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At least 217 records · Page 12

Modeled Aerosol Optical Properties From Measurement-Based Mixtures of Chemical Species: Assessing the Impacts of Particle Morphology and Absorption

This report serves as the final report for the Colorado State University portion of this grant. The original grant was awarded to CSU under the direction of co-Principal Investigators Kirk Fuller and Sonia Kreidenweis. Upon Dr. Fuller's relocation to the University of Alabama - Huntsville, the major portion of the award was also relocated. The following summarizes only that work completed by Prof. Kreidenweis under her remaining award.

Kreidenweis, Sonia↗

Freezable Radiator Model Correlation Improvements and Fluids Study

Freezable radiators offer an attractive solution to the issue of thermal control system scalability. As thermal environments change, a freezable radiator will effectively scale the total heat rejection it is capable of as a function of the thermal environment and flow rate through the radiator. Scalable thermal control systems are a critical technology for spacecraft that will endure missions with widely varying thermal requirements. These changing requirements are a result of the space craft s surroundings and because of different thermal rejection requirements during different mission phases. However, freezing and thawing (recovering) a radiator is a process that has historically proven very difficult to predict through modeling, resulting in highly inaccurate predictions of recovery time. To attempt to improve this, tests were conducted in 2009 to determine whether the behavior of a simple stagnating radiator could be predicted or emulated in a Thermal Desktop(trademark) numerical model. A 50-50 mixture of DowFrost HD and water was used as the working fluid. Efforts to scale this model to a full scale design, as well as efforts to characterize various thermal control fluids at low temperatures are also discussed. Previous testing and modeling efforts showed that freezable radiators could be operated as intended, and be fairly, if not perfectly predicted by numerical models. This paper documents the improvements made to the numerical model, and outcomes of fluid studies that were determined necessary to go forward with further radiator testing.

Lillibridge, Sean↗

Effects of soil tillage on the microwave emission of soils

In order to understand the interactions of soil properties and microwave emission better, a series of field experiments were conducted in 1984. Small plots were measured with a truck-mounted passive microwave radiometer operating at 1.4 GHz. These data were collected concurrent with ground observations of soil moisture and bulk density. Treatment effects studied included different soil moisture contents and bulk densities. Evaluations of the data have shown that commonly used models of the dielectric properties of wet soils do not explain the observations obtained in these experiments. This conclusion was based on the fact that the roughness parameters determined through optimization were significantly larger than those observed in similar investigations. These discrepancies are most likely due to the soil structure. Commonly used models assume a homogeneous three phase mixture of soil solids, air and water. Under tilled conditions the soil is actually a two phase mixture of aggregates and voids. Appropriate dielectric models for this tilled condition were evaluated and found to explain the observations. These results indicate that previous conclusions concerning the effects of surface roughness in tilled fields may be incorrect, and they may explain some of the inconsistencies encountered in roughness modeling.

Jackson, T. J.↗

Parameterization of Shortwave Cloud Optical Properties for a Mixture of Ice Particle Habits for use in Atmospheric Models

Based on the single-scattering optical properties pre-computed with an improved geometric optics method, the bulk absorption coefficient, single-scattering albedo, and asymmetry factor of ice particles have been parameterized as a function of the effective particle size of a mixture of ice habits, the ice water amount, and spectral band. The parameterization has been applied to computing fluxes for sample clouds with various particle size distributions and assumed mixtures of particle habits. It is found that flux calculations are not overly sensitive to the assumed particle habits if the definition of the effective particle size is consistent with the particle habits that the parameterization is based. Otherwise, the error in the flux calculations could reach a magnitude unacceptable for climate studies. Different from many previous studies, the parameterization requires only an effective particle size representing all ice habits in a cloud layer, but not the effective size of individual ice habits.

Chou, Ming-Dah↗

Thermodynamics of a solar mixture of molecular hydrogen and helium at high pressure

The thermodynamic properties of a model molecular hydrogen and helium mixture are calculated in the strongly interacting region of 0.005 to 0.3 per cu cm for a range of temperatures that are of interest for the envelopes of the Jovian planets. Computed adiabats fit the gravity data and boundary conditions from model atmospheres of Jupiter.

