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NASA NTRS2015

Martian Chlorobenzene Identified by Curiosity in Yellowknife Bay: Evidence for the Preservation of Organics in a Mudstone on Mars

The Sample Analysis at Mars (SAM) instrument on the Curiosity rover is designed to determine the inventory of organic and inorganic volatiles thermally evolved from solid samples using a combination of evolved gas analysis (EGA), gas chromatography mass spectrometry (GCMS), and tunable laser spectroscopy. The first sample analyzed by SAM at the Rocknest (RN) aeolian deposit revealed chlorohydrocarbons derived primarily from reactions between a martian oxychlorine phase (e.g. perchlorate) and terrestrial carbon from N-methyl-N-(tert-butyldimethylsilyl) trifluoroacetamide (MTBSTFA) vapor present in the SAM instrument background. No conclusive evidence for martian chlorohydrocarbons in the RN sand was found. After RN, Curiosity traveled to Yellowknife Bay and drilled two holes separated by 2.75 m designated John Klein (JK) and Cumberland (CB). Analyses of JK and CB by both SAM and the CheMin x-ray diffraction instrument revealed a mudstone (called Sheepbed) consisting of approx.20 wt% smectite clays, which on Earth are known to aid the concentration and preservation of organic matter. Last year at LPSC we reported elevated abundances of chlorobenzene (CBZ) and a more diverse suite of chlorinated hydrocarbons including dichloroalkanes in CB compared to RN, suggesting that martian or meteoritic organic compounds may be preserved in the mudstone. Here we present SAM data from additional analyses of the CB sample and of Confidence Hills (CH), another drill sample collected at the base of Mt. Sharp. This new SAM data along with supporting laboratory analog experiments indicate that most of the chlorobenzene detected in CB is derived from martian organic matter preserved in the mudstone.

Glavin, D.↗

NASA NTRS2015

Martian Chlorobenzene Identified by Curiosity in Yellowknife Bay: Evidence for the Preservation of Organics in a Mudstone on Mars

Curiosity in Yellowknife↗

NASA NTRS2014

Analytical Techniques for Retrieval of Atmospheric Composition with the Quadrupole Mass Spectrometer of the Sample Analysis at Mars Instrument Suite on Mars Science Laboratory

The Sample Analysis at Mars (SAM) instrument suite is the largest scientific payload on the Mars Science Laboratory (MSL) Curiosity rover, which landed in Mars׳ Gale Crater in August 2012. As a miniature geochemical laboratory, SAM is well-equipped to address multiple aspects of MSL׳s primary science goal, characterizing the potential past or present habitability of Gale Crater. Atmospheric measurements support this goal through compositional investigations relevant to martian climate evolution. SAM instruments include a quadrupole mass spectrometer, a tunable laser spectrometer, and a gas chromatograph that are used to analyze martian atmospheric gases as well as volatiles released by pyrolysis of solid surface materials (Mahaffy et al., 2012). This report presents analytical methods for retrieving the chemical and isotopic composition of Mars׳ atmosphere from measurements obtained with SAM׳s quadrupole mass spectrometer. It provides empirical calibration constants for computing volume mixing ratios of the most abundant atmospheric species and analytical functions to correct for instrument artifacts and to characterize measurement uncertainties. Finally, we discuss differences in volume mixing ratios of the martian atmosphere as determined by SAM (Mahaffy et al., 2013) and Viking (Owen et al., 1977, Oyama and Berdahl, 1977) from an analytical perspective. Although the focus of this paper is atmospheric observations, much of the material concerning corrections for instrumental effects also applies to reduction of data acquired with SAM from analysis of solid samples.

quadropole mass spectometer↗

NASA NTRSDate not supplied

Investigation of the Glen Torridon Clay-Bearing Unit and Overlying Greenheugh Pediment by the Sample Analysis at Mars Instrument Suite

