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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Low-Threshold Visible-to-Ultraviolet Solid-State Triplet-Fusion Upconversion

Visible-to-ultraviolet (UV) triplet-triplet annihilation (TTA) upconversion is an energy-relevant photon-management strategy that converts visible photons into UV photons capable of driving high-energy photochemical processes. Practical implementation requires solid-state thin films, which often require high excitation power. Here, we demonstrate the first solid-state visible-to-UV TTA upconversion thin-film device, using 1,4-bis((tricyclopentylsilyl)ethynyl)naphthalene (TCPS-NAP) as the annihilator and tris(2-phenylpyridine)iridium(III) (Ir(ppy) 3 ) as the sensitizer on silver. Under incoherent 455 nm excitation, the device exhibits blue-to-UV upconversion with a threshold of 4.8 mW/cm 2 . Using surface plasmons in the planar silver film, we achieve green-to-UV upconversion with a 1.11 eV anti-Stokes shift and 6.9 mW/cm 2 threshold, a 12.2 × threshold enhancement over far-field 532 nm excitation. In solution, TCPS-NAP shows excimer-dominated anti-Stokes emission rather than UV upconversion. These results establish a platform for harvesting low-intensity visible light to drive UV processes while demonstrating that solution-phase screening does not predict solid-state upconversion performance.

Luminescence↗
DOE OSTI2020

Fast Organic Vapor Phase Deposition of Thin Films in Light-Emitting Diodes

Fast deposition of thin films is essential for achieving low-cost, high throughput phosphorescent organic light emitting diode (PHOLED) production. In this work, we demonstrate rapid and uniform growth of semiconductor thin films by organic vapor phase deposition (OVPD). A green PHOLED comprising an emission layer (EML) grown at 50 Å/s with bis[2-(2-pyridinyl-N)phenyl-C](acetylacetonato)iridium(III) (Ir(ppy)2(acac)) doped into 4,4 bis(N-carbazolyl)-1,1zolylld (CBP) exhibits a maximum external quantum efficiency of 20 ± 1%. The morphology, charge transport properties, and radiative efficiency under optical and electrical excitation of the PHOLED EML are investigated as functions of the deposition rate via both experimental and theoretical approaches. The EML shows no evidence for gas phase nucleation of the organic molecules at deposition rates as high as 50 Å/s. However, the roll-off in quantum efficiency at high current progressively increases with deposition rate due to enhanced triplet-polaron annihilation. The roll-off results from accumulation of stress within the PHOLED EML that generates a high density of defect states. Here, the defects, in turn, act as recombination sites for triplets and hole polarons, leading to enhanced triplet-polaron annihilation at high current. We introduce a void nucleation model to describe the film morphology evolution that is observed using electron microscopy.

42 ENGINEERING↗
DOE OSTI2023

Promoting multiexciton interactions in singlet fission and triplet fusion upconversion dendrimers

Abstract Singlet fission and triplet-triplet annihilation upconversion are two multiexciton processes intimately related to the dynamic interaction between one high-lying energy singlet and two low-lying energy triplet excitons. Here, we introduce a series of dendritic macromolecules that serve as platform to study the effect of interchromophore interactions on the dynamics of multiexciton generation and decay as a function of dendrimer generation. The dendrimers (generations 1–4) consist of trimethylolpropane core and 2,2-bis(methylol)propionic acid (bis-MPA) dendrons that provide exponential growth of the branches, leading to a corona decorated with pentacenes for SF or anthracenes for TTA-UC. The findings reveal a trend where a few highly ordered sites emerge as the dendrimer generation grows, dominating the multiexciton dynamics, as deduced from optical spectra, and transient absorption spectroscopy. While the dendritic structures enhance TTA-UC at low annihilator concentrations in the largest dendrimers, the paired chromophore interactions induce a broadened and red-shifted excimer emission. In SF dendrimers of higher generations, the triplet dynamics become increasingly dominated by pairwise sites exhibiting strong coupling (Type II), which can be readily distinguished from sites with weaker coupling (Type I) by their spectral dynamics and decay kinetics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Observation of the antimatter hypernucleus $^4_{\bar{\Lambda}}\overline{\hbox{H}}$

