Influence of Polymer Aggregation and Liquid Immiscibility on Morphology Tuning by Varying Composition in PffBT4T-2DT/Nonfullerene Organic Solar Cells
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99 GENERAL AND MISCELLANEOUS↗
SEARCH · Engineering Papers
Results for “cell behavior”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Comments on the paper 'Does the subgrain size influence the rate of creep'?
A reply is given to a recent paper which questioned the validity of experimental observations and conclusions on the importance of cells in determining the creep behavior of materials. The reply clarifies experimental procedures and observations on NaCl single crystals and examines the importance of cells in determining creep behavior. It is concluded that cells are not spurious microstructural features and that they should be included along with subgrains and 'free' dislocations in developing creep models.
Raj, S. V.↗
Mechanical Roles of Polysaccharide Assembly and Interactions in Plant Cell Walls
Plants synthesize polysaccharide-based primary cell walls that possess unique microstructures and mechanical properties to accommodate plant growth and provide protection. Here, it remains challenging to assess the role of polysaccharide organization and interactions in the mechanical behavior of primary cell walls owing to their complex microstructure and highly nonlinear mechanical responses. Employing a coarse-grained molecular dynamics model developed for onion epidermal walls, this work explores the conditions under which polysaccharide assembly and interactions might play a significant role in primary cell wall mechanics. Cellulose–cellulose adhesion plays a dominant role in the wall load-bearing capacity, but when cellulose–cellulose adhesion was disrupted computationally, cellulose–xyloglucan adhesion could influence the wall load-bearing capacity. Contrary to the common concept that xyloglucans mechanically tether well-separated cellulose microfibrils, xyloglucans functioned in this case as interfibrillar adhesives capable of transmitting tensile forces between cellulose microfibrils. Our findings may inform design criteria of new materials inspired by plant cell walls.
59 BASIC BIOLOGICAL SCIENCES↗
Optical Detection of Crack Separation in Si PV Modules
Studying the mechanical behavior of silicon cell fractures is critical for understanding changes in PV module performance. Traditional methods of detecting cell cracks, e.g., electroluminescence (EL) imaging, utilize electrical changes and defects associated with cell fracture. Therefore, these methods reveal crack locations, but do not operate at the time or length scales required to accurately measure other physical properties of cracks, such as separation width and behavior under dynamic loads.
14 SOLAR ENERGY↗
Microtubule reorganization in tobacco BY-2 cells stably expressing GFP-MBD
Microtubule organization plays an important role in plant morphogenesis; however, little is known about how microtubule arrays transit from one organized state to another. The use of a genetically incorporated fluorescent marker would allow long-term observation of microtubule behavior in living cells. Here, we have characterized a Nicotiana tabacum L. cv. Bright Yellow 2 (BY-2) cell line that had been stably transformed with a gfp-mbd construct previously demonstrated to label microtubules (J. Marc et al., 1998, Plant Cell 10: 1927-1939). Fluorescence levels were low, but interphase and mitotic microtubule arrays, as well as the transitions between these arrays, could be observed in individual gfp-mbd-transformed cells. By comparing several attributes of transformed and untransformed cells it was concluded that the transgenic cells are not adversely affected by low-level expression of the transgene and that these cells will serve as a useful and accurate model system for observing microtubule reorganization in vivo. Indeed, some initial observations were made that are consistent with the involvement of motor proteins in the transition between the spindle and phragmoplast arrays. Our observations also support the role of the perinuclear region in nucleating microtubules at the end of cell division with a progressive shift of these microtubules and/or nucleating activity to the cortex to form the interphase cortical array.
NASA Discipline Plant Biology↗
Characterization of Commercial Li-ion Cells in Pouch Format
The li-ion pouch design cells exhibit similar behavior under off-nominal conditions as those in metal cans that do not have the internal safety devices. Safety should be well characterized before batteries are designed. Some of the li-ion pouch cell designs studied in this program reacted most violently to overcharge conditions at the medium rates but were tolerant to overcharge at very low rates. Some pouch cell designs have higher tolerance to vacuum exposures than some others. A comparison of the pouch material itself does not show a correlation between this tolerance and the number of layers or composition of the pouch indicating that this is a property of the electrode stack design inside the pouch. Reduced pressure (8 to 10 psi) test environments show that the extent of capacity degradation under reduced pressure environments is much less than that observed under vacuum conditions. Lithium-ion Pouch format cells are not necessarily true polymer cells.
Jeevarajan, Judith↗
Perspective—On the Safety of Aged Lithium-Ion Batteries
Concerns about the safety of lithium-ion batteries have motivated numerous studies on the response of fresh cells to abusive, off-nominal conditions, but studies on aged cells are relatively rare. This perspective considers all open literature on the thermal, electrical, and mechanical abuse response of aged lithium-ion cells and modules to identify critical changes in their behavior relative to fresh cells. We outline data gaps in aged cell safety, including electrical and mechanical testing, and module-level experiments. Understanding how the abuse response of aged cells differs from fresh cells will enable the design of more effective energy storage failure mitigation systems.
