of control stability and showed that DRL-based methods should address the span of hardware lifetimes in practical operations.

control stability↗
DOE OSTI2024

Oxygen‐Assisted Supercapacitive Swing Adsorption of Carbon Dioxide

We report on the supercapacitive swing adsorption (SSA) of carbon dioxide at different voltage windows in the presence of oxygen using activated carbon electrodes, and deliquescent, aqueous electrolytes. The presence of O 2 in the CO 2 /N 2 gas mixture results in an up to 11 times higher CO 2 adsorption capacity with 3 M MgBr 2 (at 0.6 V) and up to 4–5 times higher adsorption capacity with 3 M MgCl 2 (at 1 V). A tradeoff between high CO 2 adsorption capacities and lower coulombic efficiencies was observed at voltages above 0.6 V. The energetic and adsorptive performance of the electrodes in the presence of oxygen below 0.5 V was similar to the performance with a CO 2 /N 2 mixture without oxygen at 1 V. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) of the electrodes demonstrate that the specific capacitance increases while the diffusion resistance decreases in the presence of oxygen. Oxygen concentrations ranging between 5–20 % give similar energetic and adsorptive performance. The electrodes exhibit stable performance for up to 100 cycles of operation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Interrogating organo-mineral interactions by Py-GC/MS and ToF-SIMS

Soil organic matter (SOM) is crucial to soil fertility and agricultural sustainability in the face of climate change, and organo-mineral interactions are a key mechanism for stabilizing SOM. The stability of mineral-associated organic matter (MAOM) can be approximated by the strength of bonds between biomolecules and mineral surfaces. We hypothesized that factors such as mineral reactivity and solution pH would impact bonding strength. To test these factors, sorption isotherms were performed on minerals differing in particle size, morphology, and reactivity (quartz, goethite, gibbsite, kaolinite, montmorillonite), under two pH conditions (4 and 6), and across a range of tannic acid concentration (0-1400 ppm). The quantity and quality of organo-mineral bonds was assessed by quantifying post-sorption solution compounds using an absorbance plate reader and assessing the thermal energy needed to break bonds using evolved gas analysis (EGA) on a pyrolysis gas chromatograph-mass spectrometer (Py-GC/MS). Organo-mineral surfaces were also interrogated using Time-of-flight secondary ion mass spectrometry (ToF-SIMS). Sorption experiments revealed an asymptotic relationship between sorbed tannic acid and increasing initial concentrations which suggests our concentration range saturated available mineral surfaces. Results indicated that mineral identity, chiefly surface area and native pH, impacted the amount of compound sorbed to mineral surfaces. Evolved gas analyses of organo-mineral samples uncovered increased thermal stability of sorbed compounds compared to our tannic acid standard particularly on the iron oxide, goethite. ToF-SIMS revealed that goethite surface ions were covered by increasing concentrations of adsorbed tannic acid with the replacement of chlorine and sulfate ions by tannic acid related ions. Our results indicate that Py-GC/MS and ToF-SIMS are useful techniques to determine the nature and strength of organo-mineral bonds and are steppingstones to understanding controls on carbon sequestration in terrestrial systems.

58 GEOSCIENCES↗
NASA NTRS2016

The Effect of Dust on the Martian Polar Vortices

The influence of atmospheric dust on the dynamics and stability of the martian polar vortices is examined, through analysis of Mars Climate Sounder observations and MarsWRF general circulation model simulations. We show that regional and global dust storms produce transient vortex warming events that partially or fully disrupt the northern winter polar vortex for brief periods. Increased atmospheric dust heating alters the Hadley circulation and shifts the downwelling branch of the circulation poleward, leading to a disruption of the polar vortex for a period of days to weeks. Through our simulations, we find this effect is dependent on the atmospheric heating rate, which can be changed by increasing the amount of dust in the atmosphere or by altering the dust optical properties (e.g., single scattering albedo). Despite this, our simulations show that some level of atmospheric dust is necessary to produce a distinct northern hemisphere winter polar vortex.

Guzewich, Scott D.↗
DOE OSTI2023

Overcoming the Entropy Penalty of Direct Air Capture for Efficient Gigatonne Removal of Carbon Dioxide

Atmospheric carbon poses an existential threat to civilization via global climate change. Hundreds of gigatonnes of carbon dioxide must be removed from earth’s atmosphere in the next three decades, necessitating a low-cost, energy-efficient process to extract low concentrations of carbon dioxide for conversion to a stable material permanently stored for thousands of years. In this work, the challenge of removing gigatonnes of CO 2 is described via the scale of effort and the thermodynamics of collecting and reducing this diffuse chemical, the accumulation of which imparts a substantial entropy penalty on any atmospheric carbon capture process. The methods of CO 2 reduction combined with upstream direct air capture (DAC) including absorption, membrane separation, and adsorption are compared with biomass torrefaction and permanent burial (BTB). A Monte Carlo model assesses the mass, energy, and economics of the full process of biomass torrefaction from biomass collection and transport to stable carbon burial to determine that 95% of scenarios could remove carbon for less than $200 per CO 2 -tonne-equivalent. Torrefied carbon is further discussed for its long-term stability and availability at the scale required to substantially mitigate the threat of climate change.

biomass↗
NASA NTRSDate not supplied

Estimating Bidirectional Reflectance and Monitoring Stability of SNPP-VIIRS Reflective Solar Bands Using A Deep Neural Network

