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At least 217 records · Page 12

Influence of Cu/Li Ratio on the Welding Forces and Mechanical Properties of Two Bobbin Tool Friction Stir Welded Al-Cu-Li Alloys

Increasing space activities produce a high number of space objects and lead to increasing collision risks which urges leading industries to look for future removal strategies. Material substitution in order to raise demisability during atmospheric reentry is a possible solution. Modern aluminum lithium alloys are under consideration to replace high-temperature melting materials like titanium. Further, friction stir welding was proposed as suitable joining technology in order to avoid high heat inputs during manufacturing. In this work, two modern Al-Li-Cu alloys, AA 2060 and AA 2196, in peak-aged temper were welded using the stationary shoulder variant of bobbin tool friction stir welding. Identical process parameters led to defect-free welds in both alloys. The macrostructural and microstructural features are shown and analyzed. The welds were mechanically tested to an efficiency of 78 and 70% of the base metal ultimate tensile strength for AA 2060 T8 and AA 2196 T8, respectively. The process forces as well as the thermal cycle experienced by the workpiece material were used to explain the mechanical performance. The difference in composition regarding the Cu/Li ratio of the alloys was taken into account when the mechanical properties were correlated with the thermally affected microstructure of the weldments.

36 MATERIALS SCIENCE↗

Microstructure and Mechanical Characterization of Friction-Stir-Welded 316L Austenitic Stainless Steels

Fusion welding of austenitic stainless steels (ASSs) causes undesirable metallographic changes. An attempt has been made to join 3-mm-thick 316L ASS plates using friction stir welding and correlate the microstructural evolution and the mechanical properties under various welding conditions. Tungsten alloy (W-Re) tool was employed for welding. Successful joints were obtained within a range of traverse speeds (45-85 mm/min) used in this work. Various zones were observed across the joint line. The stir zone exhibited considerable grain refinement and traces of delta ferrite phase. EBSD images showed a decreasing grain size with increased traverse speed. XRD patterns and TEM images confirmed the existence of delta ferrite. The mechanical properties of the joints including microhardness, tensile strength, impact toughness and bending were further reported.

36 MATERIALS SCIENCE↗

Statistical Strength Analysis of Dissimilar AA2024-T6 and AA6061-T6 Friction Stir Welded Joints

Friction stir welding has been emerged as one of the most reliable processes for joining aerospace-grade aluminum alloys. However, limited studies have been focused so far on the reliability of these joint types. In this study, the effect of welding parameters (traverse and rotation speeds) on the fracture strength of dissimilar AA2024-T6 and AA6061-T6 friction stir welded joints was statistically analyzed by the Weibull approach. Based on the results, the Weibull approach was found to be much more accurate than widely used standard deviation for evaluating the scatter of the fracture strength data. The improper selection of the process parameters not only decreased the average fracture strengths of the joints, but also scattered them around the mean value, and increased the failure probability under the same applied tension. According to the microscopic and macroscopic examinations and microhardness measurements, although the microstructural inhomogeneities caused by the improper setting of the welding parameters negatively affected the joints hardness and fracture strength, the welding defects were likely to be the most responsible factor affecting the fracture strength and its reliability.

36 MATERIALS SCIENCE↗

Fabrication and Characterization of A5083-WC-Al{sub 2}O{sub 3} Surface Composite by Friction Stir Processing

In this study, WC-Al{sub 2}O{sub 3} ceramic composite was incorporated into Al5083 to produce a surface composite by friction stir processing (FSP), and the microstructure, hardness and wear properties of Al5083-WC-Al{sub 2}O{sub 3} surface composite were evaluated. Optical microscopy of FSPed samples showed grain refinement in the stir zone. The addition of WC-Al{sub 2}O{sub 3} particles as well as increase in FSP pass number had a considerable effect on grain refinement, and the grain size of Al5083 base metal of 36 µm reduced to 11 µm for Al5083-WC-Al{sub 2}O{sub 3} surface composite after four passes. The SEM observation of the surface composite revealed that the WC-Al{sub 2}O{sub 3} particles distributed homogenously in the matrix and by increasing the FSP passes, the initial agglomerates of mechanochemically synthesized WC-Al{sub 2}O{sub 3} powders could be fractured. Microhardness evaluation showed a substantial improvement by adding WC-Al{sub 2}O{sub 3} particles and increase in FSP pass number. The maximum microhardness value of 101 HV belonged to surface composite after four passes, while the microhardness of the base metal was 65 HV. Wear test results revealed enhanced tribological behavior with a similar trend of microhardness values. Scanning electron microscopy tests revealed both adhesive and abrasive wear mechanisms on the surface of the wear test specimens.