Matter-antimatter asymmetry is a research topic of fundamental interest, as it is the basis for the existence of the matter world, which survived annihilation with antimatter in the early Universe. High energy nuclear collisions create conditions similar to the Universe microseconds after the Big Bang, with comparable amounts of matter and antimatter. Much of the antimatter created escapes the rapidly expanding fireball without annihilation, making such collisions an effective experimental tool to create heavy antimatter nuclear objects and study their properties. In this paper, we report the first observation of the antimatter hypernucleus $^4_{\bar{\Lambda}}\overline{\hbox{H}}$, composed of an $\bar{\Lambda}$, an antiproton and two antineutrons. The discovery was made through its two-body decay after production in ultrarelativistic heavy ion collisions by the STAR experiment at the Relativistic Heavy Ion Collider. In total, 15.6 candidate $^4_{\bar{\Lambda}}\overline{\hbox{H}}$ antimatter hypernuclei are obtained with an estimated background count of 6.4. Lifetimes of the antihypernuclei $^3_{\bar{\Lambda}}\overline{\hbox{H}}$ and $^4_{\bar{\Lambda}}\overline{\hbox{H}}$ are measured and compared with lifetimes of their corresponding hypernuclei, testing the symmetry between matter and antimatter. Various production yield ratios among (anti)hypernuclei and (anti)nuclei are also measured and compared with theoretical model predictions, shedding light on their production mechanism.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2026

A skyrmionic topology perspective on Lehmann clusters

When two parallel coplanar dislocations with opposite Burgers vectors are brought into collision by the action of stress in solid crystals, they annihilate each other. In cholesterics with pitch p, under certain conditions, colliding dislocations with Burgers vectors b = p and b = − p are immune against annihilation and form stable twin-like pairs known as Lehmann clusters. We point out that this immunity is due to the escape of the director field into the third dimension. We show that from a topological point of view, Lehmann clusters can be seen as skyrmion tubes embedded in a helicoidal background, and their extremities have the topology of monopoles.

Pieranski, Pawel [Univ. Paris-Saclay, Orsay (Franc↗
DOE OSTI2021

Topology-dependent stability of vortex-antivortex structures

The non-trivial topology of magnetic structures such as vortices and skyrmions is considered as a key concept to explain the stability of those structures. The stability, dictated by non-trivial topology, provides great potential for device applications. Although it is a very critical scientific and technological issue, it is elusive to experimentally study the topology-dependent stability owing to the difficulties in establishing stably formed magnetic structures with different topologies. Here, we establish a platform for vortex-antivortex structures with different topological charges within Ni 80 Fe 20 rectangular elements thick enough to stabilize a unique three-dimensional magnetic structure with non-uniform magnetization along the thickness of the elements. The detailed magnetization configurations of the three-dimensional vortex-antivortex structures and their annihilations during their field-driven motions are investigated by utilizing magnetic transmission soft x-ray microscopy and micromagnetic simulation. We demonstrate that the stability of vortex-antivortex structures significantly depends on their topologies and the topology-dependent stability is associated with their different annihilation mechanisms. Furthermore, we believe that this work provides in-depth insight into the stability of magnetic structures and its topology dependence.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Mixed halide bulk perovskite triplet sensitizers: Interplay between band alignment, mid-gap traps, and phonons

Photon upconversion, particularly via triplet-triplet annihilation (TTA), could prove beneficial in expanding the efficiencies and overall impacts of optoelectronic devices across a multitude of technologies. The recent development of bulk metal halide perovskites as triplet sensitizers is one potential step toward the industrialization of upconversion-enabled devices. In this work, we investigate the impact of varying additions of bromide into a lead iodide perovskite thin film on the TTA upconversion process in the annihilator molecule rubrene. We find an interplay between the bromide content and the overall device efficiency. In particular, a higher bromide content results in higher internal upconversion efficiencies, enabled by more efficient charge extraction at the interface, likely due to a more favorable band alignment. However, the external upconversion efficiency decreases, as the absorption cross section in the near infrared is reduced. The highest upconversion performance is found in our study for a bromide content of 5%. This result can be traced back to a high absorption cross section in the near infrared and higher photoluminescence quantum yield in comparison to the iodide-only perovskite, as well as an increased driving force for charge transfer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Hazma: a python toolkit for studying indirect detection of sub-GeV dark matter

