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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

New circumstellar dust component in oxygen rich environments

Spectra of oxygen rich stars in the IRAS low-resolution spectra (LRS) catalog were found to display two distinct classes of curcumstellar excess emission. The first group has the normal silicate with emission peaking at 10 and 18 microns. The second group has an emission spectrum peaking at 13 and 20 microns. There are also spectra with a mixture of the above types. Generally the continuum temperature associated with the second group is much warmer than that associated with the normal silicate group. Laboratory spectra are compared with the new excess which associates the emission with a class of materials represented by hydrated aluminates and silicates. Possible interpretations include equilibrium condensation sequences and peculiar metal abundance ratios.

Goebel, John H.↗
DOE OSTI2026

Unraveling Defect-Dependent Conductivity-Type Switching in CuFe 2 O 4 for Enhanced Photoelectrocatalytic Reduction of Benzaldehyde

Photoelectrocatalytic (PEC) reduction provides a sustainable route for upgrading biomass-derived feedstocks with reduced energy requirements, yet remains largely unexplored beyond hydrogen evolution and CO 2 reduction due to the scarcity of stable photocathodes. Here, we report a defect-engineered CuFe 2 O 4 photocathode that enables directly quantified PEC reduction of benzaldehyde to benzyl alcohol using a singlecomponent, earth-abundant oxide. By controlling annealing temperature and oxygen partial pressure, CuFe 2 O 4 is systematically tuned from n-type to p-type conductivity. Electrochemical measurements, X-ray and ultraviolet photoelectron spectroscopy, and firstprinciples defect calculations collectively show that oxygen-rich annealing conditions suppress deep donor-type oxygen vacancies while stabilizing shallow acceptor-type copper vacancies, resulting in enhanced hole concentration and improved charge transport. In a mixed acetonitrile/water electrolyte employing 1,4-benzoquinone as a redox mediator, the optimized CuFe 2 O 4 photocathode achieves stable photoelectrochemical operation over 18 h under continuous illumination with a benzyl alcohol production rate of 2.57 μmol/h at −0.50 V vs Ag/AgNO 3 , corresponding to a Faradaic efficiency of 51.3%. This PEC approach lowers the required applied potential by ∼1 V compared to traditional electrocatalytic methods, offering a more energy-efficient route for carbonyl reduction. These findings establish CuFe 2 O 4 as a viable photocathode platform for sustainable photoelectrocatalytic organic transformations under mild reaction conditions.

benzaldehyde reduction↗
NASA NTRS1986

Mass, heat and freshwater fluxes in the South Indian Ocean

Six hydrographic sections were used to examine the circulation and property fluxes in the South Indian Ocean from 10 to 32 deg S. The calculations were made by applying an inverse method to the data. In the interior of the South Indian Ocean, the geostrophic flow is generally northward. At 18 deg S, the northward interior mass flux is balanced by the southward Ekman mass flux at the surface, whereas at 32 deg S the northward interior mass flux is balanced by the southward mass flux of the Agulhas Current. There is a weak, southward mass flux of 6 x 10 to the 9th kg/s in the Mozambique Channel. The rate of water exchange between the Pacific Ocean and the Indian Ocean is dependent on the choice of the initial reference level used in the inverse calculation. The choice of 1500 m, the depth of the deep oxygen minimum, has led to a flux of water from the Pacific Ocean to the Indian Ocean at a rate of 6.6 x 10 to the 9th kg/s. Heat flux calculations indicate that the Indian Ocean is exporting heat to the rest of the world's oceans at a rate of -0.69 x 10 to the 15th W at 18 deg S and -0.25 x 10 to the 15th W at 32 deg S (negative values being southward).

Fu, Lee-Lueng↗
DOE OSTI2022

Spatial Microbial Respiration Variations in the Hyporheic Zones Within the Columbia River Basin