36 MATERIALS SCIENCE↗

Cooling Environment Effect on the Microstructure and Mechanical Properties of Friction Stir-Welded Joints

The heat input in friction stir welding (FSW) influences the localized properties in welded joint. The external cooling during FSW reduces the localized heating and post-weld cooling time by extracting heat comparatively at a faster rate. In the present study, we have investigated the effect of different cooling environments on the performance of friction stir-welded (FSWed) AA5052 strain-hardenable aluminum alloy. Welding was performed under three different cooling environments such as natural air, water and liquid nitrogen in order to understand their effects on grain structure, metallurgical changes and mechanical properties of the joints. It has been noted that the width of weld nugget zone, thermo-mechanically affected zone and heat-affected zone has been decreased with the respective change in cooling environments. Welding speed could also influence the width of different zones in weldment alike the cooling environments. Finer grain size has been noticed with water cooling against the liquid nitrogen cooling. Comparatively, water was observed to be more favorable cooling environment against liquid nitrogen because of its better weld quality (97%) compared with base metal. The favorable mechanical properties resulting from the different weldment regions for different cooling environments have been elaborated in the present study.

36 MATERIALS SCIENCE↗

Microstructure Evolution of Ultra-Fine-Grained AZ31 B Magnesium Alloy Produced by Submerged Friction Stir Processing

Ten-millimeter-thick strain-hardened AZ31B-H24 magnesium sheets were subjected to friction stir processing (FSP) in air and submerged friction stir processing (SFSP) under water to investigate their microstructures and microhardness properties. Different rotational speeds of 500, 630, 800, and 1000 rpm and traverse speeds of 50, 100, 200, and 350 mm/min were employed for processing the materials. For SFSPed samples, the rotational speed of 500 rpm and 200 mm/min of traverse speed resulted in an ultra-fine-grained structure with a minimum grain size of about 400-500 nm, which is half compared to that of FSPed. It was found that both processes led to variation of crystallographic orientation, and enhancing the rotational speed and lowering the traverse speed promoted the development of a {0002} basal texture. The microhardness of SFSPed material increased significantly up to 110% (~ 95 Hv), while the microhardness was 45% (~ 65 Hv) higher than the base metal (~ 45 Hv) for FSPed material.

36 MATERIALS SCIENCE↗

Effect of Rotational Speed on Microstructure and Mechanical Properties in Submerged Friction Stir Welding of ME20M Magnesium Alloy

Submerged friction stir welding of magnesium alloys has not been well investigated to date. ME20M is an important lightweight magnesium (Mg) alloy with enhanced yield strength and heat resistance that merits further research. In this paper, submerged friction stir welding of the ME20M Mg alloy was carried out using different parameters for the underwater cooling. Defect-free weld joints were produced, and the macrostructure, microstructure, tensile properties, and hardness were investigated. The results show that by increasing the rotational speed, the grain size of the weld nugget increased, the tensile strength of the joint decreased, and the microhardness of the different weld zones decreased. The finest obtained grain size was about 3.5 µm in the weld nugget at a rotational speed of 1100 rpm. The highest tensile strength achieved was 183.2 MPa, which was ~ 76.32% of the base metal. The highest and lowest hardness values of the weld joint were obtained at rotational speeds of 1100 and 1600 rpm, respectively, in the weld nugget and heat-affected zones.

36 MATERIALS SCIENCE↗

Effect of Welding Parameters on Junction Structure and Fracture Behavior of Friction-Stir-Welded Joints of 2024 Aluminum Alloys

In this paper, the effect of welding speed and tool rotation speed on the junction structure and fracture behavior of friction-stir-welded joints was investigated with use of 2024 aluminum alloys of 3.2 mm thick. Results show that the formation of junction structure is more affected by tool rotation speed than by welding speed due to the differences of heat input levels. When welding speed is at 100 mm/min and tool rotation speed is in the range of 400-600 r/min, the joint junction structure causes complete bonding with no welding defects. While under improper welding parameters, the junction structure causes the precipitate aggregation on the bonding line and the partial bonding with the appearance of both tunnel defects and kissing bond defects. Meanwhile, the results of tensile tests show that the tensile fracture of all FSW joints occur at the weld center. The failure mode of joints with defects-free junction structure characterized by shear fracture is ductile. While the failure mode of joints with defects-existent junction structure characterized by layered fracture surface is brittle. Furthermore, that heterogeneous microstructure, precipitate aggregation and welding defects converge inside the junction structure is the main factor affecting the tensile properties and fracture behavior of the friction-stir-welded joint.

