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At least 217 records · Page 12
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Cogenetic Rock Fragments from a Lunar Soil: Evidence of a Ferroan Noritic-Anorthosite Pluton on the Moon

The impact that produced North Ray Crater, Apollo 16 landing site, exhumed rocks that include relatively mafic members of the lunar ferroan anorthositic suite. Bulk and mineral compositions indicate that a majority of 2-4 mm lithic fragments from sample 67513, including impact breccias and monomict igneous rocks, are related to a common noritic-anorthosite precursor. Compositions and geochemical trends of these lithic fragments and of related samples collected along the rim of North Ray Crater suggest that these rocks derived from a single igneous body. This body developed as an orthocumulate from a mixture of cumulus plagioclase and mafic intercumulus melt, after the plagioclase had separated from any cogenetic mafic minerals and had become concentrated into a crystal mush (approximately 70 wt% plagioclase, 30 wt% intercumulus melt). We present a model for the crystallization of the igneous system wherein "system" is defined as cumulus plagioclase and intercumulus melt. The initial accumulation of plagioclase is analogous to the formation of thick anorthosites of the terrestrial Stillwater Complex; however, a second stage of formation is indicated, involving migration of the cumulus-plagioclase-intercumulus-melt system to a higher crustal level, analogous to the emplacement of terrestrial massif anorthosites. Compositional variations of the lithic fragments from sample 67513 are consistent with dominantly equilibrium crystallization of intercumulus melt. The highly calcic nature of orthocumulus pyroxene and plagioclase suggests some reaction between the intercumulus melt and cumulus plagioclase, perhaps facilitated by some recrystallization of cumulus plagioclase. Bulk compositions and mineral assemblages of individual rock fragments also require that most of the mafic minerals fortned in close contact with cumulus plagioclase, not as separate layers. The distribution of compositions (and by inference, modes) has a narrow peak at anorthosite and a broader, larger peak at noritic anoilhosite. Characteristics of the samples and their geochemical trends imply an origin in a system that was large relative to the (unknown) size of the impact that produced the breccias of ferroan noritic-anorthosite composition that were excavated later by the formation of North Ray Crater, and they appear to be consistent with an origin of the suite within a perched plagioclase cumulate. If the Moon's crust formed by accumulation of plagioclase in a magma ocean, ferroan noritic anothosite, formed as an orthocumulate, is an alternative to extensive adcumulus formation of ferroan anorthosite (greater than 90 vol% plagiclase). This provides a relatively mafic ferroan anorthositic component (approximately 15 vol% mafics), which is required by mass-balance models of compositions of polymict lunar-crustal materials. The inferred bulk composition of the system of cumulus plagioclase and intercumulus melt is similar to that of ferroan regolith breccia MacAlpine Hills 88104/5, a lunar-highland meteorite, and may represent a common and widespread component of the Moon's early highland crust.

Jolliff, B. L.↗
NASA NTRS2000

Performance of Adsorption - Based CO2 Acquisition Hardware for Mars ISRU

Chemical processing of the dusty, low-pressure Martian atmosphere typically requires conditioning and compression of the gases as first steps. A temperature-swing adsorption process can perform these tasks using nearly solid-state hardware and with relatively low power consumption compared to alternative processes. In addition, the process can separate the atmospheric constituents, producing both pressurized CO2 and a buffer gas mixture of nitrogen and argon. To date we have developed and tested adsorption compressors at scales appropriate for the near-term robotic missions that will lead the way to ISRU-based human exploration missions. In this talk we describe the characteristics, testing, and performance of these devices. We also discuss scale-up issues associated with meeting the processing demands of sample return and human missions.