25 ENERGY STORAGE↗
Engineered bone marrow as a clinically relevant ex vivo model for primary bone cancer research and drug screening
Osteosarcoma (OS) is the most common primary malignant bone cancer in children and adolescents. While numerous other cancers now have promising therapeutic advances, treatment options for OS have remained unchanged since the advent of standard chemotherapeutics and offer less than a 25% 5-y survival rate for those with metastatic disease. This dearth of clinical progress underscores a lack of understanding of OS progression and necessitates the study of this disease in an innovative system. Here, we adapt a previously described engineered bone marrow (eBM) construct for use as a three-dimensional platform to study how microenvironmental and immune factors affect OS tumor progression. We form eBM by implanting acellular bone-forming materials in mice and explanting the cellularized constructs after 8 wk for study. We interrogate the influence of the anatomical implantation site on eBM tissue quality, test ex vivo stability under normoxic (5% O 2 ) and standard (21% O 2 ) culture conditions, culture OS cells within these constructs, and compare them to human OS samples. We show that eBM stably recapitulates the composition of native bone marrow. OS cells exhibit differential behavior dependent on metastatic potential when cultured in eBM, thus mimicking in vivo conditions. Furthermore, we highlight the clinical applicability of eBM as a drug-screening platform through doxorubicin treatment and show that eBM confers a protective effect on OS cells that parallel clinical responses. Combined, this work presents eBM as a cellular construct that mimics the complex bone marrow environment that is useful for mechanistic bone cancer research and drug screening.
59 BASIC BIOLOGICAL SCIENCES↗
Polythiophene-based terpolymers with modulated aggregation behaviors for high-performance organic solar cells with 16.6% efficiency
Polythiophenes (PTs) are an attractive class of polymer donors (PDs) for organic solar cells (OSCs) owing to their relatively simple structures and scalable synthesis. Herein, a series of chlorinated thiazole-incorporated PT terpolymers are designed and high-performance OSCs with a power conversion efficiency (PCE) of 16.6% are demonstrated. By incorporating two different units, 3,3'-difluoro-2,2'-bithiophene (T2F2) and thieno[3,2-b]thiophene (TT), the aggregation properties of the terpolymers (PTz-FX; X = 0, 30, 50, 70, and 100, where X represents the mole percentage of T2F2 to total T2F2 +TT) are modulated. Among the PTz-FX series, PTz-F70 is found to be the optimal P D because its suitably tuned aggregation property leads to an optimized blend morphology with well-developed crystalline structures and donor–acceptor intermixed domains. The balanced morphology not only promotes charge generation/transport but also suppresses charge recombination in OSC devices. Thus, the PTz-F70-based OSCs achieve the highest PCE (16.6%), outperforming the OSCs based on PTz-FX with extremely strong (PTz-F100, PCE = 14.7%) or weak (PTz-F0, PCE = 12.0%) aggregation properties. The PCE of the PTz-F70-based OSCs is one of the highest performances among PT-based binary OSCs. Finally, this study highlights the importance of controlling the aggregation property of PTs for achieving high-performance PT-based OSCs.
14 SOLAR ENERGY↗
The degradation and recovery behavior of mixed-cation perovskite solar cells in moisture and a gas mixture environment
Perovskite solar cell stability was investigated in moisture and gas mixtures. Moisture accelerates the degradation rate, but once light is removed, the performance is recoverable.
36 MATERIALS SCIENCE↗
Behavior of interdigitated back-contact solar cells
This paper presents experimental data concerning operation mechanisms of two versions of interdigitated back-contact solar cells: the tandem junction cell and the front-surface field cell. It is shown that a photogenerated forward bias at the front junction of a tandem junction cell is a critical parameter for cell performance which not only causes photogenerated carriers to migrate to the back junction, but also eliminates the reduction in photoresponse over back p(+) metallization regions. However, no similar light effects are observed in the performance of front-surface field cells. Finally, a discussion on mechanisms concerning the performance of front-surface field and tandem junction cells along with their merits is given.
Cheng, L. J.↗
Behavior Of NbSe3 Cathode In Rechargeable Li Cell
Report discusses series of ac impedance measurements of niobium triselenide cathodes in lithium secondary (rechargeable) cells. Reported work done to improve understanding of intercalation of NbSe3 with Li and to find out whether state of charge of NbSe3 determined nondestructively from impedance parameters. Authors conclude impedance parameters of NbSe3 do not vary in sufficiently regular fashion to be useful as indicators of state of charge.