Abstract While the hyporheic zone (HZ) accounts for a significant portion of whole stream CO 2 concentrations, HZ respiration modeling studies are lacking in quantifying their contributions to the total CO 2 at large watershed/basin scales. Quantifying the contribution of anaerobic respiration is also underappreciated. This study used a carbon‐nitrogen‐coupled river corridor model to quantify HZ aerobic and anaerobic respiration and determined the key factors controlling their spatial variability within the Columbia River Basin (CRB). The modeled respiration patterns showed high spatial variability. Among the nine sub‐basins composing the CRB, the Lower Columbia and the Willamette, which receive higher precipitation, had higher respiration. Medium‐sized rivers (fourth to sixth orders) produced the highest aerobic and anaerobic respiration among reaches of different sizes. At the basin scale, aerobic respiration is dominant, representing approximately 98.7% of the total respiration across the CRB. While most of the reaches were dominant with aerobic respiration, reaches in agricultural land showed a relatively higher anaerobic respiration (18%) ratio. A variable importance analysis showed that hyporheic exchange flux controlled most of the spatial variability of HZ respiration, dominating over other physical variables such as residence time, stream dissolved organic carbon (DOC), nitrate, and dissolved oxygen (DO). The influence of substrate concentration (DOC and DO) is larger in modeling anaerobic respiration than aerobic respiration. Future efforts will focus on improving the estimation of the HZ exchange flux and the implementation of spatially explicit parameterizations for the reactions of interest to reduce model uncertainty.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1979

16-39 micron spectroscopy of oxygen-rich stars

Airborne observations of the 16-39-micron spectra of 10 oxygen-rich stars with excess emission in the infrared have been obtained. The stars show excess emission attributed to circumstellar dust grains in the 16-39-micron region in the form of a broad hump peaking near 18 microns and falling smoothly to longer wavelengths. The emission is similar in character to the emission from the Trapezium region of the Orion Nebula, indicating the grain materials are quite similar in these objects. The existence of a feature in the 20-micron region is consistent with the O-Si-O bending resonance expected for silicate material. The lack of any sharp structure in the spectra indicates the silicate is in an amorphous, disordered form. A simple model of small grains of carbonaceous chondrite silicate material in a diffuse circumstellar envelope is shown to give a good qualitative fit to the observed 8-39-micron circumstellar spectra. Comparison of the observed spectra with the model spectra indicates the grain emissivity falls as the inverse square of wavelength from 20 to 40 microns.

Forrest, W. J.↗
NASA NTRS1991

Relative abundances in the low-metallicity dwarf irregular galaxy UGC 4483

UGC 4483 is a dwarf irregular galaxy in the M 81 group. Narrow-band optical imaging has revealed an H II region in UGC 4483 with an H-alpha flux of about 2 x 10 to the -13th erg/sq cm per A per s. Optical, UV and NIR spectroscopy of this H II region yield He, C, N, O, Ne, and S abundances for the ISM in this galaxy. With an oxygen abundance of 0.000021 12 + log(O/H) = 7.3, this galaxy is among the most metal-poor dwarf irregulars known to date. A comparison of the S/O abundance ratio in this galaxy with that in I Zw 18 supports the claim by Garnett (1990) that the S/O ratio is consistent with the solar ratio for low-metallicity dwarf irregulars. The C/O ratio in UGC 4483 is lower than that derived for I Zw 18 and, therefore, more in line with the trend seen in higher metallicity H II regions. The derived helium abundance is He/H = 0.075, which converts to a He mass fraction of 0.23, consistent with earlier determinations of the primordial He abundance.

Skillman, Evan D.↗
NASA NTRS2003

Determining Possible Building Blocks of the Earth

Introduction: One of the fundamental questions concerning the formation of the Earth is what is it made out of. The Earth appears to have condensed out of material from the solar nebula. We sample this "primitive" material in the form of chondritic meteorites. One of the most important constraints on possible building blocks for the Earth is the Earth#s oxygen iso-topic composition. Rocks from the Earth and Moon plot along a line (the terrestrial fractionation line) in diagrams of delta(sup 17)O (% relative to Standard Mean Ocean Water or SMOW) versus delta(sup 18)O (% relative to SMOW). Chondritic meteorites fall above and below this line. Distances from this line are given as Delta(sup 17)O (%) (= delta(sup 17)O - 0.52 x delta(sup 18)O).

Burbine, T. H.↗
NASA NTRS2015

Identification of Highly Fractionated (18)O-Rich Silicate Grains in the Queen Alexandra Range 99177 CR3 Chondrite

Carbonaceous chondrites contain a mixture of solar system condensates, presolar grains, and primitive organic matter. The CR3 chondrite QUE 99177 has undergone minimal al-teration [1], exemplified by abundant presolar silicates [2, 3] and anomalous organic matter [4]. Oxygen isotopic imaging studies of this meteorite have focused on finding submicrometer anomalous grains in fine-grained regions of thin sections. Here we present re-sults of an O isotopic survey of larger matrix grains.