Finn, John E.↗
NASA NTRS2002

Status of the RBCC Direct-Connect Mixer Combustor Experiment

The NASA Glenn Research Center is developing hydrogen based combined cycle propulsion technology for a single-stage-to-orbit launch vehicle application under a project called GTX. Rocket Based Combined Cycle (RBCC) propulsion systems incorporate one or more rocket engines into an airbreathing flow path to increase specific impulse as compared to an all rocket-powered vehicle. In support of this effort, an RBCC direct-connect test capability was established at the Engine Components Research Laboratory to investigate low speed, ejector ramjet, and initial ramjet operations and performance. The facility and test article enables the evaluation of two candidate low speed operating schemes; the simultaneous mixing and combustion (SMC) and independent ramjet stream (IRS). The SMC operating scheme is based on the fuel rich operations of the rocket where performance depends upon mixing between the rocket plume and airstream. In contrast, the IRS scheme fuels the airstream separately and uses the rocket plume to ignite the fuel-air mixture. This paper describes the test hardware and facility upgrades installed to support the RBCC tests. It also defines and discusses low speed technical challenges being addressed by the experiments. Finally, preliminary test results, including rocket risk mitigating tests, unfueled airflow tests, and the integrated system hot fire test will be presented.

Walker, James F.↗
NASA NTRS2002

Status of the RBCC Direct-Connect Mixer Combustor Experiment

The NASA Glenn Research Center is developing hydrogen based combined cycle propulsion technology for a single-stage-to-orbit launch vehicle application under a project called GTX. Rocket Based Combined Cycle (RBCC) propulsion systems incorporate one or more rocket engines into an airbreathing flow path to increase specific impulse as compared to an all rocket-powered vehicle. In support of this effort, an RBCC direct-connect test capability was established at the Engine Components Research Laboratory to investigate low speed, ejector ramjet, and initial ramjet operations and performance. The facility and test article enables the evaluation of two candidate low speed operating schemes; the simultaneous mixing and combustion (SMC) and independent ramjet stream (IRS). The SMC operating scheme is based on the fuel rich operations of the rocket where performance depends upon mixing between the rocket plume and airstream. In contrast, the IRS scheme fuels the airstream separately and uses the rocket plume to ignite the fuel-air mixture. This paper describes the test hardware and facility upgrades installed to support the RBCC tests. It also defines and discusses low speed technical challenges being addressed by the experiments. Finally, preliminary test results, including rocket risk mitigating tests, unfueled airflow tests, and the integrated system hot fire test will be presented.

Walker, James F.↗
NASA NTRS1995

Simultaneous concentration and purification through gradient deformation chromatography

Mobile-phase additives, commonly used to modulate absorbate retention in gradient elution chromatography, are usually assumed to be either linearly retained or unretained. Previous theoretical work from our laboratory has shown that these modulators, such as salts in ion-exchange and hydrophobic interaction chromatography and organic modifiers in reversed-phase chromatography, can absorb nonlinearly, giving rise to gradient deformation. Consequently, adsorbate peaks that elute in the vicinity of the head of the deformed gradient may exhibit unusual shapes, form shoulders, and/or be concentrated. These effects for a reversed-phase sorbent with aqueous acetonitrile (ACN) as the modulator are verified experimentally. Gradient deformation is demonstrated experimentally and agrees with simulations based on ACN isotherm parameters that are independently determined from batch equilibrium studies using the layer model. Unusual absorbate peak shapes were found experimentally for single-component injections of phenylalanine, similar to those calculated by the simulations. A binary mixture of tryptophan and phenylalanine is used to demonstrate simultaneous concentration and separation, again in agreement with simulations. The possibility of gradient deformation in ion-exchange and hydrophobic interaction chromatography is discussed.

