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At least 217 records · Page 12

Validation and Initial Characterization of the Long-period Planet Kepler-1654 b

Fewer than 20 transiting Kepler planets have periods longer than one year. Our early search of the Kepler light curves revealed one such system, Kepler-1654b (originally KIC 8410697b), which shows exactly two transit events and whose second transit occurred only five days before the failure of the second of two reaction wheels brought the primary Kepler mission to an end. A number of authors have also examined light curves from the Kepler mission searching for long-period planets and identified this candidate. Starting in 2014 September, we began an observational program of imaging, reconnaissance spectroscopy, and precision radial velocity (RV) measurements that confirm with a high degree of confidence that Kepler-1654b is a bona fide transiting planet orbiting a mature G5V star (T {sub eff} = 5580 K, [Fe/H] = −0.08) with a semimajor axis of 2.03 au, a period of 1047.84 days, and a radius of 0.82 ± 0.02 R {sub Jup}. RV measurements using Keck’s HIRES spectrometer obtained over 2.5 years set a limit to the planet’s mass of <0.5 (3σ) M {sub Jup}. The bulk density of the planet is similar to that of Saturn or possibly lower. We assess the suitability of temperate gas giants like Kepler-1654b for transit spectroscopy with the James Webb Space Telescope, as their relatively cold equilibrium temperatures (T {sub pl} ∼ 200 K) make them interesting from the standpoint of exoplanet atmospheric physics. Unfortunately, these low temperatures also make the atmospheric scale heights small and thus transmission spectroscopy challenging. Finally, the long time between transits can make scheduling JWST observations difficult—as is the case with Kepler-1654b.

79 ASTRONOMY AND ASTROPHYSICS↗

INTERNAL STRUCTURE OF ASTEROIDS HAVING SURFACE SHEDDING DUE TO ROTATIONAL INSTABILITY

Surface shedding of an asteroid is a failure mode where surface materials fly off due to strong centrifugal forces beyond the critical spin period, while the internal structure does not deform significantly. This paper proposes a possible structure of an asteroid interior that leads to surface shedding due to rapid rotation rates. A rubble pile asteroid is modeled as a spheroid composed of a surface shell and a concentric internal core, the entire assembly called the test body. The test body is assumed to be uniformly rotating around a constant rotation axis. We also assume that while the bulk density and the friction angle are constant, the cohesion of the surface shell is different from that of the internal core. First, developing an analytical model based on limit analysis, we provide the upper and lower bounds for the actual surface shedding condition. Second, we use a Soft-sphere Discrete Element Method (SSDEM) to study dynamical deformation of the test body due to a quasi-static spin-up. In this paper we show the consistency of both approaches. Additionally, the SSDEM simulations show that the initial failure always occurs locally and not globally. In addition, as the core becomes larger, the size of lofted components becomes smaller. These results imply that if there is a strong core in a progenitor body, surface shedding is the most likely failure mode.

79 ASTRONOMY AND ASTROPHYSICS↗

In-flight alloying of nanocrystalline yttria-stabilized zirconia using suspension spray to produce ultra-low thermal conductivity thermal barriers.

Previous researchers have shown that it is possible to combine rare-earth oxides with the standard thermal barrier coating material (4.5 mol% Y{sub 2}O{sub 3}-ZrO{sub 2} or YSZ) to form ultra-low thermal conductivity coatings using a standard powder manufacturing route. A similar approach to making low thermal conductivity coatings by adding rare-earth oxides is discussed presently, but a different manufacturing route was used. This route involved dissolving hydrated ytterbium and neodymium nitrates into a suspension of 80 nm diameter 4.5 mol% YSZ powder and ethanol. Suspension plasma spray was then used to create coatings in which the YSZ powders were alloyed with rare-earth elements while the plasma transported the melted powders to the substrate. Mass spectrometry measurements showed a YSZ coating composition, in mol%, of ZrO{sub 2}-4.4 Y{sub 2}O{sub 3}-1.4 Nd{sub 2}O{sub 3}-1.3 Yb{sub 2}O{sub 3}. The amount of Yb{sup 3+} and Nd{sup 3+} ions in the final coating was {approx}50% of that added to the starting suspension. Wide-angle X-ray diffraction revealed a cubic ZrO{sub 2} phase, consistent with the incorporation of more stabilizer into the zirconia crystal structure. The total porosity in the coatings was {approx}35-36%, with a bulk density of 3.94 g/cm{sup 3}. Small-angle X-ray scattering measured an apparent void specific surface area of {approx}2.68 m{sup 2}/cm{sup 3} for the alloyed coating and {approx}3.19 m{sup 2}/cm{sup 3} for the baseline coating. Thermal conductivity (k{sub th}) of the alloyed coating was {approx}0.8 W/m/K at 800 C, as compared with {approx}1.5 W/m/K at 800 C for the YSZ-only baseline coating. After 50 h at 1200 C, k{sub th} increased to {approx}1.1 W/m/K at 800 C for the alloyed samples, with an associated decrease in the apparent void specific surface area to {approx}1.55 m{sup 2}/cm{sup 3}.