Exploring the Glen Torridon (GT) clay-bearing unit in Gale crater has long been a prime goal for the Mars Science Laboratory (MSL) because of spectral signatures of smectite identified from orbit. Smectite clay minerals can indicate habitable environments [1,2] and possibly facilitate the preservation of organic compounds [e.g., 3-7].Also, sulfate-bearing layers overlie GT and this sequence may record a large-scale change in aqueous conditions overtime [8].The Sample Analysis at Mars (SAM) instrument suitehas been essential in understanding volatile-bearing phases in Gale crater materials. SAM EGA has detected H2O, CO2, O2, H2, SO2, H2S, HCl, NO, and other trace gases, including organic fragments, evolved from many samples on heating. The identity and evolution temperature of evolved gases can support mineral detection by CheMin instrument X-ray diffraction (XRD)and place constraints on trace volatile-bearing phases, clay mineral compositions, and X-ray amorphous materials. In GT, SAM analyzed the sample Kilmarie (KM) from the Jura member, Glen Etive (GE), Mary Anning (MA) and Groken (GR)from the Knockfarril Hill member (KHm), Glasgow (GG) and Hutton (HU) from the fractured Intermediate Unit (fIU), and Edinburgh (EB) from the Stimson formation rocks of the Greenheugh Pediment (GP). The Jura, KHm and fIU are all members of the Murray formation. HU was sampled near the basal Siccar Point group (SPg) unconformity between the fIU and GP, in an area that exhibits a brighter tone and differences in geochemistry compared to Murray materials down-section [9,10]. CheMin XRD of most samples (except for HU and EB)showed large abundances of smectite clay minerals (~25-35%) and all samples showed X-ray amorphous materials and relatively low amounts of well-crystalline hematite[11]. SAM evaluated mineralogy through evolved gas analysis mass spectrometry (EGA) while detailed organic chemistry of several samples was examined by pyrolysis gas chromatography mass spectrometry and wet chemistry experiments [12,13].Here we discuss data and interpretations from SAM EGA analyses.

Mars↗

NASA NTRS1985

Transport processes as manifested in satellite and lidar aerosol measurements

A large increase in stratospheric aerosol data has become available recently from the SAM II and SAGE satellite sensors and the impetus from increased volcanic perturbations. Six years of SAM II and nearly 3 years of SAGE measurements have been accumulated. The increase in large volcanic eruptions since 1979 has caused an acceleration of new data sets from worldwide lidars and airborne lidar campaigns and from various airborne in situ measurements. The SAM II and SAGE data sets show the tropical stratosphere as a source for background stratospheric aerosols, and midlatitudes as a possible sink. Analyses of SAM II data show that the aerosol within the northern wintertime polar vortex becomes isolated from the outside. Subsidence occurs within the vortex, changing the vertical aerosol distribution over the winter period. SAM II and SAGE data show that the aerosol is transported in the stratosphere from low to high latitudes in wintertime. Entry regions of tropospheric air in the Tropics are also evident in the SAGE data as shown by stratospheric cirrus clouds being formed well above the local tropopause. Nature has provided over the past 5 years a number of large volcanic eruptions which spewed tons of new aerosol into the stratosphere. These eruptions have occurred at various latitudes which allow transport differences to be studied. Satellite and lidar aerosol data will be used to describe the stratospheric motions of aerosols produced after these violet volcanic eruptions.

Mccormick, M. P.↗

NASA NTRS1992

Microgravity acceleration measurement and environment characterization science (17-IML-1)

The Space Acceleration Measurement System (SAMS) is a general purpose instrumentation system designed to measure the accelerations onboard the Shuttle Orbiter and Shuttle/Spacelab vehicles. These measurements are used to support microgravity experiments and investigation into the microgravity environment of the vehicle. Acceleration measurements can be made at locations remote from the SAMS main instrumentation unit by the use of up to three remote triaxial sensor heads. The prime objective for SAMS on the International Microgravity Lab (IML-1) mission will be to measure the accelerations experienced by the Fluid Experiment System (FES). The SAMS acceleration measurements for FES will be complemented by low level, low frequency acceleration measurements made by the Orbital Acceleration Research Experiment (OARE) installed on the shuttle. Secondary objectives for SAMS will be to measure accelerations at several specific locations to enable the acceleration transfer function of the Spacelab module to be analyzed. This analysis effort will be in conjunction with similar measurements analyses on other Spacelab missions.

Source record↗

NASA NTRS1991

Control of a small working robot on a large flexible manipulator for suppressing vibrations

The short term objective of this research is the completion of experimental configuration of the Small Articulated Robot (SAM) and the derivations of the actuator dynamics of the Robotic Arm, Large and Flexible (RALF). In order to control vibrations SAM should have larger bandwidth than that of the vibrations. The bandwidth of SAM consist of 3 parts; structural rigidity, processing speed of controller, and motor speed. The structural rigidity was increased to a reasonably high value by attaching aluminum angles at weak points and replacing thin side plates by thicker ones. The high processing speed of the controller was achieved by using parallel processors (three 68000 process, three interface board, and one main processor (IBM-XT)). Maximum joint speed and acceleration of SAM is known as about 4 rad/s and 15 rad/sq s. Hence SAM can move only .04 rad at 3 Hz which is the natural frequency of RALF. This will be checked by experiment.