NASA Discipline Number 93-10↗
NASA NTRS2000

Separation of Carbon Monoxide and Carbon Dioxide for Mars ISRU-Concepts

Solid oxide electrolyzers, such as electrolysis cells utilizing yttria-stabilized zirconia, can produce oxygen from Mars atmospheric carbon dioxide and reject carbon monoxide and unreacted carbon dioxide in a separate stream. The oxygen-production process has been shown to be far more efficient if the high-pressure, unreacted carbon dioxide can be separated and recycled back into the feed stream. Additionally, the mass of the adsorption compressor can be reduced. Also, the carbon monoxide by-product is a valuable fuel for space exploration and habitation, with applications from fuel cells to production of hydrocarbons and plastics. In our research, we will design, construct, and test an innovative, robust, low mass, low power separation device that can recover carbon dioxide and carbon monoxide for Mars ISRU. Such fundamental process technology, involving gas-solid phase separation in a reduced gravitational environment, will help to enable Human Exploration and Development of Space. The separation device will be scaled to operate with a CO2 sorption compressor and a zirconia electrolysis device built at the NASA Ames Research Center and the University of Arizona, respectively. In our research, we will design, construct, and test an innovative, robust, low mass, low power separation device that can recover carbon dioxide and carbon monoxide for Mars ISRU, Such fundamental process technology, involving gas-solid phase separation in a reduced gravitational environment, will help to enable Human Exploration and Development of Space. The separation device will be scaled to operate with a CO2 sorption compressor and a zirconia electrolysis device built at the NASA Ames Research Center and the University of Arizona, The separation device will be scaled to operate with a CO2 sorption compressor and a zirconia electrolysis device built at the NASA Ames Research Center and the University of Arizona, Research needs for the design shown are as follows: (1) The best adsorbent for the process must be determined. (2) Adsorption isotherms must be measured, both for pure components and mixtures. (3) Mathematical modeling must be performed to provide a solid framework for design. (4) The separation system must be constructed and tested. (5) System integration must be studied.

LeVan, M. Douglas↗
NASA NTRS1970

Combining micro dry column chromatography and mass spectrometry

Dry column chromatography principles applied in microscale produce technique to minimize time in preparing and analyzing colorless constituents of soluble mixtures. Glass pipette microcolumns filled with finely sieved adsorbents permit capillary attraction and separation in 3 to 15 minutes. Technique is adaptable to gas chromatography.

Bauman, A. J.↗
NASA NTRS1986

Theoretical and experimental separation dynamics in capillary zone electrophoresis

The mathematical model of Bier et al. (1983) is used in a computer aided analysis of the conditions in capillary zone electrophoresis (ZE) under which sample zones migrate noninteractively with the carrier electrolyte. The monitoring of sample zones with a capillary analyzer that features both on-line conductivity and UV detection at the end of the separation trough is discussed. Data from a ZE analysis of a 5-component mixture are presented, and it is noted that all five components can be monitored via their conductivity change if enough sample is present. It is suggested from the results that the concentration ratio of background buffer to sample should be a minimum of 100:1 to effectively apply the plate concept to ZE.

Thormann, Wolfgang↗
NASA NTRS1994

Surfactant-based critical phenomena in microgravity

The objective of this research project is to characterize by experiment and theoretically both the kinetics of phase separation and the metastable structures produced during phase separation in a microgravity environment. The particular systems we are currently studying are mixtures of water, nonionic surfactants, and compressible supercritical fluids at temperatures and pressures where the coexisting liquid phases have equal densities (isopycnic phases). In this report, we describe experiments to locate equilibrium isopycnic phases and to determine the 'local' phase behavior and critical phenomena at nearby conditions of temperature, pressure, and composition. In addition, we report the results of preliminary small angle neutron scattering (SANS) experiments to characterize microstructures that exist in these mixtures at different fluid densities.

Kaler, Eric W.↗
NASA NTRS2020

Tensile Creep Behavior of SiC(f)/SiC Ceramic Matrix Minicomposites

Single fiber-tow minicomposites represent the major load-bearing element of woven and laminate ceramic matrix composites (CMCs). To understand the effects of fiber type, fiber content, and matrix cracking on tensile creep in SiCf/SiC CMCs, single-tow SiCf/SiC minicomposites with different fiber types and contents were investigated. The minicomposites studied contained either Hi-Nicalon™ or Hi-Nicalon™ Type S SiC fibers with a boron nitride (BN) interphase and a chemical-vapor-infiltrated-silicon-carbide (CVI-SiC) matrix. Tensile creep was performed at 1200 °C in air. A bottom-up creep modeling approach was applied where creep parameters of the fibers and matrix were obtained separately at 1200 °C. Next, a theoretical model based on the rule of mixtures was derived to model the fiber and matrix creep-time-dependent stress redistribution. Fiber and matrix creep parameters, load transfer model results, and numerical modeling were used to construct a creep strain model to predict creep damage evolution of minicomposites with different fiber types and contents.