36 MATERIALS SCIENCE↗

Influence of moisture content, particle size and forming temperature on productivity and quality of rice straw pellets

Highlights: • Optimized conditions were determined for the production of rice straw pellets. • The moisture content and forming temperature are key factors. • High quality rice pellets in the lower heating value and durability were produced. - Abstract: A large amount of rice straw is generated and left as much in paddy fields, which causes greenhouse gas emissions as methane. Rice straw can be used as bioenergy. Rice straw pellets are a promising technology because pelletization of rice straw is a form of mass and energy densification, which leads to a product that is easy to handle, transport, store and utilize because of the increase in the bulk density. The operational conditions required to produce high quality rice straw pellets have not been determined. This study determined the optimal moisture content range required to produce rice straw pellets with high yield ratio and high heating value, and also determined the influence of particle size and the forming temperature on the yield ratio and durability of rice straw pellets. The optimal moisture content range was between 13% and 20% under a forming temperature of 60 or 80 °C. The optimal particle size was between 10 and 20 mm, considering the time and energy required for shredding, although the particle size did not significantly affect the yield ratio and durability of the pellets. The optimized conditions provided high quality rice straw pellets with nearly 90% yield ratio, ⩾12 MJ/kg for the lower heating value, and >95% durability.

09 BIOMASS FUELS↗

Sintering of Iron Ores in a Millipot in Comparison with Tablet Testing and Industrial Process

To explore the feasibility of small-scale sintering pot testing, a ‘millipot’ facility (diameter of 53 mm and height of 400 mm) was established and used to examine the sintering performance of iron ores and other non-traditional ferrous materials. The sintering performance of a millipot was examined across a range of different operational conditions (coke rate and suction pressure) and compared with an industrial sinter strand operation. Tablet tests were also performed to assist in the design of the millipot experiments and identify conditions for achieving mineral composition similar to the industrial sinter. For the millipot experiments, the materials used need to be compacted to increase the bulk density, and a higher coke rate is required to compensate the high heat loss caused by wall effects. A higher suction pressure is also necessary to maintain an oxidizing atmosphere in the sinter bed. As expected, it was not possible to eliminate the wall effect, which resulted in more primary hematite at edges of the sintered column. However, the sintered material from the center of column simulates industrial sinter reasonably well. As such, millipot provides a practical way to evaluate the sintering process and material performance at laboratory scale, helping to bridge the gap between tablet sintering and large scale pot sintering, or full scale plant trial. The results of millipot testing can be used for designing larger scale experiments or commercial sintering trials.

36 MATERIALS SCIENCE↗

Long-Term Effects of Crude Oil Spillage on Selected Physicochemical Properties Including Heavy Metal Contents of Sandy Tropical Soil

Crude oil spillage effects on the environment often wane with time, making late remediation of affected soils look irrelevant. Physicochemical quality of a sandy soil under 9-year-old spillage was compared with that of adjacent unaffected site in southern Nigeria. Soil bulk density and equilibrated water content were higher in affected than unaffected site, but permeability did not change. The spillage increased soil pH, organic carbon, total nitrogen and available phosphorus by about 7%, 1700%, 133% and − 16%, respectively. It lowered divalent exchangeable bases/acidity but raised base saturation. It increased total petroleum hydrocarbon (PHC{sub t}) and micronutrients/heavy metals (Fe, Mn, Zn, Cd and Pb), all of which were below their critical limits in soils by regulatory bodies. Soil pH, organic carbon and PHC{sub t} correlated positively with all five micronutrients/heavy metals; total nitrogen did so with Zn and Pb. Nine-year period may be insufficient for spillage effects in sandy soils to cease to be evident. Such effects for PHC{sub t} and heavy metals, however, are deemed tolerable for ecological safety.