With several proposed MeV gamma-ray telescopes on the horizon, it is of paramount importance to perform accurate calculations of gamma-ray spectra expected from sub-GeV dark matter annihilation and decay. We present hazma, a python package for reliably computing these spectra, determining the resulting constraints from existing gamma-ray data, and prospects for upcoming telescopes. For high-level analyses, hazma comes with several built-in dark matter models where the interactions between dark matter and hadrons have been determined in detail using chiral perturbation theory. Additionally, hazma provides tools for computing spectra from individual final states with arbitrary numbers of light leptons and mesons, and for analyzing custom dark matter models. hazma can also produce electron and positron spectra from dark matter annihilation, enabling precise derivation of constraints from the cosmic microwave background

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Constraining time dependent dark matter signals from the Sun

Dark matter (DM) particles captured by the Sun can produce high-energy electrons outside the Sun through annihilating into meta-stable mediators. The corresponding cosmic-ray electron signals observed by the space-based experiments will be time dependent due to the orbital motion of the space-based detectors. The shape of this time dependence is predictable given the orbital information of the detectors. Since the high-energy CR electron (with energy E > 100 GeV) fluxes are expected to be constant in time, non-observation of such time variation can be used to place upper limits on the DM annihilation cross section. Here we analyze the time dependence of dark matter cosmic-ray signals in three space-based experiments: AMS-02, DAMPE and CALET. Under the assumption that no time dependent signal is observed, we derive the 95% C.L. exclusion limits on the signal strength from the current data. We map our limits onto the parameter space of the dark photon model and find that the constraints are comparable with that derived from the supernova SN1987A.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Neutrino point source searches for dark matter spikes

Any dark matter spikes surrounding black holes in our Galaxy are sites of significant dark matter annihilation, leading to a potentially detectable neutrino signal. In this paper we examine 10-10 5 M ⊙ black holes associated with dark matter spikes that formed in early minihalos and still exist in our Milky Way Galaxy today, in light of neutrino data from the ANTARES and IceCube detectors. In various regions of the sky, we determine the minimum distance away from the solar system that a dark matter spike must be in order to have not been detected as a neutrino point source for a variety of representative dark matter annihilation channels. Given these constraints on the distribution of dark matter spikes in the Galaxy, we place significant limits on the formation of the first generation of stars in early minihalos — stronger than previous limits from gamma-ray searches in Fermi Gamma-Ray Space Telescope data. The larger black holes considered in this paper may arise as the remnants of Dark Stars after the dark matter fuel is exhausted; thus neutrino observations may be used to constrain the properties of Dark Stars. The limits are particularly strong for heavier WIMPs. For WIMP masses ~ 5TeV, we show that ≲ 10 % of minihalos can host first stars that collapse into BHs larger than 10 3 M ⊙ .

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Hazma meets HERWIG4DM: precision gamma-ray, neutrino, and positron spectra for light dark matter

Herein we present a new open-source package, Hazma 2, that computes accurate spectra relevant for indirect dark matter searches for photon, neutrino, and positron production from vector-mediated dark matter annihilation and for spin-one dark matter decay. The tool bridges across the regimes of validity of two state of the art codes: Hazma 1, which provides an accurate description below hadronic resonances up to center-of-mass energies around 250 MeV, and Herwig4DM, which is based on vector meson dominance and measured form factors, and accurate well into the few GeV range. The applicability of the combined code extends to approximately 1.5 GeV, above which the number of final state hadrons off of which we individually compute the photon, neutrino, and positron yield grows exceedingly rapidly. We provide example branching ratios, particle spectra and conservative observational constraints from existing gamma-ray data for the well-motivated cases of decaying dark photon dark matter and vector-mediated fermionic dark matter annihilation. Finally, we compare our results to other existing codes at the boundaries of their respective ranges of applicability. Hazma 2 is freely available on GitHub athttps://github.com/LoganAMorrison/Hazma.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Constraints on dark matter scattering with long lived mediators from observations of the Sun with the Fermi Large Area Telescope