SiC/SiC Minicomposites Creep↗
NASA NTRS2014

Kinematic Modeling of Separation Compression for Paired Approaches to Closely-Spaced Parallel Runways

In a simultaneous paired approach to closely-spaced parallel runways, a pair of aircraft flies in close proximity on parallel approach paths. The longitudinal separation between the aircraft must be maintained within a range that avoids wake encounters and, if one of the aircraft blunders, avoids collision. To increase operational availability, the approach procedure must accommodate a mixture of aircraft sizes and, consequently, approach speeds. In these procedures, the slower aircraft is placed in the lead position. The faster aircraft maintains separation from the slow aircraft in a dependent operation until final approach and flies independently afterward. Due to the higher approach speed of the fast aircraft, longitudinal separation will decrease during final approach. Therefore, the fast aircraft must position itself before the final approach so that it will remain within the safe range of separation as separation decreases. Given the approach geometry and speed schedule for each aircraft, one can use kinematics to estimate the separation loss between a pair of aircraft. A kinematic model can complement fast-time Monte-Carlo simulations of the approach by enabling a tailored reduction in the variation of starting position for the fast aircraft. One could also implement the kinematic model in ground-based or on-board decision support tools to compute the optimal initial separation for a given pair of aircraft. To better match the auto-coupled flight of real aircraft, the paper derives a kinematic model where the speed schedule is flown using equivalent airspeed. The predicted time of flight using the equivalent airspeed kinematic model compares well against a high-fidelity aircraft simulation performing the same approach. This model also demonstrates a modest increase in the predicted loss of separation when contrasted against a kinematic model that assumes the scheduled speed is true airspeed.

Madden, Michael M.↗
NASA NTRS2018

Solid State Ultracapacitor

An ink of the formula: 60-80% by weight BaTiO3 particles coated with SiO2; 5-50% by weight high dielectric constant glass; 0.1-5% by weight surfactant; 5-25% by weight solvent; and 5-25% weight organic vehicle. Also a method of manufacturing a capacitor comprising the steps of: heating particles of BaTiO3 for a special heating cycle, under a mixture of 70-96% by volume N2 and 4-30% by volume H2 gas; depositing a film of SiO2 over the particles; mechanically separating the particles; incorporating them into the above described ink formulation; depositing the ink on a substrate; and heating at 850-900 C for less than 5 minutes and allowing the ink and substrate to cool to ambient in N2 atmosphere. Also a dielectric made by: heating particles of BaTiO3 for a special heating cycle, under a mixture of 70-96% by volume N2 and 4-30% by volume H2 gas; depositing a film of SiO2 over the particles; mechanically separating the particles; forming them into a layer; and heating at 850-900 C for less than 5 minutes and allowing the layer to cool to ambient in N2 atmosphere.

Rolin, Terry D.↗
NASA NTRS2014

Optical Constants of Mars Candidate Materials used to Model Laboratory Reflectance Spectra of Mixtures

Data obtained at visible and nearinfrared wavelengths by OMEGA on MarsExpress and CRISM on MRO provide definitive evidence for the presence of phyllosilicates and other hydrated phases on Mars. A diverse range of both Fe/Mg-OH and Al- OH-bearing phyllosilicates were identified including the smectites nontronite, saponite, and montmorillonite. To constrain the abundances of these phyllosilicates, spectral analyses of mixtures are needed. We report on our effort to enable the quantitative evaluation of the abundance of hydrated-hydroxylated silicates when they are contained in mixtures. Here we focus on two component mixtures of the hydrated/ hydroxylated silicates, saponite and montmorillonite (Mg- and Al-rich smectites) with each other and with two analogs for other Martian materials; pyroxene (enstatite) and palagonitic soil (an alteration product of basaltic glass, hereafter referred to as palagonite). We prepared three size separates of each end-member for study: 20-45, 63-90, and 125-150 micron. Here we focus upon mixtures of the 63-90 m size fractions.

