On the Synthesis and Adsorption Properties of Single-Unit-Cell Hierarchical Zeolites Made by Rotational Intergrowths
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Metal–organic frameworks (MOFs) containing more than two types of metal ions mixed within one secondary building unit are studied.
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Under base free and mild reaction conditions, 80.5% selectivity of lactic acid (LA) was achieved at 89.8% conversion of glycerol using a bifunctional Pt/Sn-MFI catalyst.
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Cation–cation interaction: A new 2 D sheet structure containing a side-on cation–cation interaction (CCI) has been synthesized and characterized (see figure). Unprecedentedly, no chelating ligands between the cations are present. We explore the nature of the side-on interaction and ligand effects by using a variety of quantum chemical methods. The spin–orbit-coupled ground state mixes singlet, triplet, and quintet-pure spin states.
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