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At least 217 records · Page 12

Mechanical degradation of duplex SiC-fiber reinforced SiC matrix composite tubes under a controlled high-temperature steam environment

This paper describes results from the mechanical evaluation of unirradiated SiC fiber–reinforced SiC matrix composite tubes under a controlled high-temperature steam environment. The experiments were aimed at identifying key material degradation behavior under environments relevant to loss-of-coolant accidents of light water reactors. Mechanical tests of the SiC composite tubes at 1000 °C under steam and inert environments were conducted using a unique test capability. Further, the material tested was a duplex tube with a thick monolithic SiC layer on the outer surface. The tubes were subjected to preloading at ~100 MPa in tension before exposure to high-temperature steam with up to 75% of the preload at a constant displacement. In the presence of matrix cracks, the steam exposure caused embrittlement of the SiC composite tubes and failure at a stress level below the pretest stress. The material degradation was explained by a fiber oxidation model, which can be applied to various SiC cladding concepts. The embrittlement could be a limiting factor for using SiC cladding subjected to loss-of-coolant accident conditions.

36 MATERIALS SCIENCE↗

Enriched hydrogen production over air and air-steam fluidized bed gasification in a bubbling fluidized bed reactor with CaO: Effects of biomass and bed material catalyst

Gasification is one of the methods of generating biopower or biofuels from biomass waste. In this study, a benchscale fluidized bed reactor was used for biomass air and air-steam gasification. Gasification was performed under constant operating conditions (~780 °C, equivalence ratio = ~0.32) to investigate the effect of biomass (switchgrass, pine residues) and bed materials (sand, CaO+ sand, Al 2 O 3 , and CaO + Al 2 O 3 ). All gasification products, such as synthesis gas (syngas), contaminant gases, tar, and biochar (solid) were comprehensively analyzed. The composition of biomass significantly impacted CO and H 2 yield from volatile combustible matter and fixed carbon. Further, the presence of CaO made the condition favorable for the water-gas shift (WGS) reaction combined with the CO 2 carbonation reaction, which increased H 2 concentration. Additional steam with CaO increased H 2 concentration closer to 50% (N 2 free condition) through the combination reactions of steam hydrocarbon reforming and WGS by producing 44 g H 2 /kg dry biomass and 143 g CO /kg dry biomass . The usage of steam reduced the overall yield of contaminant gases, whereas the usage of CaO or Al 2 O 3 decreased the amount of gasification tar by approximately 5.8–6.5 g tar /kg dry biomass . In conclusion, this study can provide valuable experimental data for biomass waste to produce better quality syngas.

08 HYDROGEN↗

A fast and accurate modeling approach for water and steam thermodynamics with practical applications in district heating system simulation

In U.S. district heating (DH) systems, steam is the most common heat transport medium. Industry demand for new advanced modeling capabilities of complete steam DH systems is increasing; however, the existing models for water/steam thermodynamics are too slow for large system simulations because of computationally expensive algebraic loops that require the solution to nonlinear systems of equations. For practical applications, this work presents a novel split-medium approach that implements numerically efficient liquid water models alongside various water/steam models, breaking costly algebraic loops by decoupling mass and energy balance equations. New component models for steam DH systems are also presented. We implemented the models in the equation based Modelica language and evaluated accuracy and computing speed across multiple scales: from fundamental thermodynamic properties to complete districts featuring 10 to 200 buildings. Compared to district models with the IF97 water/steam model and equipment models from the Modelica Standard Library, the new implementation improves the scaling rate for large districts from cubic to quadratic with negligible compromise to accuracy. Additionally, for an annual simulation with 180 buildings, this translates to a computing time reduction from 33 to 1-1.5 h. These results are critically important for industry practitioners to simulate steam DH systems at large scales.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode

Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

09 BIOMASS FUELS↗

Scaling of two-phase water-steam relative permeability and thermal fluxes in porous media