54 ENVIRONMENTAL SCIENCES↗

A Highly Eccentric Warm Jupiter Orbiting TIC 237913194

The orbital parameters of warm Jupiters serve as a record of their formation history, providing constraints on formation scenarios for giant planets on close and intermediate orbits. Here, we report the discovery of TIC 237913194b, detected in full-frame images from Sectors 1 and 2 of the Transiting Exoplanet Survey Satellite (TESS), ground-based photometry (Chilean–Hungarian Automated Telescope, Las Cumbres Observatory Global Telescope), and Fiber-fed Extended Range Optical Spectrograph radial velocity time series. We constrain its mass to M P = 1.942 -0.091 +0.091 M J and its radius to R P = 1.117 -0.047 +0.054 R J , implying a bulk density similar to Neptune’s. It orbits a G-type star (M &lowast; = 1.026 -0.055 +0.057 M ⊙ , V = 12.1 mag) with a period of 15.17 days on one of the most eccentric orbits of all known warm giants (e ≈ 0.58). This extreme dynamical state points to a past interaction with an additional, undetected massive companion. A tidal evolution analysis showed a large tidal dissipation timescale, suggesting that the planet is not a progenitor for a hot Jupiter caught during its high-eccentricity migration. TIC 237913194b further represents an attractive opportunity to study the energy deposition and redistribution in the atmosphere of a warm Jupiter with high eccentricity.

79 ASTRONOMY AND ASTROPHYSICS↗

GEOMETRIC CROSS SECTIONS OF DUST AGGREGATES AND A COMPRESSION MODEL FOR AGGREGATE COLLISIONS

Geometric cross sections of dust aggregates determine their coupling with disk gas, which governs their motions in protoplanetary disks. Collisional outcomes also depend on geometric cross sections of initial aggregates. In a previous paper, we performed three-dimensional N-body simulations of sequential collisions of aggregates composed of a number of sub-micron-sized icy particles and examined radii of gyration (and bulk densities) of the obtained aggregates. We showed that collisional compression of aggregates is not efficient and that aggregates remain fluffy. In the present study, we examine geometric cross sections of the aggregates. Their cross sections decrease due to compression as well as to their gyration radii. It is found that a relation between the cross section and the gyration radius proposed by Okuzumi et al. is valid for the compressed aggregates. We also refine the compression model proposed in our previous paper. The refined model enables us to calculate the evolution of both gyration radii and cross sections of growing aggregates and reproduces well our numerical results of sequential aggregate collisions. The refined model can describe non-equal-mass collisions as well as equal-mass cases. Although we do not take into account oblique collisions in the present study, oblique collisions would further hinder compression of aggregates.

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THE ONSET OF DIFFERENTIATION AND INTERNAL EVOLUTION: THE CASE OF 21 LUTETIA

Asteroid 21 Lutetia, seen by the Rosetta spacecraft, plays a crucial role in the reconstruction of primordial phases of planetary objects. Its high bulk density and its primitive chondritic crust suggest that Lutetia could be partially differentiated. We developed a numerical code, also used for studying the geophysical history of Vesta, to explore several scenarios of internal evolution of Lutetia. These scenarios differ in the strength of their radiogenic sources and in their global post-sintering porosity. The only significant heat source for partial differentiation is {sup 26}Al; the other possible sources ({sup 60}Fe, accretion, and differentiation) are negligible. In scenarios in which Lutetia completed its accretion in less than 0.7 Myr from the injection of {sup 26}Al in the solar nebula and for post-sintering values of macroporosity not exceeding 30% by volume, the asteroid experienced only partial differentiation. The formation of the proto-core, a structure enriched in metals and also containing pristine silicates, requires 1-4 Myr and the size of the proto-core varies from 6-30 km.

79 ASTRONOMY AND ASTROPHYSICS↗

Riverbank temperatures on the Selawik River, Alaska 2010-2012, and Koyukuk River, Alaska June to July 2018.

The data package includes temperature measurements from riverbanks along the Selawik and Koyukuk Rivers in northwest Alaska. The Selawik River data also includes meteorological data collected locally and the Koyukuk River includes bulk density and ice content data from the riverbanks. The Selawik River data was collected between 2010 and 2013 with meteorological data collected for the entire time period and riverbank temperatures collected in shorter time intervals between 2010 to 2012. All of the Selawik River data were collected a single river bend. The Koyukuk River temperature data was collected from late June to early July 2018 at a total of five locations on three riverbanks. Ice content measurements on the Koyukuk were made at five riverbank locations. The data collection on both rivers was done in support of studies on the influence of permafrost on riverbank erosion. The temperature data was collected to monitor the thermal conditions of the river banks both seasonally and during periods of erosion. The ice content of the banks was measured to better understand how bank erosion rates are influenced by ice in the frozen riverbanks.