Nguyen, A. N.↗
DOE OSTI2023

Neonatal respiratory support strategies—short and long-term respiratory outcomes

Mechanical ventilation (MV), although life-saving, is associated with chronic respiratory morbidity in both preterm and term born infants. New ventilation modes have been developed with the aim of minimising lung injury. These include invasive and non-invasive respiratory support strategies, techniques for less invasive surfactant administration (LISA) and closed-loop automated oxygen control (CLAC) systems. Increasingly, newborn infants with signs of respiratory distress are stabilised on continuous positive airway pressure (CPAP) and receive LISA. Early CPAP when compared to mechanical ventilation reduced the incidence of BPD and respiratory morbidity at 18 to 22 months corrected age. Nasal intermittent positive pressure ventilation reduced treatment failure rates compared to CPAP, but not bronchopulmonary dysplasia (BPD). LISA compared with intubation and surfactant delivery reduced BPD, but there is no evidence from randomised trials regarding long-term respiratory and neurodevelopmental outcomes. Synchronisation of positive pressure inflations with the infant's respiratory efforts used with volume targeting should be applied for infants requiring intubation as this strategy reduces BPD. A large RCT with long term follow up data demonstrated that prophylactic high frequency oscillatory ventilation (HFOV) improved respiratory and functional outcomes at school age, but those effects were not maintained after puberty. CLAC systems appear promising, but their effect on long term clinical outcomes has not yet been explored in randomised trials. Further studies are required to determine the role of newer ventilation modes such as neurally adjusted ventilator assist (NAVA). All such respiratory support strategies should be tested in randomised controlled trials powered to assess long-term outcomes.

Kaltsogianni, Ourania↗
NASA NTRS1994

Growth studies of erbium-doped GaAs deposited by metalorganic vapor phase epitaxy using noval cyclopentadienyl-based erbium sources

Erbium-doped GaAS layers were grown by metalorganic vapor phase epitaxy using two new sources, bis(i-propylcyclopentadienyl)cyclopentadienyl erbium and tris(t-butylcyclopentadienyl) erbium. Controlled Er doping in the range of 10(exp 17) - 10(exp 18)/cu cm was achieved using a relatively low source temperature of 90 C. The doping exhibits a second-order dependence on inlet source partial pressure, similar to behavior obtained with cyclopentadienyl Mg dopant sources. Equivalent amounts of oxygen and Er are present in 'as-grown' films indicating that the majority of Er dopants probably exist as Er-O complexes in the material. Er(+3) luminescence at 1.54 micrometers was measured from the as-grown films, but ion implantation of additional oxygen decreases the emission intensity. Electrical compensation of n-type GaAs layers codoped with Er and Si is directly correlated to the Er concentration is proposed to arise from the deep centers associated with Er which are responsible for a broad emission band near 0.90 micrometers present in the photoluminescence spectra of GaAs:Si, Er films.

Redwing, J. M.↗
NASA NTRS1993

Inter- and intra-crystalline oxygen isotope distribution of fassaites in Allende CAI

Calcium, aluminum-rich inclusions (CAI's) from carbonaceous chondrite are believed to be among the first solids to have formed in the early solar system and thus to preserve a record of conditions and processes that prevailed early in the solar nebula. We have measured inter- and intra- crystalline oxygen isotope distribution of fassaite in Type B1 CAI of Allende meteorite. Secondary ion mass spectrometry (SIMS) using negative Au primary ion was applied to in situ oxygen isotope ratio analysis on a polished thin section of the CAI. Present data indicate that O isotope composition is homogeneous inside of fassaite grains as well as among grains in the HN3-1 CAI, and that the delta(exp 18) O value (-24.14 percent relative to SMOW) determined previously could be applied to most fassaite grains. The results suggest that most fassaite grains are preexisting solids like spinel grains.

Yurimoto, Hisayoshi↗
NASA NTRS2010

Comparative Spectra of Oxygen-Rich Versus Carbon-Rich Circumstellar Shells: VY Canis Majoris and IRC(plus)10216 at 215-285 GHz