Bugga, Ratnakumar V.↗
Spectroscopic Behavior of Composite, Black Thermal Paint, Solar Cell, and Multi-Layered Insulation Materials in a GEO Simulated Environment
The population of objects orbiting Earth is dominated by orbital debris. The following study presents reflectance spectroscopic measurements and bidirectional reflectance distribution function (BRDF) evaluations taken on common spacecraft materials (Table 1), some of which are likely candidates in the orbital debris population. Their optical properties were assessed in their pristine conditions, as well as after exposure in a space environmental chamber used to simulate space weathering. The materials studied will prove that they have excellent properties in resisting the effects of damage that are common in both low Earth orbit and geosynchronous Earth orbit (GEO) based on the research discussed in this work.
Reyes, Jacqueline A.↗
Radiation effects on p+n InP junctions grown by MOCVD
The superior radiation resistance of InP over other solar cell materials such as Si or GaAs has prompted the development of InP cells for space applications. The early research on radiation effects in InP was performed by Yamaguchi and co-workers who showed that, in diffused p-InP junctions, radiation-induced defects were readily annealed both thermally and by injection, which was accompanied by significant cell recovery. More recent research efforts have been made using p-InP grown by metalorganic chemical vapor deposition (MOCVD). While similar deep level transient spectroscopy (DLTS) results were found for radiation induced defects in these cells and in diffused junctions, significant differences existed in the annealing characteristics. After injection annealing at room temperature, Yamaguchi noticed an almost complete recovery of the photovoltaic parameters, while the MOCVD samples showed only minimal annealing. In searching for an explanation of the different annealing behavior of diffused junctions and those grown by MOCVD, several possibilities have been considered. One possibility is the difference in the emitter structure. The diffused junctions have S-doped graded emitters with widths of approximately 0.3 micrometers, while the MOCVD emitters are often doped with Si and have widths of approximately 300A (0.03 micrometers). The difference in the emitter thickness can have important effects, e.g. a larger fraction of the total photocurrent is generated in the n-type material for thicker emitters. Therefore the properties of the n-InP material may explain the difference in the observed overall annealing behavior of the cells.
Messenger, Scott R.↗
Computational Modeling of Heterogeneity of Stress, Charge, and Cyclic Damage in Composite Electrodes of Li-Ion Batteries
Charge heterogeneity is a prevalent feature in many electrochemical systems. In a commercial cathode of Li-ion batteries, the composite is hierarchically structured across multiple length scales including the sub-micron single-crystal primary-particle domains up to the macroscopic particle ensembles. The redox kinetics of charge transfer and mass transport strongly couples with mechanical stresses. This interplay catalyzes substantial heterogeneity in the charge (re)distribution, stresses, and mechanical damage in the composite electrode during charging and discharging. We assess the heterogeneous electrochemistry and mechanics in a LiNi x Mn y Co z O 2 (NMC) cathode using a fully coupled electro-chemo-mechanics model at the cell level. A microstructure-resolved model is constructed based on the synchrotron X-ray tomography data. We calculate the stress field in the composite and then quantitatively evaluate the kinetics of surface charge transfer and Li transport biased by mechanical stresses. We further model the cyclic behavior of the cell. The repetitive deformation of the active particles and the weakening of the interfacial strength cause gradual increase of the interfacial debonding. The mechanical damage impedes electron transfer, incurs more charge heterogeneity, and results in the capacity degradation in batteries over cycles.
25 ENERGY STORAGE↗
Building an extensible cell wall
Abstract This article recounts, from my perspective of four decades in this field, evolving paradigms of primary cell wall structure and the mechanism of surface enlargement of growing cell walls. Updates of the structures, physical interactions, and roles of cellulose, xyloglucan, and pectins are presented. This leads to an example of how a conceptual depiction of wall structure can be translated into an explicit quantitative model based on molecular dynamics methods. Comparison of the model’s mechanical behavior with experimental results provides insights into the molecular basis of complex mechanical behaviors of primary cell wall and uncovers the dominant role of cellulose–cellulose interactions in forming a strong yet extensible network.
59 BASIC BIOLOGICAL SCIENCES↗
A 2-D Piston Effect Solution for the Relaxation in the MISTE Cell
When a large density stratification is no longer a problem in a microgravity environment, one would like to increase the sample size in order to increase the signal-to-noise ratio for a specific heat measurement. To reduce the equilibration time associated with the large sample size, we designed a cylindrical cell containing a stack of plates that separate the bulk fluid into 60 equally thin layers. To understand the thermal behavior of the whole cell, we analyzed the thermal behavior of a 2-D composite system of a cylindrical near-critical fluid layer in contact with a cylindrical copper plate. In this 2-D analysis, the circumference boundary of the two cylindrical layers is subjected to a step temperature change. The solution of this 2-D composite system includes the piston effect that speeds up the equilibration in the near-critical fluid layer and the pure diffusion in the copper plate. The results of this analysis indicate that the characteristic length for the equilibration of the stacked cell is determined by an effective thickness of a single fluid layer instead of the total height of the cylindrical cell.
Weilert, Mark↗