Slattery, W. L.↗

Acoustic velocities of two-phase mixtures of cryogenic fluids

Calculated values of the acoustic velocity are presented for single-component and two-component, two-phase mixtures. Three different analytic models were employed. For purposes of comparison, all three models were used in making acoustic-velocity calculations for single-component, equivalent bubbly two-phase mixtures (with insoluble gas) of oxygen and helium and hydrogen and helium. In all cases the results are shown graphically so that the effects of variation in quality or void fraction, temperature and pressure are illustrated.

Griggs, E. I.↗

The Safe Removal of Frozen Air from the Annulus of an LH2 Storage Tank

Large Liquid Hydrogen (LH2) storage tanks are vital infrastructure for NASA. Eventually, air may leak into the evacuated and perlite filled annular region of these tanks. Although the vacuum level is monitored in this region, the extremely cold temperature causes all but the helium and neon constituents of air to freeze. A small, often unnoticeable pressure rise is the result. As the leak persists, the quantity of frozen air increases, as does the thermal conductivity of the insulation system. Consequently, a notable increase in commodity boil-off is often the first indicator of an air leak. Severe damage can result from normal draining of the tank. The warming air will sublimate which will cause a pressure rise in the annulus. When the pressure increases above the triple point, the frozen air will begin to melt and migrate downward. Collection of liquid air on the carbon steel outer shell may chill it below its ductility range, resulting in fracture. In order to avoid a structural failure, as described above, a method for the safe removal of frozen air is needed. A thermal model of the storage tank has been created using SINDA/FLUINT modeling software. Experimental work is progressing in an attempt to characterize the thermal conductivity of a perlite/frozen nitrogen mixture. A statistical mechanics model is being developed in parallel for comparison to experimental work. The thermal model will be updated using the experimental/statistical mechanical data, and used to simulate potential removal scenarios. This paper will address methodologies and analysis techniques for evaluation of two proposed air removal methods.

cryogenic insulation↗

Theoretical Thermodynamics of Mixtures at High Pressures

The development of an understanding of the chemistry of mixtures of metallic hydrogen and abundant, higher-z material such as oxygen, carbon, etc., is important for understanding of fundamental processes of energy release, differentiation, and development of atmospheric abundances in the Jovian planets. It provides a significant theoretical base for the interpretation of atmospheric elemental abundances to be provided by atmospheric entry probes in coming years. Significant differences are found when non-perturbative approaches such as Thomas-Fermi-Dirac (TFD) theory are used. Mapping of the phase diagrams of such binary mixtures in the pressure range from approx. 10 Mbar to approx. 1000 Mbar, using results from three-dimensional TFD calculations is undertaken. Derivation of a general and flexible thermodynamic model for such binary mixtures in the relevant pressure range was facilitated by the following breakthrough: there exists an accurate nd fairly simple thermodynamic representation of a liquid two-component plasma (TCP) in which the Helmholtz free energy is represented as a suitable linear combination of terms dependent only on density and terms which depend only on the ion coupling parameter. It is found that the crystal energies of mixtures of H-He, H-C, and H-O can be satisfactorily reproduced by the same type of model, except that an effective, density-dependent ionic charge must be used in place of the actual total ionic charge.

Hubbard, W. B.↗

Using partially labeled data for normal mixture identification with application to class definition

The problem of estimating the parameters of a normal mixture density when, in addition to the unlabeled samples, sets of partially labeled samples are available is addressed. The density of the multidimensional feature space is modeled with a normal mixture. It is assumed that the set of components of the mixture can be partitioned into several classes and that training samples are available from each class. Since for any training sample the class of origin is known but the exact component of origin within the corresponding class is unknown, the training samples as considered to be partially labeled. The EM iterative equations are derived for estimating the parameters of the normal mixture in the presence of partially labeled samples. These equations can be used to combine the supervised and nonsupervised learning processes.

Shahshahani, Behzad M.↗

Microgravity two-phase fluid flow pattern modeling

When gas and liquid mixtures flow in a pipe, the distribution of the two phases may take many forms. A flow pattern, or flow regime, is the characteristic spatial distribution of the phases of flow in a pipe. Because heat transfer and pressure drop are dependent on the characteristic distribution of phases, it is necessary to describe flow patterns in an appropriate manner so that a hydrodynamic or heat transfer theory applicable to that can be chosen. A theoretical two phase flow regime transition map under a microgravity environment was developed on physical concepts. These transitions use four basic flow patterns: dispersed flow, slug flow, stratified flow, and annular flow. The forces considered are body force, surface tension force, inertial force, friction, and the force from eddy turbulent fluctuation. Three dimensionless parameters were developed. Because these transition boundaries were developed based on physical concepts, they should be applicable to flow regimes occurring in various design conditions. Because the flow pattern data from KC-135 experiments are insufficient to verify these theoretical transition lines completely, an adiabatic experiment for flow regime analysis is recommended.