Lee, Soo Han↗

NASA NTRS1994

Distribution and nature of UV absorbers on Triton's surface

Substantial evidence suggests that a UV Spectrally Absorbing Material (UV-SAM) exists on Triton's surface. This evidence is found in the positive slope in Triton's spectrum from the UV to the near-IR, and the increasing contrast in Triton's light curve in the blue and UV. Although it is now widely-thought that UV-SAM's exist on Triton, little is known about their distribution and spectral properties. The goal of this NDAP Project is to determine the spatial distribution and geological context of the UV-SAM material. We hope to determine if UV-SAM's on Triton are correlated with geologic wind streaks, craters, calderas, geomorphic/topographic units, regions containing (or lacking) volatile frosts, or some other process (e.g., magnetospheric interactions). Once the location and distribution of UV-SAM's has been determined, further constraints on their composition can be made by analyzing the spectrographic data set. To accomplish these goals, various data sets will be used, including Voyager 2 UV and visible images of Triton's surface, IUE and HST spectra of Triton, and a geologic map of the surface based on Voyager 2 and spectrophotometric data. The results of this research will be published in the planetary science literature.

Stern, S. Alan↗

NASA NTRS1995

Distribution and nature of UV absorbers on Trition's surface

Substantial evidence suggests that a UV (ultraviolet) Spectrally Absorbing Material (UV-SAM) exists on Triton's surface. This evidence is found in the positive slope in Triton's spectrum from the UV to the near-IR, and the increasing contrast in Triton's light curve in the blue and UV. Although it is now widely-thought that UV-SAM's exist on Triton, little is known about their distribution and spectral properties. The goal of this NDAP Project is to determine the spatial distribution and geological context of the UV-SAM material. We hope to determine if UV-SAM's on Triton are correlated with geologic wind streaks, craters, calderas, geomorphic/topographic units, regions containing (or lacking) volatile frosts, or some other process (e.g., magnetospheric interactions). Once the location and distribution of UV-SAM's has been determined, further constraints on their composition can be made by analyzing the spectrographic data set. To accomplish these goals, various data sets will be used, including Voyager 2 UV and visible images of Triton's surface, IUE and HST spectra of Triton, and a geologic map of the surface based on Voyager 2 and spectrophotometric data. The results of this research will be published in the planetary science literature.

Stern, S. Alan↗

NASA NTRS1995

Distribution and nature of UV absorbers on Triton's surface

Substantial evidence suggests that a UV spectrally Absorbing Material (UV-SAM) exists on Triton's surface. This evidence is found in the positive slope in Triton's spectrum from the UV to the near-IR, and the increasing contrast in Triton's light curve in the blue and UV. Although it is now widely-thought that UV-SAMs exist on Triton, little is known about their distribution and spectral properties. The goal of this NDAP Project is to determine the spatial distribution and geological context of the UV-SaM material. We hope to determine if UV-SAMs on Triton are correlated with geologic wind streaks, craters, calderas, geomorphic/topographic units, regions containing (or lacking) volatile frosts, or some other process (e.g., magnetospheric interactions). Once the location and distribution of UV-SAMs has been determined, further constraints on their composition cable made by analyzing the spectrographic data set. To accomplish these goals, various data sets will be used, including Voyager 2 UV and visible images of Triton's surface, IUE and HST spectra of Triton, and a geologic map of the surface based on voyager 2 and spectrophotometric data. The results of this research will be published in the planetary science literature.

Stern, S. Alan↗

NASA NTRS1998

Internal Dynamics and Boundary Forcing Characteristics Associated with Interannual Variability of the Asian Summer Monsoon