36 MATERIALS SCIENCE↗

Forced Cooling Friction Stir Welding of 2060-T8 Al-Li Alloy

Friction stir welding of 2060-T8 Al-Li alloy was experimentally investigated. Forced cooling process was realized by placing two copper pressure plates with a waterway on both sides of weld top surface. The relations between joint formation, microstructures and mechanical properties were mainly discussed. Compared with conventional joint by natural cooling, the welding joint with smaller flashes by forced cooling has the smaller well-distributed grains and higher microhardness in the stir zone (SZ). The tensile strength and elongation of forced cooling joint, respectively, reach 445.7 MPa and 6.7%, which are obviously higher than those of the conventional joint. The fracture locations of the conventional and forced cooling joints are located in the SZ, and the fracture surface morphologies show a typical ductile fracture mode.

36 MATERIALS SCIENCE↗

Effect of Tool Offset and Rotational Speed in Dissimilar Friction Stir Welding of AISI 304 Stainless Steel and Mild Steel

In the present study, dissimilar friction stir welding was carried out between stainless steel (UNS S30400) and mild steel (UNS G10080) plates of 4 mm thickness using a tungsten carbide tool. The influence of tool rotational speeds (600, 875 rpm) and tool offsets (0.6, 1.2 mm) on mechanical properties, i.e., hardness, tensile strength, and impact toughness of welded joints was investigated. Maximum tensile strength of the joint was about 107.6% of the mild steel under rotational speed of 875 rpm and tool offset of 1.2 mm. The maximum hardness reached in the stir zone was about 281 HV{sub 0.5} due to the phase transformations and grain refinement. Charpy’s notch toughness of the welded joints was observed lower than the base materials. The microstructural characterizations were carried by using an optical microscope, and FESEM–EDS analysis which revealed the complex material mixing and material movement during the welding. Tungsten-rich bands were observed in the weld micrograph especially toward the advancing side. During this study, various wear mechanisms like oxidation wear, abrasive wear, and adhesion wear were responsible for the degradation of tungsten carbide tool.

36 MATERIALS SCIENCE↗

Neutron Diffraction Residual Stress Study of a AA2219-T87 Self-Reacting Friction Stir Weld

2219-T87 is a precipitation hardenable aluminum-copper alloy which sees wide use in structural aerospace components. Thick panels of this alloy are joined via self-reacting friction welding (SRFSW); however, this thermomechanical process can result in significant loss of the alloy’s strengthening precipitates and large residual stresses which are detrimental to mechanical behavior and performance. High-resolution maps of the residual strain and stress states along the normal, transverse, and longitudinal directions of 2219-T87 SRFSW were obtained using neutron diffraction measurements. Residual stress had the highest tensile value in the heat-affected zone (HAZ) and the largest compressive stress in the base metal region of the normal and transverse directions. Line profile residual stress distributions displayed an “M”-shaped distribution in each direction with the longitudinal direction being the most pronounced while 2D residual stresses displayed an hourglass-shaped pattern. Further, average maximal longitudinal residual stress values ranged from 60.6 to 85.6% of yield. Microhardness testing across the transverse weld section produced a “V”-shaped curve with slight hardness recovery in the stir zone. Maximal and minimal microhardness values were observed in the base metal (154 HV) and thermomechanically affected zone (82 HV), respectively. Microstructural evolution was recorded using optical microscopy and showed decreasing grain size from the HAZ to the stir zone.