Two-phase water-steam flow conditions are frequently encountered in many engineering applications, including geothermal reservoirs. Although routine calculations are based on the multiphase Darcy’s law, the role of the topology of the flowing phases at the pore-scale is usually neglected in the estimation of relative permeabilities. Instead, the latter are frequently computed using empirical models like the Corey correlation. In this work, we first apply the model for relative permeabilities based on pore-scale flow regimes developed by Picchi and Battiato (2019), Relative permeability scaling from pore-scale flow regimes, Water Resour. Res. 55, 3215–3233, to scenarios typical of geothermal reservoirs and then extend it by deriving the scaling laws for the transmissibilities and the thermal properties as a function of temperature. First, we discuss the scaling behavior of normalized relative permeabilities in terms of viscosity ratio and capillary number of water-steam systems and, then, we provide a validation of the model against experimental data available in the literature. The model captures well the data trends collected in real 3D porous media. These results suggest that water-steam relative permeabilities follow the same scaling behavior of gas-liquid systems where the non-wetting phase is much less viscous than the wetting phase. Finally, we investigate the impact that relative permeabilities have on heat transfer rates at two-phase flow conditions and the scaling of mass and energy transmissibility and thermal properties of the mixture. An estimation of the exergy carried by the two-phase water-steam mixture is also included.

42 ENGINEERING↗

Microstructural analysis of tristructural isotropic particles in high-temperature steam mixed gas atmospheres

High-temperature gas-cooled reactors (HTGRs) use tristructural isotropic (TRISO) particles embedded in a graphitic matrix material to form the integral fuel element. Potential off-normal reactor conditions for HTGRs include steam ingress with temperatures above 1,000 °C. Fuel element exposure to steam can cause the graphitic matrix material to evolve, forming an atmosphere composed of oxidants and oxidation products and potentially exposing the TRISO particles to these conditions. Investigating the oxidation response of TRISO particles exposed to a mixed gas atmosphere will provide insight into the stability under off-normal conditions. In this study, surrogate TRISO particles were exposed to high temperatures (T = 1,200 °C) in flowing steam (3% < pH 2 O < 21%) and CO (pCO < 1%) to determine the oxidation behavior of the SiC layer when exposed to various mixed gas atmospheres. Scanning electron microscopy, x-ray diffraction, and focused ion beam milling was used to determine the impact of CO and steam on the oxidation behavior of the SiC layer. Therefore, the data presented demonstrates how the SiC layer showed strong oxidation resistance due to limited SiO 2 growth and maintained its structural integrity under these off-normal conditions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Implementation and Rejection of Industrial Steam System Energy Efficiency Measures

Steam systems consume approximately one third of energy applied at U.S. industrial facilities. To reduce energy consumption, steam system energy assessments have been conducted on a wide range of industry types over the course of five years through the Energy Savings Assessment (ESA) program administered by the U.S. Department of Energy (U.S. DOE). ESA energy assessments result in energy efficiency measure recommendations that are given potential energy and energy cost savings and potential implementation cost values. Saving and cost metrics that measure the impact recommended measures will have at facilities, described as percentages of facility baseline energy and energy cost, are developed from ESA data and used in analyses. Developed savings and cost metrics are examined along with implementation and rejection rates of recommended steam system energy efficiency measures. Based on analyses, implementation of steam system energy efficiency measures is driven primarily by cost metrics: payback period and measure implementation cost as a percentage of facility baseline energy cost (implementation cost percentage). Stated reasons for rejecting recommended measures are primarily based upon economic concerns. Additionally, implementation rates of measures are not only functions of savings and cost metrics, but time as well.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Once-Through Steam Generator Model Analysis Using Python and Advanced Optimization Tools (Summer Internship Report)