The NASA Clouds and the Earth's Radiant Energy System project provides the scientific community with observed top-of-atmosphere shortwave and longwave fluxes for climate monitoring and climate model validation. To provide consistent VIIRS cloud retrievals, the CERES Imager and Geostationary Calibration Group (IGCG) must understand and quantify the stability of the VIIRS instruments. To achieve this, the IGCG utilizes tropical deep convective clouds (DCCs) as invariant targets. Proper seasonal characterization of the DCC bidirectional reflectance distribution function (BRDF) is key to the success of DCC-based calibration methods, particularly for shortwave infrared (SWIR) bands. This article proposes the use of a deep neural network (DNN) to characterize VIIRS solar reflective band BRDF reflectance, with which individual channel trends are isolated by manipulating the DNN time input. Initial results show that the DNN method can extract statistically significant SNPP-VIIRS band trends, using only SNPP-VIIRS inputs, that are correlative to and match the magnitude of significant trends determined using methods that rely on an external angular distribution model. It may be possible to apply this approach to actively monitor the stability of new instruments without the need for predetermined seasonal BRDF corrections.

Benjamin Scarino↗
NASA NTRS2022

Ambiguous Stability of Glaciers at Bed Peaks

Increasing ice flux from glaciers retreating over deepening (retrograde) bed topography has been implicated in the recent acceleration of mass loss from the Greenland and Antarctic ice sheets. We show in observations that some glaciers have remained at peaks in bed topography without retreating despite enduring significant changes in climate. Observations also indicate that some glaciers which persist at bed peaks undergo sudden retreat years or decades after the onset of local ocean or atmospheric warming. Using model simulations, we show that persistence of a glacier at a bed peak is caused by ice slowing as it flows up a reverse-sloping bed to the peak. Persistence at bed peaks may lead to two very different future behaviors for a glacier: one where it persists at a bed peak indefinitely, and another where it retreats from the bed peak after potentially long delays following climate forcing. However, it is nearly impossible to distinguish which of these two future behaviors will occur from current observations. We conclude that inferring glacier stability from observations of persistence obscures our true commitment to future sea-level rise under climate change. We recommend that further research is needed on seemingly stable glaciers to determine their likely future.

ice dynamics↗
NASA NTRSDate not supplied

Pushing the Application Limit of Hyperspectral IR Sounder Remote Sensing for Frontiers of Weather and Climate Studies

Since the launch of AQUA Atmospheric Infrared Sounder (AIRS) in 2002, space-borne hyperspectral infrared (IR) sounders have provided information-rich, climate quality, and time-continuous spectral radiance measurements at the top of the atmosphere for more than two decades. Satellite based hyperspectral IR sensors, including AIRS, Cross-track Infrared Sounder (CrIS), and Infrared Atmospheric Sounding Interferometer (IASI), have demonstrated their critical roles for various weather applications and climate related studies. New use of hyperspectral IR sounder data will focus on underexplored areas. Current use of those data is generally limited by the capability of fully exploring and exploiting high spectral resolution information content, achieving radiometric accuracy and stability defined by the instruments, and merging data from different sensors to build a consistent, long-term climate data record. We will present the on-going research efforts at NASA Langley Research Center (LaRC) to develop novel hyperspectral IR sounder data products to address those potentials yet to be fully realized. Some applications of these products, including the study of Planetary Boundary Layer (PBL), the construction of climate data record over polar region, and the fusion of AIRS and CrIS data via the radiometric consistent climate fingerprinting method will be discussed.

Wan Wu↗
NASA NTRS1983

A climate hypothesis describing the solar-terrestrial system as a frequency domain with specific response characteristics

A climatological model of the earth-sun system based on an analogy to Planck's law of quantum mechanics is developed. The role of the diabatically important trace gases O3, H2O, and CO2 in the complex processes by which solar cycles affect tropospheric-stratospheric stability, and the value of the resonance concept in understanding these phenomena are examined. Consideration is given to climate complexity and the Laplace transform of the solar cycle, direct versus indirect solar signals, intense convection in coupled dynamics, the basic mechanisms of solar-terrestrial interaction, and the Planck's-law analog. The quantum approach, taking complexity into account, is shown to be more appropriate for evaluating the effects of anthropogenic modifications of the atmosphere (e.,g., increasing CO2) than the linear bulk-heating approaches usually applied.

Paine, D. A.↗
NASA NTRS1988

Climate, atmosphere, and volatile inventory evolution: Polar processes, climate records, volatile inventories

Climate change on Mars was driven by long term changes in the solar luminosity, variations in the partitioning of volatiles between the atmosphere and near-surface reservoirs, and astronomical variations in axial and orbital properties. There are important parallels between these drives for Mars and comparable ones for Earth. In the early history of the solar system, the Sun's luminosity was 25 to 30 percent lower than its current value. It is suggested that an early benign climate on Earth was due to the presence of much more carbon dioxide in its atmosphere at these early times than currently resides there. Such a partitioning of carbon dioxide, at the expense of the carbonate rock reservoir, may have resulted from a more vigorous tectonic and volcanic style at early times. Such a line of reasoning may imply that much more carbon dioxide was present in the Martian atmosphere during the planet's early history than resides there today. It is now widely recognized that astronomical variations of the Earth's axial and orbital characteristics have played a dominant role in causing the succession of glacial and interglacial periods characterizing the last several million years. The magnitude of the axial and eccentricity variations are much larger for Mars than for Earth. Such changes on Mars could result in sizeable variations in atmospheric pressure, dust storm activity, and the stability of perennial carbon dioxide and water ice polar caps. These quasi-periodic climate changes occur on periods of 100,000 to 1,000,000 years and may be recorded in the sedimentary layers of the polar layered terrain.

Pollack, J. B.↗