36 MATERIALS SCIENCE↗

Deformation mechanisms and ductile fracture characteristics of a friction stir processed transformative high entropy alloy

Deformation mechanisms of a friction stir processed Fe 40 Mn 20 Co 20 Cr 15 Si 5 transformative high entropy alloy using three different process parameters were studied to explain the microstructural dependence of tensile response in these specimens. The relative strain hardening contribution due to transformation and twinning effects was different for the three different microstructural conditions and thus resulted in different magnitude of work hardening. Crystal plasticity simulations confirmed that synergistic activity of face centered cubic and hexagonal close packed slip and twin mechanisms resulted in sustained work hardening and enhanced uniform elongation. The non-uniform ductility and extent of void nucleation and growth in these specimens were limited. Nevertheless, fractography and X-ray microscopy of fractured tensile specimens verified that microstructural flexibility induced different propensities for void growth and ductile fracture mode. Thus, alloy design induced phase stability, adaptive phase evolution due to friction stir processing, extent and kinetics of martensitic transformation and related work hardening capability of the individual phases combined together to determine the overall tensile response. The crystallographic orientation dependence of deformation induced phase transformation was also thoroughly studied. Finally, this study included quantitative determination of the crystallographic orientation where resolved shear stress on leading and trailing partial dislocations favored separation of the partials to cause transformation at a critical value of applied stress.

36 MATERIALS SCIENCE↗

Direct current in a stirred optical lattice

We study how the energy dispersion of bosonic atoms loaded into an optical lattice becomes modified due to periodic circular stirring of the lattice to the second order in the strength of stirring. If the lattice breaks mirror symmetry, the bosonic atoms may acquire a nonzero group velocity at the center of the Brillouin zone and produce a nonzero direct current. Furthermore, this effect is similar to the circular photogalvanic effect in solid-state physics. It can be used to transport neutral bosonic atoms in an optical lattice over a given distance in an arbitrary direction. However, when the drive frequency is detuned to avoid resonant transitions with energy absorption, we argue that the induced current is not persistent, but transient. An experimental study of the relaxation of the induced current can provide insight about equilibrization in driven systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Friction stir processing of dual certified 304/304L austenitic stainless steel for improved cavitation erosion resistance

Cavitation phenomenon is known to be prevalent in equipment in hydraulic environments. Understanding cavitation and improving the cavitation resistance of commonly used materials is of interest for both scientific and economic reasons. In this study, friction stir processing was employed to modify commercial dual certified AISI 304/304L austenitic stainless steel plates. The cavitation erosion resistance of the processed plates was evaluated and compared to that of the unprocessed steel. A temperature control algorithm was employed to maintain a target tool temperature during the processing. The cross sections of the processed nuggets were evaluated using optical microscopy, scanning electron microscopy and Vickers hardness testing. Cavitation testing was performed conforming to ASTM G134 on specimens cut out of the nuggets of the commercially unprocessed and the processed 304/304L steel. The tool temperature was found to affect the microstructure and the cavitation performance. Friction stir processed steel showed 3 times better cavitation resistance than the unprocessed 304/304L. Surface cavitation patterns and cavitation rates were characterized and the mechanisms of material removal were discussed.

Jiang, Xiujuan↗

Aeration costs in stirred-tank and bubble column bioreactors

To overcome knowledge gaps in the economics of large-scale aeration for production of commodity products, Aspen Plus is used to simulate steady-state oxygen delivery in both stirred-tank and bubble column bioreactors, using published engineering correlations for oxygen mass transfer as a function of aeration rate and power input, coupled with new equipment cost estimates developed in Aspen Capital Cost Estimator and validated against vendor quotations. Here, these simulations describe the cost efficiency of oxygen delivery as a function of oxygen uptake rate and vessel size, and show that capital and operating costs for oxygen delivery drop considerably moving from standard-size (200 m 3 ) to world-class size (500 m 3 ) reactors, but only marginally in further scaling up to hypothetically large (1000 m 3 ) reactors. Finally, this analysis suggests bubble-column reactor systems can reduce overall costs for oxygen delivery by 10-20% relative to stirred tanks at low to moderate oxygen transfer rates up to 150 mmol/L-h.