This study focuses on the parametric analysis of design parameters for a once-through steam generator (OTSG) model, using python and advanced optimization tools to facilitate applications such as the flowing autoclave steam generator (FASG) test cases. Building on previous research involving another OTSG with a different design, this project aims to enhance our understanding of how steam generators (SGs) behave and how their outputs are influenced by changes in design. The reason for this design change is to allow for more precise modeling and optimization of SG performance, to provide a comparative analysis between the two designs, and to set up the model for integration with the FASG test case. The OTSG python-model is a mathematical representation (including fluid flow and heat transfer equations/models/correlations) of a steam-generating unit in a pressurized water reactor-type small modular reactor system. Design studies involve changing the model’s input design parameters to observe the resulting effects on the output of the system. By using advanced optimization tools, such as the Risk Analysis Virtual Environment (RAVEN) developed at Idaho National Laboratory, detailed design parametric studies and model optimization were performed. Six input parameters—pressure, temperature, and mass flow rate for the inlet of the primary-side (hot fluid) and secondary-side (cold fluid), respectively, of the SG—were randomly perturbed via RAVEN’s Monte Carlo Sampler module, using uniform distributions (i.e., ±1%, ±5% and ±10% relative changes) for 600 samples. The analysis provides valuable insights into SG optimization and can be used for sensor placement optimization to effectively monitor and obtain experimental data in other tests.

20 FOSSIL-FUELED POWER PLANTS↗

Steam Generators: Thermal Hydraulic Measurements and Instrumentation

Steam generators are integral components of both conventional and advanced reactors utilizing steam power cycles, as they influence the power conversion performance. Steam generator designs are highly influenced by the type of reactor coolant used, which mainly governs the different control, monitoring, and safety system actuation requirements. Therefore, the present work reviews the thermal hydraulics instrumentation within steam generators designed for pressurized water reactors (PWRs), high-temperature gas-cooled reactors (HTGRs), sodium fast reactors (SFRs), and molten salt cooled reactors (MSRs). Emphasis is given to measurement techniques that are either unique or particularly important to specific reactor types. Lastly, a discussion is provided on the instrumentation and measured parameters. The work identifies standard parameters of interest and is expected to aid the development of test beds and novel measurements techniques.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

BWR ex-vessel steam explosion analysis with MC3D code

A steam explosion may occur, during a severe reactor accident, when the molten core comes into contact with the coolant water. A strong enough steam explosion in a nuclear power plant could jeopardize the containment integrity and so lead to a direct release of radioactive material to the environment. To resolve the open issues in steam explosion understanding and modeling, the OECD program SERENA phase 2 was launched at the end of year 2007, focusing on reactor applications. To verify the progress made in the understanding and modeling of fuel coolant interaction key phenomena for reactor applications a reactor exercise has been performed. In this paper the BWR ex-vessel steam explosion study, which was carried out with the MC3D code in conditions of the SERENA reactor exercise for the BWR case, is presented and discussed. The premixing simulations were performed with two different jet breakup modeling approaches and the explosion was triggered also at the expected most challenging time. For the most challenging case, at the cavity wall the highest calculated pressure was {approx}20 MPa and the highest pressure impulse was {approx}90 kPa.s. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Control blade degradation test under temperature gradient in steam atmosphere

The core of a boiling water reactor (BWR) consists of an array of fuel assemblies with cross-shaped control blades located between these assemblies. The typical control blade consists of a control blade sheath made of 316L-type S.S., a center pole made of 316L-type S.S., and control rods. In order to understand the degradation process of the control blade channel, control blade degradation tests were performed under various atmospheres with a temperature increase condition and in the presence of a temperature gradient. A test device was built. Four carbon heaters are set on both sides at the upper and the middle parts of the test device. The bottom ceramic part of the test device is cooled by water. Heating in the upper region and cooling at the bottom of the test piece give rise to the temperature gradient in the test piece. Temperatures of the test piece are measured by five W-Re type thermocouples placed close to the test piece. Steam carried by the argon gas is supplied from the bottom of the device and flows to the top inside a square carbon muffle in which the test piece is set. Three windows for visual observations are installed, with one located above the furnace and the others located at the back of the furnace. In the steam atmosphere with a steam flow rate of 0.0125 g/s/rod, the control blade, channel box, and fuel rods were degraded, especially at the upper part of the test piece. This result was similar to that observed in the argon atmosphere test. However, the observed degradation was rather different at a higher steam flow rate of 0.0417 g/s/rod. At the upper part of the test piece, only the control blade was degraded preferentially and did not react with the channel box wall. In contrast, the eutectic reaction of the stainless steel/boron carbide melt and zircaloy occurred at the lower part by coexisting with the relocated melt from the top part. These observations suggested the existence of a threshold condition for the control rod degradation between 0.0125 and 0.0417 g/s/rod which is significantly affected by the thickness of the oxide layer on zircaloy.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Experimental Study for Two Phase Flow Instability in the PCHE Type Steam Generator in SMR