A sensitive (1sigma rms at 1 MHz resolution approx.3 mK) 1 mm spectral line survey (214.5-285.5 GHz) of VY Canis Majoris (VY CMa) and IRC +10216 has been conducted to compare the chemistries of oxygen- and carbon-rich circumstellar envelopes. This study was carried out using the Submillimeter Telescope of the Arizona Radio Observatory with a new Atacama Large Millimeter Array type receiver. This survey is the first to chemically characterize an O-rich circumstellar shell at millimeter wavelengths. In VY CMa, 128 emission features were detected arising from 18 different molecules; and in IRC +10216, 720 lines were observed, assigned to 32 different species. The 1 mm spectrum of VY CMa is dominated by SO, and SiS; in IRC +10216, C4H and SiC2 are the most recurrent species. Ten molecules were common to both sources: CO, SiS, SiO, CS, CN, HCN, HNC, NaCl, PN, and HCO(+). Sulfur plays an important role in VY CMa, but saturated/ unsaturated carbon dominates the molecular content of IRC +102.16, producing CH2NH, for example. Although the molecular complexity of IRC +10216 is greater, VY CMa supports a unique "inorganic" chemistry leading to the oxides PO, AlO, and AlOH. Only diatomic and triatomic compounds were observed in VY CMa, while species with four or more atoms are common in IRC +10216, reflecting carbon's ability to form multiple strong bonds, unlike oxygen. In VY CMa, a new water maser (v2 = 2) has been found, as well as vibrationally excited NaCl. Toward IRC +10216, vibrationally excited CCH was detected for the first time.

Tenebaum, E. D.↗
NASA NTRS2008

Oxygen Isotope Systematics of Chondrules from the Least Equilibrated H Chondrite

Oxygen isotope compositions of bulk chondrules and their mineral separates in type 3 ordinary chondrites (UOC) show several % variability in the oxygen three isotope diagram with slope of approx.0.7 [1]. In contrast, ion microprobe analyses of olivine and pyroxene phenocrysts in ferromagnesian chondrules from LL 3.0-3.1 chondrites show mass dependent isotopic fractionation as large as 5% among type I (FeO-poor) chondrules, while type II (FeO-rich) chondrules show a narrow range (less than or equal to 1%) of compositions [2]. The .Delta(exp 17)O (=delta(exp 17)O-0.52xdelta(exp 18)O) values of olivine and pyroxene in these chondrules show a peak at approx.0.7% that are systematically lower than those of bulk chondrule analyses as well as the bulk LL chondrites [2]. Further analyses of glass in Semarkona chondrules show .17O values as high as +5% with highly fractionated d18O (max +18%), implying O-16-poor glass in chondrules were altered as a result of hydration in the parent body at low temperature [3]. Thus, chondrules in LL3.0-3.1 chondrites do not provide any direct evidence of oxygen isotope exchange between solid precursor and O-16-depleted gas during chondrule melting events. To compare the difference and/or similarity between chondrules from LL and H chondrites, we initiated systematic investigations of oxygen isotopes in chondrules from Yamato 793408 (H3.2), one of the least equilibrated H chondrite [4]. In our preliminary study of 4 chondrules, we reported distinct oxygen isotope ratios from dusty olivine and refractory forsterite (RF) grains compared to their host chondrules and confirmed their relict origins [5].

Kita, N. T.↗
DOE OSTI2025

A high-resolution record of Late Holocene drought in the eastern Sierra Nevada (California, USA) from June Lake carbonate geochemistry

As historic drought conditions become more common in western North America, Late Quaternary hydroclimate records become vital for putting present anthropogenic conditions into a longer-term context. Here, we establish a high-resolution record of drought for the eastern Sierra Nevada (California) using lacustrine carbonates from well-dated sediment cores. We used oxygen and carbon stable-isotope ratios, combined with high-resolution scanning X-ray fluorescence counts of calcium (Ca) and titanium (Ti), to reconstruct the drought record over the last 4600 years in June Lake. We found elevated δ 18 O and δ 13 C carbonate isotope values coinciding with peaks in both total inorganic carbon and Ca/Ti, suggesting enhanced carbonate precipitation in response to evaporative concentration of lake water. At least six intervals of prolonged (centennial-scale) carbonate deposition were identified, including three pulses during the Late Holocene Dry Period (LHDP; ~3500–2000 cal yr BP), the Medieval Climate Anomaly (~1200–800 cal yr BP), and the Current Warm Period, which began around 100 cal yr BP. This record highlights the complexities of the LHDP, an interval that was more variable at June Lake than has been previously described in regional records.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Tetrahedral Zn 2+ doping LiNi 0.6 Mn 0.2 Co 0.2 O 2 improves discharge capacity retention by altering surface Ni valence during cycling and preventing oxygen evolution