54 ENVIRONMENTAL SCIENCES↗

RELATING CHANGES IN COMETARY ROTATION TO ACTIVITY: CURRENT STATUS AND APPLICATIONS TO COMET C/2012 S1 (ISON)

We introduce a parameter, X, to predict the changes in the rotational period of a comet in terms of the rotational period itself, the nuclear radius, and the orbital characteristics. We show that X should be a constant if the bulk densities and shapes of nuclei are nearly identical and the activity patterns are similar for all comets. For four nuclei for which rotational changes are well documented, despite the nearly factor 30 variation observed among the effective active fractions of these comets, X is constant to within a factor two. We present an analysis for the sungrazing comet C/2012 S1 (ISON) to explore what rotational changes it could undergo during the upcoming perihelion passage where its perihelion distance will be ∼2.7 solar radii. When close to the Sun, barring a catastrophic disruption of the nucleus, the activity of ISON will be sufficiently strong to put the nucleus into a non-principal-axis rotational state and observable changes to the rotational period should also occur. Additional causes for rotational state changes near perihelion for ISON are tidal torques caused by the Sun and the significant mass loss due to a number of mechanisms resulting in alterations to the moments of inertia of the nucleus.

79 ASTRONOMY AND ASTROPHYSICS↗

STATISTICAL ANALYSIS OF TANK 5 FLOOR SAMPLE RESULTS

Sampling has been completed for the characterization of the residual material on the floor of Tank 5 in the F-Area Tank Farm at the Savannah River Site (SRS), near Aiken, SC. The sampling was performed by Savannah River Remediation (SRR) LLC using a stratified random sampling plan with volume-proportional compositing. The plan consisted of partitioning the residual material on the floor of Tank 5 into three non-overlapping strata: two strata enclosed accumulations, and a third stratum consisted of a thin layer of material outside the regions of the two accumulations. Each of three composite samples was constructed from five primary sample locations of residual material on the floor of Tank 5. Three of the primary samples were obtained from the stratum containing the thin layer of material, and one primary sample was obtained from each of the two strata containing an accumulation. This report documents the statistical analyses of the analytical results for the composite samples. The objective of the analysis is to determine the mean concentrations and upper 95% confidence (UCL95) bounds for the mean concentrations for a set of analytes in the tank residuals. The statistical procedures employed in the analyses were consistent with the Environmental Protection Agency (EPA) technical guidance by Singh and others [2010]. Savannah River National Laboratory (SRNL) measured the sample bulk density, nonvolatile beta, gross alpha, radionuclide, inorganic, and anion concentrations three times for each of the composite samples. The analyte concentration data were partitioned into three separate groups for further analysis: analytes with every measurement above their minimum detectable concentrations (MDCs), analytes with no measurements above their MDCs, and analytes with a mixture of some measurement results above and below their MDCs. The means, standard deviations, and UCL95s were computed for the analytes in the two groups that had at least some measurements above their MDCs. The identification of distributions and the selection of UCL95 procedures generally followed the protocol in Singh, Armbya, and Singh [2010]. When all of an analyte's measurements lie below their MDCs, only a summary of the MDCs can be provided. The measurement results reported by SRNL are listed in Appendix A, and the results of this analysis are reported in Appendix B. The data were generally found to follow a normal distribution, and to be homogeneous across composite samples.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The effects of digital elevation model resolution on the calculation and predictions of topographic wetness indices.