In this paper, we present a description of the internal dynamics and boundary forcing characteristics of two major components of the Asian summer monsoon (ASM), i.e., the South Asian (SAM) and the Southeast-East Asian monsoon (SEAM). The description is based on a new monsoon-climate paradigm in which the variability of ASM is considered as the outcome of the interplay of a "fast" and an "intermediate" monsoon subsystem, under the influenced of the "slow" varying external forcings. Two sets of regional monsoon indices derived from dynamically consistent rainfall and wind data are used in this study. For SAM, the internal dynamics is represented by that of a "classical" monsoon system where the anomalous circulation is governed by Rossby-wave dynamics, i.e., generation of anomalous vorticity induced by an off-equatorial heat source is balanced by planetary vorticity advection. On the other hand, the internal dynamics of SEAM is characterized by a "hybrid" monsoon system featuring multi-cellular meridional circulation over the East Asian section, extending from the deep tropics to midlatitudes. These meridional-cells link tropical heating to extratropical circulation system via the East Asian jetstream, and are responsible for the characteristic occurrences of zonally oriented anomalous rainfall patterns over East Asian and the subtropical western Pacific. In the extratropical regions, the major upper level vorticity balance is by anomalous vorticity advection and generation by the anomalous divergent circulation. A consequence of this is that compared to SAM, the SEAM is associated with stronger teleconnection patterns to regions outside the ASM. A strong SAM is linked to basin-scale sea surface temperature (SST) fluctuation with significant signal in the equatorial eastern Pacific. During the boreal spring SST warming in the Arabian Sea and the subtropical western Pacific may lead to a strong SAM. For SEAM, interannual variability is tied to SSTA over the Sea of Japan and the South China Sea regions, while the linkage to equatorial basin-scale SSTA is weak at best. A large scale SSTA dipole with warming (cooling) in the subtropical central (eastern) Pacific foreshadows a strong SEAM.

Lau, K.- M.↗

NASA NTRS1998

Principal Investigator Microgravity Services: USMP-3

Two accelerometers provided acceleration data during the STS-75 mission in support of the third United States Microgravity Payload (USMP-3) experiments. The Orbital Acceleration Research Experiment (OARE) and the Space Acceleration Measurement System (SAMS) provided a measure of the microgravity environment of the Space Shuttle Columbia. The OARE provided investigators with quasi-steady acceleration measurements after about a six hour time lag dictated by downlink constraints. SAMS data were downlinked in near-real-time and recorded on-board for post-mission analysis. These two accelerometer systems are briefly described. Using a combination of data analysis techniques, the microgravity environment related to several different Orbiter, crew, and experiment operations is presented and interpreted. The microgravity environment represented by SAMS and OARE data is comparable to the environments measured by these instruments on earlier microgravity science missions. Thruster activity on this mission seen in the SAMS data appear to be more frequent than on other microgravity missions with the combined firings of the F5L and F5R jets producing significant acceleration transients. Of the events studied, the crew activities performed in the middeck and flight deck, SPREE table rotations, a waste collection system compaction, and a fuel cell purge had negligible effects on the microgravity environment of the USMP-3 carriers. The Ku band antenna repositioning activity resulted in a brief interruption of the ubiquitous 17 Hz signal in the SAMS data. In addition, the auxiliary power unit operations during the Flight Control System checkout appeared to have a significant impact on the microgravity environment.

Rogers, Melissa J. B.↗

NASA NTRS1999

Summary Report of Mission Acceleration Measurements for STS-89: Launched January 22, 1998

Support of microgravity research on the 89th flight of the Space Transportation System (STS-89) and a continued effort to characterize the acceleration environment of the Space Shuttle Orbiter and the Mir Space Station form the basis for this report. For the STS-89 mission, the Space Shuttle Endeavour was equipped with a Space Acceleration Measurement System (SAMS) unit, which collected more than a week's worth of data. During docked operations with Mir, a second SAMS unit collected approximately a day's worth of data yielding the only set of acceleration measurements recorded simultaneously on the two spacecraft. Based on the data acquired by these SAMS units, this report serves to characterize a number of acceleration events and quantify their impact on the local nature of the accelerations experienced at the Mechanics of Granular Materials (MGM) experiment location. Crew activity was shown to nearly double the median root-mean-square (RMS) acceleration level calculated below 10 Hz, while the Enhanced Orbiter Refrigerator/Freezer operating at about 22 Hz was a strong acceleration source in the vicinity of the MGM location. The MGM science requirement that the acceleration not exceed q I mg was violated numerous times during their experiment runs; however, no correlation with sample instability has been found to this point. Synchronization between the SAMS data from Endeavour and from Mir was shown to be close much of the time, but caution with respect to exact timing should be exercised when comparing these data. When orbiting as a separate vehicle prior to docking, Endeavour had prominent structural modes above 3 Hz, while Mir exhibited a cluster of modes around 1 Hz. When mated, a transition to common modes was apparent in the two SAMS data sets. This report is not a comprehensive analysis of the acceleration data, so those interested in further details should contact the Principal Investigator Microgravity Services team at the National Aeronautics and Space Administration's John H. Glenn Research Center.