Conventional U-tube type heat exchangers have some limitations when applied to Small Modular Reactor (SMRs). In particular, the size of steam generators is important in the SMR, as it greatly affects the size, and thus the cost, of the reactor vessel.. Therefore, the circuit heat exchanger (PCHE) is suggested as an alternative. PCHE, a compact type heat exchanger manufactured by HEATRIC, has several advantages such as the reduced size, wide operation range until 900? and 900 bar and high power density due to the large heat transfer area over volume ratio. Recently, it is newly suggested as an application of a steam generator. MIT and KAIST have already conceptually suggested PCHE as a steam generator. Under boiling condition, flow instability is one of the critical issues-resulting in unstable mass flow rate, sudden temperature change and system control failure. According to the flow mechanism, there are various types of instabilities in the heat exchanger and each flow tendency is different. Typical examples are Ledinegg instability of the static instability and pressure-drop oscillation and density-wave oscillation of the dynamic instability. The characteristic of Ledinegg instability is that the flow under unstable condition changes into the stable flow. The characteristic of dynamic instability is that the flow fluctuates continuously. Pressure-drop oscillation has the period of tens of seconds and the system pressure also highly oscillates with the period of flow instability. In comparison, the density-wave oscillation has the period of few seconds and the system pressure is relatively stable. Previous studies on flow instability are focused on the single channel flow and helical tube type heat exchanger. There has been very limited experimental research on flow instability using PCHE. In KAIST, the test facility was constructed to study the thermal hydraulics in PCHE. The objectives of our test facility are: (1) to identify the occurrence of instability under two phase and super-heated steam flow in PCHE, and (2) to examine whether it can operate normally using throttling effect. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Potential Integration Between Residual Biogenic Process Resources and Greener Hydrogen Production from Steam Reformers

Biomass conversion processes have varying efficiencies towards specific products like liquid fuels; process inefficiencies result in byproducts such as off-gases, heat, and solid residues such as char. The efficient use of these byproducts is key towards getting the maximum sustainability benefits from valuable biomass resources. For example, there are various utility product options that can utilize heat and off-gases from biomass pyrolysis processes; they include process heat and steam, hydrogen, fuel gas, and electricity. Further, there is potential for the use of the off-gases to supplement natural gas feed into steam reformers for hydrogen production. This presentation highlights results from previous analyses on tradeoffs based on utility byproduct choices (https://doi.org/10.1039/D3SE00745F); maximizing hydrogen production from off-gases is one potential winning strategy. This leads to the question regarding the utilization of these off-gases in existing steam reformers and the process impacts from feeding off-gases. Process modeling of a steam reformer system (https://doi.org/10.1002/adsu.20230021) quantifies those impacts and shows how much off-gas substitution is possible within the limits of an existing design with such an integration strategy.

biogenic gases↗

Improving Steam System Performance: A Sourcebook for Industry, Second Edition

This sourcebook is designed to provide steam system users with a reference that describes the basic steam system components, outlines opportunities for energy and performance improvements, and discusses the benefits of a systems approach in identifying and implementing these improvement opportunities. The sourcebook is divided into three main sections: steam system basics, performance improvement opportunities, and where to find help.

steam, steam system, steam system performance, AMO↗

Characterizing and improving the performance of molten-salt-steam heat exchangers in concentrating solar power plants