One of the largest exports in the Southeast U.S. is forest products. Interest in biofuels using forest biomass has increased recently, leading to more research into better forest management BMPs. The USDA Forest Service, along with the Oak Ridge National Laboratory, University of Georgia and Oregon State University are researching the impacts of intensive forest management for biofuels on water quality and quantity at the Savannah River Site in South Carolina. Surface runoff of saturated areas, transporting excess nutrients and contaminants, is a potential water quality issue under investigation. Detailed maps of variable source areas and soil characteristics would therefore be helpful prior to treatment. The availability of remotely sensed and computed digital elevation models (DEMs) and spatial analysis tools make it easy to calculate terrain attributes. These terrain attributes can be used in models to predict saturated areas or other attributes in the landscape. With laser altimetry, an area can be flown to produce very high resolution data, and the resulting data can be resampled into any resolution of DEM desired. Additionally, there exist many maps that are in various resolutions of DEM, such as those acquired from the U.S. Geological Survey. Problems arise when using maps derived from different resolution DEMs. For example, saturated areas can be under or overestimated depending on the resolution used. The purpose of this study was to examine the effects of DEM resolution on the calculation of topographic wetness indices used to predict variable source areas of saturation, and to find the best resolutions to produce prediction maps of soil attributes like nitrogen, carbon, bulk density and soil texture for low-relief, humid-temperate forested hillslopes. Topographic wetness indices were calculated based on the derived terrain attributes, slope and specific catchment area, from five different DEM resolutions. The DEMs were resampled from LiDAR, which is a laser altimetry remote sensing method, obtained from the USDA Forest Service at Savannah River Site. The specific DEM resolutions were chosen because they are common grid cell sizes (10m, 30m, and 50m) used in mapping for management applications and in research. The finer resolutions (2m and 5m) were chosen for the purpose of determining how finer resolutions performed compared with coarser resolutions at predicting wetness and related soil attributes. The wetness indices were compared across DEMs and with each other in terms of quantile and distribution differences, then in terms of how well they each correlated with measured soil attributes. Spatial and non-spatial analyses were performed, and predictions using regression and geostatistics were examined for efficacy relative to each DEM resolution. Trends in the raw data and analysis results were also revealed.

09 BIOMASS FUELS↗

THE RETURN OF THE ANDROMEDIDS METEOR SHOWER

The Andromedid meteor shower underwent spectacular outbursts in 1872 and 1885, producing thousands of visual meteors per hour and described as ''stars fell like rain'' in Chinese records of the time. The shower originates from comet 3D/Biela whose disintegration in the mid-1800's is linked to the outbursts, but the shower has been weak or absent since the late 19th century. This shower returned in 2011 December with a zenithal hourly rate of approximately 50, the strongest return in over a hundred years. Some 122 probable Andromedid orbits were detected by the Canadian Meteor Orbit Radar while one possible brighter Andromedid member was detected by the Southern Ontario Meteor Network and several single station possible Andromedids by the Canadian Automated Meteor Observatory. The shower outburst occurred during 2011 December 3-5. The radiant at R.A. +18 Degree-Sign and decl. +56 Degree-Sign is typical of the ''classical'' Andromedids of the early 1800s, whose radiant was actually in Cassiopeia. Numerical simulations of the shower were necessary to identify it with the Andromedids, as the observed radiant differs markedly from the current radiant associated with that shower. The shower's orbital elements indicate that the material involved was released before 3D/Biela's breakup prior to 1846. The observed shower in 2011 had a slow geocentric speed (V{sub G} = 16 km s{sup -1}) and was comprised of small particles: the mean measured mass from the radar is {approx}5 Multiplication-Sign 10{sup -7} kg, corresponding to radii of 0.5 mm at a bulk density of 1000 kg m{sup -3}. Numerical simulations of the parent comet indicate that the meteoroids of the 2011 return of the Andromedids shower were primarily ejected during 3D/Biela's 1649 perihelion passage. The orbital characteristics, radiant, and timing as well as the absence of large particles in the streamlet are all broadly consistent with simulations. However, simulations of the 1649 perihelion passage necessitate going back five Lyapunov times (which is only 25 yr for the highly perturbed parent). As a result, the stream evolution is somewhat uncertain and some discrepancy with the observations is to be expected: the radiant is 8 Degree-Sign off, the inclination 3 Degree-Sign higher, and the peak of the shower occurs a day earlier than predicted. Predictions are made regarding other appearances of the shower in the years 2000-2047 based on our numerical model. We note that the details of the 2011 return can, in principle, be used to better constrain the orbit of 3D/Biela prior to the comets first recorded return in 1772 and we address this issue briefly as well.