Lee, Doojeong↗

Reactions of SiC with H2/H2O/Ar mixtures at 1300 C

Thermochemical modeling anticipates the existence of three reaction regions for the case of a sintered alpha-SiC with 5 percent H2/H2O/Ar at 1300 C, depending on the initial water vapor or, equivalently, oxygen, content of the gas stream. While a high oxygen content leads to SiC-protecting SiO2 surface film formation and limits consumption of the SiC through passive oxidation, intermediate oxygen contents lead to SiO and CO formation and rapid SiC consumption. In this intermediate region, reaction rates appear to be controlled by H2O gas-phase transport to the sample; reacted microstructures exhibit extensive grain-boundary attack in this region. Very low oxygen content is predicted to selectively remove carbon, with free silicon formation.

Jacobson, Nathan S.↗

Development of Detonation Modeling Capabilities for Rocket Test Facilities: Hydrogen-Oxygen-Nitrogen Mixtures

The objective of the presented work was to develop validated computational fluid dynamics (CFD) based methodologies for predicting propellant detonations and their associated blast environments. Applications of interest were scenarios relevant to rocket propulsion test and launch facilities. All model development was conducted within the framework of the Loci/CHEM CFD tool due to its reliability and robustness in predicting high-speed combusting flow-fields associated with rocket engines and plumes. During the course of the project, verification and validation studies were completed for hydrogen-fueled detonation phenomena such as shock-induced combustion, confined detonation waves, vapor cloud explosions, and deflagration-to-detonation transition (DDT) processes. The DDT validation cases included predicting flame acceleration mechanisms associated with turbulent flame-jets and flow-obstacles. Excellent comparison between test data and model predictions were observed. The proposed CFD methodology was then successfully applied to model a detonation event that occurred during liquid oxygen/gaseous hydrogen rocket diffuser testing at NASA Stennis Space Center.

Allgood, Daniel C.↗

Spectral Variability among Rocks in Visible and Near Infrared Multispectral Pancam Data Collected at Gusev Crater: Examinations using Spectral Mixture Analysis and Related Techniques

Visible and Near Infrared (VNIR) multispectral observations of rocks made by the Mars Exploration Rover Spirit s Panoramic camera (Pancam) have been analysed using a spectral mixture analysis (SMA) methodology. Scenes have been examined from the Gusev crater plains into the Columbia Hills. Most scenes on the plains and in the Columbia Hills could be modeled as three endmember mixtures of a bright material, rock, and shade. Scenes of rocks disturbed by the rover s Rock Abrasion Tool (RAT) required additional endmembers. In the Columbia Hills there were a number of scenes in which additional rock endmembers were required. The SMA methodology identified relatively dust-free areas on undisturbed rock surfaces, as well as spectrally unique areas on RAT abraded rocks. Spectral parameters from these areas were examined and six spectral classes were identified. These classes are named after a type rock or area and are: Adirondack, Lower West Spur, Clovis, Wishstone, Peace, and Watchtower. These classes are discriminable based, primarily, on near-infrared (NIR) spectral parameters. Clovis and Watchtower class rocks appear more oxidized than Wishstone class rocks and Adirondack basalts based on their having higher 535 nm band depths. Comparison of the spectral parameters of these Gusev crater rocks to parameters of glass-dominated basaltic tuffs indicates correspondence between measurements of Clovis and Watchtower classes, but divergence for the Wishstone class rocks which appear to have a higher fraction of crystalline ferrous iron bearing phases. Despite a high sulfur content, the rock Peace has NIR properties resembling plains basalts.