5 mol-% Zn 2+ was added to the co-precipitation synthesis of LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) to understand Zn's effect on the structural and electronic properties of NMC622. Zn is determined to successfully dope into the NMC crystal lattice as there is an increase in d-spacing along the [003], [104], and [110] directions and an increase in molar volume (100.75 cm 3 mol -1 for NMC622 and 101.00 cm 3 mol -1 for Zn-NMC). Through XPS, Zn is determined to dope on the tetrahedral 6c Wyckoff site in the NMC structure and TEM-EDS reveals that despite a slight ZnO impurity phase, 1.4 mol-% Zn successfully dopes into the crystal structure. Furthermore, cyclic voltammetry shows a suppressed anodic wave associated with oxygen evolution and EIS demonstrates that Zn-doped NMC decreases charge transfer resistance and increases Li diffusion by an order of magnitude. After the formation cycles, NMC has a higher 1 C accessible capacity, 141 mAh/g, over Zn-NMC (132 mAh/g), but after long term cycling Zn-NMC has a higher accessible capacity (117 mAh/g compared to 96 mAh/g for NMC) and increases discharge capacity retention by 18% leading to longer cycle life.

Electrochemistry↗
DOE OSTI2024

Simulated plant-mediated oxygen input has strong impacts on fine-scale porewater biogeochemistry and weak impacts on integrated methane fluxes in coastal wetlands

Methane (CH 4 ) emissions from wetland ecosystems are controlled by redox conditions in the soil, which are currently underrepresented in Earth system models. Plant-mediated radial oxygen loss (ROL) can increase soil O 2 availability, affect local redox conditions, and cause heterogeneous distribution of redox-sensitive chemical species at the root scale, which would affect CH 4 emissions integrated over larger scales. In this study, we used a subsurface geochemical simulator (PFLOTRAN) to quantify the effects of incorporating either spatially homogeneous ROL or more complex heterogeneous ROL on model predictions of porewater solute concentration depth profiles (dissolved organic carbon, methane, sulfate, sulfide) and column integrated CH 4 fluxes for a tidal coastal wetland. From the heterogeneous ROL simulation, we obtained 18% higher column averaged CH 4 concentration at the rooting zone but 5% lower total CH 4 flux compared to simulations of the homogeneous ROL or without ROL. This difference is because lower CH 4 concentrations occurred in the same rhizosphere volume that was directly connected with plant-mediated transport of CH 4 from the rooting zone to the atmosphere. Sensitivity analysis indicated that the impacts of heterogeneous ROL on model predictions of porewater oxygen and sulfide concentrations will be more important under conditions of higher ROL fluxes or more heterogeneous root distribution (lower root densities). Despite the small impact on predicted CH 4 emissions, the simulated ROL drastically reduced porewater concentrations of sulfide, an effective phytotoxin, indicating that incorporating ROL combined with sulfur cycling into ecosystem models could potentially improve predictions of plant productivity in coastal wetland ecosystems.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1976

Substorm generated fluxes of heavy ions at the geostationary orbit

Measurements of heavy energetic heavy ions present in the vicinity of the geostationary orbit of the ATS-6 satellite, taken with the aid of a solid-state detector telescope, are reported and analyzed. Data extracted from a single fairly isolated injection event (June 18, 1974) are examined: ions of Z not below 6 and energy above 4.0 MeV; energization of these heavy ions in the magnetosphere during substorm events; comparison of the heavy ion intensity and proton intensity; ratio of intensity of carbon ions and oxygen ions. The heavy ions are identified with oxygen for the most part. The heavy-ion spectrometer is described.

Fritz, T. A.↗
NASA NTRS1956

High-temperature oxidation and ignition of metals

A study of the high-temperature oxidation of several aircraft construction materials was undertaken to assess the possibility of ignition under high-temperature flight conditions.Tests have been made both in open and closed jets, and, in addition, the burning of metals has been observed under static conditions in a pressurized vessel containing either air, oxygen, or nitrogen. When heated in an atmosphere of oxygen or when heated and plunged into a supersonic airstream, titanium, iron, carbon steel, and common alloys such as 4130 were found to have spontaneous-ignition temperatures in the solid phase (below melting) and they melted rapidly while burning. Inconel, copper, 18-8 stainless steel, Monel, and aluminum could not be made to ignite spontaneously at temperatures up to melting with the equipment available. Magnesium ignited spontaneously in either type of test at temperatures just above the melting temperature.A theory for the spontaneous ignition of metals, based on the first law of thermodynamics, is presented. Good correlation was obtained between calculated spontaneous-ignition temperatures and values measured in supersonic jet tests. There appears at the present time to be no need for concern regarding the spontaneous ignition of Inconel, the stainless steels, copper, aluminum, or magnesium for ordinary supersonic airplane or missile applications where the material temperature is kept within ordinary structural limits or at least below melting. For hypersonic applications where the material is to be melted away to absorb the heat of convection, the results of the present tests do not apply sufficiently to allow a conclusion.

Hill, Paul R↗