09 BIOMASS FUELS↗

Experimental and modeling studies of a biofuel surrogate compound: laminar burning velocities and jet-stirred reactor measurements of anisole

Lignocellulosic biomass is a promising alternative fuel source which can promote energy security, reduce greenhouse gas emissions, and minimize fuel consumption when paired with advanced combustion strategies. Pyrolysis is used to convert lignocellulosic biomass into a complex mixture of phenolic-rich species that can be used in a transportation fuel. Anisole (or methoxybenzene) can be used as a surrogate to represent these phenolic-rich species. Anisole also has attractive properties as a fuel component for use in advanced spark-ignition engines because of its high blending research octane number of 120. Presented in the current work are new measurements of laminar burning velocities, jet-stirred reactor (JSR) speciation of anisole/O 2 /N 2 mixtures, and the development and validation of a detailed chemical kinetic mechanism for anisole. Homogeneous, steady state, fixed gas temperature, perfectly stirred reactor CHEMKIN simulations were used to validate the mechanism against the current JSR measurements and published JSR experiments from CNRS-Nancy. Pyrolysis and oxidation simulations were based on the experimental reactant compositions and thermodynamic state conditions including P = 1 bar and T = 675–1275 K. The oxidation compositions studied in this work span fuel-lean (φ = 0.5), stoichiometric, and fuel rich (φ = 2.0) equivalence ratios. Laminar burning velocities were measured on a heat flux stabilized burner at an unburnt T = 358 K, P = 1 bar and simulated using the CHEMKIN premixed laminar flame speed module. Ignition delay times of anisole were then simulated at conditions relevant to advanced combustion strategies. Current laminar burning velocity measurements and predicted ignition delay times were compared to gasoline components (e.g., n-heptane, iso-octane, and toluene) and gasoline surrogates to highlight differences and similarities in behavior. Reaction path analysis and sensitivity analysis were used to explain the pathways relevant to the current studies. Under pyrolysis and oxidative conditions, unimolecular decomposition of anisole to phenoxy radicals and methyl radicals was found to be important due to the relatively low bond strength between the oxygen and methyl group, ~65 kcal/mol. Finally, reactions of these abundant phenoxy radicals with O 2 were found to be critical to accurately reproduce anisole's reactivity.

10 SYNTHETIC FUELS↗

Computational studies of impurity migration during induction stirring of molten uranium

Understanding and controlling impurity behavior in actinide metal casting processes are foundational for efficient part production yet remain major challenges for researchers and industry. To help provide insight regarding impurity distribution during actinide metal casting, we have developed computational fluid dynamics (CFD) models for a laboratory-scale system using commercial and open-source code. Multiple simulation frameworks allow for improved confidence in the resulting outputs, while taking advantage of the maturity and convenience offered by commercial platforms and simultaneously maintaining the transparency and flexibility often provided by open-source software. Here, we describe multiple experiment-informed models designed to simulate a specific laboratory system in which uranium melt, containing a known starting concentration of carbon impurity, is electromagnetically stirred in an induction furnace. Here, the goal of the simulations is to predict the motion of uranium carbide microparticles in the velocity field of the melt. Prior to simulating the uranium-carbon system, numerical models were validated using a previously published nonradioactive experimental system. Effects of the size and shape of impurity particles in the models were investigated and agree with experimental findings. Simulation of smaller particles (< 50 µm) shows more homogenous distribution throughout the stirred melt. With increased particle size (100 µm), the body forces, which include the buoyancy force, dominate over the drag force, causing larger particles to move toward the crucible walls and upward in the system.

36 MATERIALS SCIENCE↗

Interfacial microstructure and properties of copper clad steel produced using friction stir welding versus gas metal arc welding

A preliminary study compares the feasibility and microstructures of pure copper claddings produced on a pressure vessel A516 Gr. 70 steel plate, using friction stir welding versus gas metal arc welding. A combination of optical and scanning electron microscopy is used to characterize the grain structures in both the copper cladding and heat affected zone in the steel near the fusion line. The friction stir welding technique produces copper cladding with a grain size of around 25 μm, and no evidence of liquid copper penetration into the steel. The gas metal arc welding of copper cladding exhibits grain sizes over 1 mm, and with surface microcracks as well as penetration of liquid copper up to 50 μm into the steel substrate. Transmission electron microscopy reveals that metallurgical bonding is produced in both processes. Increased diffusion of Mn and Si into the copper cladding occurs when using gas metal arc welding, although some nano-pores were detected in the FSW joint interface. - Highlights: • Cladding of steel with pure copper is possible using either FSW or GMAW. • The FSW yielded a finer grain structure in the copper, with no evidence of cracking. • The FSW joint contains some evidence of nano-pores at the interface of the steel/copper. • Copper cladding by GMAW contained surface cracks attributed to high thermal stresses. • The steel adjacent to the fusion line maintained a hardness value below 248 HV.

36 MATERIALS SCIENCE↗