Farrand, W. H.↗

An empirical model for the complex dielectric permittivity of soils as a function of water content

The recent measurements on the dielectric properties of soils shows that the variation of dielectric constant with moisture content depends on soil types. The observed dielectric constant increases only slowly with moisture content up to a transition point. Beyond the transition it increases rapidly with moisture content. The moisture value of transition region was found to be higher for high clay content soils than for sandy soils. Many mixing formulas were compared with, and were found incompatible with, the measured dielectric variations of soil-water mixtures. A simple empirical model was proposed to describe the dielectric behavior of ths soil-water mixtures. The relationship between transition moisture and wilting point provides a means of estimating soil dielectric properties on the basis of texture information.

Wang, J. R.↗

Analytical and Numerical Modeling of Flame-Balls in Hydrogen-Air Mixtures

Flame-balls are stationary spherical premixed flames observed in certain near-limit mixtures. It is believed that radiative heat losses are an important stabilizing influence. Numerical solutions of flame balls are constructed for hydrogen-air mixtures using an accurate description of the chemical kinetics, diffusive transport, and radiation losses. A lean limit equivalence ratio of 0.0866 is predicted and a rich limit of 2,828. For any equivalence ratio between the two limits there are two solutions. One is characterized by a small flame, incomplete reactant consumption, and negligible radiation losses. The other by a large flame, complete consumption of one of the reactants, and significant radiation losses. The maximum temperature varies between 1200 and 900 K as the two solution branches are traversed. Much of our discussion is a reprise and modification of previously published analytical results, for these provide physical insight into the nature of the solutions, and suggest that a portion of the large flame branch near the lean limit is stable and so corresponds to observable flames.

Buckmaster, J.↗

A Computational Study of Plume Modeling for Space Launch System Abort Scenarios

A series of viscous CFD simulations depicting Space Launch System (SLS) post Mode-1abort scenarios are conducted and analyzed. The primary purpose of these simulations is to study the effect of launch abort vehicle attitude control motor (ACM) and abort motor(AM) plume modeling fidelity on the drag of the aborted core stage. The simulations are first conducted with a fully-coupled, multi-species and chemically reacting model for the freestream gases and the solid rocket abort motor combustion products. Following this, equivalent species are created for the ACM and AM exhaust gases. These equivalent species aim to provide near the same results for core stage drag as the chemically reacting model at a significantly lower computational cost. Finally, the exhaust gases are modeled as calorically perfect air. It was concluded that under most scenarios, both the equivalent species and the perfect air models predict the drag of the aborted core stage sufficiently close to that predicted by the chemically reacting simulations. In these cases, the flow and geometry conditions did not induce significant changes in the composition of the ‘true’ exhaust gas via afterburning of the combustion products. For cases where this was not the case, the properties of the essentially frozen equivalent species and perfect air models deviated from the true mixture, yielding unsatisfactory results. Finally, the accuracy improvements by using the chemically reacting model are weighed against the significant increase in associated computational costs. It was found that the simplified exhaust gas models are at least 4 times less expensive than the chemically reacting model. This may justify the judicious use of these simple models in future work.

CFD↗

A Computational Study of Plume Modeling for Space Launch System Abort Scenarios

A series of viscous CFD simulations depicting Space Launch System (SLS) post Mode-1abort scenarios are conducted and analyzed. The primary purpose of these simulations is to study the effect of launch abort vehicle attitude control motor (ACM) and abort motor(AM) plume modeling fidelity on the drag of the aborted core stage. The simulations are first conducted with a fully-coupled, multi-species and chemically reacting model for the freestream gases and the solid rocket abort motor combustion products. Following this, equivalent species are created for the ACM and AM exhaust gases. These equivalent species aim to provide near the same results for core stage drag as the chemically reacting model at a significantly lower computational cost. Finally, the exhaust gases are modeled as calorically perfect air. It was concluded that under most scenarios, both the equivalent species and the perfect air models predict the drag of the aborted core stage sufficiently close to that predicted by the chemically reacting simulations. In these cases, the flow and geometry conditions did not induce significant changes in the composition of the ‘true’ exhaust gas via afterburning of the combustion products. For cases where this was not the case, the properties of the essentially frozen equivalent species and perfect air models deviated from the true mixture, yielding unsatisfactory results. Finally, the accuracy improvements by using the chemically reacting model are weighed against the significant increase in associated computational costs. It was found that the simplified exhaust gas models are at least 4 times less expensive than the chemically reacting model. This may justify the judicious use of these simple models in future work.

CFD↗