Hrovat, Kenneth↗

NASA NTRS2000

Summary Report of Mission Acceleration Measurements for STS-95: Launched October 19, 1998

John H. Glenn's historic return to space was a primary focus of the STS-95 mission. The Hubble Space Telescope (HST) orbital Systems Test (HOST), an STS-95 payload, was an in-flight demonstration of HST components to be installed during the next HST servicing mission. One of the components under evaluation was the cryocooler for the Near Infrared Camera and Multi-Object Spectrometer (NICMOS). Based on concerns about vibrations from the operation of the NICMOS cryocooler affecting the overall HST line-of-sight requirements, the Space Acceleration Measurement System for Free-Flyers (SAMS-FF) was employed to measure the vibratory environment of the STS-95 mission, including any effects introduced by the NICMOS cryocooler. The STS-95 mission represents the first STS mission supported by SAMS-FF. Utilizing a Control and Data Acquisition Unit (CDU) and two triaxial sensor heads (TSH) mounted on the HOST support structure in Discovery's cargo bay, the SAMS-FF and the HOST project were able to make vibratory measurements both on-board the vibration-isolated NICMOS cryocooler and off-board the cryocooler mounting plate. By comparing the SAMS-FF measured vibrations on-board and off-board the NICMOS cryocooler, HST engineers could assess the cryocooler g-jitter effects on the HST line-of-sight requirements. The acceleration records from both SAMS-FF accelerometers were analyzed and significant features of the microgravity environment are detailed in this report.

McPherson, Kevin↗

NASA NTRS2011

Calibration of the Quadrupole Mass Spectrometer of the Sample Analysis at Mars Instrument Suite

The SAM suite of instruments on the "Curiosity" Rover of the Mars Science Laboratory (MSL) is designed to provide chemical and isotopic analysis of organic and inorganic volatiles for both atmospheric and solid samples. The mission of the MSL investigations is to advance beyond the successful search for aqueous transformation in surface environments at Mars toward a quantitative assessment of habitability and preservation through a series of chemical and geological measurements. The SAM suite was delivered in December 2010 (Figure 1) to the Jet Propulsion Laboratory for integration into the Curiosity Rover. We previously outlined the range of SAM solid and gas calibrations implemented or planned and here we discuss a specific set of calibration experiments to establish the response of the SAM Quadrupole Mass Spectrometer (QMS) to the four most abundant gases in the Martian atmosphere CO2, N2, Ar, and O2, A full SAM instrument description and calibration report is presently in preparation.

Mahaffy, P. R.↗

NASA NTRS1999

Summary Report of Mission Acceleration Measurements for STS-89

Support of microgravity research on the 89th flight of the Space Transportation System (STS-89) and a continued effort to characterize the acceleration environment of the Space Shuttle Orbiter and the Mir Space Station form the basis for this report. For the STS-89 mission, the Space Shuttle Endeavour was equipped with a Space Acceleration Measurement System (SAMS) unit, which collected more than a week's worth of data. During docked operations with Mir, a second SAMS unit collected approximately a day's worth of data yielding the only set of acceleration measurements recorded simultaneously on the two spacecraft. Based on the data acquired by these SAMS units, this report serves to characterize a number of acceleration events and quantify their impact on the local nature of the accelerations experienced at the Mechanics of Granular Materials (MGM) experiment location. Crew activity was shown to nearly double the median root-mean-square (RMS) acceleration level calculated below 10 Hz, while the Enhanced Orbiter Refrigerator/Freezer operating at about 22 Hz was a strong acceleration source in the vicinity of the MGM location. The MGM science requirement that the acceleration not exceed plus or minus 1 mg was violated numerous times during their experiment runs; however, no correlation with sample instability has been found to this point. Synchronization between the SAMS data from Endeavour and from Mir was shown to be close much of the time, but caution with respect to exact timing should be exercised when comparing these data. When orbiting as a separate vehicle prior to docking, Endeavour had prominent structural modes above 3 Hz, while Mir exhibited a cluster of modes around 1 Hz. When mated, a transition to common modes was apparent in the two SAMS data sets. This report is not a comprehensive analysis of the acceleration data, so those interested in further details should contact the Principal Investigator Microgravity Services team at the National Aeronautics and Space Administration's John H. Glenn Research Center.