MarsExpress and CRISM↗
NASA NTRS1979

Formulated plastic separators for soluble electrode cells

The fabrication and milling of membranes comprising a hydrochloric acid-insoluble sheet of a mixture of a rubber and a powdered ion transport material are described. The sheet can be present as a coating upon a flexible and porous substrate. These membranes can be used in oxidation-reduction electrical accumulator cells wherein the reduction of one member of a couple is accompanied by the by the oxidation of the other member of the couple on the other side of the cell and this must be accompanied by a change in chloride ion concentration in both sides.

Sheibley, D. W.↗
NASA NTRS1979

High performance N2O4/amine elements blowapart

Hypergolic earth-storable N2O4/Amine propellants are used for a wide range of liquid propulsion system applications. These propellants are highly reactive and can experience reactive stream separation (RSS, i.e., blowapart) which can inhibit intraelement mixing, hence reducing the overall spray mixture ratio and mass distribution, which can result in altered combustion efficiency, gas-side heat transfer coefficient, and stability. An experimental and analytical program was conducted to develop an understanding of the mechanisms controlling RSS. The program and product was development of design criteria for coping with RSS to allow the design of high performing, stable injectors. RSS mechanisms were identified using high speed color photography to observe reactive stream mixing of single element injectors tested with N2O4/MMH, N2O4/A-50, and N2O4/N2H4 propellants. The parametric characterization included modeling of the Space Shuttle Orbital Maneuvering System and Reaction Control System engine injectors.

Source record↗
NASA NTRS1982

Method of making formulated plastic separators for soluble electrode cells

A method making a membrane comprised of a hydrochloric acid-insoluble sheet of a mixture of a rubber and a powdered ion transport material is disclosed. The sheet can be present as a coating upon a flexible and porous substrate. These membranes can be used in oxidation-reduction electrical accumulator cells wherein the reduction of one member of a couple is accompained by the oxidation of the other member of the couple on the other side of the cell and this must be accompained by a change in chloride ion concentration in both sides. The method comprises preparing a mixture of fine rubber particles, a solvent for the rubber and a powdered ion transport material. The mixture is formed into a sheet and dried to produce a microporous sheet. The ion transport material includes particles ranging from about 0.01 to 10 microns in size and comprises from 20 to 50 volume percent of the microporous sheet.

Sheibley, D. W.↗
NASA NTRS1987

Effects on H(-) production in a multicusp ion source by mixture of H2 with H2O, NH3, CH4, N2H4, and SF6

Effects of H(-) production in a multicusp ion source are measured by separately mixing with hydrogen small amounts (0.33-10 percent) of water, ammonia, methane, and hydrazine these are molecules which produce large amounts of H(-) via dissociative attachment (DA) resonances at higher electron energies. The mixing was done in a separate reservoir, with careful measurement of individual pressures. Experimental enhancements of 1.4 and less were observed, whereas calculated enhancements, using accurate DA cross sections for ground-state H2, should have produced factors of 1.5, 3.0, 1.3, and 2.4 enhancements for water, ammonia methane, and hydrazine, respectively, at a mean electron energy of 1.0 eV in the extraction region. The difference is accounted for by including, in the enhancement calculation, vibrationally and rotationally excited H2 molecules, with v-double prime = 5-11, and J-double prime = 0-5, and the large DA cross sections for the excited H2 (v-double prime, J-double prime). The relative populations of H2 (v-double prime, J-double prime) thus obtained are found to be substantially smaller than those predicted by theoretical calculations. The effect on H(-) current was also studied by mixing small amounts of SF6 with H2. A 1.5 percent mixture was found to reduce the H(-) output by one half.

Orient, O. J.↗
NASA NTRS1991

Casting Of Multilayer Ceramic Tapes

Procedure for casting thin, multilayer ceramic membranes, commonly called tapes, involves centrifugal casting at accelerations of 1,800 to 2,000 times normal gravitational acceleration. Layers of tape cast one at a time on top of any previous layer or layers. Each layer cast from slurry of ground ceramic suspended in mixture of solvents, binders, and other components. Used in capacitors, fuel cells, and electrolytic separation of oxygen from air.

Collins, Earl R., Jr.↗