79 ASTRONOMY AND ASTROPHYSICS↗

Soil Physical, Chemical, and Thermal Characterization, Council Road Site, Seward Peninsula, Alaska, 2016

This dataset provides the results of physical, chemical, and thermal characterization of soils at the Council Road Site, Seward Peninsula, Alaska. Soil pits were dug from 11 September 2016 at three locations CPIT1, CPIT3, and CPIT4 at the Council Road MM71 Site (CN_MM71). This dataset includes field observations and descriptions of soil layers or horizons, field measurements of soil volumetric water content, soil temperature, thermal conductivity, and heat capacity. Laboratory measurements (*.csv files) of soil properties include gravimetric water content, bulk density, volumetric water content, and total carbon and nitrogen. A synthesis data file (*.csv), photographs (*.jpg) of the respective soil pits, and a user guide (*.pdf) are also included. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Soil Physical, Chemical, and Thermal Characterization, Teller Road Site, Seward Peninsula, Alaska, 2016

This dataset provides the results of physical, chemical, and thermal characterization of soils at the Teller Road Site, Seward Peninsula, Alaska. Soil pits were dug from 7-14 September 2016 at designated Intensive Stations 2 through 9 at the Teller Road MM 27 Site. This dataset includes field observations and descriptions of soil layers or horizons, field measurements of soil volumetric water content, soil temperature, thermal conductivity, and heat capacity. Laboratory measurements of soil properties include gravimetric water content, bulk density, volumetric water content, and total carbon and nitrogen. The data files are CSV with additional information in a PDF user guide. Soil pit JPG images are in a zip file. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Analysis of the Tank 5f Final Characterization Samples-2011

The Savannah River National Laboratory (SRNL) was requested by SRR to provide sample preparation and analysis of the Tank 5F final characterization samples to determine the residual tank inventory prior to grouting. Two types of samples were collected and delivered to SRNL: floor samples across the tank and subsurface samples from mounds near risers 1 and 5 of Tank 5F. These samples were taken from Tank 5F between January and March 2011. These samples from individual locations in the tank (nine floor samples and six mound Tank 5F samples) were each homogenized and combined in a given proportion into 3 distinct composite samples to mimic the average composition in the entire tank. These Tank 5F composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 5F composite samples include bulk density and water leaching of the solids to account for water soluble species. With analyses for certain challenging radionuclides as the exception, all composite Tank 5F samples were analyzed and reported in triplicate. The target detection limits for isotopes analyzed were based on customer desired detection limits as specified in the technical task request documents. SRNL developed new methodologies to meet these target detection limits and provide data for the extensive suite of components. While many of the target detection limits were met for the species characterized for Tank 5F, as specified in the technical task request, some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The Technical Task Request allows that while the analyses of these isotopes is needed, meeting the detection limits for these isotopes is a lower priority than meeting detection limits for the other specified isotopes. The isotopes whose detection limits were not met in all cases included the following: Al-26, Sn-126, Sb-126, Sb-126m, Eu-152 and Cf-249. SRNL, in conjunction with the plant customer, reviewed all these cases and determined that the impacts were negligible.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of the Tank 5F Final Characterization Samples-2011 (U)

The Savannah River National Laboratory (SRNL) was requested by SRR to provide sample preparation and analysis of the Tank 5F final characterization samples to determine the residual tank inventory prior to grouting. Two types of samples were collected and delivered to SRNL: floor samples across the tank and subsurface samples from mounds near risers 1 and 5 of Tank 5F. These samples were taken from Tank 5F between January and March 2011. These samples from individual locations in the tank (nine floor samples and six mound Tank 5F samples) were each homogenized and combined in a given proportion into 3 distinct composite samples to mimic the average composition in the entire tank. These Tank 5F composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 5F composite samples include bulk density and water leaching of the solids to account for water soluble species. With analyses for certain challenging radionuclides as the exception, all composite Tank 5F samples were analyzed and reported in triplicate. The target detection limits for isotopes analyzed were based on customer desired detection limits as specified in the technical task request documents. SRNL developed new methodologies to meet these target detection limits and provide data for the extensive suite of components. While many of the target detection limits were met for the species characterized for Tank 5F, as specified in the technical task request, some were not met. In a few cases, the relatively high levels of radioactive species of the same element or a chemically similar element precluded the ability to measure some isotopes to low levels. The Technical Task Request allows that while the analyses of these isotopes is needed, meeting the detection limits for these isotopes is a lower priority than meeting detection limits for the other specified isotopes. The isotopes whose detection limits were not met in all cases included the following: Al-26, Sn-126, Sb-126, Sb-126m, Eu-152 and Cf-249. SRNL, in conjunction with the plant customer, reviewed all these cases and determined that the impacts were negligible.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