Hrovat, Kenneth↗

NASA NTRS2000

Summary Report of Mission Acceleration Measurements for STS-95

John H. Glenn's historic return to space was a primary focus of the STS-95 mission. The Hubble Space Telescope (HST) Orbital Systems Test (HOST). an STS-95 payload, was an in-flight demonstration of HST components to be installed during the next HST servicing mission. One of the components under evaluation was the cryocooler for the Near Infrared Camera and Multi-Object Spectrometer (NICMOS). Based on concerns about vibrations from the operation of the NICMOS cryocooler affecting the overall HST line-of-sight requirements, the Space Acceleration Measurement System for Free-Flyers (SAMS-FF) was employed to measure the vibratory environment of the STS-95 mission, including any effects introduced by the NICMOS cryocooler. The STS-95 mission represents the first STS mission supported by SAMS-FF. Utilizing a Control and Data Acquisition Unit (CDU) and two triaxial sensor heads (TSH) mounted on the HOST support structure in Discovery's cargo bay, the SAMS-FF and the HOST project were able to make vibratory measurements both on-board the vibration-isolated NICMOS cryocooler and off-board the cryocooler mounting plate. By comparing the SAMS-FF measured vibrations on-board and off-board the NICMOS cryocooler, HST engineers could assess the cryocooler g-jitter effects on the HST line-of-sight requirements. The acceleration records from both SAMS-FF accelerometers were analyzed and significant features of the microgravity environment are detailed in this report.

McPherson, Kevin↗

NASA NTRS2012

The Role of (Delta)C-13 in the Search for Reduced Organics on the Surface of Mars

The capabilities of the Sample Analysis at Mars (SAM) instrument suite on the Mars Science Laboratory (MSL) to detect trace amounts of organic carbon compounds are unprecedented, and MSL may be the first mission to reveal the presence of organic carbon on Mars. The search for reduced organic carbon on Mars is inextricably tied to: a) the preservation potential of the environment from which we take a solid sample, and b) the evolved gas analysis (EGA) techniques used by SAM to release volatiles from this solid sample. Several prospective targets have been identified for sample analysis at Gale Crater. Stratigraphic sequences of phyllosilicates and sulfates at Gale are thought to represent a period of global climate transition from a moderate pH lacustrine environment to an evaporitic environment, both of which could sequester organic carbon (Thomson et al. 2011). The sediment mound in Gale Crater contains a range of lithologies suggesting changes in redox conditions, and evidence of both lacustrine and fluvial depositional processes, which may have transported organic carbon from the layer in which it formed and resulted in its preservation elsewhere within the crater (Anderson and Bell, 2010). Inverted channel fills suggest erosion resistant material that could serve to preserve organics originally deposited in a low energy aqueous environment. The lithology sampled will affect not only the preservation of organics, but also our ability to detect organics during our evolved gas analysis, based on the sample matrix. For example, reduced organics may be trapped in the mineral structure, and thermal evolution of these organics will occur during thermal decomposition of the host mineral. If organics are occluded in minerals that have very high thermal decomposition temperatures, they may be, in effect, "too well preserved," and difficult to detect during EGA. Alternatively, the possible presence of perchlorate, or other strong oxidants in surface regolith, may result in destruction of structural information identifying organic molecules before reaching the QMS on SAM via oxidation to C02 during heating. If this is the case, the stable carbon isotopic composition (delta 13C) of the C02 evolved and measured by the Tunable Laser Spectrometer (TLS) on SAM may help identify the presence of organics. On Earth, biological activity can cause large fractionations of 13C/12C, which can preserved in sedimentary deposits and distinguish the organic products of biotic processes from inorganic atmospheric and geological reservoirs. It is plausible that similar fractionations could occur on Mars and be preserved in reduced organic matter in sediments. Bulk delta 13C measurements alone may not reveal a signature of trace organic carbon that may be present along with inorganic carbon. If both organic and inorganic carbon compounds are present, it may be possible to detect the organic carbon by comparing the 013C of pyrolysis and combustion experiments. The TLS on SAM is capable of obtaining high precision measurements of delta13C from C02 evolved during pyrolysis and combustion of solid regolith samples. Because carbonates are expected to be present at abundances of 0.1-1 % in Martian soil, and organics in the ppb range (Webster and Mahaffy, 2011), analog samples must represent this mix of reduced organic carbon and carbonate. The work presented here will examine the use of delta13C of C02 produced during combustion of bulk Mars analog samples as a proxy for detection of reduced organic carbon.

Stern, J. C.↗