Shell-and-tube heat exchangers (HXs) for steam generation from molten salts in concentrating solar power (CSP) plants experience thermal fatigue due to significant temperature gradients and inherent transient operation. Molten salt-steam HX design lifespans exceed actual lifespans, and, as a consequence, designers overpredict plant profitability and operators neglect appropriate prescriptions to optimize these lifetimes. Here, this study refines HX lifespan estimates with data benchmarked against thermal-fluid mechanical modeling of stress and accumulated fatigue. Reduced-order thermal models of the molten salt-steam, shell-and-tube evaporator and superheater predict transient temperature profiles along the two HXs salt-steam flow paths. The modeled evaporator and superheater temperature profiles enable assessment of cyclic stresses within the HX tubesheets, where molten-salt HX failures are most common. Evaporator and superheater performance data from a current 110 MW elec commercial CSP plant provide a basis for validating the reduced-order HX models. HX life predictions derived from stochastic failure distributions serve as inputs for simulating and optimizing existing plant operations. The impact of the updated lifespans on overall plant revenue depends on operating scenarios. This study suggests that typical ramping rates for a CSP plant with a high-temperature Rankine cycle result in an evaporator and superheater life of approximately 10 and 25 years, respectively, compared to the design target of 30 years. Reduced HX lifespans decrease operational plant revenue on average by 4.6-5.1%. Furthermore, there may be as many as four HX replacements over the 30-year lifetime of the plant; and, purchase agreement loss due to failure to meet contractual production requirements can have ramifications that include the risk of bankruptcy.

14 SOLAR ENERGY↗

Fracture behavior of a melt-infiltration-processed SiC/Si composite at 900°C in argon, air, and steam

The fracture behavior of a melt-infiltration-processed SiC/Si composite, used to mimic the matrices of industrial fiber-reinforced ceramic composites, was examined in different atmospheres and temperatures. Specimens tested in four-point bending at 900 °C in oxygen-gettered argon, dry air, or steam-rich atmospheres exhibited higher average fracture strengths than specimens tested at 25°C. Higher mean fracture strength values were obtained for specimens tested in dry air or in a steam-rich atmosphere at 900°C than for specimens tested in high-purity, oxygen-gettered argon at this temperature. The increased fracture strengths obtained in air and in steam-rich atmospheres coincided with increased specimen oxidation and apparent oxide filling and blunting of flaws in these composites. Further, a transition in the location of catastrophic failure, from sites of preexisting damage created by Vickers indentations for tests in argon to other locations for tests in air or steam-rich atmospheres, was also consistent with such apparent oxide filling/blunting of indentation-induced flaws.

36 MATERIALS SCIENCE↗

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture

We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst-capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst-capture agents on (1) the syngas composition, (2) CO 2 and H 2 S capture, and (3) the steam-coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO-CaCO 3 chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO 3 was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO-CaCO 3 cycles. The increased steam-coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2-4% per CaO-CaCO 3 cycle. We also discuss an important application of this combined gasifier-calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO 4 and ash in the precalcined feedstock.

01 COAL, LIGNITE, AND PEAT↗

Contactless steam generation and superheating under one sun illumination

Steam generation using solar energy provides the basis for many sustainable desalination, sanitization, and process heating technologies. Recently, interest has arisen for low-cost floating structures that absorb solar radiation and transfer energy to water via thermal conduction, driving evaporation. However, contact between water and the structure leads to fouling and pins the vapour temperature near the boiling point. Here we demonstrate solar-driven evaporation using a structure not in contact with water. The structure absorbs solar radiation and re-radiates infrared photons, which are directly absorbed by the water within a sub-100 μm penetration depth. Due to the physical separation from the water, fouling is entirely avoided. Due to the thermal separation, the structure is no longer pinned at the boiling point, and is used to superheat the generated steam. We generate steam with temperatures up to 133 °C, demonstrating superheated steam in a non-pressurized system under one sun illumination.

14 SOLAR ENERGY↗