The Sun represents a promising target for indirect dark matter searches, as dark matter particles from the Galactic halo can be gravitationally trapped in its core or in external orbits, and their annihilations can lead to final states with standard model particles that are able to reach the Earth. In this work we have considered a scenario in which dark matter particles can annihilate into pairs of long-lived mediators, which in turn can escape from the Sun and decay into pairs of gamma rays or into the bb̅, τ+τ-, μ+μ- channels, with the production of gamma rays in the final states. All these processes are expected to yield an excess in the energy spectrum of gamma rays towards the Sun. We have therefore analyzed the data collected by the Fermi Large Area Telescope during its first 13.5 years of operation, searching for possible excesses in the solar gamma-ray spectrum. Since no statistically significant excess is found, we have set constraints on the dark matter-nucleon scattering cross sections in both the spin-dependent and spin-independent cases. For all the mediator decay channels explored and for dark matter masses between a few GeV/c 2 and 1 TeV/c 2 , we have found that the upper limits on the spin-dependent and spin-independent cross sections are in the ranges from 10 -45 to 10 -39 cm 2 and from 10 -47 up to 10 -42 cm 2 , respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Primordial black hole dark matter from catastrogenesis with unstable pseudo-Goldstone bosons

We propose a new scenario for the formation of asteroid-mass primordial black holes (PBHs). Our mechanism is based on the annihilation of the string-wall network associated with the breaking of a U(1) global symmetry into a discrete Z N symmetry. If the potential has multiple local minima ( N > 1) the network is stable, and the annihilation is guaranteed by a bias among the different vacua. The collapse of the string-wall network is accompanied by catastrogenesis , a large production of pseudo-Goldstone bosons (pGBs) — e.g. axions, ALPs, or majorons — gravitational waves, and PBHs. If pGBs rapidly decay into products that thermalize, as predicted e.g. in the high-quality QCD axion and heavy majoron models, they do not contribute to the dark matter population, but we show that PBHs can constitute 100% of the dark matter. The gravitational wave background produced by catastrogenesis with heavy unstable axions, ALPs, or majorons could be visible in future interferometers.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Putting all the X in one basket: Updated X-ray constraints on sub-GeV Dark Matter

Sub-GeV dark matter particles can annihilate or decay producing e ± pairs which upscatter the low-energy photon fields in the Galaxy and generate an X-ray emission (via the Inverse Compton effect). Here, using X-ray data from X MM -N EWTON , I NTEGRAL , N U S TAR and S UZAKU , we derive new constraints on this class of dark matter (DM). In the annihilation case, our new bounds are the strongest available for DM masses above 180 MeV, reaching $\langle$σv$\rangle$ ≲ 10 -28 cm 3 /s for m DM ≃ 1 GeV. In the decay case, our bounds are the strongest to date over a large fraction of the considered mass range, constraining τ ≳ 10 28 s for m DM ≃ 1 GeV and improving by up to 3 orders of magnitude upon existing limits.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Search for heavy dark matter from dwarf spheroidal galaxies: leveraging cascades and subhalo models

Abstract TheFermiLarge Area Telescope (Fermi-LAT) has been widely used to search for Weakly Interacting Massive Particle (WIMP) dark matter signals due to its unparalleled sensitivity in the GeV energy band. The leading constraints for WIMP byFermi-LAT are obtained from the analyses of dwarf spheroidal galaxies within the Local Group, which are compelling targets for dark matter searches due to their relatively low astrophysical backgrounds and high dark matter content. In the meantime, the search for heavy dark matter with masses above TeV remains a compelling and relatively unexplored frontier. In this study, we utilize 14-yearFermi-LAT data to search for dark matter annihilation and decay signals in 8 classical dwarf spheroidal galaxies within the Local Group. We consider secondary emission caused by electromagnetic cascades of prompt gamma rays and electrons/positrons from dark matter, which enables us to extend the search withFermi-LAT to heavier dark matter cases. We also update the dark matter subhalo model with informative priors respecting the fact that they reside in subhalos of our Milky Way halo aiming to enhance the robustness of our results. We place constraints on dark matter annihilation cross section and decay lifetime for dark matter masses ranging from 10 3 GeV to 10 11 GeV, where our limits are more stringent than those obtained by many other high-energy gamma-ray instruments.

Astronomy & Astrophysics↗
DOE OSTI2025

Dark matter in X-rays: revised XMM-Newton limits and new constraints from eROSITA

We investigate two classes of dark matter (DM) candidates, sub-GeV particles and primordial black holes (PBHs), that can inject low-energy electrons and positrons into the Milky Way and leave observable signatures in the X-ray sky. In the case of sub-GeV DM, annihilation or decay into e + e - contributes to the diffuse sea of cosmic-ray (CR) leptons, which can generate bremsstrahlung and inverse Compton (IC) emission on Galactic photon fields, producing a broad spectrum from X-rays to γ-rays detectable by instruments such as eROSITA and XMM-Newton. For PBHs with masses below ∼10 17 g, Hawking evaporation similarly yields low-energy e ± , leading to comparable diffuse emission. Using the first data release from eROSITA and incorporating up-to-date CR propagation and diffusion parameters, we derive new constraints on both scenarios. For sub-GeV DM, we exclude thermally averaged annihilation cross sections in the range ∼ 10 -27 –10 -25 cm 3 /s and decay lifetimes of ∼ 10 24 –10 25 s for masses between 1 MeV and 1 GeV, with eROSITA outperforming previous X-ray constraints below ∼ 30 MeV. For asteroid-mass PBHs, we set new bounds on the DM fraction based on their Hawking-induced emission. Finally, we revisit previous constraints in 10.1088/1475-7516/2023/07/026JCAP 07 (2023) 026 and consequently 10.3847/1538-4357/ad41e0Astrophys. J. 968 (2024) 46 derived from XMM-Newton, finding that they were approximately four orders of magnitude too stringent due to the use of the instrument's geometric solid angle rather than its exposure-weighted solid angle. Upon using the exposure-weighted solid angle, we show that the revised XMM-Newton limits are slightly weaker than those from eROSITA.

X-rays↗
DOE OSTI2026

Combined dark matter search towards dwarf spheroidal galaxies with Fermi -LAT, HAWC, H.E.S.S., MAGIC, and VERITAS

Dwarf spheroidal galaxies (dSphs) are excellent targets for indirect dark matter (DM) searches using gamma-ray telescopes because they are thought to have high DM content and a low astrophysical background. The sensitivity of these searches is improved by combining the observations of dSphs made by different gamma-ray telescopes. We present the results of a combined search by the most sensitive currently operating gamma-ray telescopes, namely: the satellite-borne Fermi -LAT telescope; the ground-based imaging atmospheric Cherenkov telescope arrays H.E.S.S., MAGIC, and VERITAS; and the HAWC water Cherenkov detector. Individual datasets were analyzed using a common statistical approach. Results were subsequently combined via a global joint likelihood analysis. We obtain constraints on the velocity-weighted cross section 〈σv〉 for DM self-annihilation as a function of the DM particle mass. This five-instrument combination allows the derivation of up to 2-3 times more constraining upper limits on 〈σv〉 than the individual results over a wide mass range spanning from 5 GeV to 100 TeV. Depending on the DM content modeling, the 95% confidence level observed limits reach 1.5×10 -24 cm 3 s -1 and 3.2×10 -25 cm 3 s -1 , respectively, in the τ + τ - annihilation channel for a DM mass of 2 TeV.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Heavy dark matter in rapidly evolving massive stars

We study the impact of heavy dark matter (DM) captured in massive stars via scattering(s) with the star constituents. We focus on the first stars and use stellar evolution simulations to track down how DM capture evolves over time from the zero-age main sequence to the late metal-rich stages of stellar evolution. During the early hydrogen-helium-dominated phase, the capture process is well described by scattering with two targets. As a star evolves, metal production leads to the formation of a dense core surrounded by a lighter envelope. The core significantly enhances the capture of ultra-heavy DM; in this case, three distinct nuclear species are required to accurately describe multiple-scattering capture. We use the Eddington inversion method to obtain a realistic DM velocity distribution, better suited when the star is near the center of a halo, than the widely used Maxwell-Boltzmann distribution. We find that heavy DM would be able to thermalize and achieve capture-annihilation equilibrium within a massive star's lifetime for regions of the parameter space not excluded by direct detection. For non-annihilating DM, because of the high amount of targets available for capture and despite massive stars being short-lived, it would even be possible for DM to achieve self-gravitation and collapse to a black hole, which eventually could swallow the star from within before the expected end of the star's life, for non-excluded regions of the parameter space. Our results highlight the dependence of DM capture on the stellar evolutionary stage, composition, and halo location, demonstrating that accurate modeling of massive stars is essential for constraining heavy DM with primordial stellar populations.

dark matter theory↗